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1 t concentrate catalytically active levels of palladium.
2 th 2:1 and 1:1 stoichiometry with respect to palladium.
3 al catalysts including those of rhodium(II), palladium(0 and II), silver(I), mercury(II), copper(I an
4 , including promotion of direct oxidation of palladium(0) by O2, bypassing the typical requirement fo
5 s, derived from allylic ester carbonates and palladium(0) catalyst, were found to undergo the Friedel
9 a highly efficient incorporation procedure, palladium-103, a brachytherapy radioisotope in clinical
11 aminone precursors in the presence of either palladium acetate/cupric acetate catalytic system under
12 catalytic system under oxygen atmosphere or palladium acetate/silver carbonate in the presence of pi
15 we report a 2-pyridone ligand that binds to palladium and accelerates non-directed C-H functionaliza
17 y inhomogeneous surfaces comprising of gold, palladium and nickel were generated on copper substrates
18 ations using ZoI assays, gold/platinum, gold/palladium and platinum/palladium were indicative of syne
19 tion catalyst that combines highly dispersed palladium and ultrafine molybdenum phosphate nanoparticl
20 ymethyl cellulose (CMC) coating, addition of palladium, and other iron species as metal surfaces on t
26 regioselective alpha- and gamma-arylation of palladium azapentadienyl intermediates is presented.
27 single synthetic protocol to obtain uniform palladium-based bimetallic nanocrystals (PdM, M = V, Mn,
28 nced platinum alloys, core-shell structures, palladium-based catalysts, metal oxides and chalcogenide
30 at by incorporating trace amounts of gold in palladium-based ternary (Pd6CoCu) nanocatalysts, the dur
31 r and stable aromatic backbone with multiple palladium binding sites to engineer the controlled synth
34 ent, Cp*2Yb, with bipyrimidine (bipym) and a palladium bis-alkyl fragment, PdMe2, allows the rapid fo
37 ly in the latter case, where coordination of palladium by the pyridine is hindered, 3'-halogenation d
42 rends between the charge distribution at the palladium-carbon interface and the metal's selectivity f
43 at conformation of the substrates to achieve palladium-catalysed amine-directed conversion of C-H bon
44 Here we report a straightforward method for palladium-catalysed arylation of aryl(heteroaryl)methane
48 When an allenic sulfone is treated under palladium catalysis in the presence of a weak acid, isom
49 n and alkenyl nucleophiles that couple under palladium catalysis leading to sp-, sp(2) -, and sp(3) -
50 eact with alpha-aryl-alpha-diazoesters under palladium catalysis to form alpha-(N-indolyl)-alpha-aryl
51 acted with aromatic and vinyl halides, under palladium catalysis, to produce 4-substituted homopropar
55 amma positions proceeds in the presence of a palladium catalyst and a catalytic amount of amino acid.
56 d by C-C bond formation when the appropriate palladium catalyst and alpha-fluoro enolate precursor we
58 kinetic analysis of CO2 hydrogenation over a palladium catalyst in order to address the factors gover
60 n with aromatic halides in the presence of a palladium catalyst with exceptionally high levels of ste
67 cial charge distribution in carbon-supported palladium catalysts with consequential changes in hydrog
68 nd allylic carbonates, engaging vanadium and palladium catalysts, is an exemplary case of a cooperati
69 e design and application of cancer-targeting palladium catalysts, with their specific uptake in brain
74 lene acceptor groups can be synthesized by a palladium catalyzed copolymerization between 9,10-dibrom
75 hydrocarbon embedded ladder polymers using a palladium catalyzed cyclopentannulation polymerization f
76 acid acceptor were synthesized by utilizing palladium catalyzed direct (hetero)arylation reaction.
83 erent ligands that have been used to support palladium-catalyzed aerobic oxidation reactions and, whe
85 of substituted gamma- and delta-lactams via palladium-catalyzed alkene carboamination reactions betw
86 his study describes the first para-selective palladium-catalyzed alkenylation of tertiary amines.
89 isubstituted allylic N-arylamines based on a palladium-catalyzed allylic amination has been developed
90 y from 2-halobenzoates and ketones through a palladium-catalyzed alpha-arylation step followed by an
91 e tricyclic tetrahydrocarbazolone core via a palladium-catalyzed amination and oxidative indole forma
93 orward synthesis of 2-amidoglycals through a palladium-catalyzed aminocarbonylation reaction between
98 A continuous-flow synthesis of aziridines by palladium-catalyzed C(sp(3) )-H activation is described.
100 Synthesis was achieved through efficient palladium-catalyzed C-H activated annulation between abu
102 itroquinoxaline, are shown to undergo facile palladium-catalyzed C-H direct arylation with a variety
104 nistic insight, a new ligand (EPhos) for the palladium-catalyzed C-N cross-coupling between primary a
105 opment of a general catalytic system for the palladium-catalyzed carbocyclization of unactivated alky
108 nones is described applying a four-component palladium-catalyzed carbonylative coupling of aryl boron
109 aroylquinolin-4(1H)-ones, prepared through a palladium-catalyzed carbonylative cyclization of N-(2-io
113 y rhodium-catalyzed alkyne hydroboration and palladium-catalyzed coupling reactions of E-1,2-dichloro
115 me, we report the use of bromo-carboranes in palladium-catalyzed cross-coupling for efficient B-N, B-
117 and validated for effective room-temperature palladium-catalyzed cross-coupling reactions (CCRs) of a
118 uted indene derivatives through conventional palladium-catalyzed cross-coupling reactions and iodine-
119 promise as reaction media for thermomorphic palladium-catalyzed cross-coupling reactions is demonstr
120 o-functionalized IF-TTF building block using palladium-catalyzed cross-coupling reactions, such as th
125 ion of unsaturated secondary lactams via the palladium-catalyzed cyclization of O-phenyl hydroxamates
126 es has been achieved in 39-94% yield through palladium-catalyzed cyclocondensation of aryl/vinyl iodi
127 s of alpha-chloro ketones and pyrazoles, and palladium-catalyzed cyclopropanation reactions on labora
129 ihydroxylation step followed by a late-stage palladium-catalyzed decarboxylation-allylation procedure
130 amide enolates and of a (2) enantioselective palladium-catalyzed decarboxylative allylic alkylation r
131 origin of an enantiodivergent effect in the palladium-catalyzed decarboxylative asymmetric protonati
132 sted Liebeskind-Srogl C-C cross-coupling and palladium-catalyzed decarboxylative coupling reactions.
134 d at 6,7,13,14-positions are synthesized via palladium-catalyzed dialkylacetylene insertion/C-H aryla
136 nstruction of a C(aryl)-C(sp(3)) bond by the palladium-catalyzed direct allylation of arenes with all
140 he synthesis of alpha-ketoamide compounds by palladium-catalyzed double-carbonylative amination react
144 have been prepared with each subjected to a palladium-catalyzed intramolecular Alder-ene (IMAE) reac
145 rther converted into phenanthrothiazoles via palladium-catalyzed intramolecular direct arylation.
146 a chiral BINOL derivative was followed by a palladium-catalyzed Mizoroki-Heck cyclization, resulting
152 cess of iridium-catalyzed C-H borylation and palladium-catalyzed ortho-C-H arylation directed to acce
155 of overall four C-C bonds and proceeds via a palladium-catalyzed oxidative transformation with insert
156 uoro-3-methylphenol in six steps featuring a palladium-catalyzed phenyl carboxylation in the last ste
162 sing arenophile cycloaddition and subsequent palladium-catalyzed substitution with nonstabilized lith
164 INOL derivatives is accomplished through the palladium-catalyzed Suzuki-Miyaura coupling of the unpro
165 zation and tosylate formation, followed by a palladium-catalyzed Suzuki-Miyaura cross-coupling of the
169 Compounds such as 20 were prepared using a palladium-catalyzed Ullmann cross-coupling reaction betw
170 ituted cyclohexenone 12, generated through a palladium-catalyzed Ullmann cross-coupling reaction betw
171 ich is readily prepared through an efficient palladium-catalyzed Ullmann cross-coupling reaction, is
175 ssembled by addition of a slight excess of a palladium chelator, and the interaction can be reversibl
176 n of nitrogen tethered alkenols catalyzed by palladium chloride leads to substituted morpholines in g
177 nd that the ground state structures of small palladium clusters are more sensitive to the charge stat
180 nnels of the ultrapure two-dimensional metal palladium cobaltate (PdCoO2) has a large viscous contrib
181 ,4-ethylenedioxythiophene (EDOT-BPI) and its palladium complex (EDOT-PdBPI) were synthesized and char
182 spensable to the enzyme immobilization, with palladium complex bearing monomer, which is mediate the
184 alpha-fluoro carbonyl compounds catalyzed by palladium complexes have been reported, but palladium fl
186 ates with alpha-fluoroindanones catalyzed by palladium complexes of a BINOL-derived monophosphine and
187 rphyrin and carbachlorin, and the nickel and palladium complexes, were characterized by X-ray crystal
188 reaction promotes the formation of dinuclear palladium complexes, wherein only a single metal center
189 utations of noble and base metals (platinum, palladium, copper, nickel, and cobalt) were synthesized
191 (II)Cl2(o-dppp)2] (o-dppp = o-(Ph2P)C6H4), a palladium dichloride complex featuring a Lewis acidic tr
192 suggest that acetophenone is formed from the palladium enolate intermediate by protonation from H2O2.
193 mpetitive processes, one of which involves a palladium enolate intermediate that has not been previou
194 l hydroperoxide and found that, although the palladium enolate intermediate was observed, it was not
195 palladium complexes have been reported, but palladium fluoroenolate intermediates relevant to such r
196 dicates that the use of plants to accumulate palladium for industrial applications has the potential
197 hese species were able to grow, and take up, palladium from both synthetic and mine-sourced tailings.
198 ic assays against biofilms demonstrated gold/palladium, gold/platinumand platinum/palladium resulted
199 elective label free colorimetric assay using palladium-gold nanorod as nanozyme is reported for malat
200 tudy demonstrated the catalytic potential of palladium-gold nanorods, which can be employed as nanozy
205 both the Cl(-) and H(+) and is catalyzed by palladium(II) acetate, with loadings as low as 25 ppm.
208 um(II) acetate to give excellent yields of a palladium(II) complex that showed weakly diatropic prope
209 s the C-bound isomer of the ligand-supported palladium(II) complexes and leads to significantly impro
212 us hydrogen peroxide (H2O2) and the cationic palladium(II) compound, [(PBO)Pd(NCMe)2][OTf]2 (PBO = 2-
213 then encapsulating bis[tri(2-furyl)phosphine]palladium(II) dichloride in a biocompatible poly(lactic-
214 scopic studies and isotope effects support a palladium(II) hydride-mediated pathway and reveal crucia
217 ll-defined metal polypyridyl complexes and a palladium(II) salt to form electrochemically addressable
218 of a substituted pyrazole ring catalyzed by palladium(II) was straightforward and convenient for ary
219 er(III), silver(III), gold(III), nickel(II), palladium(II), platinum(II), rhodium(III), iridium(III),
220 nce of a preformed biarylphosphine-supported palladium(II)-aryl complex and a weak base, lysine amino
222 methyl)arylmethylamines that consists of the palladium(II)-catalyzed addition of arylboroxines to imi
223 f isochroman motifs has been accomplished by palladium(II)-catalyzed allylic C-H oxidation from termi
231 ays where electron-rich substrates undergo a palladium(II)-catalyzed decarboxylation and electron-def
232 the first example of kinetic resolution by a palladium(II)-catalyzed enantioselective C-H activation
235 strained cyclic dienes were accomplished via palladium(II)-catalyzed oxidative cyclizations of termin
236 trocyclization pathway was demonstrated by a palladium(II)-catalyzed oxidative homocoupling/8pi-elect
237 ienyne complexes were readily synthesized by palladium(II)-catalyzed oxidative macrocyclizations of b
238 lic C-H amination reaction is reported under palladium(II)/bis-sulfoxide/Bronsted base catalysis.
239 We demonstrate that the minimum level of palladium in Arabidopsis dried tissues for catalytic act
242 onates and organolithium reagents, engage in palladium-induced metallate rearrangement wherein 1,2-mi
243 hyl quinoline ligands that enable asymmetric palladium insertion into prochiral C-H bonds on a single
244 ble desymmetrization of isopropyl groups via palladium insertion into the C(sp(3))-H bonds of one of
245 ligand, the reaction proceeds via an alkoxy palladium intermediate that increases the proton acidity
246 the chain ends, small molecule ligands, and palladium ions; polyMOCs are formed via metal-ligand coo
252 dition, through experiments on gram scale in palladium, mechanistically important additional Pd- and
253 original methods including electrophilic or palladium-mediated cyclization of unsaturated hydroxylam
255 the pathway was concluded to be initiated by palladium metal catalyzed partial hydrogenation of the p
256 nic replacement reaction was carried out for palladium modification on template electrodeposited copp
258 ding skyrmions in an exchange-coupled cobalt/palladium multilayer at room temperature with Lorentz tr
259 cavitation process that can transform solid palladium nanocrystals into hollow palladium nanocrystal
260 orm solid palladium nanocrystals into hollow palladium nanocrystals through insertion and extraction
263 tion-the hydrogenation of single-crystalline palladium nanocubes from 15 to 80 nm-to better understan
264 rings in the para-position were prepared by palladium nanoparticle-catalyzed Suzuki-Miyaura cross-co
267 N-acetylcysteine- and l-cysteine-stabilized palladium nanoparticles are introduced, and carbon polar
268 was 160 nm, demonstrating that non-spherical palladium nanoparticles coupled with 2D MXene yield a br
269 n one-step hybridization of silver, gold and palladium nanoparticles from solution onto exfoliated tw
270 tion was investigated indicating that 1-5 nm palladium nanoparticles may serve as the active catalyst
273 vity comparable to commercially available 3% palladium-on-carbon catalysts was achieved from dried pl
274 that required for commercially available 3% palladium-on-carbon catalysts, this study both sets the
275 horylation of a wide range of amides using a palladium or nickel catalyst giving aryl phosphonates in
276 on of hydrogenocarbonate ions on metals like palladium or platinum, a model is developed that allows
279 entity of three different species containing palladium-oxygen-boron linkages, a tricoordinate boronic
280 demonstrate the NHC being coordinated to the palladium particles and affecting their electronic prope
282 is selective cathode with a carbon-supported palladium (Pd/C) anode to establish a membrane-free, roo
283 ying energetic minima of neutral and charged palladium Pdn(Q) (n = 2-20, Q = 0, + 1 and -1) clusters
284 phosphorus from the compound nanocrystals of palladium phosphide and consequently the inward diffusio
285 tionalization of cyclic 1,3-dienes where the palladium plays a remarkable dual role, catalyzing both
286 more sustainable alternative to traditional palladium precatalysts for the Suzuki-Miyaura coupling r
287 ts, and, most importantly, the nature of the palladium precursor and the choice of the phosphine liga
288 s cell membranes on its own, addition of the palladium reagent induces an efficient cell internalizat
289 ed gold/palladium, gold/platinumand platinum/palladium resulted in the greatest antimicrobial efficac
293 ed investigation of the catalytically active palladium species pointed toward a dual role of the NHC
295 lladium hydride, generated from insertion of palladium to O-H of an allyl alcohol, that is responsibl
298 olutions (silver, copper, platinum, gold and palladium) were determined individually and in combinati
299 ption resonances the spatial distribution of palladium (with average elemental concentration of 0.4
300 ical genosensor based on Zinc oxide/platinum-palladium (ZnO/Pt-Pd) modified fluorine doped tin oxide
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