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1 n hydrosilane and B(C6F5)3 but zero-order in phosphine.
2 ion is highly dependent on the nature of the phosphine.
3 these, and other, decomposition products of phosphine.
4 diene, 9,10-dihydroanthracene, and triphenyl phosphine.
5 u complexes 1 and 3 featuring a bifunctional phosphine.
6 tly observed superconductivity in compressed phosphine.
7 ted shapes by judicious choice of thiols and phosphines.
8 ability of ketene complexes with monodentate phosphines.
9 on starting from InCl3 and tris(dialkylamino)phosphines.
10 primary and secondary alkyl/aryl diamantane phosphines.
11 simple Lewis base adducts with electron-rich phosphines.
12 n between cyclopropenones and functionalized phosphines.
13 ne adducts are isoelectronic with amines and phosphines.
14 aintain robust reactivity with bioorthogonal phosphines.
15 in we report a protocol that is catalytic in phosphine (1-phenylphospholane) employing phenylsilane t
16 selenium-sulfur bond by tris(2-carboxyethyl)phosphine; (2) stabilize the newly formed intermediate s
17 sence of an L-threonine-derived bifunctional phosphine, 3,4-dihydropyrans were obtained in high yield
18 Under the latter conditions, the fluorous phosphines 3a,b that must dissociate to generate the act
21 undergoes intermolecular nitrene transfer to phosphine, abstracts H atoms from weak C-H bonds (1,4-cy
22 ](2+) (1), in combination with a Lewis basic phosphine, acts as a purely phosphorus-based frustrated
23 n may also be accomplished through exogenous phosphine additives, therefore allowing the tuning of re
26 13)C labeled CO, and exchange reactions with phosphines afford the corresponding (phosphino)phosphini
27 (3)-Csp(3) activation, by abstraction of the phosphine, an example of regulated, reversible alkyl mig
28 f methane, 2 equiv from deprotonation of the phosphine and 2 equiv from C-H bond activation of one me
32 vergent processes, one catalyzed by a chiral phosphine and the other by a chiral Pd/phosphine complex
33 d Ag67 NC facilitated by the combined use of phosphine and thiol paves the way for synthesizing other
34 y form heteroleptic complexes containing two phosphine and two nitrogen donors due to steric factors.
35 cies is able to transfer a nitrene moiety to phosphines and abstract a hydrogen atom from weak C-H bo
38 ligand libraries lags far behind that of the phosphines and the development of new libraries is antic
39 ands: the niche between the classic tertiary phosphines and the sterically undemanding aminophosphine
40 ntermediate readily convertible into various phosphines and their derivatives with high enantiomeric
41 s L-BH3 (where L is NHC, amine, pyridine, or phosphine) and the cyanoborohydride anion have been asse
42 d azide group is inhibited, even with excess phosphine, and good yields of the monofunctionalized pro
43 aldehyde, ketone, imine, hydrogen, ammonia, phosphine, and silane, were explored computationally.
48 d a combination of Pd(OAc)2 and tris(o-tolyl)phosphine as catalyst, and Cs2CO3 as the base under iner
52 Our simple approach, photocaging the key phosphine atom, allows for the facile production of reag
54 sion of these compounds to HNO (trapped as a phosphine aza-ylide) and the corresponding barbituric ac
55 ds generate HNO quantitatively (trapped as a phosphine aza-ylide) with half-lives spanning 3 orders o
56 hine)-is a direct tagging strategy that uses phosphine-based chemical probes, allowing enrichment of
59 ee system is the first reported example of a phosphine being able to hydrodefluorinate on its own.
60 by rationally combining robust site-specific phosphine bioconjugation methods and a lipid-binding pro
61 , the stereoselective synthesis of secondary phosphine borane amino acid derivatives was achieved by
64 ition, the electrochemical behavior of a C60-phosphine borane amino ester was investigated by cyclic
66 ydrophosphination reactions of [60]fullerene/phosphine borane compounds offer a promising new strateg
67 ination reaction of [60]fullerene by the sec-phosphine borane compounds was performed under PTC to ob
73 nd enones catalyzed by an amino acid derived phosphine catalyst has been investigated by the use of d
75 yllic acid, with the key step being a chiral phosphine-catalyzed [3 + 2] annulation between an imine
77 Building on a single example by Tong of a phosphine-catalyzed [4 + 1] annulation of an amine with
78 Methods have recently been developed for the phosphine-catalyzed asymmetric gamma-addition of nucleop
79 thesis of benzylic ethers through the chiral phosphine-catalyzed coupling of two readily available pa
80 he development of asymmetric variants of the phosphine-catalyzed intermolecular [3+2] annulation of a
81 characterized intermediates observed in the phosphine-catalyzed ketene homodimerization reaction.
88 A challenging question is whether the gold phosphine complex is a prodrug that is administered in a
92 ugh serendipitous discovery, a palladium bis(phosphine) complex was identified as a catalyst for the
95 try may be anticipated whenever labile metal-phosphine complexes are used to catalyze reactions of su
100 and are confined to reactions promoted by a phosphine-copper catalyst (with an alkyl Grignard reagen
101 ns are catalyzed by readily available chiral phosphine/copper(I) complexes and produce beta-hydroxybo
102 Catalytic synthesis of nonracemic P-chiral phosphine derivatives remains a significant challenge.
104 surface glycans and efficiently labeled with phosphine-derivatized fluorophore-conjugated bovine seru
105 c isotope effects implies a rate-determining phosphine dissociation for the decarbonylation of aldehy
106 of the decarbonylation pathway with partial phosphine dissociation reveals the barrier is reduced si
108 orbital alignment is modulated by auxiliary phosphine donors and selectively results in electron loc
109 hene linkers connecting the flanking dialkyl phosphine donors to the central carbene can be attached
110 ng power approaching that of strongest known phosphine electron donors such as P(t-Bu)3 and PCy3.
111 influenced by the nature of L, with smaller phosphines favoring the thermodynamically preferred (fro
115 at the most acidic position (C7), whereas a phosphine-free catalyst targets the most electron-rich p
116 ild a computational model of the kinetics of phosphine-free cobalt-catalyzed hydroformylation and hyd
120 he poor pi-accepting imidazol-2-ylidene, and phosphines giving rise to the corresponding phosphaketen
121 this reason, the obtention of optically pure phosphine has always been challenging in the development
123 d mixed halide-acetate with chiral bidentate phosphines have been explored and deuterium labeling stu
125 alyst optimization and, while parameters for phosphines have been used for decades with low-valent sy
126 N,N,N-tris(azolyl)borate and P is a tertiary phosphine, have been synthesized and characterized by me
127 employing a reductant, tris(2-carboxyethyl) phosphine hydrochloride (TCEP) in the detection buffer s
132 he approach-SNOTRAP (SNO trapping by triaryl phosphine)-is a direct tagging strategy that uses phosph
134 s and selectivity using tris(4-methoxyphenyl)phosphine (L3) in acetonitrile, while branched amides we
137 e copper catalyst (CuBr.SMe2 or Cu(OAc)2), a phosphine ligand (DPEphos) and a base (LiOtBu) in 1,4-di
138 recatalyst supported by a new biaryl(dialkyl)phosphine ligand (VPhos) in combination with octanoic ac
139 the compound with the most electron-donating phosphine ligand and the most basic amine functions perf
140 molytic P-C bond cleavage in the labile aryl phosphine ligand and the reaction of low-valent Ni(0/I)
142 Ag, Au) (4-6), in which compound 3 acts as a phosphine ligand bearing a bulky tetrel Zintl cluster mo
145 ladium(II) in combination with a monodentate phosphine ligand enables the unprecedented direct and al
147 action reveal that mono-oxidation of the bis-phosphine ligand is critical for the formation of the ac
150 system of cationic rhodium(I) precursor and phosphine ligand promotes redox-neutral [4+2] annulation
152 hanistic foundation behind the identity of a phosphine ligand that best promotes a desired reaction o
153 table Ni(II) salt and commercially available phosphine ligand to transform tertiary alcohol derivativ
156 gated palladium(0) intermediate, Pd(0)L (L = phosphine ligand), was detected for the first time from
157 conditions, employing a small-bite-angle bis-phosphine ligand, allowing for good functional group tol
158 combined with the use of a bulky monodentate phosphine ligand, interrupts the catalytic cycle by prev
159 s was selectively functionalized by a single phosphine ligand, particle stability, synthetic yield, a
161 ursor, Ni(acac)2, and an appropriately tuned phosphine ligand, PPh2Cy, resulted in the exclusive asse
162 hown to depend on the stoichiometry of Pd to phosphine ligand, the order of addition of the reagents,
166 alkenylsilanolate complexes bearing various phosphine ligands (both bidentate and monodentate) have
169 igated crucial parameters, such as different phosphine ligands and the influence of various nucleophi
171 cently discovered that nickel with bidentate phosphine ligands can selectively activate the C(acyl)-O
172 ents have shown that nickel with monodentate phosphine ligands favors the C(aryl)-O activation over t
173 II) arylsilanolate complexes bearing various phosphine ligands have been isolated, fully characterize
175 structural influence of different classes of phosphine ligands on the reaction mechanism(s), and deli
177 of copper catalysts based on bulky bidentate phosphine ligands originates from the attractive ligand-
179 ammonia complex supported by terpyridine and phosphine ligands that lowers the nitrogen-hydrogen bond
180 can be controlled by using three calixarene-phosphine ligands to create a selective nanoscale enviro
182 ions of reaction outcomes using 38 different phosphine ligands were combined with classic potentiomet
184 For one of the most powerful new generation phosphine ligands, PtBu3, oxidation state Pd(I), and not
185 ination reactions using structurally diverse phosphine ligands, revealing the critical role of bulky
189 e empty field on the stereoelectronic map of phosphine ligands: the niche between the classic tertiar
190 nstrate that, contrary to current proposals, phosphine ligated Ag(I)-carboxylates can efficiently car
191 osure of diverse N-cyclopropylacrylamides to phosphine-ligated cationic Rh(I) catalyst systems under
192 H catalyst by reaction with a silane, with a phosphine-ligated copper(I) benzoate as the catalyst res
193 ion mixture and independent experiments with phosphine-ligated ruthenium complexes indicated the invo
196 rs (FLPs) based on zirconocene aryloxide and phosphine moieties that exhibit a broad range of small m
198 stabilized through functionalization with a phosphine molecule, whereas the surface of the membranes
202 f vinyldiazaphosphonates from N-heterocyclic phosphine (NHP) and allenes via phospha-Michael/intramol
204 When an allenic sulfone is treated with a phosphine nucleophile and a proton shuttle, an isomeriza
208 rom acyclic 2-oxo-butanoate 10 to 2H-azirine phosphine oxide 1 led to vinylogous N-acyl-alpha-aminoal
210 center of the undesired (R,R)-diastereomeric phosphine oxide 19 through chlorination followed by crys
211 economy and the generation of stoichiometric phosphine oxide and hydrazine by-products that complicat
212 ubstituted tert-butyl(1,4-cyclohexadien-3-yl)phosphine oxide and its derivatives has been described.
219 xide-iodotriazole hybrids that incorporate a phosphine oxide XB acceptor and a 1,4-diphenyl-5-iodotri
220 unique structural feature of brigatinib is a phosphine oxide, an overlooked but novel hydrogen-bond a
221 selective Kv 1.5 channel inhibitor diphenyl phosphine oxide-1 but unaffected by the presence of the
222 inib represents the most clinically advanced phosphine oxide-containing drug candidate to date and is
223 sign and synthesis of two self-complementary phosphine oxide-iodotriazole hybrids that incorporate a
225 (AuNPs, 1a-5a) ligated by various secondary phosphine oxides (SPOs), [R(1)R(2)P(O)H] (R(1) = Naph, R
226 1 led to vinylogous N-acyl-alpha-aminoalkyl phosphine oxides 12, involving the carbonyl group and th
228 of P-stereogenic compounds such as secondary phosphine oxides and boron-protected monophosphines.
230 nd, whereas the size tuning brought about by phosphine oxides can be attributed to a solubility chang
231 ynamic resolution of tertiary phosphines and phosphine oxides was monitored by NMR spectroscopy.
232 yzed enantioselective arylation of secondary phosphine oxides with diaryliodonium salts for the synth
234 Herein, the hydrogen peroxide adducts of phosphine oxides, [tBu3POH2O2]2 and [Ph3POH2O2]2H2O2, ar
238 ounds and then encapsulating bis[tri(2-furyl)phosphine]palladium(II) dichloride in a biocompatible po
240 nol esters using Rh catalysts bearing chiral phosphine-phosphite ligands (P-OP) has been studied.
243 hydroperoxide-sensitive coumarin-conjugated phosphine probe to enable rapid quantification of both c
244 penones were further treated with a panel of phosphine probes, and reaction rates were measured.
248 terodehydrocoupling of primary and secondary phosphines (R(1)R(2)PH, R(2) = H or R(1)) with hydrosila
249 r orbital energy levels of the corresponding phosphine radical cations obtained by density functional
250 ic studies indicate that AgOPiv ligated by a phosphine reacts with the arene to form an arylsilver(I)
252 The lack of ammine ligands and need for phosphine represent a springboard for future design of p
253 oupling of primary phosphines to form cyclic phosphine rings and the first example of a non-metal-cat
254 s observed depending on the bulkiness of the phosphine's alkyl substituents and on the number of hype
255 creening revealed a significant influence of phosphine's electronic nature on activity and selectivit
257 It was found that upon treatment with a phosphine scavenger, these NiL complexes are active cata
258 reaction between cadmium oleate and trialkyl phosphine selenide by binding to cadmium and preventing
261 e(CN) (where [SiP(iPr) 3 ] represents a tris(phosphine)silyl ligand), on exposure to proton and elect
262 f palladium catalysts with bulky monodentate phosphines (SPhos and Cy-CarPhos) and aryl bromides or c
264 is behavior sends a warning about the use of phosphine-stabilized metathesis catalysts in donor solve
266 )20(PH3)12 model analogue, with triisopropyl phosphine substituents replaced by H atoms, revealed a p
268 noparticles Ru1-Ru4 supported with different phosphines such as dbdocphos, dppp, DPEphos, and Xantpho
269 ed to the enantiomerically enriched tertiary phosphine sulfide, possessing a cyclohexyl fragment at t
270 idazoles starting from alpha-diketones using phosphine supported ruthenium nanoparticles (RuNPs) as c
272 ible decomposition or activation pathway for phosphine-supported Au(III) catalysts and should not be
273 is uniquely effective (vs. the corresponding phosphine systems) and the basis for different trends in
277 dy the optoelectronic properties of aqueous, phosphine-terminated gold nanoparticles (core diameter =
278 ctions of benzhydryl cations (Ar2CH(+)) with phosphines, tert-amines, pyridines, and related Lewis ba
279 phino)ethane [DPPE], and tris(4-fluorophenyl)phosphine [TFPP] to design and synthesize a new class of
282 vel 1,3,2-diazaphospholidine (N-heterocyclic phosphine)-thiourea-mediated phospha-Mannich/intramolecu
283 ole of thiourea moiety of the N-heterocyclic phosphine-thiourea in the sequential intramolecular nucl
285 catalyzes the homodehydrocoupling of primary phosphines to form cyclic phosphine rings and the first
286 erocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of
287 ms an air-stable CO2 adduct that was used as phosphine transfer agent, providing a convenient access
291 bserved by Drozdov, Eremets, and Troyan when phosphine was subject to pressures of 207 GPa in a diamo
293 etween perfluoroaryl azides (PFAAs) and aryl phosphines, which occurs readily under ambient condition
294 The reaction of phenyl(2,4,6-trimethylphenyl)phosphine with a substituted benzoquinone in the presenc
296 of PhCN to the reactions involving secondary phosphines with hydrosilanes allowed the heterodehydroco
297 rations, with the surprising conclusion that phosphines with relatively small Tolman steric parameter
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