ライフサイエンスコーパス: photolytic

1 ion to the N-acylhydrazones under thermal or photolytic (300 nm) conditions.

2 terface of the recording chamber after their photolytic activation in a diffraction-limited volume.

3 ium sulfate with methylglyoxal changes under photolytic aging by UVA radiation in the aqueous phase.

4 Photolytic aging induced significant changes in the ligh

5 (i)Pr)]}(2)(mu-eta(1):eta(1)-N(2)) (9) under photolytic and dark conditions, respectively, to produce

6 f dediazoniation in the IL (both thermal and photolytic) and the evolution of the products were direc

7 n IP3 receptor antagonist, and reproduced by photolytic application of IP3.

8 e explored further for the identification of photolytic aromatic dechlorination reactions.

9 Interestingly, photolytic back-transformation to SMX was observed for 4

10 By reducing the size of the photolytic beam, glutamate was released at several diffe

11 for photolysis, DECM-caged glutamate and its photolytic byproducts were found to be biologically iner

12 Neurons undergoing targeted photolytic cell death degenerate by apoptosis.

13 the O3 + hnu --> O((3)P) + O2(X(3)Sigmag(-)) photolytic channel at the interface, leads to an enhance

14 The pulsed photolytic chlorine-initiated oxidation of methyl-tert-b

15 e extent of isotope fractionation during SMX photolytic cleavage is pH-dependent.

16 This easy photolytic cleavage makes the NHC-boryl sulfides good ty

17 lytic cycle with thiophenol (PhSH) by way of photolytic cleaveage of the disulfide bond.

18 borylene that can be liberated by selective photolytic CO extrusion and that, although highly reacti

19 ue decomposed to inactive products under the photolytic conditions of the catalysis.

20 ith C60 in toluene solution under thermal or photolytic conditions produces C60{eta(1)-Ru(CO)2(eta(5)

21 Third, under photolytic conditions with hexamethylditin, primary radi

22 Under similar photolytic conditions, H/D exchange reactions between D2

23 xygen trapping products did not change under photolytic conditions, where dediazoniation occurs at ro

24 ion was achieved under both the tin-free and photolytic conditions; in this case, the adduct bears al

25 e-dependent paired-pulse facilitation of the photolytic currents, indicating that a change in the sub

26 Acetylenes undergo thermal and photolytic cycloaddition/1,5-sigmatropic rearrangement r

27 ally mimicking the effect of locomotion, and photolytic damage of VIP neurons abolished the enhanceme

28 Photolytic decarbonylation of 1 results in the incorpora

29 In this work, we investigated the photolytic dechlorination of 2-Cl- and 3-Cl-aniline to a

30 r current and previous work illustrates that photolytic dechlorinations of 2-Cl-, 3-Cl-, and 4-Cl-ani

31 h a yield of ca. 30-35% after correction for photolytic decomposition of 3b.

32 In addition, product studies confirmed clean photolytic decomposition to the expected alcohol, 2-hydr

33 oduct ArF is also formed in both thermal and photolytic dediazoniation, depending on the substituent(

34 These syntheses also feature stereospecific photolytic deformylation of beta,gamma-unsaturated aldeh

35 Because photolytic degeneration simulates some mechanisms underl

36 Photolytic degradation half-lives of TDBDPB ranged from

37 cabromodiphenyl ether (BDE-209), that formed photolytic degradation products in tetrahydrofuran (THF)

38 , which may be linked to a TDBDPB source via photolytic degradation to more bioavailable and persiste

39 tive depolymerization of gels produced under photolytic deliganding of CO hemoglobin S.

40 '-OH group by a thioacetyl unit, followed by photolytic deoxygenation or radical-based 2'-deoxygenati

41 the methane abundance was maintained against photolytic depletion throughout Titan's history, either

42 in the form of cyanuric acid, preventing the photolytic destruction of residual chlorine by sunlight.

43 n isotopic fractionation mechanism, based on photolytic destruction, to explain the 15N/14N and 18O/1

44 After photolytic dissociation of CO, the majority, but not all

45 denine dinucleotide phosphate induced by the photolytic event.

46 e) have been investigated by thermolytic and photolytic experiments to investigate the chemical react

47 The same ratios were reproduced via photolytic experiments, which suggested that the condens

48 d to solutions with SRN, indicating that the photolytic fate of select antibiotics varies for agricul

49 This study examined the photolytic fate of the chlortetracycline (CTC), ciproflo

50 Finally, the ability to analyze the photolytic fate of trace chemicals at natural abundance

51 ng carbons on the PAH framework, followed by photolytic formation and ejection of H(2).

52 Under MALDI conditions, partial photolytic fragmentation of the MBB-peptide bound occurr

53 haracterized as the radical 5b, based on its photolytic generation in the less polar CH(3)CN and on i

54 the appearance of vinylcyclopropyl following photolytic generation of pentadienyl is more likely the

55 Photolytic H(+) uncaging from 2-nitrobenzaldehyde also r

56 Neither N2 fixation nor direct photolytic hydrogenogenesis was significant to this H2 e

57 dary C(sp(3) )-H bonds, by either thermal or photolytic initiation, is supported by NMR and UV/Vis da

58 3- completely suppresses the yield of 3b The photolytic intermediate is identified as the aryloxenium

59 Prior photolytic labeling with agonist analogues of the neighb

60 -metal carbonyl complexes is demonstrated by photolytic liberation of CO and subsequent intramolecula

61 The photolytic lifetime of IMD at a solar zenith angle of 35

62 Photolytic ligand displacement and salt metathesis route

63 This strategy, using a photolytic ligation auxiliary and a desulphurization rea

64 The photolytic link between O3 and N2O is identified as the

65 5]- and [5.6.6.5]tetracyclic systems via the photolytic method of Livinghouse.

66 We have developed a photolytic method to determine the concentration of reac

67 ubility of the assembly was measured using a photolytic micromethod over a temperature range of 17-31

68 Key steps include a 'one-pot' photolytic N-N bond cleavage of a Group 6 dinuclear dini

69 r environments, thus, limiting the extent of photolytic OH sources.

70 transporter currents (GTCs) were induced by photolytic or synaptic glutamate release and isolated ph

71 d cis-fused gamma-lactones efficiently under photolytic or thermolytic conditions.

72 ent, the possibility of OH formation through photolytic pathways indoors has been ignored up to now.

73 ed BPs can be used as markers to distinguish photolytic PBDE transformation products from naturally p

74 However, under comparable conditions, no photolytic pH(2)/oH(2) interconversion was observed for

75 ne of the reasons why the quantum yields for photolytic polymer degradation (and long-chain molecules

76 spectrometry measurements confirmed that the photolytic process did not produce dye radicals.

77 most suitable model to explore environmental photolytic processes in situ.

78 material escaping from Pluto, as well as the photolytic processing of this material into more complex

79 at it is possible to adjust and modulate the photolytic product distribution by varying the parameter

80 concentrations, with desulfinyl fipronil (a photolytic product) contributing about 25%.

81 can therefore serve as a stable reactant for photolytic production of [5,6]-C(60)O.

82 Ca2+ release triggered by photolytic production of cADPr was initially slow, with

83 ccelerating growth may result from increased photolytic production of condensable organic species in

84 that Fe(III)-binding ligands can enhance the photolytic production of reactive iron species in the eu

85 lausible mechanism of formation of different photolytic products is suggested.

86 ng gulls are exposed (e.g., via the diet) to photolytic products of TeDB-DiPhOBz, OH-PB-DiPhOBz and o

87 d visible light spectroscopic signatures and photolytic rate constant in the troposphere.

88 kcal/mol) and, as a result, the (laser flash photolytic) rate constants for fragmentation were essent

89 ds and the formation of the O-O bond in this photolytic reaction involve low-energy triplet states an

90 e major component (approximately 86%) of the photolytic reaction is 45 microseconds, while that of th

91 Legrand et al. reported on the photolytic reaction of an alpha-pyrone confined in a cry

92 Product analysis of the photolytic reaction showed clean conversion of NPE-caged

93 by 71% within 50 ms of the initiation of the photolytic reaction when the concentration of released D

94 Preparation and varied thermal and photolytic reactions of 2-diazo-5,6-(disubstituted)acena

95 Over the past two decades, the photolytic reactions of dibenzyl ketones sorbed on zeoli

96 -bi-1,2,3-triazolyl) undergoes unprecedented photolytic reactivity to liberate free btz (Phi363 appro

97 In cerebellar slices rapid photolytic release (t (1/2) < 0.7 ms) of 7--70 microM L-

98 of the probe angle change and tension after photolytic release [Ca2+] by laser photolysis of NP-EGTA

99 In control experiments, photolytic release from photolabile precursors of carbam

100 The response to photolytic release of ADP showed that the rate of NADH d

101 ned at 0.09 ML s-1 immediately following the photolytic release of ATP and at 0.04 ML s-1 prior to th

102 ontractions were elicited at 12 degrees C by photolytic release of ATP from the P3 -1-(2-nitrophenyl)

103 rse of isometric force development following photolytic release of ATP in the presence of Ca(2+) was

104 bserved during brief activations elicited by photolytic release of ATP.

105 ured on activation from the relaxed state by photolytic release of Ca2+ from a caged Ca2+ compound, n

106 ulture, including puffer pipet spritzing and photolytic release of caged effectors, each is limited i

107 We used electrophysiological recording, photolytic release of caged glutamate and a newly develo

108 and Cl(-) currents following the controlled photolytic release of caged-InsP(3) or caged-Ca(2+).

109 Photolytic release of free alanine results in the genera

110 The photolytic release of free kainate from the caged kainat

111 ors of glutamate clearance after synaptic or photolytic release of glutamate in striatal slices.

112 current evoked by uncaging Ca(2+) or by the photolytic release of higher concentrations of InsP(3).

113 Photolytic release of InsP(3) elicited a transient outwa

114 the role of InsP3 in the induction of LTD by photolytic release of InsP3 from its biologically inacti

115 Photolytic release of IP(3) elicited a transient Ca(2+)

116 trypanosomes or isolated acidocalcisomes and photolytic release of IP(3) in intact trypanosomes loade

117 rlying the sEPSP was investigated with rapid photolytic release of L-glutamate from nitroindolinyl (N

118 ooth muscle, but rigor force decreased after photolytic release of Mg(2+) in the presence of ADP.

119 Photolytic release of MgADP (25-300 microM) from caged A

120 s, in the microsecond time scale through the photolytic release of substrates from caged compounds.

121 The photolytic release of substrates from caged substrates h

122 was invariably induced, even with low-level photolytic release of threshold amounts of InsP(3).

123 mixed-valence CO complex with (18)O(2) after photolytic removal of CO.

124 Potentiation of photolytic responses developed rapidly in a stepwise man

125 Also, neither this caged urea nor its photolytic side products inhibit hydrolysis of free urea

126 on resonance mass spectrometry of N(2)/CH(4) photolytic solid products at 60 and 82.5 nm indicates th

127 cordingly, the rate limitation in the second photolytic step originates from a slow calcium-induced d

128 2 Mn atoms are involved in the rate-limiting photolytic step under steady-state conditions.

129 (4) Prior to the next photolytic step, one Ca2+ ion must bind at its effector

130 Responses to strong synaptic and photolytic stimulation were selectively prolonged by sma

131 Time-resolved infrared (TRIR) flash photolytic techniques have been employed to initiate and

132 Steady-state and time-resolved photolytic techniques show that an efficient transductio

133 Applying LC/MS/MS, multiple photolytic transformation products of IPAs were observed

134 Photolytic uncaging and release of free glutamate occur

135 , we addressed this question by applying the photolytic uncaging approach to induce focal increases i

136 Localized photolytic uncaging of Ca(2+) from o-nitrophenyl-EGTA in

137 Photolytic uncaging of p-hydroxyphenacyl (pHP) GABA demo

138 -activation of presynaptic GABA receptors by photolytic uncaging of RuBi-GABA has a biphasic effect o

139 m using whole-cell patch-clamp recording and photolytic uncaging of RuBi-GABA.