ライフサイエンスコーパス: oxyanion

1 fectiveness of the binding of the developing oxyanion.

2 ize a second water for protonation of the 3'-oxyanion.

3 s of Ca bound directly and indirectly to the oxyanion.

4 and down-gradient wells have little or no Se oxyanions.

5 the diamagnetic anisotropy of these trigonal oxyanions.

6 h we interpret as incomplete reduction of Se oxyanions.

7 model SRM, we screened a panel of inorganic oxyanions.

8 ples was a mixture of elemental Se(0) and Se oxyanions.

9 on of the cells from the inhibition by these oxyanions.

10 Evidence for an unexpected oxyanion-accelerated 1,2-sigmatropic shift was also foun

11 proposed reaction steps can be formulated as oxyanion-accelerated pericyclic processes.

12 Upon reduction of the oxyanions, an iron(III)-oxo is formed, which in the pres

13 supporting a role for N85 in stabilizing the oxyanion and in coordinating, along with S138, the attac

14 tial position of the nascent peptide and the oxyanion and places the amine near the critical A76 2'-O

15 ving neighboring group participation by a C2-oxyanion and rate-limiting formation of a 1,2-anhydro su

16 repulsion between bound P(i) and the Ser102 oxyanion and the binding of P(i) in its trianionic form

17 Such mixed anion bonding of inorganic oxyanions and OM to iron(III) and aluminum(III) in envir

18 ppeared to derive from both desorption of Se oxyanions and oxidative dissolution of elemental Se(0).

19 tion of the pyridine nitrogen, the phenoxide oxyanion, and the carboxylate anion of the 1-glycine imi

20 er contaminants (i.e., halogenated organics, oxyanions, and nitrosamines), and identifies key researc

21 d toward the oxygen lone pairs on a trigonal oxyanion are stronger than hydrogen bonds to the pi-elec

22 Our results indicate that Se oxyanions are the most labile species; however, the magn

23 emediation strategy for arsenic in which the oxyanion arsenate is transported aboveground, reduced to

24 on transfer within the substrate to yield an oxyanion as the initial step in catalysis.

25 oxide surfaces and interact differently with oxyanions, as examined here experimentally.

26 However, the WPD-loop in the presence of oxyanions assumes a half-closed conformation, in contras

27 toring post-mining natural attenuation of Se oxyanions at ISR sites.

28 neutral pKa stabilizes the transition-state oxyanion, at least to the extent that CCdApPmn accuratel

29 energy of formation for previously measured oxyanion-bearing feldspathoid phases.

30 These structures also show that tetrahedral oxyanions bind at a novel secondary site and function to

31 ogenic SOD1 mutant D125H reveals the mode of oxyanion binding in the active site channel and implies

32 ct, acetate, reveals details of the putative oxyanion binding site, and suggests that substrates bind

33 Active site substitutions, including at the oxyanion binding site, enable the production of substitu

34 Oxyanion binding to the P-loop in W354F is analogous to

35 )H NMR titration experiments, which show the oxyanion binding trend HCO3(-) > H2PO4(-) > HSO4(-), whe

36 NrtA is significantly larger than other oxyanion-binding proteins, representing a previously unc

37 By contrast, a nitrogen oxyanion-binding sensor (NasS) is required for nitrate/n

38 of, or altered accessibility to, the S1 and oxyanion-binding sites.

39 The measurement of trace metals and oxyanions by MBL-DGT was independent of pH (5.03-8.05) a

40 ifying the problems associated with modeling oxyanions by means of two fixed water molecules (or rela

41 d with the preferential retention of arsenic oxyanions by schwertmannite.

42 Selenium oxyanions can serve as an electron acceptor in anaerobic

43 a stable analogue of the shared family alpha-oxyanion carboxylate intermediate/transition state) and

44 adenosine 3',5'-diphosphate and the original oxyanion.) Chlorate and perchlorate form dead-end E.MgAT

45 ely measured the concentration of metals and oxyanions (CMBL/CSol = 0.85-1.12) over 4 days, with the

46 ion model for NOM (NOM-CD), the pH-dependent oxyanion competition of the organo-mineral oxide fractio

47 Three new diruthenium oxyanion complexes have been prepared, crystallographica

48 n dissociation constants of dead end E.MgATP.oxyanion complexes were all increased.

49 lorate and perchlorate form dead-end E.MgATP.oxyanion complexes.

50 large oxyanion:Fe solids ratio, depletes the oxyanion concentration with only small amounts of Fe.

51 , form with little dependence on the initial oxyanion concentration.

52 Trends suggest that deep-ocean Se oxyanion concentrations increased because of progressive

53 sopropyl fluorophosphonate, which mimics the oxyanion-containing tetrahedral intermediate of the hydr

54 these two positions in the selection of the oxyanion countersubstrate.

55 a secondary coordination sphere that aids in oxyanion deoxygenation.

56 iation constant of E.APS, and the monovalent oxyanion dissociation constants of dead end E.MgATP.oxya

57 , consistent with formation of a tetrahedral oxyanion during nucleophilic attack by Ser112.

58 The results show that oxyanion exchange with structural sulfate was the main m

59 ed by a combination of surface complexes and oxyanion exchange.

60 he two types of proximal homoallylic lithium oxyanions exerts an analogous effect.

61 f Fe(II) oxidation and, because of its large oxyanion:Fe solids ratio, depletes the oxyanion concentr

62 Nonetheless, certain prokaryotes use arsenic oxyanions for energy generation, either by oxidizing ars

63 t chromium Cr(VI), typically existing as the oxyanion form of CrO4(2-), is being considered for more

64 formation of the deprotonated, nucleophilic oxyanion form of the 2'-hydroxyl group.

65 ific 2'-O-MTase VP39 does not promote RNA 2'-oxyanion formation but that instead it acts by steering

66 lytic residues at the enediolate O-1 and O-2 oxyanions formed on deprotonation of GAP and DHAP, respe

67 s suggests that there was no upwelling of Se oxyanions from an oxic deep-ocean reservoir, which is co

68 ntal release of soluble, toxic selenium (Se) oxyanions generated by mining.

69 While the systems containing these oxyanions had more growth, the system containing only ir

70 n-state binding studies of the receptor with oxyanions have also been carried out by (1)H NMR titrati

71 rimary specificity pocket (Asp-189), and the oxyanion hole (Gly-193) hold most of the favorable contr

72 site are mediated by two waters, one in the oxyanion hole (H(2)O(oxy)) and one on the other (S2) sid

73 This conformation disconnects the oxyanion hole (the amides of Gly193 and Ser195) from the

74 d oxygen with the backbone of Ser-195 in the oxyanion hole and a loop opening between residues 216-22

75 ant features of the active site including an oxyanion hole and a polar binding pocket that interacts

76 a with the pyridine and alcohol to act as an oxyanion hole and activate the bound acyl-spiroligozyme

77 The work also offers a detailed view of the oxyanion hole and an exceptional "in-action" depiction o

78 ement that places the scissile amide into an oxyanion hole and forces the nucleophilic residue into a

79 with its carbonyl oxygen pointing out of the oxyanion hole and forming hydrogen bonds with Lys-234 an

80 cement of the main chain atoms that form the oxyanion hole and movement of the lid loop region when t

81 of the acyl-enzyme complex was located in an oxyanion hole and positioned to hydrogen bond with the b

82 ocated between the 190 strand leading to the oxyanion hole and the 220-loop that contributes to the a

83 earrangement of residues that stabilizes the oxyanion hole and the dimer interface.

84 in SHV-1: one with the acyl CO group in the oxyanion hole and the second with the acyl group rotated

85 phenolate can rotate freely relative to the oxyanion hole and thus loses the preorganization contrib

86 to the active site via polar contacts to the oxyanion hole and to residues 268 and 301 as well as by

87 -phase calculations with a fixed model of an oxyanion hole are sufficient for assessing the correspon

88 ed to the structures for the E166A form, the oxyanion hole becomes smaller, providing one explanation

89 me is that the inhibitor is not bound to the oxyanion hole but interacts extensively with the "roof"

90 ide nitrogens of Asp224 and Thr223 create an oxyanion hole by hydrogen bonding to the terminal amide

91 al substrate facilitates construction of the oxyanion hole by stabilizing the position of the active

92 Each rotamer-oxyanion hole combination limits the location of the moi

93 In addition, rather than the typical oxyanion hole composed of backbone amides, IroE employs

94 ck as the thioester oxygen is forced into an oxyanion hole composed of Gly388 NH and CoA N2''.

95 ls in the boronyl center (O2) is held by the oxyanion hole comprising the amides of Ser-44 and His-21

96 s of cinchona alkaloid catalysts involves an oxyanion hole consisting of purely C-H functionality.

97 timate that the H-bonding interaction in the oxyanion hole contributes a stabilization of the ground

98 bstituted Tyr residues suggests that the KSI oxyanion hole does not provide catalysis by forming an e

99 backbone amide group of Gly 159 provides an oxyanion hole for stabilization of the tetrahedral trans

100 gen bond connects to a peptide that forms an oxyanion hole for stabilization of transient negative ch

101 ubstrate and not the TF binding that induces oxyanion hole formation and functional active site geome

102 splacement, d-Phe-Pro-Arg incorporation, and oxyanion hole formation by a flip of the 192-193 peptide

103 The transition state is stabilized by an oxyanion hole formed by the backbone amides of Ala102 an

104 The active site contains an oxyanion hole formed by the main chain nitrogen atoms of

105 This pocket, reminiscent of the oxyanion hole found in serine proteases, is completed th

106 eometrical constraints and impairment of the oxyanion hole function.

107 structural consequences of substituting the oxyanion hole hydrogen bond donors and several residues

108 ase (KSI) reported that substitution of both oxyanion hole hydrogen bond donors gives a 10(5)- to 10(

109 eemingly conservative mutations replaced the oxyanion hole hydrogen bond donors with hydrophobic side

110 e complex structure, which has only a single oxyanion hole hydrogen bond, is proposed to give rise to

111 sin-like proteases and the importance of the oxyanion hole in protease function suggest that this mec

112 (224) and the side chain of Arg(233) form an oxyanion hole in sortase B that stabilizes high energy t

113 the Thr-80 O(gamma) atom and a role for the oxyanion hole in stabilizing the negatively charged tetr

114 butions of each protonation state showed the oxyanion hole in the active site of wild-type Delta(5)-3

115 Ala(78) and Gly(118) form an oxyanion hole in the active site that includes only thre

116 owed that the carboxylate group occupies the oxyanion hole in the enzyme, while the sulfonamide provi

117 The role of the oxyanion hole in the reaction catalyzed by pig medium-ch

118 N of Gly(193) in FVIIa points away from the oxyanion hole in this structure.

119 ing the catalysis and that the electrostatic oxyanion hole interactions may not be sufficient to lead

120 n suggest that the sorting signal-stabilized oxyanion hole is a universal feature of enzymes within t

121 Importantly, the oxyanion hole is also absent in the benzamidine-FVIIa/sT

122 m its position in the active E form, and the oxyanion hole is disrupted by a flip of the Glu(192)-Gly

123 In the B chain, the oxyanion hole is disrupted due to absence of the I16-D19

124 This C-H oxyanion hole is found to play a pivotal role for stabil

125 larization caused by hydrogen bonding in the oxyanion hole is intimately linked to substrate turnover

126 e-emphasize the point that the effect of the oxyanion hole is mainly due to the fact that the relevan

127 ly known to use a Tyr side chain to form the oxyanion hole is prolyl oligopeptidase, but the Y44F mut

128 Absence of oxyanion hole is unusual and has biologic implications f

129 ecular modeling suggests that an alternative oxyanion hole may have been recruited, consisting of the

130 (8)-fold rate reduction, suggesting that the oxyanion hole may provide the major contribution to KSI

131 roduct analog bound to ketosteroid isomerase oxyanion hole mutants and concluded that the active-site

132 ycles revealed similar contributions from an oxyanion hole mutation in the wild-type and base-rescued

133 Further, oxyanion hole mutations have the same effect on reaction

134 and the presence of a water molecule in the oxyanion hole of AVCPDelta2 (AVCP with a deletion of the

135 ydrogen bonds donated by Y16 and D103 in the oxyanion hole of bacterial ketosteroid isomerase.

136 oxygen of (-)-cocaine benzoyl ester and the oxyanion hole of BChE in the TS1 structure for (-)-cocai

137 The oxyanion hole of serine proteases is formed by the backb

138 Thus, either the oxyanion hole plays only a minor role in stabilizing the

139 nion intermediate is stabilized by an enzyme oxyanion hole provided by Lys104 and Tyr158 of SpvC.

140 ts carbonyl oxygen positioned outside of the oxyanion hole provides a rationale for the stability of

141 ydrogen bond energetics and suggest that the oxyanion hole provides an important, but moderate, catal

142 riad of Cys-98, His-212, and Asp-227 and the oxyanion hole residue Asn-93.

143 d by the amide O of Gln19-a component of the oxyanion hole that binds the tetrahedral species formed

144 catalytically relevant water molecule and an oxyanion hole that both orients the substrate and offset

145 tive site catalytic residues and surrounding oxyanion hole that covalently binds the core of the alph

146 ackbone amides (Ile126 and Gly127) create an oxyanion hole that helps orient the formyl group for nuc

147 A water molecule now moves into the putative oxyanion hole that is constituted of a main-chain amide

148 an, asparagine, and tyrosine residues in the oxyanion hole that stabilizes the transition state for e

149 teraction of the inhibitor with the proposed oxyanion hole through interaction with a helix dipole an

150 11 side-chain alcohol hydrogen away from the oxyanion hole to hydrogen bond with the backbone carbony

151 -268 were identified as participating at the oxyanion hole to stabilize the tetrahedral species in th

152 plicate a role for Arg197 in formation of an oxyanion hole to stabilize the transition state.

153 (F-Tyr's) in the ketosteroid isomerase (KSI) oxyanion hole to systematically vary the proton affinity

154 ue of the enzyme, Thr(352), and stabilize an oxyanion hole via main chain amide hydrogen bonds.

155 donors and several residues surrounding the oxyanion hole with smaller residues in an attempt to cre

156 zation of the transition state in forming an oxyanion hole with the protonated Glu83.

157 Interestingly, although the "oxyanion hole" has been formed in the Michaelis complex,

158 lar, the Zn(1) ion is likely to serve as an "oxyanion hole" in stabilizing the carbonyl oxygen, while

159 The "oxyanion hole" of the alpha/beta-hydrolase fold, typical

160 hydrogen bonding from the amide backbone of 'oxyanion hole' residues, consistent with formation of a

161 t Thr57 Ogamma and a water molecule form an 'oxyanion hole' that likely stabilizes the proposed oxyox

162 on intermolecular hydrogen bonding (with an oxyanion hole), which is crucial for the transition stat

163 on of FVIIa active site in the region of the oxyanion hole, a "flipped" Lys192-Gly193 peptide bond.

164 tion by these compounds does not involve the oxyanion hole, an unprecedented departure from known and

165 We identify the position of the oxyanion hole, and the S- and S'-binding subsites of Glp

166 nformational changes in the active site, the oxyanion hole, and the substrate specificity pocket resi

167 vicinity may stabilize the S1 pocket and the oxyanion hole, and they may have general implications fo

168 yanion hole; and Asp-9, which stabilizes the oxyanion hole, are among the most highly conserved resid

169 A conserved asparagine in the oxyanion hole, Asn-169, is found to be H-bonded to subst

170 n of the S1 substrate binding pocket and the oxyanion hole, evident by an increased affinity for p-am

171 rized three histidine substitutions near the oxyanion hole, G57H, L58H, and M162H, which significantl

172 characterization: three corresponded to the oxyanion hole, hydrolase motif, and catalytic aspartate

173 nding between the substrate and the enzyme's oxyanion hole, the structure of the product analogue hex

174 that introducing a positive charge near the oxyanion hole, W197I/C60R or W197I/C60K, results in a fu

175 nt Cys408 is triply oxidized and lies in the oxyanion hole, which would block the binding of substrat

176 by X-ray with the acyl carbonyl outside the oxyanion hole, while the Delta (2) species corresponds t

177 etry and determines the rotamer state of the oxyanion hole-forming Asn295, and thus adds a second lev

178 5 and its carbonyl moiety is situated in the oxyanion hole.

179 ated by a photoacid bound to the active site oxyanion hole.

180 the OXA-1-doripenem complex is bound in the oxyanion hole.

181 nolate intermediate that is stabilized in an oxyanion hole.

182 ds between the acyl-enzyme thioester and the oxyanion hole.

183 ic contributions from KSI's general base and oxyanion hole.

184 ide bond and the correct architecture of the oxyanion hole.

185 he Tyr 433 containing loop, and the proposed oxyanion hole.

186 ke catalytic triad and its uniquely designed oxyanion hole.

187 nds to the form with the carbonyl inside the oxyanion hole.

188 stabilization of negative charge within the oxyanion hole.

189 he nonpolar form of the TSAs relative to the oxyanion hole.

190 igand, presumably anionic, is located in the oxyanion hole.

191 ter enolate anions stabilized by a conserved oxyanion hole.

192 n of the tetrahedral transition state by the oxyanion hole.

193 amide N of Glu(193) may not point toward the oxyanion hole.

194 the cocE employs a tyrosine hydroxyl in the oxyanion hole.

195 up is completely displaced from the enzyme's oxyanion hole.

196 tation through interaction with the proposed oxyanion hole.

197 honate moiety of the TSA and, hence, form an oxyanion hole.

198 N of Glu(193) to point correctly toward the oxyanion hole.

199 the active site His164 rather than with the oxyanion hole.

200 o activate the glutaminase by unblocking the oxyanion hole.

201 and the backbone N-H group of Gly-193 in the oxyanion hole.

202 rbon atom by binding of the keto group in an oxyanion hole.

203 as the other contacts backbone amides in the oxyanion hole.

204 hich use a serine residue deprotonated by an oxyanion hole.

205 h neighboring amide can be used in the local oxyanion hole.

206 -74, and Arg-75 in exosite I; Gly-193 in the oxyanion hole; and Asp-221 and Asp-222 in the Na+ site.

207 lytic dyad; Arg-17 and Ser-56, which form an oxyanion hole; and Asp-9, which stabilizes the oxyanion

208 One boronate oxygen is held in the oxyanion hole; the other, occupying the leaving group si

209 enzyme oxyanion holes or chemically designed oxyanion-hole mimics are N-H and O-H groups.

210 Oxyanion holes are commonly found in many enzyme structu

211 tic dyads and triads are usually paired with oxyanion holes for substrate activation, but it is diffi

212 und much higher success rates using designed oxyanion holes formed by backbone NH groups rather than

213 Small-molecule transition state analogues of oxyanion holes have been characterized by computations,

214 That is, although the energetics of oxyanion holes have been fully quantified in early studi

215 Typical functionalities found in enzyme oxyanion holes or chemically designed oxyanion-hole mimi

216 Oxyanion holes play a major role in catalyzing enzymatic

217 tificial catalysts using catalytic dyads and oxyanion holes.

218 e electron equivalents required to reduce Te oxyanions; however, the reduction rates were modestly in

219 receptor's crown ether ring and the trigonal oxyanion hydrogen bonded to the receptor NH residues.

220 resting enzyme and to the inhibitor-derived oxyanion in a chloromethyl ketone complex, observations

221 ophile, moving more than 2 A and placing the oxyanion in contact with Gln19 and the backbone amide of

222 ead to suboptimal solvation of the incipient oxyanion in the mutants, thereby potentially exaggeratin

223 may assist the catalysis by stabilizing the oxyanion in the reaction intermediate.

224 barrier is achieved by stabilization of the oxyanion in the transition state.

225 ed, and the coordination geometries of these oxyanions in both structures are reported.

226 igher accuracy of Metsorb for measuring some oxyanions in freshwater and seawater, and the possibilit

227 Low concentrations of oxyanions in our data set and structural underestimation

228 asured the concentration of trace metals and oxyanions in synthetic freshwater (CMBL/CSol = 0.82-1.18

229 observed by both direct quantification of Se oxyanions in the leachate and the corresponding loss of

230 he leachate and the corresponding loss of Se oxyanions in the solid phase.

231 vity at pH 8.7 in buffers containing various oxyanions, including acetate, carbonate, EDTA, and phosp

232 gh concentrations of molybdate and tungstate oxyanions inhibit growth, thus requiring the tight regul

233 nserved asparagine side chain stabilizes the oxyanion intermediate formed during lysine attack.

234 ermodynamically favored than maintaining the oxyanion intermediate necessary for catalysis to proceed

235 o receive the hydride, disassociation of the oxyanion intermediate to form the dead-end adduct is mor

236 ists in polarizing substrate/stabilizing the oxyanion intermediate.

237 d neither residue is likely to stabilize the oxyanion intermediate.

238 crucial for the stabilization of high-energy oxyanion intermediates or transition states through hydr

239 e followed by fragmentation of the resulting oxyanion into the carboxylic acid and a benzyl anion.

240 In all solid-state structures, the trigonal oxyanion is not located symmetrically inside the recepto

241 ts main-chain carbonyl carbon, the resulting oxyanion is stabilized by a protonated glutamate.

242 The crystal structure confirms that the oxyanion is stabilized by the main chain amide of Ser-20

243 tative Se reduction to drive the residual Se oxyanions isotopically heavy.

244 ally the N3 of A1 is the proton donor to the oxyanion leaving group.

245 nvolving pre-equilibrium dissociation of the oxyanion ligand (RO(-)) followed by nucleophilic attack

246 the helix 6 interaction with the active site oxyanion loop is therefore used in two independent regul

247 o 9.5), the leachable Se was comprised of Se oxyanions, mainly selenite.

248 ystem had the highest water content and that oxyanions may bridge iron(III) hydroxide polymeric embry

249 d His144 and hydrogen bonds of Arg228 to the oxyanion O5.

250 Phosphite (Phi), a phloem-mobile oxyanion of phosphorous acid (H(3)PO(3)), protects plant

251 teractions between the catalyst and the C-5'-oxyanion of the basic alkoxy leaving group.

252 idic species is formed by protonation of the oxyanion of the para-hydroxy-cinnamyl cysteine chromopho

253 osed role of H84 is as a proton donor to the oxyanion of the quinoid species such that subsequent C-H

254 The oxyanion of the tetrahedral intermediate interacts with

255 effects reported suggests that these simple oxyanions of nitrogen have a much richer profile of biol

256 he determination of biospherically important oxyanions of selenium (Se) and tellurium and another Se-

257 strial strategies to chemically reduce these oxyanions often require the use of harsh conditions, but

258 HNO release is expected to occur through the oxyanion (OHN-PY) of each HAPY compound.

259 s oxic conditions with lower availability of oxyanions or increased bioproductivity along continental

260 tion of acetic acid, most likely through the oxyanion produced by nucleophilic attack at the carbonyl

261 The oxyanion reactively dehydrogenates ethane at the melt-ga

262 ected mutagenesis, and energetic analyses of oxyanion recognition by the P-loop in the ATP/ADP bindin

263 y in the pure form compared to that of other oxyanion reductases, such as the membrane-bound and peri

264 ly for analysis of such low-abundant, labile oxyanion reductases.

265 ase in the order fluoroanions > carboranes > oxyanions, reflecting the relative basicities of the ani

266 rmed in the presence of bivalent cations and oxyanions represent important components of the global F

267 e formation mechanisms and structures of the oxyanion-rich Fe(III) polymers determined in this study

268 growth medium and amended with the selenium oxyanion selenate, selenite, or selenocyanate, produces

269 e efficient method, the predominant selenium oxyanions, selenite (Se(IV)) and selenate (Se(VI)), can

270 REMs were also tested for oxyanion separation.

271 These oxyanions share similar structures but differ significan

272 used to capture TcO4(-) and closely related oxyanions so far and discuss the possibility of using me

273 Applying phosphorus oxyanion solutions to HLB-positive sweet orange trees re

274 istent with the catalytic antibody providing oxyanion stabilization as its major contribution to cata

275 se for UDP-glucose alcohol oxidation and for oxyanion stabilization during formation and breakdown of

276 nction as an aldehyde trap and also provides oxyanion stabilization.

277 ched to the catalytic serine alone, with the oxyanion stabilized by unusual tripartite interactions w

278 identified that enable high selectivity: an oxyanion-steering mechanism and a CH-pi interaction.

279 plications for the flux of As and also other oxyanions, such as phosphate, across the groundwater-lak

280 The orientation of the enzyme-associated oxyanion suggests that both the self-oxidative and exter

281 hed the well-known stimulatory effect of the oxyanion sulfite on MgATP hydrolysis.

282 aqueous streams containing soluble tellurium oxyanions, tellurate (Te(VI)), and tellurite (Te(IV)).

283 olarize the carbonyl group and stabilize the oxyanion tetrahedral intermediate.

284 e oxygen of the substrate, and stabilize the oxyanion tetrahedral intermediate.

285 to a Weinreb amide, rather than by a simple oxyanion that is generated from an epoxide.

286 These simulations revealed formation of the oxyanion thiohemiacetal intermediate only when the nicot

287 able to biocatalyze the reduction of both Te oxyanions to produce Te(0) nanoparticles (NPs) in sulfur

288 sed on conversion of water soluble, toxic Se oxyanions to water insoluble, elemental Se.

289 ansfer allowing for the stabilization of the oxyanion transition state and subsequent protonation of

290 ically repels the product phosphate, another oxyanion, tungstate, binds more strongly in the presence

291 bility, MOFs can be applied to capture these oxyanions under real-life conditions.

292 urce, these Fe(III) polymers, which dominate oxyanion uptake, form with little dependence on the init

293 trace metal (Mn, Co, Ni, Cu, Cd, and Pb) and oxyanion (V, As, Mo, Sb, W, and P) concentrations in fre

294 AP active site is known to stabilize another oxyanion, vanadate, in trigonal bipyramidal geometry, bu

295 pivotal role for stabilizing the developing oxyanion, via C-H...O hydrogen bonds, in our newly propo

296 The predominant oxyanion was nitrate (60-75%) followed by nitrite.

297 ltispecies biofilms biotransforming selenium oxyanions were characterized using X-ray fluorescence im

298 The affinities and selectivities for oxyanions were determined using UV/vis titration techniq

299 tion of outer-sphere complexes for all three oxyanions with increasing Al substitution.

300 es such as basaluminite for As(V) and Se(VI) oxyanions, with adsorption capacities on the same order