ライフサイエンスコーパス: oxone

1 peracetic acid, m-chloroperbenzoic acid, and OXONE.

2 on with use of more ketone catalyst and less Oxone.

3 d in situ from a fructose-derived ketone and Oxone.

4 cleavage of an osmate ester by the action of oxone.

5 ,6-tetramethyl-2-iodobenzoic acid (TetMe-IA)/oxone.

6 functionality to the corresponding acid with oxone.

7 mol 1)(-1) hr(-1) and K(M) = 53 +/- 5 mM for oxone ([1] = 7.5 microM), and V(max) = 6.5 +/- 0.3 mol O

8 to catalyze the epoxidation of alkenes using Oxone (2KHSO(5)+KHSO(4)+K(2)SO(4)), and significant leve

9 acid and arenes by a one-pot procedure using Oxone (2KHSO5.KHSO4.K2SO4) as an inexpensive and environ

10 oxyarylacrylic acids has been developed with Oxone (2KHSO5.KHSO4.K2SO4); the oxidation reaction invol

11 keto esters and 1,3-diketones mediated by an Oxone/aluminum trichloride system.

12 dependent on the relative concentrations of oxone and 1.

13 The use of Oxone and a palladium(II) catalyst enables the efficient

14 -linking in the presence of oxidants such as oxone and monoperoxyphthalic acid (MMPP).

15 metallic alternative to ozonolysis utilizing oxone and OsO(4) is presented.

16 trimethylsilyl enol ethers is possible using Oxone as a stoichiometric oxidant and sodium hydrogen ph

17 m hydrogen sulfate from 2-iodobiphenyl using Oxone as an inexpensive and environmentally safe oxidant

18 using 1-iodo-4-nitrobenzene as catalyst and oxone as an inexpensive and environmentally safe termina

19 angement of carboxamides to carbamates using Oxone as an oxidant can be efficiently catalyzed by iodo

20 ination of tetrabutylammonium iodide (TBAI), Oxone as non-nucleophilic and easy to handle co-oxidant,

21 ble glucose-derived ketone 2 as catalyst and Oxone as oxidant to form cis-propargyl epoxides in high

22 zolidinone-containing ketone as catalyst and Oxone as oxidant via a sequential asymmetric epoxidation

23 tose-derived chiral ketone 1 as catalyst and Oxone as oxidant.

24 peptides using potassium peroxymonosulfate (oxone) as an oxidant.

25 d, and tested in heterogeneous activation of Oxone for phenol degradation in aqueous solution.

26 ve catalysts for asymmetric epoxidation with Oxone has been evaluated.

27 azole compounds using commercially available oxone improves the energetic properties and reveals a st

28 catalytic amount (10 mol %) of TetMe-IA and oxone in acetonitrile-water mixture (1:1, v/v) at rt.

29 lenes, phenanthrenes, anthracenes, etc. with Oxone in an acetonitrile-water mixture (1:1, v/v) at rt.

30 ted in situ from catalytic amount of PhI and Oxone in the presence of 1,1,1,3,3,3-hexafluoroisopropan

31 he corresponding perfluoroalkyl iodides with Oxone in trifluoroacetic acid at room temperature and su

32 The operational parameters, such as MnO2 and Oxone loading, phenol concentration and temperature, wer

33 h could then competitively react with either oxone or water/hydroxide to produce O(2).

34 (2) evolution from either KHSO(5) (potassium oxone) or NaOCl.

35 ly oxidized to the corresponding oxides 2 by OXONE over silica gel or alumina, as well as by (CH(3))(

36 OXONE over silica gel or, in some cases, alumina has bee

37 s initial dihydroxylation of the olefin with oxone, oxidative cleavage by the in situ-generated 3,4,5

38 Oxone (potassium peroxomonosulfate) is an efficient oxid

39 catalyzed reactions (sulfite and oxygen, and oxone) produce an imine intermediate that spontaneously

40 dation to iodine by peroxymonosulfate (i.e., Oxone reagent).

41 ne not only acts as a PTC but also activates Oxone, through hydrogen bonding, toward electrophilic at

42 y showed varying activities in activation of Oxone to generate sulfate radicals for phenol degradatio

43 2-(diphenylmethyl)pyrrolidine 1 reacted with Oxone to give a mixture of ammonium salts containing the

44 cal reaction: see text] Biacetyl reacts with oxone to give bis-dioxirane [3,3'-dimethyl-3,3'-bidioxir

45 benign reagent KHSO(5), prepared easily from Oxone, to diesters in one simple transformation.

46 s for asymmetric epoxidation of alkenes with Oxone, via a dioxirane intermediate.

47 ) complexes to cleave DNA in the presence of Oxone was strongly dependent on both the nature and the

48 When oxone was used, oxygen was not required for the deaminat

49 uickly and selectively oxidized with aqueous Oxone without the need for protection of most peptide si