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1 is synthesized from the amino acid Phe, via phenylpyruvate.
2 ay from a precursor other than Phe, possibly phenylpyruvate.
3 ; no turnover is observed in the presence of phenylpyruvate.
4 his specificity is the alternative substrate phenylpyruvate.
5 esis, the transamination of phenylalanine to phenylpyruvate.
6 nine and tyrosine are synthesized either via phenylpyruvate/4-hydroxyphenylpyruvate or via arogenate.
7 ndence of the kcat/Km for the enolization of phenylpyruvate (6.0 +/- 0.1) are comparable and in reaso
8 ng with shikimate also led to prephenate and phenylpyruvate accumulation and a partial recovery of th
10 outcome of the work is the confirmation that phenylpyruvate acts as the intermediate in the synthesis
11 hat interconverts the enol and keto forms of phenylpyruvate and (p-hydroxyphenyl)pyruvate and convert
13 ne and tryptophan are first deaminated (to 3-phenylpyruvate and 3-indolepyruvate, respectively) and t
14 ral basis for the affinity of native MDH for phenylpyruvate and a rationale for the improved catalyti
17 ared role in the light-mediated synthesis of phenylpyruvate and Phe, because they are iteratively int
18 fic role in blue light-mediated synthesis of phenylpyruvate and subsequently of phenylalanine (Phe).
19 ase (CHMI), and catalyzes the enolization of phenylpyruvate and the ketonization of (p-hydroxyphenyl)
20 -naturally occurring D-isomer of dopachrome, phenylpyruvate, and certain catecholamines, suggesting t
22 eraction with a carboxylate oxygen at C-1 of phenylpyruvate, and it may be partially responsible for
23 from phenylalanine via its transamination to phenylpyruvate, and mining of the transcriptome identifi
25 riant with Asn101Va1102 is as efficient with phenylpyruvate as is the wild-type enzyme (Asn101Gln102)
26 e contribution of an alternative pathway via phenylpyruvate, as occurs in most microbes, has not been
28 n summer as a heat adaptation that uses rose phenylpyruvate decarboxylase (RyPPDC) as a novel enzyme.
31 ynthesized from prephenate exclusively via a phenylpyruvate intermediate in model microbes, the alter
32 ertainty as to whether plants use arogenate, phenylpyruvate, or both as obligatory intermediates in P
33 contained 76, 74, and 42% lower activity for phenylpyruvate, p-hydoxyphenylpyruvate, and indolepyruva
34 ow that plants also utilize a microbial-like phenylpyruvate pathway to produce phenylalanine, and flu
36 ponsible for the light-mediated synthesis of phenylpyruvate, Phe, and those metabolites that derive f
40 ized from prephenate via an arogenate and/or phenylpyruvate route in which arogenate dehydratase (ADT
46 ory perception (olfactory receptors, OR) and phenylpyruvate tautomerase/dopachrome isomerase activity
48 omers {2-keto-3-[2H]-4-pentenoate and 3-[2H]-phenylpyruvate}, where the (3R)-isomers predominate.
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