ライフサイエンスコーパス: photoinduced

1 A photoinduced [2 + 2] cycloaddition occurs between the co

2 Photoinduced [2+2] and [4+4] cycloaddition reactions, is

3 rb quality for both the ground state and the photoinduced (3)MLCT excited state that have allowed us

4 we measure fission dynamics using ultrafast photoinduced absorption and present a first-principles e

5 on alpha-Fe2O3 photoanodes are studied using photoinduced absorption spectroscopy and transient photo

6 e density on a hematite photoanode employing photoinduced absorption spectroscopy.

7 Moreover, using photoinduced absorption, we show how the populations of

8 iation, and that oxygen is essential for the photoinduced action.

9 fer (AT), whereas, in the absence of ligand, photoinduced activation likely proceeds through a single

10 so highlights the catalytic activity and the photoinduced activation of ruthenium(ii) complexes, thei

11 rly with applied electric field and exhibits photoinduced ambipolar charge transport (mu approximatel

12 Photoinduced and native redox reactions that contributed

13 f photoinduced isomerization as well as both photoinduced and thermal back-isomerization, resolving d

14 Finally, procedures to spatially map photoinduced and thermal isomerization rates on live cel

15 s retain their ability to undergo reversible photoinduced and/or thermally induced structural changes

16 uents were investigated as leaving groups in photoinduced ArS(N)1 reactions.

17 onamides (3), followed by intramolecular C-C photoinduced arylation under soft conditions without the

18 Photoinduced ATRP was successfully performed in aqueous

19 owever, details of mechanisms that can use a photoinduced base-promoted homolytic aromatic substituti

20 t (ballistic disintegration and motion), and photoinduced bending by dimerization.

21 ption of the quasi-static and time-dependent photoinduced bending of macroscopic single crystals is p

22 The growing realization that photoinduced bending of slender photoreactive single cry

23 ry and model chromophore experiments such as photoinduced bimolecular charge transfer.

24 a very promising candidate for evoking large photoinduced biological responses during the multiphoton

25 nd integrals of the pump-probe spectra where photoinduced bleaching rises abruptly 20 fs after photoe

26 t herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electro

27 This photoinduced borylation protocol does not require expens

28 We report herein a photoinduced carboborative ring contraction of monounsat

29 albic acid has been enabled by a sequence of photoinduced carboborative ring contraction, Rauhut-Curr

30 n spectroscopy confirms that the increase in photoinduced carriers in PCBDR under irradiation is prim

31 A photoinduced cascade strategy leading to a variety of di

32 t such that adiabatic processes dominate the photoinduced change of the magnetic order--the three-tem

33 The study of photoinduced changes in nuclear architecture is a flouri

34 By action spectroscopy of photoinduced channel currents in HEK293 cells and absorp

35 tubes facilitate separation and migration of photoinduced charge carriers, enhance the adsorption and

36 ion experiments determine driving forces for photoinduced charge separation (CS) and thermal charge r

37 s, showing the occurrence, in both cases, of photoinduced charge separation and corroborating the for

38 les and repel electrons, that is, facilitate photoinduced charge separation and hinder charge recombi

39 amely light-harvesting, energy transfer, and photoinduced charge separation and the design of novel,

40 : i) absorption of photons from the sun; ii) photoinduced charge separation and the generation of mob

41 tors forms superstructures that undergo fast photoinduced charge separation following assembly.

42 ine-tuned upon interaction with graphene and photoinduced charge separation in the absence and presen

43 The traditional view on the photoinduced charge separation involves excitation of a

44 ffer molecular-level insights into ultrafast photoinduced charge separation potentially triggered by

45 Following photoinduced charge separation to form a contact radical

46 n by localized electric field as a result of photoinduced charge separation, in contrast to a global

47 electronic components capable of performing photoinduced charge separation.

48 demonstrates the sensitivity of the yield of photoinduced charge transfer between a QD and a molecula

49 The high responsivity is enabled by photoinduced charge transfer between the nanocrystals an

50 semblies on a colloidal template and studies photoinduced charge transfer in them.

51 ncorporation of FC60 allows for an effective photoinduced charge transfer quenching of the encased SW

52 mers while maintaining a high efficiency for photoinduced charge transfer to suitable electron accept

53 The dynamics and efficiency of photoinduced charge transport has been investigated in D

54 ete account of the mechanism and dynamics of photoinduced charge transport in these DNA hairpins.

55 Photoinduced charge-separated (CS) states are formed on

56 The spin chemistry of photoinduced charge-separated (CS) states of three triad

57 r (D-A) pairs for prolonging the lifetime of photoinduced charge-separated states.

58 ctional molecular rotary motors that harness photoinduced cis-trans (E-Z) isomerization are promising

59 atalytic photochemical reaction based on the photoinduced cleavage of an alpha-diketone bridge from t

60 On the other hand, the decay of the photoinduced conductivity in MAPbI3/PCBM is on the time

61 on of the azobenzenes, the complexity of the photoinduced conformational transition of the pentameric

62 s provides a detailed understanding of their photoinduced conformational transitions, resembling simi

63 Here we describe a photoinduced copper-catalyzed method for coupling readil

64 We describe both a new thermal and photoinduced copper-mediated cross-coupling between pota

65 In the present study, we establish that photoinduced, copper-catalyzed alkylation can also be ap

66 alide, as well as the first illustrations of photoinduced, copper-catalyzed alkylation with either a

67 cal, and product studies) to investigate the photoinduced, copper-catalyzed coupling of carbazole wit

68 n-metal-catalyzed approach: in particular, a photoinduced, copper-catalyzed monoalkylation of primary

69 y functionalized cryogel monoliths through a photoinduced cross-linking reaction.

70 The ability to control the photoinduced crystal deformation by manipulating crystal

71 lectronic excitation generates PDI(-.) via a photoinduced CS reaction (tauCS approximately 0.4 ps, Ph

72 After a laser flash, I forms through photoinduced CS, accumulates to a maximum concentration,

73 dular synthesis of photoprecursors and their photoinduced cyclization into substituted 1-benzazocanes

74 The photoinduced cycloaddition was performed under metal-fre

75 The photochemical properties and photoinduced cytotoxicity of 3 were compared to those of

76 Through dual-laser excitation of bright and photoinduced dark states, mutations to the residues surr

77 A new method was developed for the photoinduced dearomatization of arenes through an intram

78 In this work, we took advantage of the photoinduced decarbonylative rearrangement of bicyclo[2.

79 el borylation reaction proceeding via a mild photoinduced decarboxylation of redox-activated aromatic

80 1-3, with amino acids at their rim, undergo photoinduced decarboxylations to give baskets 4-6 formin

81 conditions, one by dehydration and others by photoinduced degradation.

82 rent approach toward E-stilbene syntheses by photoinduced direct C-H arylation of alkenes at rt witho

83 the anthropogenic source, substantiates the photoinduced dissolved inorganic nitrogen (DIN) incorpor

84 it is important to resolve the mechanism of photoinduced DNA damage.

85 We show that this photoinduced doping arises from microscopically coupled

86 Here, we report photoinduced doping in van der Waals heterostructures co

87 We demonstrate that this photoinduced doping maintains the high carrier mobility

88 These intermediates were generated via a photoinduced double elimination process occurring in (ch

89 nd some other photoresponsive proteins where photoinduced double-bond isomerization occurs.

90 t herein a simple, additive- and metal-free, photoinduced, dual C-H/C-X borylation of chloro-, bromo-

91 There is a fundamental interest in studying photoinduced dynamics in nanoparticles and nanostructure

92 Observed photoinduced dynamics is further analyzed in details usi

93 ultrafast ISC in cis-4TCE is consistent with photoinduced dynamics of related thiophene-based oligome

94 The finding of a photoinduced elastic unit cell deformation elucidates a

95 strated that the C-N regiospecificity of the photoinduced electrocyclization is a general feature of

96 gh an efficient photochemical route requires photoinduced electron transfer (ET) from a light harvest

97 (epsilon(S)) within a protein matrix after a photoinduced electron transfer (ET) reaction.

98 Rhodamine Voltage Reporters, or RhoVRs, use photoinduced electron transfer (PeT) as a trigger for vo

99 and theoretical studies points to a role for photoinduced electron transfer (PET) between a highly co

100 uence of the thermodynamic driving force for photoinduced electron transfer (PET) between single-wall

101 Occurrence of ultrafast photoinduced electron transfer (PET) leading to the form

102 lacement of the internal charge transfer and photoinduced electron transfer (PET) modulators on the s

103 Photoinduced electron transfer (PET) occurs from a Ru(II

104 ere we reported the development of the first photoinduced electron transfer (PeT) probe (1) to direct

105 r in the medium is attributable to arrest in photoinduced electron transfer (PET) process.

106 te the electron inoculation to TNT through a photoinduced electron transfer (PET) process.

107 QMeNN, whose fluorescence is deactivated by photoinduced electron transfer (PeT) quenching that resu

108 sensors has been attributed to some form of photoinduced electron transfer (PET) quenching, which is

109 cence response, most commonly by suppressing photoinduced electron transfer (PET) quenching.

110 crown ether receptor due to reduction of the photoinduced electron transfer (PET) quenching.

111 Fluorescent photoinduced electron transfer (PET) sensor molecules ta

112 oltage with high speed and sensitivity using photoinduced electron transfer (PeT) through a conjugate

113 extension to modular switch systems based on photoinduced electron transfer (PET) towards the emulati

114 IR voltage sensitive dyes that make use of a photoinduced electron transfer (PeT) trigger for optical

115 l reconfiguration dynamics of the chain, and photoinduced electron transfer (PET), a contact-based me

116 ate locally excited triplet states by way of photoinduced electron transfer (PeT), followed by recomb

117 Photoinduced electron transfer (PET), which causes pH-de

118 electron affinity material (acceptor) [i.e., photoinduced electron transfer (PET), which we term Chan

119 The dye/enzyme hybrids are composed of a photoinduced electron transfer (PeT)-based fluorescent v

120 are triplet-state quenchers that operate via photoinduced electron transfer (PeT).

121 Photoinduced electron transfer and final regeneration of

122 sized and investigated in order to elucidate photoinduced electron transfer and hole migration mechan

123 ta rule out substrate activation by means of photoinduced electron transfer and instead support a mec

124 The photoinduced electron transfer and intramolecular charge

125 nceptual analogies between bridge effects in photoinduced electron transfer and optical intervalence

126 moiety, distinctly rectify both the forward photoinduced electron transfer and the subsequent charge

127 An efficient photoinduced electron transfer between coumarin and dG s

128 strate that SF competes with the traditional photoinduced electron transfer between pentacene and C60

129 has been established that the first step of photoinduced electron transfer can be fast, of order 100

130 We show that these sites can be revealed by photoinduced electron transfer dissociation, which produ

131 The reaction begins with the photoinduced electron transfer from CsPbX3 NCs to dihalo

132 ransfer mechanism from Hb/AuNCs to Cyt c and photoinduced electron transfer from DNA/AgNCs to the apt

133 solved spectroscopy experiments demonstrated photoinduced electron transfer from the graphene to the

134 An efficient photoinduced electron transfer from the tetraphenylborat

135 Photoinduced electron transfer in fluorescent proteins f

136 The mechanism of this photoinduced electron transfer in the solid state and th

137 ghly efficient energy transfer and ultrafast photoinduced electron transfer in well-defined multichro

138 the phenomenon of fluorescence quenching by photoinduced electron transfer into the isolated NTD of

139 Redox sensing is mediated by a photoinduced electron transfer intramolecular switch.

140 Density functional theory studies validate a photoinduced electron transfer intramolecular switching

141 Photoinduced electron transfer is central to many biolog

142 Intramolecular photoinduced electron transfer leading to charge-separat

143 The results support a photoinduced electron transfer mechanism for the 1,3-rea

144 Photoinduced electron transfer plays key roles in many a

145 Ultrafast photoinduced electron transfer preceding energy equilibr

146 catalyst system is achieved by a consecutive photoinduced electron transfer process (conPET) and allo

147 ies suitable for cascade energy transfer and photoinduced electron transfer processes in appropriate

148 c systems and in chemical systems capable of photoinduced electron transfer processes in general.

149 ical reactions, particularly those involving photoinduced electron transfer processes, establish a su

150 gates, and sequence defined polymers through photoinduced electron transfer reactions are also invest

151 ount of the fundamentals and applications of photoinduced electron transfer reactions in polymer synt

152 diffusion free, rate constant of bimolecular photoinduced electron transfer reactions, fluorescence q

153 ion implicate a photoredox pathway involving photoinduced electron transfer to generate a key radical

154 clobutane pyrimidine dimers in DNA or RNA by photoinduced electron transfer using longer wavelength U

155 Cu(I) and PET (photoinduced electron transfer) catalysis are treated se

156 duction to the principle of fluorescent PET (photoinduced electron transfer) sensors and switches, th

157 s of photocatalysis are discussed, including photoinduced electron transfer, hydrogen atom transfer,

158 emphasis on differences between thermal and photoinduced electron transfer, oxidative and reductive

159 xchange is an effective model to rationalize photoinduced electron transfer, particularly when molecu

160 Following photoinduced electron transfer, the rate of charge recom

161 a unified design, based on the principle of photoinduced electron transfer, to access a panel of hig

162 photoactivated living polymerization, named photoinduced electron transfer-reversible addition-fragm

163 By developing cytocompatible PET-RAFT (photoinduced electron transfer-reversible addition-fragm

164 e (ZnTPP)) were able to selectively activate photoinduced electron transfer-reversible addition-fragm

165 PY-ATP) was quenched by Fe(III) ions through photoinduced electron transfer.

166 ryl moiety to reduce the process of acceptor photoinduced electron transfer.

167 h dielectric constants (DMF), most likely by photoinduced electron transfer.

168 a decrease in the efficiency of collisional photoinduced electron transfer.

169 Photoinduced electron- and energy-transfer processes bet

170 studies have revealed the possibility for a photoinduced electron-transfer (PET) pathway.

171 ith cationic fullerene derivatives to create photoinduced electron-transfer cascades that lead to exc

172 e reveal the existence of a new, low-energy, photoinduced electron-transfer mechanism in molecules he

173 he rates of individual steps in a reversible photoinduced electron-transfer process.

174 The dynamics of bimolecular photoinduced electron-transfer reactions has been invest

175 Described here is a previously unreported photoinduced electron-transfer-quenched probe (HMBQ-Nap

176 polymerization via a visible-light-mediated photoinduced electron/energy transfer-reversible additio

177 of a few picoseconds, as well as associated photoinduced electronic transitions and charge transfer

178 Transferring photoinduced electrons and holes at the same time, leadi

179 osition-dependent exciton decay dynamics and photoinduced energy transfer of QDs is addressed.

180 ers for the generation of singlet oxygen via photoinduced energy transfer processes, but under light

181 aration of molecules and materials featuring photoinduced energy transfer.

182 /or perform valuable functions by exploiting photoinduced energy- or electron-transfer processes, pho

183 allow us to draw clear distinctions between photoinduced EngT and EleT.

184 es why the experimentally observed ultrafast photoinduced ET in an Au-TiO2 system is possible in spit

185 the effective dielectric constant following photoinduced ET, from epsilon(S) approximately 8 to epsi

186 Photoinduced force microscopy shows that doping level ca

187 romic shift of the absorption maximum of the photoinduced form, whereas no difference was found for c

188 ction ratio is markedly increased due to the photoinduced formation of massive two-dimensional electr

189 The photoinduced formation of nanosized aggregates was detec

190 During the study of photoinduced generation of 5-thyminyl-5,6-dihydrothymine

191 ocatalytic processes, invariably starts with photoinduced generation of energy-rich electrons.

192 epends critically upon the driving force for photoinduced hole transfer (HT) from these low-band-gap

193 by hole transfer to the nonexcited donor or photoinduced hole transfer (PHT), which we term Channel

194 (5)-(i)Pr4C5H)(CO)2Os(*) radicals, formed by photoinduced homolysis of the corresponding osmium dimer

195 -A light centered at 350 nm does not lead to photoinduced hydrogen transfer whereas the addition of a

196 ggest an electronic mechanism dominating the photoinduced IMT, but also highlight the difficulty to d

197 The process includes the photoinduced in situ formation of acylazirines combined

198 Photoinduced interfacial charge transfer is at the heart

199 Photoinduced, interfacial electron injection and back el

200 Here, photoinduced interstrand proton transfer (PT) triggered

201 ations, we have been able to estimate in the photoinduced isomer the distance between hydrogen atom a

202 maging technique can provide spatial maps of photoinduced isomerization as well as both photoinduced

203 00~700 ps dominate in all three iRFPs, while photoinduced isomerization was completely inhibited.

204 t using a switching potential describing the photoinduced isomerization.

205 compartments is demonstrated, culminating in photoinduced labelling within live cells.

206 lattice dynamics and show that even a small photoinduced lattice distortion can induce notable chang

207 Complex 3 also undergoes photoinduced ligand exchange when irradiated in H2O (lam

208 ciation, representing a new manner to effect photoinduced ligand exchange.

209 We have recently reported that photoinduced ligation of ZnS-overcoated quantum dots (QD

210 wavelength-dependent conversion of two rapid photoinduced ligation reactions, i.e., the light activat

211 t photoexcited QDs play a direct role in the photoinduced ligation.

212 In this Article, we report a photoinduced living polymerization technique, which is a

213 hyrins, we investigated their capability for photoinduced living polymerization under visible light i

214 Photoinduced living radical polymerization of acrylates,

215 donor-sensitizer-acceptor compound in which photoinduced long-range electron transfer is coupled to

216 lps to understand the puzzling phenomenon of photoinduced macroscopic material flow and photoexpansio

217 n recombination is thus inextricably tied to photoinduced magnetism.

218 Photoinduced metal-free atom transfer radical polymeriza

219 ts, were used as valuable substrates for the photoinduced metal-free synthesis of (hetero)biaryls wit

220 Photoinduced metal-mediated radical polymerization is a

221 er dynamics of [Fe(2,2'-bipyridine)3](2+) on photoinduced metal-to-ligand charge transfer excitation.

222 aeruginosa azurin model system, measured via photoinduced methods, can also be explained by an altern

223 provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort ti

224 In photoinduced molecular reaction dynamics, the effects of

225 This photoinduced molecular structure change has a strong dep

226 Here we report photoinduced motion (photomotility) in monolithic polyme

227 tween single electrons and the quanta of the photoinduced near-field is imaged synchronously with its

228 on of the photoproducts can be attributed to photoinduced oxidation of oil.

229 ty and the formation of metastable phases in photoinduced phase transition of VO2 are elucidated thro

230 ermal pathway for the initial process of the photoinduced phase transition.

231 hesis of photochromic liquid crystals (LCs), photoinduced phase transitions in LC, and photoalignment

232 The applications of photoinduced phase transitions, photoalignment, photomod

233 ormational analysis to explain unanticipated photoinduced pinacolization, as well as the regio- and s

234 antimicrobial properties of silver with the photoinduced plasmon-mediated photothermal effects of go

235 trinsic optoelectronic properties, including photoinduced polarization, high drift mobilities, and ef

236 nvestigation demonstrates the possibility of photoinduced polynitro-CNT explosion and provides a deta

237 efficiency is not enhanced by the ultrafast photoinduced process but achieved by the synergistic opt

238 y, we find that the experimentally indicated photoinduced process in the solvated complex is of backw

239 The focus of the review is on photoinduced processes and on electronic properties impo

240 in solution, proteins, electrochemistry, and photoinduced processes are presented, highlighting the i

241 Many photoinduced processes including photosynthesis and huma

242 Such photoinduced processes permit the engineering of propert

243 d electron transfer, oxidative and reductive photoinduced processes, charge separation and charge rec

244 eported that the Trp triad played no role in photoinduced proteolysis of dCRY in Drosophila cells.

245 an residues at the dimer interface engage in photoinduced proton coupled electron transfer reactions

246 eaction centers, are capable of generating a photoinduced proton gradient across the membrane.

247 ludes a major role of [Fe2(bdt)(CO)6](2-) in photoinduced proton reduction cycles.

248 The results of photoinduced proton transfer and voltage-driven proton-c

249 luminophore results in a complex cascade of photoinduced proton transfer processes and can be interp

250 processes, photoisomerization reactions, or photoinduced proton transfer.

251 rtant processes and serve as a prototype for photoinduced proton-coupled electron transfer (PCET).

252 icals from N-hydroxyphthalimide (NHPI) via a photoinduced proton-coupled electron transfer process is

253 trobenzene to aniline through six sequential photoinduced, proton-coupled electron transfers.

254 The photoinduced radical pairs persist up to temperatures of

255 FeMo-co state, denoted E4(2H)*, through the photoinduced re of the two bridging hydrides of E4(4H) a

256 n scattering (SERS), we directly monitor the photoinduced reaction dynamics of 4,4'-bipyridine molecu

257 Such ultrafast photoinduced reactions do no longer obey the Kasha-Vavil

258 Photoinduced reactions play an important role in the pho

259 The photoinduced rearrangement pathways of simple 2,5-dienon

260 vered surprises, especially the blinking and photoinduced recovery of emitters, which stimulated furt

261 The achievement of long-lived photoinduced redox separation lifetimes has long been a

262 We have studied photoinduced reduction of absorption and emission in p3h

263 h-molecular-weight dissolved organic matter, photoinduced reduction/oxidation of metal(hydrous)oxides

264 Here we demonstrate that time-resolved photoinduced reflectance from a semiconductor captures i

265 Photoinduced reflectivity changes distort the shape of t

266 These observations imply that photoinduced release of H2 involves a barrier to the com

267 Under basic conditions (pH = 11), a photoinduced release of the chloride anion followed by t

268 c structure and relaxation properties of the photoinduced state in Cu(hfac)2L(i-Pr) are very similar

269 However, it is not known how the photoinduced step is optimized in photolyase to attain m

270 strated, including: i) there is simultaneous photoinduced strengthening and healing after the materia

271 Photoinduced structural change (PSC) is a fundamental ex

272 Our results record the overall sequence of photoinduced structural changes in the foldamer, startin

273 processes and understanding the mechanism of photoinduced structural rearrangement are essential to a

274 The photoinduced structural switching results in spatial sep

275 Moreover, photoinduced structural transformation from 1D to 0D was

276 amine the influence of surface stress on the photoinduced structural transformation.

277 le fluorescent probes or as a source for the photoinduced supply of acidity.

278 which is rationalized by a larger number of photoinduced surface carriers.

279 This paper describes the photoinduced switching of conductance in tunneling junct

280 excellent photochromic properties allow the photoinduced switching of their second-order nonlinear o

281 rge transport and to attenuate the effect of photoinduced switching on the extent of current modulati

282 However, the photoinduced syntheses of non-metallic nanocrystalline p

283 Photoinduced syntheses offer significant advantages over

284 Herein, we demonstrate the first photoinduced synthesis of ultrafine (sub-2 nm) Ag2 S qua

285 Photoinduced threshold switching processes that lead to

286 -dimensional supramolecular polymer in which photoinduced through-space charge-transfer complexes lea

287 Photoinduced toxicity following coexposure to ultraviole

288 i-mahi embryos being at particular risk from photoinduced toxicity.

289 dition to electrochemical and photochemical (photoinduced transfer) measurements, suggests Zn-metalat

290 The photoinduced transformation of two ionic liquids, 1-meth

291 recent experimental and theoretical work on photoinduced transformations in fluorescent proteins.

292 ion of the degree of chemical and structural photoinduced transformations.

293 mployed to study the reaction pathway in the photoinduced transition of VO2, using bulk and strain-fr

294 he nature of and the impact of strain on the photoinduced transition of VO2.

295 Photoinduced transport through the bulk, into solution,

296 rap-assisted recombination through increased photoinduced trap states, PffBT4T-2OD:EH-IDTBR solar cel

297 Photoinduced water oxidation at the O2-evolving complex

298 Photoinduced water oxidation catalyzed by 1, in the pres

299 ricyclic core becomes electron-rich, and the photoinduced Wolff rearrangement produces a highly emiss

300 reported class of photoswitches, proceeds by photoinduced Z-E isomerization, followed by a thermal, c