ライフサイエンスコーパス: photochemically

1 rresponding carbodiimides both thermally and photochemically.

2 factor was reduced by NADPH or dithionite or photochemically.

3 l, reversible NTB-N transition may be driven photochemically.

4 , and 12:13 can be equilibrated thermally or photochemically.

5 or resting state) occurs either thermally or photochemically.

6 ne protonated Schiff base both thermally and photochemically.

7 Dihydrogen complexes typically lose H2 photochemically.

8 he isomers in the crystal both thermally and photochemically.

9 drive the formation of ammonia from nitrogen photochemically.

10 eactive benzyne derivatives can be initiated photochemically.

11 sing of the "gate" of the host is controlled photochemically.

12 aks in an oligodeoxynucleotide by way of two photochemically activated (caged) building blocks placed

13 By imaging the spread of H(+) ions from a photochemically-activated source (6-nitroveratraldehyde)

14 The phyA-V631M mutant protein is photochemically active and accumulates to a level simila

15 an's atmosphere, indicating that pI could be photochemically active and drive chemistry on the surfac

16 Insulin molecules, modified with a photochemically active azido functionality on specific r

17 ansfer from plastocyanin to ferredoxin via a photochemically active chlorophyll dimer (P700), a monom

18 Identifying photochemically active compounds and understanding photo

19 dings should be useful for the design of new photochemically active compounds supported by main-group

20 nine-5,5'-disulfonic acid for detection or a photochemically active dye (chlorin(e6)) for therapy of

21 flavin mononucleotide noncovalently and are photochemically active in solution.

22 totropism in transgenic Arabidopsis, whereas photochemically active LOV1 alone is not.

23 Moreover, photochemically active LOV2 alone in full-length phot1 i

24 l TiO2 nanoparticles surface modified with a photochemically active mimic of the PSII chlorophyll-Tyr

25 t question: Is the lower atmosphere of Titan photochemically active or inert?

26 izing the bilin chromophore used to assemble photochemically active phys.

27 consistent with a substantial deficiency in photochemically active phys.

28 ed by the CP43 subunit, becomes exposed in a photochemically active PSII complex lacking CP43, it is

29 omains bind riboflavin-5'-monophosphate, are photochemically active, and have major absorption peaks

30 HYA photoreceptor apoprotein, which appeared photochemically active.

31 d by (Ru-Diad)8MspA at the TiO2 electrode is photochemically active.

32 olecular receptors 1a and 1b consisting of a photochemically addressable azobenzene tether functional

33 rome yellow degradation pathways by studying photochemically aged model samples covered with a dammar

34 A concerted, photochemically allowed [4pis + 2pia] cycloaddition was

35 d the cardiopulmonary effects of exposure to photochemically altered particle-free multipollutant mix

36 Exposure to photochemically altered urban air pollution appears to a

37 mechanism in a global aerosol model yields a photochemically and biologically driven seasonal cycle o

38 we highlight recent progress in the field of photochemically and thermally induced electron transport

39 osed of (Br)U and U, which undergoes further photochemically and thermally induced transformations to

40 e cyclopropanone underwent CO extrusion both photochemically and thermally to give the cycloheptadien

41 Such reactions will be readily accessible photochemically and thermally, e.g., under the condition

42 s were virtually identical to those obtained photochemically, and thus the doubly reduced photoproduc

43 s entering the environment are mechanically, photochemically, and/or biologically degraded to the ext

44 rgano-hydride systems in electrochemically-, photochemically- and chemically-driven reductions of uns

45 Because electrons added photochemically are easily titrated, photodoping also al

46 to sunlit environments where *OH is produced photochemically, but a recent laboratory study proposed

47 ((i)Pr(3)P)(H)(2)OsSn(trip) (2) thermally or photochemically by what appears to be a radical process.

48 nt an orthogonal approach which proceeds via photochemically catalyzed isomerization of the thermodyn

49 A universal, photochemically cleavable DNA base analogue would add de

50 le linkers, a thermally labile linker, and a photochemically cleavable linker- all of which are used

51 Beads displaying photochemically cleavable pepstatin A were distributed i

52 synthesized based on our previous work with photochemically cleavable terminators.

53 a photoactivatable unnatural amino acid and photochemically cleave the backbone of the alpha subunit

54 aromatic disulfide that can be chemically or photochemically cleaved.

55 ring opening to a cyclooctatriene (12) that photochemically closes to 6.

56 r cores assembled in the plasma membrane are photochemically competent and can catalyze single turnov

57 tural and spectroscopic comparisons with the photochemically compromised D207A mutant revealed that s

58 A photochemically controlled AND gate was developed throug

59 -catalyzed and pH-sensitive processes can be photochemically controlled by using this type of photoac

60 ker in a hemicarcerand creates a new type of photochemically controlled gated hemicarcerand.

61 Proteins can be photochemically controlled through the site-specific ins

62 wedge )N)(3) complexes can be thermally and photochemically converted to facial forms, indicating th

63 We photochemically cross-linked heads and tails and produce

64 Photochemically cross-linked iAbeta42 displayed an oligo

65 obe containing this complementarity could be photochemically cross-linked to ribosomal subunits throu

66 NA analog 4-thio-dT-p-C-p-puromycin (s4TCPm) photochemically cross-links with high efficiency and spe

67 oligonucleotide containing a single 6-TG is photochemically crosslinked to cysteine-containing oligo

68 r weight reactive liquid precursors that are photochemically cured into highly proton conductive soli

69 DNA molecules have the undesirable effect of photochemically damaging the DNA through radical interme

70 ower or prolonged illumination in air, which photochemically degrades the polyviologen and thereby re

71 en indicates that models may need additional photochemically dependent pathways to low-volatility SOA

72 nimal models, photodynamic therapy (PDT) can photochemically deplete ambient tumor oxygen through the

73 In this study Co-based catalysts were photochemically deposited as 10-30 nm nanoparticles on t

74 and gold particles were electrochemically or photochemically deposited on these crystals with the pre

75 ated planetesimals inherited sulfur that was photochemically derived from gases in the early inner so

76 using the photosensitizer Pc 4 and red light photochemically destroys the antiapoptotic protein Bcl-2

77 onment has been used for the conversion of a photochemically driven chemical cycle for group 6 metal-

78 Efficiency of this photochemically driven direct arylation has been demonst

79 aryl substituent at position 2 undergo swift photochemically driven direct arylation, leading to bare

80 absorption and Raman monitoring to detect a photochemically driven EPT process (photo-EPT).

81 The mechanism of this photochemically driven pathway most likely involves the

82 generated by redox reactions that are either photochemically driven, such as those in photosynthetic

83 scribed that is thermodynamically capable of photochemically driving the energy-storing reverse water

84 itters are currently the most chemically and photochemically efficient probes for two-photon photolys

85 romophore has great promise as a generic and photochemically efficient protecting group for both one-

86 s revealed that compounds in this class are "photochemically enhanced" inhibitors, in that they bind

87 In this paper, we demonstrate how photochemically enhancing the permeability of metal-orga

88 hat H-abstraction processes are initiated by photochemically excited dissolved organic matter which w

89 into individual subsections according to the photochemically excited olefin.

90 They absorb light through a flavin cofactor, photochemically form a covalent bond between the chromop

91 system to demonstrate that the lifetime of a photochemically formed radical pair is changed by applic

92 arrangement of 2-ethoxyethylidene, generated photochemically from a nonnitrogenous precursor, leads t

93 eterolysis of a pyrimidine radical generated photochemically from an aryl sulfide.

94 ne-electron reducing intermediates generated photochemically from both untreated and borohydride-redu

95 Next, transient HCO is made photochemically from formaldehyde.

96 This compound can also be prepared photochemically from its iron(II) precursor by irradiati

97 orbornyloxychlorocarbenes (7) were generated photochemically from the corresponding diazirines (6).

98 iynylidene (MeC(5)Me, 1b) have been produced photochemically from their corresponding diazo compound

99 nd acetaldehyde, which are formed in the air photochemically from volatile organic compounds (VOCs),

100 en Rose Bengal or methylene blue was used to photochemically generate (1)O2 in the presence of Lys, w

101 uted anthraquinone (AQ), previously shown to photochemically generate benzaldehyde in methanol soluti

102 he 5020 s(-1) rate constant for decay of the photochemically generated aci-nitro intermediate (pH 7.0

103 n reactions, suggesting the involvement of a photochemically generated acid.

104 or in the rate of dark-state cleavage of the photochemically generated adduct.

105 high valent Fe(V)(O) intermediate species is photochemically generated as the active intermediate for

106 Photochemically generated benzyl radicals react with Sc(

107 The photochemically generated blue-absorbing state is in equ

108 Capture of a photochemically generated carbene 21 by methanol is the

109 ted enantioselective iminium ion trapping of photochemically generated carbon-centered radicals.

110 Transfer kinetics of photochemically generated cholesterol hydroperoxide (ChO

111 idation of the 5'-d(CCTACGCTACC) sequence by photochemically generated CO3*- radicals in low steady-s

112 excess free thiol ligands, they replaced the photochemically generated disulfides and maintained the

113 chanical switch, capable of utilizing such a photochemically generated driving force to bring about c

114 pate in C-H bond cleavage reactions with the photochemically generated fragment [Tp'Rh(CNR)] (Tp' = h

115 e thought to be silver nanoclusters that are photochemically generated from the oxide.

116 e in photodegradation could be attributed to photochemically generated halogen radicals rather than o

117 nthetically useful Diels-Alder trapping of a photochemically generated hydroxy-o-quinodimethane speci

118 Photochemically generated hydroxyl radicals were used to

119 ation concentration c* < 100 mug m(-3)) were photochemically generated in rapid bursts in situ in an

120 A very facile reaction between photochemically generated o-naphthoquinone methides (oNQ

121 The click chemistry based on the addition of photochemically generated oNQM to vinyl ether works well

122 question, the recombination efficiencies of photochemically generated radical cage pairs (denoted as

123 mass on the cage recombination efficiency of photochemically generated radical cage pairs.

124 n of this technique to the identification of photochemically generated radicals in natural water samp

125 tions of dissolved organic matter (DOM) with photochemically generated reactive halogen species (RHS)

126 Similarly, oxidative challenge by H(2)O(2), photochemically generated reactive oxygen species, or UV

127 f PCs for the assessment of the formation of photochemically generated RIs.

128 A hole scavenging reaction between the photochemically generated Ru(bpy)3(3+) and 1 occurs with

129 hore-assisted light inactivation (CALI) uses photochemically generated, reactive oxygen species to in

130 vity of purified testicular PHGPX on several photochemically-generated cholesterol hydroperoxide (ChO

131 ation product of PBDE 153 that is capable of photochemically generating 2,3,7,8-tetrabromodibenzo-p-d

132 hown that all three compounds are capable of photochemically generating other compounds of concern, i

133 t is activated by light irradiation, thereby photochemically generating reactive oxygen species (ROS)

134 A layer of MIP was photochemically grafted over the polyaniline, via N,N'-d

135 Linear and circular DNA molecules were photochemically immobilized on the surface.

136 After CIEF, charge variants are photochemically immobilized to the wall of a short coate

137 The 2(1)Ag state, which is dark but photochemically important, is a prime source of this dif

138 tes and mechanisms of decay of ASQ generated photochemically in bifurcating NADH-dependent ferredoxin

139 h is thought to involve radical pairs formed photochemically in cryptochrome proteins in the retina.

140 Phenoxyl radical (C(6)H(5)O) was prepared photochemically in low-temperature argon matrices.

141 When the carbene is generated photochemically in methanol, it reacts by a protonation

142 n phosphatidylcholine liposomes and produced photochemically in tap water.

143 immunologic potencies of live-attenuated and photochemically inactivated nucleotide excision repair m

144 Photochemically inactivated vaccine strains maintained a

145 by light in the wild type but was limited in photochemically inactive and null mutants, indicating th

146 ngle crystal X-ray diffraction analysis of a photochemically inactive dichloromethane solvate was use

147 14 new photoswitching CBCRs, one apparently photochemically inactive protein exhibiting intense red

148 shifted state (from 701 to 702 nm), which is photochemically inactive to red or white light.

149 nits is polymerized in a single crystal by a photochemically induced [4 + 4] cycloaddition reaction b

150 enabled us to perform the first examples of photochemically induced arene exchange/expansion reactio

151 Photochemically induced bound residue formation of polar

152 enerated in a layer-by-layer fashion through photochemically induced C,H insertion reactions and cons

153 The photochemically induced coupling of aromatic ketones wit

154 The observed products of this photochemically induced cycloaddition showed a stereosel

155 ve concentration, followed by shear force or photochemically induced division.

156 Photochemically induced DSBs, but not general oxidative

157 it the large enhancements arising from (13)C photochemically induced dynamic nuclear polarization ((1

158 bsorption spectroscopy and confirmed by (1)H photochemically induced dynamic nuclear polarization (ph

159 p-cage' miniprotein known as TC5b, we report photochemically induced dynamic nuclear polarization NMR

160 The CD results are correlated with photochemically induced dynamic nuclear polarization NMR

161 Photo-CIDNP (photochemically induced dynamic nuclear polarization) ca

162 Photo-CIDNP (photochemically induced dynamic nuclear polarization) MA

163 mbotic occlusion of the carotid artery after photochemically induced endothelial cell injury.

164 Measurements of photochemically induced ET and subsequent charge recombi

165 hosen neurons are revealed by diffusion of a photochemically induced fluorescent product from their s

166 The utility of photochemically induced hetero-Diels-Alder reaction for

167 terference contrast microscopies, we monitor photochemically induced microtubule breakdown on the sup

168 s, the yields of target bromosulfones in the photochemically induced reactions can be increased by re

169 lated to decomposition of organic matter and photochemically induced reactions.

170 ical reactivity and role as intermediates in photochemically induced reactions.

171 the protective effect of this enzyme against photochemically induced stress and UVB irradiation in ce

172 The latter acetals are photochemically inert but can be converted into photolab

173 ups can be armed in situ by the reduction of photochemically inert p-quinone precursors.

174 [Os(N^N)3 ](2+) complexes are supposed to be photochemically inert to ligand loss, the complex [Os(bt

175 nd Zn(bpod)(2)(CH(3)COO)(2) compound (4) are photochemically inert under the same conditions.

176 tic hydrogens of tyrosine O-methyl ether are photochemically inert, but become labile in the presence

177 gm in photopatterning: the surface itself is photochemically inert, while photoreactive component is

178 Evidence of a photochemically initiated diradical cyclization pathway

179 controlling the yield and efficiency of the photochemically initiated immobilization.

180 n the rich organic chemistry associated with photochemically initiated reactions in the upper atmosph

181 The reaction involves a photochemically initiated reduction of a quinone mediate

182 2a-c are themselves easily accessed through photochemically initiated topochemical polymerization of

183 hPF4 and KKO selectively bound to photochemically injured endothelium at sites where surfa

184 ity for acetate release, whereas NHQ-OAc was photochemically insensitive.

185 We report the syntheses of the photochemically labile 9-diazo-4,5-diazafluorene (1) fra

186 The aromatic hydrogen nuclei of tyrosine are photochemically labile and exchange with deuterons in ne

187 ed product were orthogonally protected using photochemically labile and hydrazine labile groups.

188 irst approach, substrates are treated with a photochemically labile organosilane monolayer film.

189 Therefore, the mechanism of photochemically mediated ATRP is consistent with a photo

190 A photochemically mediated catalytic tandem Pauson-Khand c

191 The polymerization mechanism of photochemically mediated Cu-based atom-transfer radical

192 The initiation mechanism of photochemically mediated Cu-based reversible-deactivatio

193 Other novel thermally and photochemically mediated skeletal rearrangement reaction

194 Photochemically, MeTAD demonstrated lower regioselectivi

195 the first time that aldehydes have been made photochemically on a solid-supported phase.

196 riginated from soil humics and appears to be photochemically or microbially modified.

197 Several nitrile imines were generated photochemically or thermally and investigated by IR spec

198 and metal oxide catalysts have been used to photochemically oxidize water.

199 present "missing" sources of urban SOA, were photochemically oxidized in an outdoor smog chamber faci

200 ed the spreading of phospholipid vesicles on photochemically patterned n-octadecylsiloxane monolayers

201 racy and large-area lateral uniformity using photochemically patterned single 1,2-dimyristoyl-sn-glyc

202 ers and rarely working in conjunction with a photochemically powered system.

203 Remarkably, the rate of the reaction of the photochemically prepared compound 2 toward sulfides incr

204 We photochemically prepared the species with stoichiometry

205 sorption band in the near IR spectrum of the photochemically prepared, mixed valence form, [(bpy)2ClR

206 ristics, and optical properties of fresh and photochemically processed emissions from biomass combust

207 ice coatings on preexisting grains that were photochemically processed into refractory organic matter

208 oredox agent into the chalcogels is shown to photochemically produce hydrogen.

209 Photochemically produced aerosols are common among the a

210 th a large energy flux from the oxidation of photochemically produced atmospheric H(2) and CO diffusi

211 Here we quantitatively examine 1O2 photochemically produced from DOM in frozen and liquid a

212 arious systems involving complex mixtures of photochemically produced oxidants of differing natures.

213 through altering the accessibility of His to photochemically produced oxidants or through shifting th

214 ects on the formation of covalent bonds from photochemically produced pairs of radicals.

215 Detection of photochemically produced peroxyl radicals is achieved by

216 ce of indirect photolysis pathways involving photochemically produced reactive intermediates (PPRIs).

217 We studied the formation of photochemically produced reactive intermediates (RI) fro

218 The antioxidant capacity and formation of photochemically produced reactive intermediates (RI) was

219 ) or sensitize photodegradation by producing photochemically produced reactive intermediates but can

220 icroenvironments with high concentrations of photochemically produced reactive intermediates, such as

221 oducing singlet oxygen (1O2) alongside other photochemically produced reactive intermediates.

222 ic hot-spot and caused extreme enrichment of photochemically produced trace gases.

223 x-active moieties can reduce the lifetime of photochemically produced Trp(*+) and thus quench Trp deg

224 The synthesis is accomplished by photochemically promoted allylic substitution reactions

225 al bisadduct 12 can only undergo syn or anti photochemically promoted intramolecular tandem [4 + 4] a

226 Systems such as 26 readily participate in photochemically promoted oxa-di-pi-methane rearrangement

227 ing adduct to the tricyclic ketone 12, and a photochemically promoted rearrangement of this last comp

228 y) light-harvesting antenna complexes into a photochemically quenched state.

229 verall, the ability of these chromophores to photochemically react under substrate control may make u

230 The results demonstrate a photochemically reactive member of the archaeal rhodopsi

231 ransferase (APRT) gene was modified with the photochemically reactive psoralen derivative 4'-(hydroxy

232 reactive under thermal conditions, they were photochemically reactive.

233 ical S-nitroso compounds is to chemically or photochemically reduce SNO functional groups to release

234 present nanohybrids were further utilized to photochemically reduce the hexyl viologen dication in th

235 with Cl(-) or Br(-) may be less likely to be photochemically reduced and re-emitted to the atmosphere

236 Photochemically reduced enzyme was reoxidized by titrati

237 Photochemically reduced FMN substituted for Fre in the r

238 d CO2 by using an electron supplied from the photochemically reduced Ru photosensitizer unit.

239 If SNO-actin is photochemically reduced with UV light or if actin filame

240 ning FeMoS inorganic clusters are capable of photochemically reducing N2 to NH3 under white light irr

241 ising from the meta-II signaling state while photochemically regenerating a pigment with ground state

242 A design principle for a two-photon photochemically removable protecting group based on sequ

243 jor outcome of this work is a novel class of photochemically removable protecting groups.

244 nylcyclopropenylidene (6), a process that is photochemically reversible at lambda=232 nm.

245 Three new photochemically reversible but thermally stable dithieny

246 cal twisting powers were found to experience photochemically reversible isomerization with thermal st

247 All the compounds exhibited photochemically reversible isomerization with thermal st

248 , this method provides a one-step route to a photochemically reversible thiol-protecting group.

249 c azobenzenophanes with axial chirality show photochemically reversible trans to cis isomerization in

250 The interaction with N2 is photochemically reversible.

251 romote degradation of chlorine-resistant and photochemically stable chemicals accumulated in swimming

252 bilized vinyl ether molecules resulting in a photochemically stable covalent link between a substrate

253 nanospheres, this pH-sensitive (pKa = 7.3), photochemically stable dye fluoresces in the red part of

254 Photochemically stable fluorescent heteroditopic ligands

255 The BHC-nicotinamide proved to be photochemically stable, which is also interpreted in ter

256 this specific base pair arrangement uniquely photochemically stable.

257 tunable, symmetric emission spectrum and are photochemically stable.

258 it was found that such systems do rearrange photochemically to afford cyclopentenes.

259 starting Rh(2)(0,II) complex is regenerated photochemically to close an oxygen-to-water reduction ph

260 med during disinfection with chlorine) react photochemically to form polychlorinated dibenzo-p-dioxin

261 mine and dissolved in toluene can be charged photochemically to give stable solutions in which electr

262 or 10-hydroxyscandine (1b) reacts with C(60) photochemically to give two products, the expected inver

263 nia were randomly assigned to receive either photochemically treated (PCT) or conventional (control)

264 We report a transfusion trial of platelets photochemically treated for pathogen inactivation using

265 al (scsc) synthesis of a 2D polymer based on photochemically triggered [2 + 2]-cycloaddition is repor

266 To investigate further the use of photochemically triggered manipulation of such pathways,

267 the fast kinetic phases observed in previous photochemically triggered spectroscopic studies of dynam

268 terized, and screened for their potential to photochemically unmask a reactive Ru-Ru horizontal lineO

269 The latter were photochemically unstable and decomposed to form triplet

270 The quinobenzoxazine (S)-A-62176 is photochemically unstable and undergoes a DNA-accelerated

271 The evolution from the photochemically unstable bisamidine (Z,Z)-BABCH to poten

272 The nitrate radical, NO(3), is photochemically unstable but is one of the most chemical

273 Substitution reactions of the chemically and photochemically unusually stable perylenetetracarboxylic

274 Typically, ZnO photodoping is achieved photochemically using ethanol (EtOH) as a sacrificial re

275 composition of the triazides was carried out photochemically, using the matrix isolation technique.

276 e and 8 mice deficient in PAI-1 were injured photochemically while blood flow was continuously monito

277 analog 4-thio-dT-p-C-p-puromycin crosslinks photochemically with G2553 of 23S ribosomal RNA (rRNA).

278 n electron donor, these complexes produce H2 photochemically with quantum yields of up to 20%.

279 The polyurethane is cured photochemically with the screws in place; on curing, it

280 As a method to initiate radical formation photochemically within beta2, a single surface-exposed c