ライフサイエンスコーパス: oxy

1 with triplet O2, forming diamagnetic (S = 0) oxy-Hb.

2 -dihydro-4,4,5,5-tetramethyl-1H-imidazolyl-1-oxy-3-oxide (carboxy-PTIO, an NO scavenger), 1H-[1,2,4]-

3 ak area reproducibility were obtained for 14 oxy-compounds present in trace amount in the complex bio

4 -tert-butyl-1,2-quinone-(3,5-di-tert-butyl-2-oxy-1-phenyl)imine) to give five-coordinate (X)(Y)Si(ON[

5 terest because of its formation from Fe(3+) (oxy)hydroxides via dissimilatory iron reduction.

6 a series of catecholic and non-catecholic 3-oxy- (and deoxy)-anthocyanidins.

7 vity relationship (SAR) for the compound's 3-oxy site.

8 ther, these results indicate that both the 3-oxy and 4'-benzylamide positions in (R)-1 can accommodat

9 ied introduction of larger moieties at the 3-oxy site in (R)-1 was offset, in part, by including unsa

10 all nonpolar, nonbulky substituents at the 3-oxy site provided compounds with pronounced seizure prot

11 roups tethered by a 1,4-phenylenebis(butyl-4-oxy) unit (the strap) and carrying a methylbenzoic ester

12 s shown that the polarizing agent 1-(TEMPO-4-oxy)-3-(TEMPO-4-amino)propan-2-ol (TOTAPOL) has a strong

13 In the Y257F-4NC-oxy complex, the O(2) is bound side-on to the Fe(II), wh

14 acetoxybenzyl-based, 4-(5-(((4-acetoxybenzyl)oxy)amino)-2-carboxy-5-oxopentyl)benzoic acid, 12, provi

15 itrate and ferric ammonium citrate), against oxy- and met-hemoglobin erythrocytes used as controls.

16 The ester 4-((tosyl-l-alanyl)oxy)phenyl tosyl-l-alaninate (TAPTA) was synthesized and

17 ular anionic cyclization of (2-alkynylbenzyl)oxy nitriles has been developed for the preparation of s

18 (20 mol %) to a solution of (2-alkynylbenzyl)oxy nitriles in tetrahydrofuran at room temperature in a

19 ed base (BB) catalysis and the use of alpha'-oxy enones as enabling Michael acceptors with ambivalent

20 Experiments show that the alpha'-oxy ketone moiety plays a key role in the above realizat

21 ones, thiazolones, and azlactones) to alpha'-oxy enones can afford the corresponding tetrasubstituted

22 ectively functionalize alpha-amino and alpha-oxy sp(3) C-H bonds in both cyclic and acyclic systems.

23 n successfully applied to a variety of alpha-oxy and alpha-amino acids, as well as simple hydrocarbon

24 y on the enantioselective synthesis of alpha-oxy carboxylic acids.

25 ds, including hydrocarbon-substituted, alpha-oxy, and alpha-amino acids, provides a versatile CO2-ext

26 nd the chlorine radical source for the alpha-oxy C(sp(3))-H arylation of cyclic and acyclic ethers.

27 way is the cleavage of peroxide to the alpha-oxy radical (likely catalyzed by Cu), which is computati

28 Overall, this approach to alpha-oxy amides provides an innovative complement to alternat

29 ing lithiated alpha-diazo carbonyls to alpha-oxy ketones.

30 We describe an alternative oxy-hemoglobin assay that eliminates dithionite and sugg

31 he aqueous AlAl12(7+) ion to solid aluminum (oxy)-hydroxide phases, we found that this ion lies close

32 cotinamide core structure, 5-((3-amidobenzyl)oxy)nicotinamides offered excellent activity against SIR

33 Therefore, 5-((3-amidobenzyl)oxy)nicotinamides represent a new class of SIRT2 inhibit

34 An oxy-heme complex, the heme-superoxo species (tetrahydrof

35 d for the first time as means to evaluate an oxy-fuel power plant with CO(2) capture.

36 It was found that in an oxy-combustion atmosphere (mostly CO2), the re-emission

37 ognition, and these are connected through an oxy-methylene linker to cross the GC.

38 rries obtained from two limestones, under an oxy-combustion atmosphere.

39 tituted pyrimidine derivatives armed with an oxy-functionalized acetate chain at the ring is describe

40 imaging of a targeted fluorescent agent and oxy- and deoxyhemoglobin gave functional information abo

41 Solubilities for both deoxy- and oxy-alpha 2beta2(E6V,T4V) were similar to that of deoxy-

42 In contrast, both deoxy- and oxy-alpha2beta2(E6V,T4V) promoted formation of tiny, dis

43 of the Fe-O(2) center in oxy-hemoglobin and oxy-myoglobin is a long-standing issue in the field of b

44 odocyclohexenone followed by methylation and oxy-Cope rearrangement delivered enantiomerically enrich

45 s (PAHs), PAH derivatives (nitro- (NPAH) and oxy-(OPAH)), organic carbon (OC), and particulate matter

46 OOD), and a coke oven (COKE), and to PAH and oxy-PAH containing fractions of these.

47 Naphthenic (CnH2n+zO2) and oxy-naphthenic (CnH2n+zOx) acids represented the largest

48 Cobalt oxides and (oxy)hydroxides have been widely studied as electrocataly

49 enolic oxidation, ketone allylation, anionic oxy-Cope rearrangement, and acid-promoted cyclization.

50 amura's chiral allylzinc reagent, an anionic oxy-Cope rearrangement, a one-pot ozonolysis-reductive a

51 amura's chiral allylzinc reagent, an anionic oxy-Cope rearrangement, and the Lewis acid-promoted cycl

52 lation of a cyclic enone followed by anionic oxy-Cope rearrangement delivered the ketone as a mixture

53 that relies on a diastereoselective anionic oxy-Cope rearrangement to set the relative configuration

54 Extended N(4)-(3-arylpropyl)oxy derivatives of uridine-5'-triphosphate were synthesi

55 Thus, an extended N(4)-(3-arylpropyl)oxy group accessed a structurally permissive region on t

56 (6S)-2-nitro-6-{[4-(trifluoromethoxy)benzyl]oxy}-6,7-dihydro-5H-imidazo[2,1-b][1, 3]oxazine (PA-824)

57 -[(Guanine-9H-yl)methyl]propane-1,3-diyl)bis(oxy)]bis(methylene)}diphosphonic acid (compound 17) exhi

58 hyrinato zinc(II) 1 and 5-(2,5-phenylene-bis(oxy)diacetamide)-10,15,20-tris(triphenylamino)porphyrina

59 on prompts reaction with H2 to give a borane-oxy-borate derivative, the product of C-O bond cleavage.

60 sT heme-bound GAF domain (GAF(DosT)) in both oxy and deoxy forms determined to a resolution of 2.3 A.

61 ut on an alert macaque demonstrate that both oxy- and deoxyhemoglobin concentrations in the frontal l

62 eoxy), CO-inhibited (carboxy), and O2-bound (oxy) hemes in myoglobin (MB) and hemoglobin (HB) solutio

63 ethyl 6-bromo-8-(4-((tert-butyldimethylsilyl)oxy)benzamido)-4-oxo-4H-chromene-2-carboxy late (19) wit

64 esis of (5S)-5,7-di[(tert-butyldimethylsilyl)oxy]-4,4-dimethylheptan-3-one an asymmetric Noyori reduc

65 e isonitrile N-(2-{[(tert-butyldimethylsilyl)oxy]methyl}phenyl)carbonitrile.

66 pyl)-4-(((4-methoxyphenyl)(methyl) carbamoyl)oxy)indolin-1-ium hydrochloride) with IC50s of 0.4 and 1

67 d analog of [4-[[N-(3-chlorophenyl)carbamoyl]oxy]-2-butynyl]trimethylammonium chloride (McN-A-343).

68 erivatives: (3beta)-3-((thiophene-2-carbonyl)oxy)-olean-12-en-28-oic acid (1a) (IZ=22mm) and (2alpha,

69 (2alpha,3beta-2,3-bis((thiophene-2-carbonyl)oxy)olean-12-en-28-oic acid (2a) (IZ=24mm).

70 cal to the double bond of 3-[(1-carboxyvinyl)oxy]benzoic acid.

71 Employing a copper-catalyzed oxy-alkenylation strategy, a range of readily available,

72 icient strategy involving a copper-catalyzed oxy-alkynylation of diazo compounds with ethynylbenziodo

73 ein, we report the first palladium-catalyzed oxy- and aminoalkynylation using aliphatic bromoalkynes,

74 Hg(2+) is similar regardless of whether CO2 (oxy-fuel combustion) or N2 (air combustion) are the main

75 In this context, oxy- and aminoalkynylation are especially important reac

76 substrate and H(2)O(2) are needed to convert oxy-DHP to the catalytically active ferric state.

77 the absence of TCP, H(2)O(2) alone converts oxy-DHP to an inactive state (compound RH) instead of ox

78 2 catalyst indicate the presence of a crotyl-oxy surface intermediate.

79 ort EPR spectroscopic studies of cryoreduced oxy-F33Y-CuBMb, a functional model of HCOs engineered in

80 o EPR signal, in contrast to the cryoreduced oxy-wild-type (WT) Mb, which is unable to deliver a prot

81 pectroscopy data on solution and crystalline oxy-Hb indicate both geometric and electronic structure

82 concentrations of deoxy-hemoglobin (ctHHb), oxy-hemoglobin (ctHbO2), water (ctH2O), lipid, and TOI (

83 f the synthesis include a diastereoselective oxy-Cope rearrangement/oxidation sequence to install the

84 The usage of a diastereoselective oxy-Michael addition/benzylidene acetal formation couple

85 including (2S,2'S)-1,1'-(butane-1,4-diylbis(oxy))bis(N-isopropylpropan-2-amine) 7, (2S,2'S)-1,1'-(pe

86 lithiated (2S,2'S)-1,1'-(pentane-1,5-diylbis(oxy))bis(N-isopropyl-3-methylbutan-2-amine) 10 is a mono

87 amine) 7, (2S,2'S)-1,1'-(pentane-1,5-diylbis(oxy))bis(N-isopropylpropan-2-amine) 8, and (2S,2'S)-1,1'

88 e) 8, and (2S,2'S)-1,1'-(heptane-1,7-diylbis(oxy))bis(N-isopropyl-3-methylbutan-2-amine) 9 are dimers

89 ies, Hf(OTf)4 was used to convert the double oxy-Michael product 28 into C1-C19 building block 10.

90 SO(2) and SO(3), is considerably high during oxy-fuel combustion even though the sulfur content in Mo

91 erefore, for Morwell coal utilization during oxy-fuel combustion, additional sulfur removal, or polis

92 tonation step to form an enantiodiscriminant oxy-allyl cation prior to the stereodefining nucleophili

93 LC-MS(3) analysis of intact esterified oxy-lipids and LC-MS(2) analysis of the hydrolysis produ

94 lfonyl fluoride and 4-ethoxyfluorophosphinyl-oxy-TEMPO, respectively, suggest that enzyme activation

95 SHSAMs: ITO/IFL/poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][ 2-[[(2-eth

96 conducting PTB7 (poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluor o-2

97 ar-cell material poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro -2

98 -b']dithiophene-2,6-diyl][ 2-[[(2-ethylhexyl)oxy]carbonyl]-3-fluorothieno[3,4-b]thiophenediyl]]:pheny

99 We report that SeO2 catalyzes the facile oxy-functionalization of (CO)5Re(I)-Me(delta-) with IO4(

100 pecies, ZnS, Zn3(PO4)2, and Zn associated Fe oxy/hydroxides, also regardless of the form of Zn added.

101 adsorption capacity for As(V) of a single Fe oxy-hydroxide combined with enhanced As(III) removal bas

102 t the ratio of ZnS and Zn associated with Fe oxy/hydroxide depended on the redox state and water cont

103 organically complexed Fe, and colloidal Fe (oxy)hydroxides, stabilized by surface interactions with

104 critical component of record-activity Ni/Fe (oxy)hydroxide (Ni(Fe)OxHy) oxygen evolution reaction (OE

105 Moreover, we found selective removal of Fe (oxy)hydroxides by aggregation at increasing salinity, wh

106 arosite and other minerals (e.g., clays, Fe-(oxy)hydroxides).

107 Ferric-oxy multimers, tetramers, and/or larger mineral nuclei f

108 inct steps: 1) initial oxidation of ferrous (oxy) to ferryl Hb; 2) autoreduction of the ferryl interm

109 multiple conformations of the binary ferrous-oxy species of the IDOs.

110 sensor and that the stability of its ferrous-oxy complex is enhanced by interdomain interactions.

111 ize the active-site structure of the ferrous-oxy complexes of human (hIDO) and Shewanella oneidensis

112 accelerates the rate of decay of the ferrous-oxy/ferric-superoxo species in substrate turnover.

113 T. cruzi and N-(3-chloro-4-((3-fluorobenzyl)oxy)phenyl)-7-(4-((4-methyl-1,4-diazepan-1-yl)sulf onyl)

114 gen, such as 4-((3-chloro-4-((3-fluorobenzyl)oxy)phenyl)amino)-6-(4-((4-methyl-1,4-diazepan-1- yl)sul

115 rophenyl) piperazin-1-yl)-2-((4-fluorobenzyl)oxy)-ethanone, or DPFE, demonstrates improved solubility

116 For oxy, two unpaired Fe(d) spins and, thus by definition, a

117 eal that: (i) the lipid binding affinity for oxy-Mb increases as the chain length increases (i.e. C12

118 t prediction of similar binding energies for oxy- and carbonmonoxymyoglobin.

119 sly for PAHs but here for the first time for oxy-PAHs and N-PACs.

120 nvolving H2O molecules, which is absent from oxy-WTMb.

121 ab-scale in a relevant environment) and full oxy-fuel combustion (TRL 4 being the component and syste

122 ational spectroscopy reveals that a furfuryl-oxy intermediate forms on TiO(2) as a result of a charge

123 rface activate the formation of the furfuryl-oxy intermediate via an electron transfer to furfuraldeh

124 This furfuryl-oxy intermediate is a highly active and selective precur

125 Cyclic gamma-oxy-beta-hydroxy-alpha-diazo carbonyls undergo Lewis aci

126 rities--typical of flue gas from natural gas oxy-fuel combustion processes--the measured dew point pr

127 DA by VMAT2 increase levels of DA-generated oxy radicals ultimately resulting in degeneration of DAe

128 -beta-d-glucopyranosyl-beta-d-glucopyranosyl)oxy]-20-[(6-O-beta-d-xylopyra nosyl-beta-d-glucopyranosy

129 -beta-d-xylopyra nosyl-beta-d-glucopyranosyl)oxy]-dammar-24-en-19-al; (3beta)-28-oxo-28-(phenylmethox

130 eta-d-glucopy ranosyl)-beta-d-glucopyranosyl]oxy]-(3beta)-lanost-9(11)-en-24-one; 4-(2Z)-2-decen-1-yl

131 onclude: (i) W188H iNOSoxy stabilizes a heme-oxy species that forms upon reduction of the heme-dioxy

132 her the processing or reactivity of the heme-oxy species and makes these steps become rate-limiting f

133 the concentration of oxygenated hemoglobin ([oxy-Hb]) in the cerebral cortex.

134 Here, using 3d-M hydr(oxy)oxides, with distinct stoichiometries and morphologi

135 hydroxybenzoate (1), 2-2-[(4-hydroxybenzoyl)-oxy]-ethyl-4-methoxy-4-2-[(4-methylpentyl)oxy]-3,4-dihyd

136 s TCE by Fe(II) associated with the Fe(III) (oxy)hydroxide coating is substantially slower than that

137 also lead to transformation of the Fe(III) (oxy)hydroxide coating to more crystalline phases, the ra

138 to the abundance of precipitated iron(III) (oxy)hydroxides, are hot spots for the removal and rediss

139 and reactivity of floc amorphous Fe((III))-(oxy)hydroxide (FeOOH) phases under ice ([FeOOH](summer)

140 ental ligands on the dissolution of Cr(III)-(oxy)hydroxide solids and associated Cr isotope fractiona

141 vestigated the stability of Cr(III)-Fe(III)-(oxy)hydroxides, common Cr(VI) remediation products, with

142 a non-natural substrate, benzaldehyde imino-oxy acetic acid (BIAA).

143 riptions are correct for the Fe-O2 center in oxy-Hb.

144 lectronic structure of the Fe-O(2) center in oxy-hemoglobin and oxy-myoglobin is a long-standing issu

145 on submicrometer fly ash at higher levels in oxy-firing than in air-blown combustion.

146 pathways of incorporation of CO(2)(m) into (oxy)hydroxide crystal structures: one in which the C(4+)

147 An intramolecular oxy-Michael reaction under basic conditions was used to

148 A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium sa

149 tion was carried out on the N1-(p-iodobenzyl)oxy]methyl derivative of compound 5 using propagyl alcoh

150 d is employed to fabricate well-defined iron oxy-hydroxides and transitional metal doped iron oxy-hyd

151 Specifically, the Co-doped iron oxy-hydroxides (Co0.54Fe0.46OOH) show the excellent elec

152 hydroxides and transitional metal doped iron oxy-hydroxides nanomaterials, which show good catalytic

153 r performance in comparison to the pure iron oxy-hydroxide (FeOOH) catalysts, originate from the bran

154 Iron (oxy)hydroxide solids in the shallowest sediments likely

155 rce of orthophosphate to WEOM-adsorbed iron (oxy)hydroxide AFM tips suggesting that the molecular mas

156 he phase transformation from amorphous iron (oxy)hydroxide to goethite, resulting in pyrite surface p

157 d a reference peat soil material to an iron (oxy)hydroxide mineral surface.

158 nding force between orthophosphate and iron (oxy)hydroxide that was coated onto atomic force microsco

159 be induced by biological reduction of iron (oxy)hydroxide solids.

160 ral organic matter (NOM) and suspended iron (oxy)hydroxides.

161 rganic matter (WEOM) for adsorption to iron (oxy)hydroxide mineral surfaces is an important factor in

162 rted over longer distances compared to iron (oxy)hydroxides.

163 f calcium phosphate, calcium carbonate, iron(oxy)(hydr)oxide, silica, and also amino acids as an exam

164 xes and precipitated as nanoparticulate iron(oxy)hydroxides which aggregated as the pH increased, wit

165 thus became more coupled to that of the iron(oxy)hydroxides downstream in the circumneutral streams.

166 M but at pH >4.5 became associated with iron(oxy)hydroxides, and its transport thus became more coupl

167 og, we developed the bis((isopropoxycarbonyl)oxy)methyl ester prodrug (ACT-281959, 45).

168 hemical interest, such as Fe(III) and Mn(IV) oxy(hydr)oxides.

169 high-spin Mn(V)-oxo complex and not a Mn(IV)-oxy radical as the most oxidized species.

170 Layered (oxy) hydroxide minerals often possess out-of-plane hydro

171 orphous aggregates without a delay time like oxy-HbS, which is in contrast to formation after a delay

172 biosolids with iron, aluminum, and manganese oxy/hydroxides has been advocated as a key mechanism lim

173 hat is, the growth of a self-assembled metal oxy(hydroxide) active layer.

174 of dissolved organic matter (DOM) to metal (oxy)hydroxide mineral surfaces is a critical step for C

175 n of a family of thin-film transition metal (oxy)hydroxides as OER catalysts.

176 oxocyclohexa-1,4-dien-1-yl)methylene]-N-meth oxy-undecanamide (E3330-amide), a novel uncharged deriva

177 l)-oxy]-ethyl-4-methoxy-4-2-[(4-methylpentyl)oxy]-3,4-dihydr o-2H-6-pyranylbutanoic acid (2) and 3-((

178 d (3S)-(15-methyl-3-((13-methyltetradecanoyl)oxy)hexadecanoyl)glycyl-l-serine, abbreviated as l-serin

179 The development of a single-phase Fe/Mn oxy-hydroxide (delta-Fe0.76Mn0.24OOH), highly efficient

180 indicated the contribution of reductive Mn (oxy)hydoxide dissolution with Mn eventually becoming a t

181 waters due to reductive dissolution of Fe/Mn(oxy)hydroxides below the SWI.

182 ypes of regio- and enantioselective multiple oxy- and amino-functionalizations of terminal alkenes vi

183 s are important as Fe-containing Co- and Ni-(oxy)hydroxides are the fastest OER catalysts known.

184 vior of the anodic peak for amorphous nickel oxy/hydroxide (a-NiOx) films in basic media was investig

185 cluding 97 different parent, alkyl-, nitro-, oxy-, thio-, chloro-, bromo-, and high molecular weight

186 unit interfaces of seven of the eight normal oxy human hemoglobins, we found that the strengths, i.e.

187 Notably, [oxy-Hb] change in the left dorsolateral prefrontal corte

188 (eta(1)-ONO(2)) demonstrating the ability of oxy coboglobin models to promote the nitric oxide dioxyg

189 Phylogenetic analysis of oxy-tryptophan dimerization gene homologs found within a

190 urther, although the rate of autoxidation of oxy-DHP is somewhat enhanced by the presence of TCP, the

191 tion that the cryoreduced ternary complex of oxy-P450scc-CH is catalytically competent and hydroxylat

192 ing measurements with substrate complexes of oxy-gsNOS (3; gsNOS is nitric oxide synthase from Geobac

193 Crystallography of oxy-F33Y-CuBMb reveals an extensive H-bond network invol

194 ioselective, with preferential deposition of oxy-Zn(II) species within the small pores of NU-1000.

195 ies, the electronic structure description of oxy-Hb remains elusive, with at least three different de

196 The effects of oxy-PAHs are, however, poorly known.

197 ic reactions of PAH lead to the formation of oxy and nitro derivatives, reviewed here, too.

198 , and oxalic acids confirms the potential of oxy aromatics to produce light-absorbing aqueous seconda

199 ped using the long-established principles of oxy-allyl cation chemistry.

200 scribed in detail the magnetic properties of oxy- and deoxyhemoglobin, as well as those of closely re

201 ossible contributions to the ground state of oxy-pfp.

202 henol (TCP) brings about facile switching of oxy-DHP to the enzymatically active ferric state via a p

203 n of spectral features identical to those of oxy-tyrosinase indicates that oxy-NspF contains a Cu(2)O

204 res with H2O vapor concentrations typical of oxy-combustion conditions.

205 ature survey showed surface complexation of (oxy)anions (As, B, and PO4) is consistently exothermic,

206 s desulfurization (WFGD) plants, focusing on oxy-coal combustion processes and differences when compa

207 reductive cyclization of the oxonium ion, or oxy-Michael cyclization.

208 ormation following binding to either met- or oxy(Fe(2+))-alpha.

209 9i (LMK235) (N-((6-(hydroxyamino)-6-oxohexyl)oxy)-3,5-dimethylbenzamide) showed similar effects compa

210 f more polar PACs including oxygenated PAHs (oxy-PAHs).

211 e included in such a study, oxygenated-PAHs (oxy-PAHs) and nitrogen containing heterocyclic PACs (N-P

212 reveals that the distal pocket of the parent oxy-P450scc-cholesterol complex exhibits an efficient pr

213 For application at cement plants, partial oxy-fuel combustion, amine scrubbing, and calcium loopin

214 4- methyl-1-oxo-2-[(1-oxopropyl)amino]pentyl]oxy]-L-leucyl-N,O-dimethyl-,(7-->1)-lac tone (9CI)}, a n

215 uantify SOx and NOx emissions from gas-phase oxy-combustion systems.

216 potent P2Y4R-selective N(4)-(3-phenylpropyl)oxy agonist was phenyl ring-substituted or replaced with

217 The potent N(4)-(3-(4-methoxyphenyl)-propyl)oxy analogue 19 (EC50: P2Y2R, 47 nM; P2Y4R, 23 nM) was f

218 nder three different atmospheres: pyrolysis, oxy-fuel combustion, and carbon dioxide gasification con

219 S(2) are the major species during pyrolysis, oxy-fuel, and gasification.

220 Po(2)-coupled allosteric transition from R (oxy)-state to T (deoxy)-state subserves the release from

221 The reactive oxy intermediate of the catalytic cycle of extradiol aro

222 formation, [2,3]-sigmatropic rearrangement, oxy-Cope rearrangement, enol-keto tautomerization and fi

223 the oxidized met form but not in the reduced oxy form.

224 ggests that the isotopic signatures of soil (oxy)hydroxide could be heterogeneous.

225 carbon dioxide component [CO(2)(m)] of soil (oxy)hydroxide minerals goethite, diaspore, and gibbsite.

226 Full-length wild-type DevS forms a stable oxy-ferrous complex.

227 the catalytically inactive oxyferrous state (oxy-DHP), we find that the combination of H(2)O(2) and t

228 ort the use of bis(((difluoromethyl)sulfinyl)oxy)zinc (DFMS) as a source of CF2H radical for a rapid

229 tor 2-hydroxy-4-[[[[(4-methylphenyl)sulfonyl]oxy]acetyl]amino]-benzoic acid (NSC74859).

230 tion and subsequent annealing of the ternary oxy-cytochrome P450scc-cholesterol complex.

231 from N-methylpyridone to a tetrahydropyranyl oxy-pyridine derivative.

232 Our results indicate that oxy-PAH containing mixtures can be as potent Ahr activat

233 al to those of oxy-tyrosinase indicates that oxy-NspF contains a Cu(2)O(2) core where peroxide is coo

234 This suggests that oxy-Mb may play an important role in fuel delivery in Mb

235 Our results suggest that [oxy-Hb] change in the prefrontal cortex during the susta

236 The oxy-cobolglobin models of the general formula (NH(3))Co(

237 The oxy-combustion mechanisms available in the literature ca

238 The oxy-ferrous complex of cytochrome P450 2B4 (2B4) has bee

239 The oxy-hemoglobin concentration change and the beta band po

240 In addition, the oxy intermediate of the reaction cycle of Y257F-4NC + O(

241 spF, we have generated and characterized the oxy form of its active site.

242 e boiler and CO2 separation units during the oxy-fuel fluidized-bed combustion using this coal.

243 This represents a new strategy for the oxy-functionalization of M-R(delta-) polarized bonds.

244 NO complex but is strongly inhibited in the oxy complex.

245 of two major conformational substates in the oxy-ferrous precursor.

246 nd higher N2O formation were observed in the oxy-fuel atmosphere.

247 Most significantly, in the oxy-P450cam complex Gly248 adopts a position midway betw

248 Raman spectra of the oxy complex of Y171F indicate that the environment of th

249 otonation and hence further reduction of the oxy complex to the hydroperoxy intermediate resulting in

250 f Y171F indicate that the environment of the oxy group is significantly altered from that in the wild

251 tudied for a century, the interaction of the oxy- and deoxy-reactions and the effects on NO dispositi

252 nd applied it to study the properties of the oxy-ferrous complex of a human membrane bound P450, CYP1

253 A sharp increase of the oxy-hemoglobin concentration change, together with a dra

254 Probing the oxy-complexes of CYP19A1 poised for hydroxylase and lyas

255 According to this structuration, the oxy-hydroxide maintains the high adsorption capacity for

256 FM-300(V(IV)) shows CO2 bound side-on to the oxy group and sandwiched between two phenyl groups invol

257 o act as a poorer hydrogen bond donor to the oxy group.

258 ve-coordinate complex is active, whereas the oxy-ferrous six-coordinate species is inactive.

259 AH fraction of the WOOD extract and with the oxy-PAH fraction of the COKE extract.

260 The [oxy-Hb] change during the sustained attention task (SAT)

261 We found that the [oxy-Hb] change during the verbal fluency task (VFT) was

262 f a three-step sequence comprising a thermal oxy-Cope rearrangement, an iridium-catalyzed hydrogenati

263 This oxy form is found to react with monophenols, indicating

264 te these results with measurements of tissue oxy- and deoxyhemoglobin concentration during oxygen dep

265 both fatty acids and acylcarnitines bind to oxy-Mb in 1:1 stoichiometry.

266 ox active form of the protein in contrast to oxy-NGB.

267 xide dioxygenation (NOD) reaction similar to oxy-hemes.

268 S)-N-isobutyl-3-methyl-1-((triisopropylsilyl)oxy)butan-2-amide forms both a 2:2 mixed aggregate and a

269 S)-N-isobutyl-3-methyl-1-((triisopropylsilyl)oxy)butan-2-amine and n-butyllithium are characterized b

270 ithium (S)-N-isopropyl-1-((triisopropylsilyl)oxy)propan-2-amide forms mostly a 2:2 ladder-type mixed

271 d from (S)-N-isopropyl-1-((triisopropylsilyl)oxy)propan-2-amine, (R)-N-(1-phenyl-2-((triisopropylsily

272 ithium (R)-N-(1-phenyl-2-((triisopropylsilyl)oxy)ethyl)propan-2-amide.

273 amine, (R)-N-(1-phenyl-2-((triisopropylsilyl)oxy)ethyl)propan-2-amine, or (S)-N-isobutyl-3-methyl-1-(

274 iyama-Michael reaction of 2-[(trimethylsilyl)oxy]furan with diverse alpha,beta-unsaturated ketones is

275 the effect of the gases present in a typical oxy-coal combustion atmosphere on mercury speciation and

276 fur was found to be converted to SO(3) under oxy-fuel combustion, whereas SO(3) was undetectable duri

277 ion of those species was also assessed under oxy-fuel condition.

278 oncentrations were considerably higher under oxy-fuel combustion compared to that in the air combusti

279 n coal in a 10 kWth fluidized bed unit under oxy-fuel combustion conditions.

280 gether, our results support a model in which oxy-Mb is a novel regulator of long-chain acylcarnitine

281 of both fatty acids and acylcarnitines with oxy-Mb using molecular dynamic simulations and isotherma

282 of either fatty acids or acylcarnitines with oxy-Mb.

283 ) fail to achieve a stable conformation with oxy-Mb.

284 developed leading to selective [2,3]-Wittig-oxy-Cope and isomerization-Claisen rearrangements.

285 table catalyst for the selective, high yield oxy-functionalization of methane.

286 ble 2',2''-(10-(2-((2,5-dioxopyrrolidin-1-yl)oxy)-2-oxoethyl)-1,4,7,10-tetraazacyclod odecane-1,4,7-t

287 with the [(2,2,6,6-tetramethylpiperidin-1-yl)oxy] (TEMPO) stable free radical.

288 nyl]-4-yl)-6-chloro-1H-benzo[d]imidazol-2-yl)oxy)-2-methylbenzo ic acid, 42 (MK-3903).

289 aminomethyl)-6-(trifluoromethyl)pyridin-2-yl)oxy)phenyl)(3- fluoro-4-hydroxypyrrolidin-1-yl)methanone

290 N-{trans-3-[(5-Cyano-6-methylpyridin-2-yl)oxy]-2,2,4,4-tetramethylcyclobutyl}imid azo[1,2-a]pyrimi

291 (2-(5-bromofuran-2-yl)-4-oxo-4H-chromen-3-yl)oxy)acetamide (CB7993113), was further tested for its ab

292 inhibitor, N-(4-((6,7-dimethoxyquinolin-4-yl)oxy)-3-fluorophenyl)-1,5-dimethyl-3-oxo-2-pheny l-2,3-di

293 omatic)-N'-{4-[(6,7-dimethoxyquinazolin-4-yl)oxy]phenyl}urea were identified as potent and selective

294 ,4-bis(acetyloxy)phenyl]-1-oxo-2-propen-1-yl]oxy]-butan edioic acid (compound 2), indicated striking

295 nthren-3-yl]o xy]-6-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol], an alkaloid iso

296 l-N-phenyl-2-{[2-(pyridin-2-yl)quinolin-4-yl]oxy}propanamide (22a; rat Ki=0.10 nM; human TSPO genotyp

297 6,7-dihydro-5H-pyrrolo[2,3-d]pyrimidin- 4-yl}oxy)-1-piperidinecarboxylate (GSK1104252A) (3), a potent

298 xy-pyridin-3-yl)-benzyl]-5-(pyridin-2-ylmeth oxy)-1H-indol-2-yl]-2,2-dimethyl-propionic acid (11j) is

299 -4-(trifluoromethyl-3H-diazirin-3-yl)ben zyl]oxy]carbonyl]nonanoyl]-sn-glycero-3-phosphocholine to th

300 -4-(trifluoromethyl-3H-diazirin-3-yl)ben zyl]oxy]carbonyl]nonanoyl]-sn-glycero-3-phosphocholine, the