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1 te undergoes a second redox cycle to produce picolinate.
2 n of a novel class of densely functionalized picolinates.
3 otide binding motif in competition with FAD, picolinate (0.07 mol/mol of nikD) and an unknown picolin
4 converts piperideine 2-carboxylate (P2C) to picolinate, a key component of the nonribosomal peptide
5 C results in the stoichiometric formation of picolinate, accompanied by the reduction of 2 mol of oxy
6 zation of piperideine-2-carboxylate (P2C) to picolinate, an essential component of nikkomycin antibio
9 oci that conferred significant resistance to picolinate auxins such as picloram, yet had minimal cros
10 ved for complexes of the reduced enzyme with picolinate, benzoate, or 1-cyclohexenoate, a 1-deaza-P2C
13 d is eliminated upon mixing nikD with excess picolinate but not by a reversible unfolding procedure t
14 ) arene complexes [(eta(6)-arene)Os(4-methyl-picolinate)Cl] that differ only in their arene ligands a
15 this question, we used a novel member of the picolinate class of synthetic auxins that is structurall
16 The nutritional dietary supplement chromium picolinate, [Cr(pic)(3)], has gained much notoriety as a
17 sly reported that the micronutrient chromium picolinate (CrP), with long-standing cardiovascular bene
18 plements were identified: chitosan, chromium picolinate, Ephedra sinica, Garcinia cambogia, glucomann
19 alyst for the hydrolysis of the coordinating picolinate ester 11, following Michaelis-Menten kinetics
22 produce an isomer that could be oxidized to picolinate in a reaction that satisfies known steric con
23 dation of piperideine-2-carboxylate (P2C) to picolinate in a remarkable aromatization reaction compri
24 ersible unfolding procedure that removes the picolinate-like compound, ruling out both compounds as t
26 esolution HPLC method, capable of separating picolinate, nicotinate and isonicotinate, was developed
27 the observed 4-electron oxidation of P2C to picolinate occurs via a mechanism involving two successi
28 mumol Cr/d (924 micrograms Cr/d) as chromium picolinate or a low-chromium placebo for 12 wk while eng
29 3-3.5 mumol as chromium chloride or chromium picolinate) or placebo (0.1 mumol Cr) and weight trainin
30 oss-bridged cyclam derivative containing two picolinate pendant arms are kinetically inert in very ha
31 mides were successfully coupled with various picolinate salts under mild conditions in yields up to 9
32 saturation was decreased more with chromium picolinate supplementation (24%) than with chromium chlo
34 These data suggest that high-dose chromium picolinate supplementation for 12 wk did not influence h
35 This study examined the effects of chromium picolinate supplementation on hematologic indexes and se
39 2) 1.92 micromol (100 microg) Cr as chromium picolinate two times per day, or 3) 9.6 micromol (500 mi
40 he analogous reactions with PicAuCl2 (Pic =2-picolinate) were found to proceed by selective 1,3-acylo
41 pon the rate of reduction in the presence of picolinate with a pK(a) of 7.4, identical to the pK(a) o
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