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1 ct to the spontaneous addition of GSH to the oxirane.
2 vinyl-substituted oxiranes, or hydroxymethyl oxiranes.
3 idation to yield a series of A2E epoxides or oxiranes.
4 w insights into the Lewis acid activation of oxiranes.
5 via regioselective ring-opening reactions of oxirane 12 and cyclic sulfamidate 22 with lithium dialky
7 tB(+/+) mice with L-3-trans-(propylcarbamoyl)oxirane-2-carbonyl-L-isoleucyl-L-proline (CA-074 Me) als
8 hether an ethyl-2-[6-(4-chlorophenoxy)hexyl]-oxirane-2-carboxylate (etomoxir)-induced inhibition of f
10 se mechanism for these enzymes, (R)- and (S)-oxirane-2-carboxylate were investigated as potential irr
11 rreversible inactivation of cis-CaaD by ( R)-oxirane-2-carboxylate with two important distinctions: t
15 NP-poly(A) molecule at one end covalently to oxirane acrylic beads, an affinity column was prepared f
17 ion of SB-3CT is 1.6 kcal/mol lower than its oxirane analogue, and the ring-opening reaction energy o
20 gioselective epoxide ring-opening of alkynyl oxiranes and a stereoselective aza-Cope-Mannich reaction
21 lent oxygen and nitrogen in the formation of oxiranes and aziridines; however, such reactivity is not
22 Cu(I) catalyst and a pyridine oxide, alkynyl oxiranes and oxetanes can be converted into functionaliz
27 This permits the use of readily available oxiranes as alternatives to aldehydes that are difficult
29 ides or related quaternary carbon-containing oxiranes can be troublesome and difficult to achieve.
31 the POC-isomer leads to the formation of an oxirane derivative with an unexpectedly high stereoselec
32 en developed that effectively utilize chiral oxiranes derived from Katsuki-Sharpless epoxidation of a
33 followed by stereocontrolled, regioreversed oxirane formation and reductive transposition of this in
35 derived from the hydroxyl group of HPP, this oxirane formation reaction is effectively a dehydrogenat
36 an was developed by employing donor-acceptor oxiranes in a new reaction with gamma-hydroxyenones.
37 ve alpha-oxazolidinonylallenylstannanes with oxiranes in the presence of BF3.OEt2 produced beta-hydro
38 onal study of the rearrangement reactions of oxiranes initiated by lithium dialkylamides is presented
39 lving rate-limiting formation of a transient oxirane intermediate that opens in water to give alpha-d
41 Finally, we showed that the formation of A2E oxiranes is strongly suppressed by treating the abcr(-/-
42 ide the intrinsic anti tendency of the vinyl oxirane moiety and forces the cuprate to undergo syn add
43 et pathway consists of a dissociation of the oxirane moiety to give a triplet carbene and aldehyde, w
45 are within hydrogen bonding distance to the oxirane or phosphonate oxygens of fosfomycin resulted in
47 five atoms inclusively, the combinations of oxirane, oxetane, and tetrahydrofuran are rather extensi
48 The relative rates of attack of ammonia on oxirane, oxetane, thiirane, and thietane were determined
51 ylative 1,5-substitution of conjugated enyne oxiranes provides a diastereoselective route to (E)-conf
52 uggested as the exclusive mechanism by which oxiranes react in the presence of organolithium bases.
56 d radical-stabilizing groups adjacent to the oxirane ring for the deoxygenation reaction to occur.
57 hed by treatment of mCPBA, and the resulting oxirane ring in resin 9 was opened with various nucleoph
59 zes the addition of glutathione (GSH) to the oxirane ring of the antibiotic, rendering it inactive.
60 N-methylamine with subsequent intramolecular oxirane ring opening and (b) a carbene insertion reactio
63 olyl azido alcohols from terminal alkyne via oxirane ring-opening of epichlorohydrin, followed by cli
65 hodology, developed by Miyashita, allowed an oxirane-ring-opening reaction with a double inversion of
68 favorable for the alkoxide obtained from the oxirane than for the thiolate obtained from the thiirane
69 attack of an active site carboxylate on the oxirane to give an ester intermediate followed by hydrol
70 al Lewis-acid-catalyzed rearrangement of the oxirane to the corresponding aldehyde via an alkyl, aryl
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