ライフサイエンスコーパス: phenanthrene

1 and a pi-bonding pattern similar to that in phenanthrene.

2 ght to arise from epoxidation of some of the phenanthrene.

3 er of 19.7 kcal/mol, and then reoxidation to phenanthrene.

4 nged the region of oxidation of biphenyl and phenanthrene.

5 ignificant effects on product formation from phenanthrene.

6 hanged the site of oxidation of biphenyl and phenanthrene.

7 d altered regioselectivity with biphenyl and phenanthrene.

8 droponic systems with high concentrations of phenanthrene.

9 the plants against the phytotoxic effects of phenanthrene.

10 ed and naturally occurring 4,5-disubstituted phenanthrenes.

11 by naphthalene, phenanthrene, and alkylated phenanthrenes.

12 ydride, the diindeno-fused 4H-cyclopenta[def]phenanthrenes 13-15 in a single operation.

13 Systems studied were 1-methylcyclopenta[def]phenanthrene 2, 11H-benz[bc]aceanthrylene 8, 5H-benzo[b]

14 ydroxy-1,2-dihydro-6-methylchrysene, benzo[c]phenanthrene, 2-amino-6-methyldipyridol[1,2-a:3',2'-d]im

15 ino-5-phosphonopentanoic acid (D-AP5) and 1-(phenanthrene-2-carbonyl)piperazine-2,3-dicarboxylic acid

16 result from trans opening at C-1 of benzo[c]phenanthrene 3,4-diol 1,2-epoxide (B[c]PhDE) isomers (i.

17 epoxide (BaP DE) and dA adducts from benzo[c]phenanthrene 3,4-diol 1,2-epoxide (BcPh DE) on DNA repli

18 s-opening at C-1 of the enantiomeric benzo[c]phenanthrene 3,4-diol 1,2-epoxides in which the epoxide

19 g]chrysene, 3,4-dihydroxy-3,4-dihydrobenzo[c]phenanthrene, 3-amino-1,4-dimethyl-5H-pyrido[4,3-b]indol

20 ysis (FS-FVP) method afforded cyclopenta[def]phenanthrene 31 and cyclopenta[jk]fluorene 52 as the pri

21 yclotris[(2,9-bis[trans-Pt(PEt(3))(2)(PF(6))]phenanthrene)(4,4'-dipyridyl)], and cyclotris[bis[cis-Pt

22 uanine adduct of the tumorigenic (-)-benzo[c]phenanthrene 4R,3S-diol 2S,1R-epoxide in the gap.

23 NO3]anthracene 3, 2,9-bis[trans-Pt(PEt3)2NO3]phenanthrene 5, and cis-Pt(PEt3)2(NO3)2 unit 6.

24 converted to isomeric 5- and 6-fluorobenzo[c]phenanthrene, 5-and 6-fluorochrysene, and 9- and 10-benz

25 hapes, X-ray data for 5- and 6-fluorobenzo[c]phenanthrene, 6-fluorochrysene, 9- and 10-fluorobenzo[g]

26 e final products being phenanthrene (P1) and phenanthrene 9,10-oxide (P3), the latter being thought t

27 11b-hexahydro-3-thia-5-azacyclopent-1-ena[c]phenanthrene-9,10-diol (5) emerged as the compound with

28 dro-2-propyl-3-thia-5-azacyclopent-1-ena[c ]-phenanthrene-9,10-diol (A86929)]; isochromans [(1R,3S)-3

29 gested by the presence of the dione product, phenanthrene-9,10-dione (P2), thought to arise from furt

30 stereoselectivity toward (2R)-1, (2S)-1, and phenanthrene-9,10-oxide, suggesting that modifications a

31 Here we show that phenanthrene, a PAH with a benzene 3-ring structure, is

32 for automerization of outer ring carbons in phenanthrene, a reaction demonstrated previously by Bala

33 The performance of phenanthrene adsorption on FA and the effects of various

34 tion was also responsible for the changes of phenanthrene adsorption on FA in the presence of HA.

35 he presence of NaC (both 100 and 8000 mg/L), phenanthrene adsorption on graphene was decreased due to

36 on of multilayer graphene and its effects on phenanthrene adsorption were investigated using a passiv

37 inity and blocking capacity, naphthalene and phenanthrene aldehydes were the most potent effectors.

38 within the anthracene nucleus of azonafide; phenanthrene analogues, in which the linear anthracene n

39 clopentylidene-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene and 1-cyclobutylidene-1a,9b-dihydro-1H-cycl

40 etection were determined to be 0.14 fmol for phenanthrene and 4 amol for caffeine and to a printed ca

41 PAHs leading to more complex structures like phenanthrene and anthracene at temperatures down to 10 K

42 five-ring PAHs as well as alkylated forms of phenanthrene and anthracene in grass and wood chars prod

43 al mutant in native form and in complex with phenanthrene and anthracene, along with those of wild-ty

44 The major PAH species formed were phenanthrene and anthracene, and emissions were sensitiv

45 The phenanthrene and azaphenanthrene analogues showed no imp

46 ized by elevated dissolved concentrations of phenanthrene and benzo(g,h,i)fluoranthene.

47 to derivatives containing peripherally fused phenanthrene and benzo[g]chrysene units.

48 ept, the NAIMS technique has been applied to phenanthrene and caffeine samples for which the limits o

49 We have found these cyclopenta[ b]phenanthrene and cyclopenta[ b]anthracene analogues to h

50 , to give derivatives of tricyclic fluorene, phenanthrene and dibenzo[7]annulene, respectively, with

51 ed statistically significant synergy between phenanthrene and drought (p < 0.0001).

52 aimed at determining the combined effects of phenanthrene and drought on the survival of the terrestr

53 f magnitude, from 0.017 to 658 mug L(-1) for phenanthrene and from 0.006 to 90.0 mug L(-1) for fluora

54 rillonite samples were loaded with pyrene or phenanthrene and ground manually or in a ball mill for s

55 hree distinct antibody clones that recognize phenanthrene and methylphenanthrenes were selected, and

56 hapten markers for petroleum contamination (phenanthrene and methylphenanthrenes).

57 exfoliation weakened the competition between phenanthrene and NaC and enhanced the adsorption capacit

58 and contained a broad gene set for degrading phenanthrene and naphthalene.

59 tals with polyaromatic hydrocarbons, such as phenanthrene and picene, but the composition and structu

60 The DIs of phenanthrene and pyrene (> 10 mug/day) in the population

61 most abundant chemicals found in films were phenanthrene and pyrene (22%), followed by perylene (21%

62 urfactant on biodegradation of (14)C-labeled phenanthrene and pyrene under desorption-limiting condit

63 iori parameter uncertainty distributions for phenanthrene and pyrene, and leads to higher values for

64 pyrene, and the oxidation rate constants for phenanthrene and pyrene.

65 en-1-yl)propan-2-ol in benzene-d(6) afforded phenanthrene and the beta-hydroxycarbene intermediate 2-

66 ihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzo[c]phenanthrene and the corresponding (-)-(1R,2S,3S,4R) iso

67 es, sterically overcrowded 4,5-disubstituted phenanthrenes and phenanthrene-based alkaloids.

68 s presorbed with pollutants (nonylphenol and phenanthrene) and additive chemicals (Triclosan and PBDE

69 thesized such that an energy transfer donor (phenanthrene) and an energy transfer acceptor (anthracen

70 aphthalene, 3.84 +/- 1.47 mg m(-2) d(-1) for phenanthrene, and 2.46 +/- 0.86 mg m(-2) d(-1) for pyren

71 ed percent of the naphthalene, fluorene, and phenanthrene, and 46% of the chrysene in the oil were bi

72 PAH profiles were dominated by naphthalene, phenanthrene, and alkylated phenanthrenes.

73 Levels of benzo[a]pyrene, phenanthrene, and carcinogenic potency of PAH mixtures w

74 change in culture media containing fluorene, phenanthrene, and fluoranthene.

75 enolic metabolites of naphthalene, fluorene, phenanthrene, and pyrene in human urine.

76 ic aromatic hydrocarbons (PAHs) naphthalene, phenanthrene, and pyrene.

77 dominated by gas-phase fluoranthene, pyrene, phenanthrene, and retene.

78 f inene, naphthalene, phenalene, anthracene, phenanthrene, and triphenylene have been observed.

79 and mixed brominated/chlorinated anthracenes/phenanthrenes, and pyrenes/fluoranthenes (Cl-PAHs and X-

80 e of wild-type NDO-O(9816-4) in complex with phenanthrene, anthracene, and 3-nitrotoluene, are presen

81 oxidize biphenyl, the LMW PAHs naphthalene, phenanthrene, anthracene, and fluorene, and the HMW PAHs

82 Relative standard deviations were <30% for phenanthrene, anthracene, fluoranthene, and pyrene imply

83 Hs) (acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, and pyrene) from

84 Naphthalene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benz[a]a

85 d the presence of seven compounds: fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)

86 d the presence of seven compounds: fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)

87 th macrophages and fibroblasts, DEP extract, phenanthrene, anthracene, phenanthrenequinone, and beta-

88 of methoxy/hydroxy-substituted naphthalenes, phenanthrenes, anthracenes, etc. with Oxone in an aceton

89 tion of anti-diol epoxide isomers of benzo[c]phenanthrene (anti-B[c]PDE) was investigated.

90 iol epoxides of benzo[g]chrysene and benzo[c]phenanthrene (anti-BGCDE and anti-BCPDE, respectively).

91 hydroxy-1,2-epoxy-1,2,3,4-tetrahydro-benzo[c]phenanthrene (anti-BPhDE) isomers are diol epoxide metab

92 simplest tricyclic PAHs like anthracene and phenanthrene are still elusive.

93 bstituted naphthalene amino esters including phenanthrene aromatic structural units is described.

94 the activity with naphthalene, biphenyl, and phenanthrene as substrates.

95 roethane, anthracene undergoes conversion to phenanthrene as the major volatile product.

96 repeated using 2-(2,6-dichlorophenyl)benzo[c]phenanthrene as the starting material, benzo[a]corannule

97 This study investigated the adsorption of phenanthrene at the interface of FA and water.

98 ibenz[a,h]anthracene (DB[a,h]A), and benzo[c]phenanthrene (B[c]Ph) by direct chiral stationary-phase

99 bons like benzo[a]pyrene (B[a]P) and benzo[c]phenanthrene (B[c]Ph) impede replication and transcripti

100 Benzo[c]phenanthrene (B[c]Ph), a representative fjord region pol

101 hydroxy-1, 2-epoxy-1,2,3,4-tetrahydrobenzo[c]phenanthrene [(-)-B[c]PhDE; fjord-region diol epoxide] o

102 mperature protonation of substituted benzo[c]phenanthrenes, B[c]Phs, and their charge delocalization

103 rcrowded 4,5-disubstituted phenanthrenes and phenanthrene-based alkaloids.

104 The two most active phenanthrene-based derivatives showed potent in vitro an

105 Moreover, both phenanthrene-based derivatives were active against stage

106 New sulfoximine- and phenanthrene-based photochemical precursors to oxynitren

107 Nineteen new phenanthrene-based tylophorine analogues with various fu

108 We recently reported that phenanthrene-based tylophorine derivative-1 (PBT-1) may

109 C9-Substituted phenanthrene-based tylophorine derivatives (PBTs) (13-36

110 ta[def]chrysene 22), monosubstituted benzo[c]phenanthrenes BcPh (3-methoxy- 23, 3-hydroxy- 24), and m

111 thynylphenyl)naphthalenes to various benzo[c]phenanthrene (BcPh) analogues was accomplished smoothly

112 diol 1,2-epoxide (DE) DNA adducts of benzo[c]phenanthrene (BcPh) at N6 of adenine on helicase activit

113 a]pyrene (BaP) diol epoxide (DE) and benzo[c]phenanthrene (BcPh) DE adducts at deoxyadenosine (dA) or

114 In contrast to BaP, the pair of benzo[c] phenanthrene (BcPh) DE adducts at G(+2), which intercala

115 ntercalating dA adducts derived from benzo[c]phenanthrene (BcPh) DEs inhibit WRN activity in a strand

116 zo[a]pyrene (BaP) series 1 (syn) and benzo[c]phenanthrene (BcPh) series 2 (anti) diol epoxides.

117 ened 3,4-diol 1,2-epoxide adducts of benzo[c]phenanthrene (BcPh) were introduced at single N2-deoxygu

118 lpha,2alpha-epoxy-1,2,3,4-tetrahydrobenzo[c ]phenanthrene [BcPh DE-2 (2)] by hexafluoropropan-2-ol (H

119 ng degrees by benzo[a]pyrene (BP) or benzo[c]phenanthrene (BPh) adducts at purine bases within the 3'

120 diol epoxide metabolites of the PAH benzo[c]phenanthrene (BPh).

121 Sequential hydrogen shifts lead to phenanthrene but with higher cumulative barriers than fo

122 250 min-1 for the R47L/Y51F/F87A mutant with phenanthrene) but the coupling efficiencies were relativ

123 ha-phenanthrene-substituted carbocation from phenanthrene C-1 position.

124 by introducing more conjugated groups to the phenanthrene center.

125 silicone controlled the chemical activity of phenanthrene (chemical stress), while saline solutions c

126 (-)-biphenyl cis-(3S,4R)-dihydrodiol and (-)-phenanthrene cis-(1S,2R)-dihydrodiol from biphenyl and p

127 nzyme also formed the opposite enantiomer of phenanthrene cis-1,2-dihydrodiol from phenanthrene to th

128 f macrocycles consisting of 9,10-substituted phenanthrenes connected by butadiynylene linkers in posi

129 relatively weak, whereas for the triangular phenanthrene-containing structures, there was a clear in

130 Here we isolate the binary caesium salts of phenanthrene, Cs(C14H10) and Cs2(C14H10), to show that t

131 Covalent benzo[a]pyrene-dG and benzo[c]phenanthrene-dA adducts in the template strand are durab

132 ably, adsorbed phosphate increased anaerobic phenanthrene degradation and bzdN catabolic gene prevale

133 sis showed a remarkably higher expression of phenanthrene degradation genes 4 h after inoculation, co

134 This indicates that the cells were active in phenanthrene degradation while experiencing stress.

135 ween %F(rap) and the fractions degraded by a phenanthrene-degrading inoculum (%F(min)) indicated that

136 o predict the bioaugmentation success of the phenanthrene-degrading Novosphingobium sp.

137 (13)C) compound-specific isotope analysis on phenanthrene deposited in a lake from the Athabasca sect

138 ndicates that the radical ion stabilities in phenanthrene derivatives are drastically improved by inc

139 A broad range of functionalized phenanthrene derivatives could be obtained in the presen

140 he corresponding fluorinated naphthalene and phenanthrene derivatives in good yields.

141 c preparation of fluorinated naphthalene and phenanthrene derivatives is described.

142 A range of phenanthrene derivatives were efficiently synthesized by

143 rogenerated chemiluminescence (ECL) of three phenanthrene derivatives, 3,6-diphenyl-9,10-bis-(4-tert-

144 es and decreased nonplanarity in the benzo[c]phenanthrene derivatives, but its influence was most pro

145 Benzo[c]phenanthrene dihydrodiol epoxide (B[c] PhDE) is well kno

146 Benzo[c]phenanthrene diol epoxide (B[c]PhDE), the ultimate carci

147 ically activated to the enantiomeric benzo[c]phenanthrene diol epoxides (B[c]PhDEs), (+)-(1S,2R,3R,4S

148 Across the entire tropical Atlantic Ocean, phenanthrene displayed on average highest dissolved conc

149 nced the adsorption capacity of graphene for phenanthrene due to exposed new sites.

150 ded %F(rap), indicating a fraction of sorbed phenanthrene (%F(slow)) remained microbially accessible.

151 s low activity for the oxidation of the PAHs phenanthrene, fluoranthene and pyrene.

152 humans and the environment in Africa toward phenanthrene, fluoranthene, pyrene, benzo(a)pyrene, 2,3,

153 M-Green to oxidize the three-ring compounds, phenanthrene, fluorene, and anthracene faster than the w

154 and C(4)G3 dendrimers afforded considerable phenanthrene formation, in addition to cis-stilbene, whe

155 Cyclohexanol, phenol, benzoic acid, and phenanthrene fractional removal (italicized words are de

156 ly (%F(rap)) and slowly (%F(slow)) desorbing phenanthrene fractions and their rate constants were det

157 ollowing: conversion of 2-ethynylbiphenyl to phenanthrene, fragmentation of phthalic anhydride to ben

158 There was an additional 25-40% removal of phenanthrene from soil by the willow and grasses, respec

159 avelength absorptions than the corresponding phenanthrene fused structure, although the differences w

160 The [a]phenanthrene-fused BODIPYs 4a-c were characterized by NM

161 hese results suggest the potential use of [a]phenanthrene-fused BODIPYs as NIR bioimaging probes.

162 systems such as naphthalene, anthracene, or phenanthrene generally only produces minor bathochromic

163 or example, FVP of 2-(o-chlorophenyl)benzo[c]phenanthrene gives 1-phenylbenzo[ghi]fluoranthene as the

164 Phenanthrene hardly degraded on Cu-montmorillonite.

165 An efficient synthesis of functionalized phenanthrenes has been developed for the first time invo

166 nally substituted 9-fluorenylidenes and 9,10-phenanthrenes have been synthesized from substituted o-h

167 enanthrol is synthesized in three steps from phenanthrene in 44% overall yield.

168 lling evidence on the efficient synthesis of phenanthrene in carbon-rich circumstellar environments.

169 he desorption kinetics and mineralization of phenanthrene in four soils was investigated after 1, 25,

170 ation of the polycyclic aromatic hydrocarbon phenanthrene in the absence and presence of bacterial fo

171 nic strength corresponded to low mobility of phenanthrene in the FA-water system.

172 Elimination of phenanthrene in the nematodes was biphasic, suggesting t

173 ability to colonize plant roots and degrade phenanthrene in vitro.

174 ous 1,2-diarylethylenes for the synthesis of phenanthrenes in excellent yield has been described.

175 nylethylidene)-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene, in C6H6 (or C6D6), at ambient temperature,

176 1-benzylidene-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene, in deuterated benzene at ambient temperatu

177 on of the substituent groups appended to the phenanthrene increases.

178 on of the substituent groups appended to the phenanthrene increases.

179 nsport in a series of conjugated alternating phenanthrene indenofluorene copolymers.

180 cyclization to form an unstable 8a,9-dihydro-phenanthrene intermediate, followed by exothermic unimol

181 Construction of key phenanthrene intermediates by a Suzuki coupling-Wittig o

182 Conversion of the phenanthrenes into the target structures was projected t

183 Phenanthrene is a ubiquitous pollutant in water and air,

184 Phenanthrene is nearly inert to the same superacid condi

185 n oxidative photocyclization of stilbenes to phenanthrenes is a well-known and synthetically valuable

186 ased ligands; A = 2,9-bis[trans-Pt(PEt3)2NO3]phenanthrene) is described with emission wavelengths spa

187 cenaphthene C12H10 (L2); anthracene (L3) and phenanthrene (L4), C14H10; pyrene (L5) and fluoranthene

188 Our findings therefore suggest that phenanthrene may be a major worldwide cause of vertebrat

189 7, 8-Benzoflavone activation of phenanthrene metabolism by CYP3A4 and dapsone activation

190 It differed from the (-)-trans-anti-benzo[c]phenanthrene-N(2)-dG adduct having S stereochemistry at

191 eoisomeric "fjord" region trans-anti-benzo[c]phenanthrene-N2-guanine (designated (BPh)G) adducts posi

192 Importantly, neither phenanthrene nor anthracene (C14 H10 ) was found, which

193 r anthracene nucleus is replaced by the bent phenanthrene nucleus; and azaphenanthrenes.

194 The adsorption of phenanthrene onto FA was noted to be spontaneous at all

195 The efficient preparation of Sn-substituted phenanthrenes opens access to convenient building blocks

196 Pyrrole dialdehydes with fused phenanthrene or acenaphthylene rings also reacted with 1

197 been observed for their fjord-region benzo[c]phenanthrene or bay-region benzo[a]pyrene analogues.

198 th an aromatic hydrocarbon (either biphenyl, phenanthrene, or naphthalene).

199 oximately 1.5 per thousand) in delta(13)C of phenanthrene over the last three decades pointed to an i

200 aturation activity, the final products being phenanthrene (P1) and phenanthrene 9,10-oxide (P3), the

201 1-methylanthracene (1-MA), phenanthrene (PA), and benzo(a)pyrene (B(a)P) caused sig

202 .e., alpha- and gamma-hexachlorocyclohexane, phenanthrene, PCB-18 and PCB-52) in samples collected at

203 veloped and applied for the determination of phenanthrene (PHE) and pyrene (PYR) in chrysanthemum tea

204 s fluoranthene (FLA), naphthalene (NAP), and phenanthrene (PHE) as sole carbon sources for energy and

205 with decay) and tested it with three aerobic phenanthrene (PHE) degraders: Novosphingobium pentaromat

206 co-metabolically degraded up to 1.8 mumol of phenanthrene (PHE) in approximately 48 h, and hydroxyphe

207 demonstrated the uptake and accumulation of phenanthrene (PHE) in lipid vesicles and its active tran

208 nature of mixtures of Cu, Cd, V, or Ni with phenanthrene (PHE) or phenanthrenequinone (PHQ) using th

209 ry mixtures of Cu, Cd, Ni, or V, with either phenanthrene (PHE) or phenanthrenequinone (PHQ).

210 laboratory microcosm with passive dosing of phenanthrene (PHE) to a model soil-atmosphere interface

211 heir sorption of dibutyl phthalate (DBP) and phenanthrene (PHE) were investigated in this study.

212 Ss) were exposed to atmospheric pollution by phenanthrene (PHE), a gaseous PAH, for 2 weeks in exampl

213 ferent volatilities, we conduct analyses for phenanthrene (PHE), pyrene (PYR), and benzo[a]pyrene (Ba

214 ree polycyclic aromatic hydrocarbons (PAHs): phenanthrene (PHE), pyrene (PYR), and benzo[a]pyrene (Ba

215 n the (1)H NMR spectrum, suggesting that the phenanthrenes pi-stack on coordination of silver(I).

216 en 20- and 100-fold for clones that bound to phenanthrene-protein conjugates.

217 below the minimum measured concentrations of phenanthrene, pyrene, and benzo(a)pyrene in the environm

218 purine adducts of PAHs, such as naphthalene, phenanthrene, pyrene, and chrysene, could be prepared by

219 Symmetric meso-tetraarylporphyrins bearing phenanthrene, pyrene, and corannulene moieties in meta p

220 tions of PAHs across the entire cruise, with phenanthrene, pyrene, and fluoranthrene all >1 ng L(-1).

221 ived from naphthalene, fluorene, anthracene, phenanthrene, pyrene, fluoranthene, chrysene, and benzo[

222 plexation, which were measured in DMF-d7 for phenanthrene, pyrene, triphenylene, and coronene by dyna

223 tures (e.g., total monomethylphenanthrene to phenanthrene ratios, MP/P ~2-3) at intermediate temperat

224 olite of the environmental pollutant benzo[c]phenanthrene, reacts with DNA primarily at the exocyclic

225 wed as all-boron analogues of anthracene and phenanthrene, respectively.

226 ne cis-(1S,2R)-dihydrodiol from biphenyl and phenanthrene, respectively.

227 The structure reveals that the phenanthrene ring system is stacked with the base pair i

228 the cyclopenta[b]anthracene and cyclopenta[b]phenanthrene ring systems (two synthetic routes).

229 arbaporphyrins with fused acenaphthylene and phenanthrene rings have been prepared, and the former de

230 s applied to the regioselective synthesis of phenanthrenes ( Scheme 2 ).

231 p. LH128 was examined after inoculation into phenanthrene spiked soil.

232 ihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzo[c]phenanthrene stereoisomer, in which intercalation is als

233 )(), providing the first example of an alpha-phenanthrene-substituted carbocation from phenanthrene C

234 (petrogenic) versus unmethylated (pyrogenic) phenanthrenes; such antibodies will be useful in detecti

235 We have taken the cyclopenta[ b]phenanthrene (tetracyclic compounds with a nonlinear rin

236 graphene had higher adsorption capacity for phenanthrene than carbon nanotube and graphite due to th

237 ining a heavy fuel spiked with (14)C-labeled phenanthrene that were incubated in the presence or abse

238 naphthalen-2-yl)-9,10-bis(4-tert-butylphenyl)phenanthrene (TnaP, T2), and 3,6-di(pyrene-1-yl)-9,10-bi

239 The binding affinity of phenanthrene to FA increased after the addition of humic

240 ions for the PAHs benzo[a]pyrene, pyrene and phenanthrene to simulated spatially resolved concentrati

241 lied that diffusive exchange was a source of phenanthrene to surface waters, while acenaphthylene vol

242 mer of phenanthrene cis-1,2-dihydrodiol from phenanthrene to that formed by biphenyl dioxygenase from

243 n kinetics of typical wastewater pollutants (phenanthrene, tonalide, and benzophenone) at different d

244 n the nematodes or that biotransformation of phenanthrene took place.

245 s, 3,6-diphenyl-9,10-bis-(4-tert-butylphenyl)phenanthrene (TphP, T1), 3,6-di(naphthalen-2-yl)-9,10-bi

246 -di(pyrene-1-yl)-9,10-bis(4-tert-butylphenyl)phenanthrene (TpyP, T3), are investigated in an acetonit

247 ketone rearrangement and the benzopinacol to phenanthrene transformation suggest that the complex has

248 yclobutylidene-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene undergo photolysis in solution at ambient t

249 dramatically enhanced the mineralization of phenanthrene, up to 30 times greater than the rate witho

250 drocarbons (PAHs), exemplified by pyrene and phenanthrene, using mild grinding in the presence of com

251 however, biofilm formation was incipient and phenanthrene was mineralized following zero-order kineti

252 nhibition of 7, 8-benzoflavone metabolism by phenanthrene was observed.

253 Phenanthrene was shown to bind in a different orientatio

254 Even with food present, dissolved phenanthrene was still the major contributor to bioaccum

255 quinone, the K-region oxidation product from phenanthrene, was formed.

256 Naphthalene, retene, and phenanthrene were consistently the highest measured PAHs

257 not detected in the samples, naphthalene and phenanthrene were detected in all of them.

258 nd 0.78 mug kg(-1)) and both naphthalene and phenanthrene were found in two commercial guarana powder

259 The dimethoxy-substituted benzo[c]phenanthrenes were demethylated with BBr3 and oxidized t

260 ates, one based on biphenyl and the other on phenanthrene, which have different degrees of planarity

261 the same conditions, FVP of 2-phenylbenzo[c]phenanthrene, which lacks a radical precursor, gave prim

262 emperature thermal rearrangement can lead to phenanthrene, which was the major product observed by Br

263 increasing trend in the adsorbed amounts of phenanthrene, while a stepwise pattern was apparent.

264 because the bacterial strain alone degraded phenanthrene with sigmoidal kinetics but could not degra