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1 complete chemoselectivity (exclusive [2 + 2] photoproduct).
2 rent species (reactants and initially formed photoproducts).
3 usion of the metastable leuco-methylene blue photoproduct.
4 discovery of 2,8-dichlorodibenzodioxin as a photoproduct.
5 g the UV-induced pyrimidine-pyrimidone (6-4) photoproduct.
6 observed to contain detectable levels of any photoproduct.
7 token ligand to two spin states of the same photoproduct.
8 e dimers (CPDs), the primary ultraviolet DNA photoproduct.
9 The other state is an ICT-EPT photoproduct.
10 abatic relaxation to the ground state of the photoproduct.
11 crystallography to further characterize this photoproduct.
12 constitute the most frequent UV-induced DNA photoproduct.
13 taining the phenolate group becomes the sole photoproduct.
14 onds 5' and 5 phosphodiester bonds 3' to the photoproduct.
15 5'-N, 3'-S conformer gives rise to the (6-4) photoproduct.
16 t in the electronically excited state of the photoproduct.
17 ng to [Cl2Sb(IV)Pt(I)Cl(o-dppp)2] (1) as the photoproduct.
18 ood pathways that can culminate in mutagenic photoproducts.
19 ference for an adenosine downstream from 6-4 photoproducts.
20 o a lesser extent, affects the repair of 6-4 photoproducts.
21 for the dioxin, biphenyl, and phenoxyphenol photoproducts.
22 ost-photochemical transformations of primary photoproducts.
23 assess the fate of TBA metabolites and their photoproducts.
24 ssipating excess photoenergy and deleterious photoproducts.
25 ormation of emissive spectrally blue-shifted photoproducts.
26 leavage and the formation of highly oxidized photoproducts.
27 ly formed via subsequent reaction of primary photoproducts.
28 pplied radioactivity) and smaller amounts of photoproducts.
29 c acid, increasing the diversity of observed photoproducts.
30 emphasis was placed on identification of the photoproducts.
31 volunteers in vivo, whereas UVB induced both photoproducts.
32 ttack on cancer cells by radicals and Pt(II) photoproducts.
33 r PARP activity in the repair of UVR-induced photoproducts.
34 energy and prevent the formation of harmful photoproducts.
35 hen DNA is replicated before repair of these photoproducts.
36 sylase that can initiate BER of dipyrimidine photoproducts.
37 ty in MC and XP cells for ODD and UV-induced photoproducts.
38 rm the respective carbodiimides 5a,b as sole photoproducts.
39 n repair of replication forks stalled at DNA photoproducts.
40 h no effect was observed for repair of (6-4) photoproducts.
41 se might be responsible for the diversity of photoproducts.
42 -distorting DNA lesions, such as UV-induced photoproducts.
43 ion of oxidative modifications in bacitracin photoproducts.
44 imers (CPDs) and pyrimidine-pyrimidone (6-4) photoproducts.
45 induced DNA lesions, namely, thymidine (6-4) photoproducts.
46 arlier results reporting ketones as the main photoproducts.
47 excited states in DNA that lead to mutagenic photoproducts.
48 ed manually generating a suspect list of 108 photoproducts.
49 s C in aqueous NaOH forms three substitution photoproducts: 2-methoxy-5-nitrophenol (2), 2-chloro-4-n
50 n authentic samples of two of the identified photoproducts, 5-chloro-methylaminobenzophenone and 2-am
52 CPD), but not of pyrimidine (6, 4)pyrimidone photoproducts (6-4PP) following UV irradiation of mammal
55 let (UV)-induced (6-4) pyrimidine-pyrimidone photoproduct [(6-4) PP] confers a large structural disto
56 24, and 48 h) and (6-4)pyrimidine-pyrimidone photoproducts [(6-4)PPs] (at 5 and 20 min and 1, 2, and
57 imers (CPDs) and pyrimidine-pyrimidone (6-4) photoproducts [(6-4)PPs] from UV-irradiated cellular and
58 imers (CPDs) and pyrimidine (6-4) pyrimidone photoproducts [(6-4)PPs] that must be repaired for the s
59 clobutane pyrimidine dimers (CPDs) and (6-4) photoproducts [(6-4)PPs], based on direct UV absorption
61 diation on DNA is the formation of the (6-4) photoproduct, 6-4PP, between two adjacent pyrimidine rin
62 rimidine dimers, pyrimidine (6-4) pyrimidone photoproducts (64PPs) and their related Dewar valence is
65 o metarhodopsin-II-like species and aberrant photoproduct accumulation with prolonged illumination.
66 these unique nonadjacent anti thymine dimer photoproducts also form in vivo, they would constitute a
67 an alter ovarian follicular development, and photoproducts alter whole-body 17beta-estradiol levels.
68 stem cells (CD34LC) were treated with the UV photoproduct and AhR ligand 6-formylindolo[3,2-b]carbazo
69 lindolo[3,2-b]carbazole (FICZ), a tryptophan photoproduct and endogenous high-affinity aryl hydrocarb
71 ps to 1 ns within the spectral range of the photoproduct and is attributed to an equilibration betwe
72 etical study of the reaction between the NH2 photoproduct and O2 in the presence of H2O supports the
73 on adds to MV(2+) to form a covalently bound photoproduct and, subsequently, evolves toward a conical
74 ing 2H-azirine 3 and ketenimine 6 as primary photoproducts and also to nitrile ylide 4 and 2,5-dimeth
75 reactive oxygen species (ROS) as well as 6-4-photoproducts and cyclobutane pyrimidine dimers (CPD) in
78 degradation and the bioactivity of resulting photoproducts and metabolites, pesticide photochemistry
80 (320-400 nm) irradiation-induced ODD and UV photoproducts and the repair capacity in MC and XP cells
81 s the sole pathway in humans for removing UV photoproducts, and DNA replication are regulated by the
82 is of the QD-molecule systems shows that the photoproduct aniline, left unprotonated, serves as a poi
83 bovine serum albumin (BSA), and intermediate photoproducts are allowed to decay, mouse rods are stabl
85 UVA/6-TG, indicating that potentially lethal photoproducts are not selectively excised from transcrib
90 cological implications by characterizing the photoproducts arising from the direct photolysis of 17be
91 t previously been characterized nor have any photoproducts arising from this transition been identifi
94 FS, and XANES results give no indication the photoproducts bind to either silica matrix, and consolid
95 mation of two distinct solvated monocarbonyl photoproducts, both of which arise from the same triplet
97 ase excision repair of pyrimidine-pyrimidine photoproducts but produce all the other proteins require
98 cleotide excision repair (NER) removes these photoproducts, but whether NER functions at telomeres is
99 etylated and this enhances the repair of DNA photoproducts by the nucleotide excision repair (NER) pa
101 ion can greatly exceed the rate at which the photoproduct can be recycled back to the chromophore by
104 that the formation of blue-shifted emissive photoproducts can have implications for analyzing single
105 in promoting replication through a (6-4) TT photoproduct carried on a duplex plasmid where bidirecti
106 Stat3 influenced the survival of ultraviolet-photoproduct cells, including those located in the hair
107 ranging from 310 to 500 nm reveal two major photoproduct channels corresponding to homolysis of aryl
109 elomeres exhibit approximately twofold fewer photoproducts compared with the bulk genome in cells, an
110 3 ps, whereas the rest goes on to the Lumi-R photoproduct consistent with the 15% photochemical quant
111 hat were no longer photoactive, with primary photoproducts consisting of monohydroxy species and pres
112 chemiluminescent detection of the excised UV photoproduct-containing oligonucleotides that are releas
114 ron and proton transfer steps, the resulting photoproduct decays via concerted PCET (tau = 4.7 mus) w
115 an spectroscopy of the corresponding trapped photoproduct demonstrates that this rapidly formed P1 in
117 lysis of these materials yields a mixture of photoproducts deriving from the presence of both carbene
118 delayed appearance after that of the primary photoproduct, diiodide radical I2(*)(-), indicates that
120 ry complex, and time-resolved probing of the photoproduct dynamics by using ultraviolet-visible absor
121 cob(II)alamin-5'-deoxyadenosyl radical pair photoproduct, either through an increased barrier to rec
122 dent manner, showing that the presence of UV photoproducts enhances spontaneous unwrapping of DNA fro
123 aging agents such as UV light (generating UV photoproducts), ethyl methanesulfonate (generating alkyl
124 at UV-stalled replication forks, it promotes photoproduct excision, suppression of translesion synthe
125 CBCRs; some examples were stable as the 15E photoproduct for days, while others reverted to the 15Z
126 d axis of a nucleosome and find that whereas photoproduct formation and deamination is greatly inhibi
128 nospot blotting to examine the efficiency of photoproduct formation and removal at telomeres purified
129 e-binding protein TRF1 significantly reduces photoproduct formation in telomeric fragments in vitro.
134 site cyclobutane pyrimidine dimers and (6-4) photoproducts formed at the TT, TC, and CC dipyrimidine
135 2)) during all the experiments, and the main photoproducts formed were characterized through accurate
138 or some Delta-S,S-Ru2H(2)/Lambda-R,R-Ru2H(2) photoproducts from Lambda to Delta (or vice versa) while
139 sion repair pathway removes ultraviolet (UV) photoproducts from the human genome in the form of short
140 ally excited molecules instead form a stable photoproduct G*C* that has undergone double hydrogen-ato
142 s have a reduced repair capacity for ODD and photoproducts; H(2)O(2) modified- and UVC-irradiated DNA
143 ionalities, and interestingly, the resulting photoproducts had spectral characteristics similar to th
147 oncentrations of the still-bioactive primary photoproduct hydroxylated 17alpha-TBOH, produced via pho
148 UVA in the induction of ODD but not bulky UV photoproducts; (ii) the high susceptibility to UVA-induc
149 (GTATCATGAGGTGC) gave rise to an unknown DNA photoproduct in approximately 40% yield at acidic pH of
150 ies determine the spin state of the CpCo(CO) photoproduct in solution on the picosecond time scale.
151 n the ratio between the different classes of photoproducts in basal and induced DNA damage suggests t
152 wavelengths of light induce the formation of photoproducts in DNA that are potentially mutagenic if n
155 ate TLS across cyclobutane pyrimidine dimers photoproducts in living cells, presenting a novel role o
156 To better define the nature of these DNA photoproducts in marine bacterioplankton and eukaryotes,
160 epair of carcinogenic UV irradiation-induced photoproducts in the DNA, such as cyclobutane pyrimidine
162 tifacts due to rotation of rhodopsin and its photoproducts in the membrane, probe light in the time-r
163 oate series; (2) their transformation to the photoproducts in the pentaenoate and then mycolactone se
164 via (1) structure determination of the four photoproducts in the tetraenoate series; (2) their trans
167 derlines the pivotal role of UVA-induced DNA photoproducts in UVA mutagenesis and carcinogenesis.
170 et reactivity for 16-electron organometallic photoproducts, in which triplets were not believed to in
171 sis of triclosan resulted in several primary photoproducts including the following: 2,8-dichlorodiben
178 at 500 +/- 10 nm, an electron-transfer (ET) photoproduct is observed to form with a time constant of
179 containing a cis-syn TT dimer or a (6-4) TT photoproduct is severely inhibited in human cells and th
181 Cyclobutane pyrimidine dimers (CPDs) are DNA photoproducts linked to skin cancer, whose mutagenicity
187 SAM (S-adenosylmethionine) enzyme, the spore photoproduct lyase (SPL), at the bacterial early germina
188 and repaired by a radical SAM enzyme, spore photoproduct lyase (SPL), at the early germination phase
190 derivatives, most of the aldehyde and ketone photoproduct mass spectra observed from the aqueous phas
192 nts of the azido probes even in the inactive photoproduct Meta I, well before the active receptor sta
194 motif and the possibility that this type of photoproduct might also form in other folded structures,
195 cate that low concentrations of 17alpha-TBOH photoproduct mixtures can alter ovarian follicular devel
196 ed that transcription-coupled repair of both photoproducts occurs exclusively on the template strand.
199 3,4-dihydroxybenzoic acid (3,4-DHB), and the photoproduct of FePB (FePB(nu)) also mediate iron delive
200 ein YclQ, are unable to use either PB or the photoproduct of FePB (FePB(nu)) for iron delivery and gr
201 s identified as a significant and stable UVA photoproduct of free 6-TG, its 2'-deoxyribonucleoside, a
202 Here we show that the 221 cm(-1) mode of the photoproduct of iNOS(P420) does not exhibit any H(2)O-D(
204 Although thymidine is the predominant UVA photoproduct of S(4)TdR in dilute solution, more complex
205 rmylindolo[3,2-b] carbazole (FICZ), is a UVB photoproduct of tryptophan and a powerful UVA chromophor
206 mistry and photosynthetic dynamics--in which photoproducts of chemical and biochemical reactions can
210 ng to reversion to the primary cycloaddition photoproduct on a time scale of hours to days, with the
211 yminyl-5,6-dihydrothymine (also called spore photoproduct or SP) is the exclusive DNA photodamage pro
212 yl-5,6-dihydrothymine (commonly called spore photoproduct or SP) is the exclusive DNA photodamage pro
213 minyl)-5,6-dihydrothymine, also called spore photoproduct or SP, is commonly found in the genomic DNA
215 abasic site, a cis-syn TT dimer, a (6-4) TT photoproduct, or a G-AAF adduct--we show that Rad5 is ne
216 tion of 5-thyminyl-5,6-dihydrothymine (spore photoproduct, or SP), coupled with the efficient repair
224 er of forms of damage in DNA, of which (6-4) photoproducts present the most formidable challenge to D
229 samples of large amounts of DEWs, a class of photoproducts rarely considered outside photochemical st
230 ir proteins survey the genome for UV-induced photoproducts remains a poorly understood aspect of the
231 ound that although p53 status contributed to photoproduct removal efficiency, its role did not seem t
232 that the Ino80-C contributes to efficient UV photoproduct removal in a region of high nucleosome occu
234 similarly increased XPC mRNA expression and photoproduct removal with less toxicity than with the am
235 ess to diverse core scaffolds in the primary photoproducts, rendering the approach compatible with th
236 ently available methods for investigating UV photoproduct repair in vivo, we developed a convenient n
238 t in 11 of 12 melanoma cell lines tested, UV photoproduct repair occurred as efficiently as in primar
240 xidized 6-TG and a previously identified UVA photoproduct--replaces 6-TG, suggesting that G(SO3) is a
242 play a crucial role for obtaining long-lived photoproducts resulting from multiphoton, multielectron
243 r, it is often thought that any diversity of photoproducts results from different conical intersectio
244 one receptor screening revealed that certain photoproducts retain significant androgenic activity, wh
245 fter visible irradiation, SFM imaging of the photoproducts revealed both the structural implications
246 e 1.55 A resolution crystal structure of the photoproduct reveals retention of the O-binding mode for
247 deoxyuridine and pyrimidine (6-4) pyrimidone photoproduct, reveals that neither reaction is reversibl
248 n was used to quantify the appearance of two photoproducts [Ru(bpz(-))(bpz)(deeb)](+) and I(2)(-*).
253 nes, suggesting that the fate and effects of photoproducts should also be incorporated into future ri
255 hermore, spectral analysis of the melanopsin photoproduct shows the formation of a protonated metarho
256 s a covalent UV-induced thymine dimer, spore photoproduct (SP), in germinating endospores and is resp
258 othymine, which is commonly called the spore photoproduct (SP), the Cadet laboratory found an incompl
260 othymine, commonly referred to as the "spore photoproduct" (SP), and 5,6-dihydro-2'-deoxyuridine (dHd
264 Our results will allow disentangling of photoproduct states in flavoproteins in often-encountere
266 ral similarity to parent steroids, and these photoproducts still retain enough biological activity to
268 efficient formation of this interstrand-type photoproduct suggests the existence of a new type of fol
270 oheptane thioketones by (1)O2 can yield more photoproducts than exclusively ketones and sulfines.
271 wledge, the first observation of a transient photoproduct that exhibits an equilibrium between two st
272 roposed where an iodine atom was the primary photoproduct that subsequently reacted with iodide, I(*)
273 sulting in chemically reduced and persistent photoproducts that are likely to exhibit transport and t
274 ndiscriminate, leading to a large mixture of photoproducts that are observed using high-resolution el
275 om cyclobutane pyrimidine dimers (CPDs), DNA photoproducts that are typically created picoseconds aft
276 of the tolerance of the UV light-induced 6-4 photoproduct, the tobacco smoke-induced benzo[a]pyrene-g
278 lations, allow us to assign the two solvated photoproducts to singlet and triplet CpCo(CO)(solvent) c
280 by a quantum chain process where the excited photoproducts transfer energy to neighboring molecules o
284 hemical capstone modification of the primary photoproducts via Suzuki coupling provides rapid access
286 verse photoconversion of the green-absorbing photoproduct was not significant in restoring the dark s
287 The percent conversion to dioxin and other photoproducts was determined and the natural product, 6-
288 f PUV irradiation and the formation of major photoproducts was observed to increase as a function of
294 r column at the end of the 63-day study; the photoproducts were the major degradates in the aqueous a
295 e dimers (CPD) and pyrimidine(6-4)pyrimidone photoproducts, which interfere with DNA replication and
296 ion, leading to two regioisomeric (exo/endo) photoproducts with complete chemoselectivity (exclusive
298 retinal binding pocket, converting into the photoproduct within about 100 ps, whereas the blue form
300 r structural features of aldehyde and ketone photoproducts without interference from the many tens of
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