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1 distance of the peptide bond or the peptide planarity.
2 ivative 3 are predicted to be distorted from planarity.
3 s amino acid to alanine leads to chromophore planarity.
4 formations that are extremely distorted from planarity.
5 he geometry of the complex considerably from planarity.
6 function to maintain the heme distorted from planarity.
7 ridgehead substituents and bridging rings on planarity.
8 that the system deviates significantly from planarity.
9 ch as the deformation of aromatic rings from planarity.
10 OX heme cofactor is extremely distorted from planarity.
11 C(2v) structure with a large distortion from planarity.
12 hosphatidylcholine bilayer surfaces approach planarity.
13 correlation between E(1/2)(ox) and degree of planarity.
14 d/or by disruption of the bridging base-pair planarity.
15 d reduce deformation of the chromophore from planarity.
16 me (d(z)(2)) orbital enhanced by iron out-of-planarity.
17 dge and there is substantial distortion from planarity.
18 a angles deviating by nearly 20 degrees from planarity.
19 ngly, Phe228 is significantly distorted from planarity.
20 peptide bonds systematically deviating from planarity--a net deviation of 53 degrees across five res
21 inducing conformational control and enhanced planarity along a polymer or small molecule backbone at
22 ortions of the Fe(2)S(2) inorganic core from planarity and displacements of the polypeptide chain.
23 k is generated, removing the distortion from planarity and enhancing the influence of the substituent
26 S1P1 agonists are described extending beyond planarity and lipophilicity, and the impact and consider
27 s 18a and 18b were canted significantly from planarity and projected the imidazoline substituents R(1
29 ions to endogenous FFAs, focused on breaking planarity and reducing lipophilicity, led to the identif
31 d several other compounds indicated that the planarity and size of a molecule are important in its in
32 chain orientation enables increased backbone planarity and steric accessibility, and finally a planar
33 ed, which could be attributed to the similar planarity and sugar conformations for these two derivati
34 groups can vary by more than 25 degrees from planarity and that the true extent of nonplanarity is un
35 arities are structural features such as ring planarity and the absence of bond length alternation, sp
36 f the coumarin moiety can reduce the overall planarity and thus resonance of the coumarin nucleus, re
37 Conjugation effectiveness, electron density, planarity, and geometry of charge-transfer pathways were
39 nonplanar, deviating by over 20 degrees from planarity, are not strongly associated with active sites
40 d pi-extension and substantial twisting from planarity, are reported: specifically, two-ring 2TTMC, d
42 aggregated form of TPE-mercury ions recovers planarity because of restricted rotational freedom promo
43 ations indicate that, despite differences in planarity between the molecules, the photophysical prope
44 ing the C-F bond of the radical anion out of planarity but also by increasing the exothermicity of th
45 gineered media not only maintain the surface planarity but also the homogeneity of the magnetic mater
47 are highly twisted, and this distortion from planarity can dramatically affect the stability and reac
48 esence of false-positives due to the maximal planarity constraint, and the inadequacy of the clusteri
49 quid phase, where structure, width, and edge planarity could be controlled chemically at the atomic l
50 n the hydrazone moiety, identified by a high planarity degree at the pyrrolidine N(sp(3)) atom, that
52 active site of the E24Q enzyme deviates from planarity due to a 30 degrees twist of the carboxylate p
57 erestingly, however, the effect of molecular planarity has greater impact on PCB sorption to the nano
59 shows that a higher propensity for backbone planarity in PBDT[2F]T leads to more pronounced, yet sta
62 fluorine atom caused a small deviation from planarity in the chrysene series and decreased nonplanar
63 events these macrocycles from achieving full planarity in the ground state, and the ethynylene moieti
64 valine residues may allow the heme to regain planarity instead of being significantly ruffled, as in
65 idging adjacent rings for maintaining a high planarity, introduction of electron-withdrawing units fo
67 y as well as distortion of the rhomboid from planarity, leading to channels that can be observed from
69 ibutes to small deviations from peptide bond planarity (<omega> = 179.3 +/- 3.1 degrees ) to the same
70 menon is not exclusive to cyclic systems-non-planarity may also be a critical biological design eleme
72 lfgang Roth proposed that a system forced to planarity might have a smaller preference for the conrot
73 transition, and significant deviations from planarity occur only at higher temperatures, but well be
74 The backbone bond lengths, bond angles, and planarity of a protein are influenced by the backbone co
75 expected mechanistic subtleties, such as the planarity of an azatrimethylenemethane diyl intermediate
76 e weaker bonding in the Nb-N network, the co-planarity of Nb-N layer as well as its relatively weaker
79 hain of Trp-86 has the largest impact on the planarity of retinal, and the mutation of this amino aci
84 If the chlorine added does not distort the planarity of the conjugated core, we found that the chlo
86 very significant distortion that breaks the planarity of the extended BODIPY pi system due to the st
87 conformation that significantly distorts the planarity of the extended conjugated system between the
88 zation, for the first time, we show that the planarity of the furan backbone is almost unaffected by
89 as well as cis-indene carbonate display near planarity of the fused cyclopentene and benzene rings.
90 determined to a large part by the degree of planarity of the fused ring system whereas functional se
92 ric distortion is due to the requirement for planarity of the hydrogen bond connecting the two octade
93 perties of I and II are similar, whereas the planarity of the ligand in III greatly lowers the energy
95 on annealing is attributed to an increase in planarity of the P3HT chains that is determined from the
96 ing pocket of the PDE10A enzyme to alter the planarity of the parent compound 1 and optimize its affi
98 e have found evidence of correlation between planarity of the polymer chain and localization of the h
105 at the macrocycles considerably diverge from planarity, particularly when methoxy substituents are pr
107 excessive dendritic protrusion with loss of planarity, reduced resurgent sodium currents and abnorma
108 tic control in interlayer stacking and layer planarity renders an ordered network with a surface area
109 -hairpin structure of Tyrc A with additional planarity, resulting in approximately 30-fold reduced he
112 fy favorable monomer properties such as core planarity, solubilizing substituent tailorability, and a
113 up away from the benzene ring or the greater planarity that results from the additional cyclic struct
114 ring-opening transition structure approaches planarity, the energy gap between allowed conrotatory an
115 ent with no restraints on bond distances and planarity, the nicotinamide rings in the two complexes a
116 of the molecule shows strong deviation from planarity, the similar electrical resistance of the diff
118 oporphyrin IX group, which is distorted from planarity to an extent not seen before in protein-bound
119 etries showed only slight shifts to the base planarity upon dearomatization by epoxidation, which is
121 c acid are significantly distorted away from planarity, which apparently disrupts their internal hydr
122 sses longer effective conjugation and better planarity, which improves electron delocalization along
124 lative, deviations from ideality in backbone planarity, which, if ignored, also lead to major errors
125 ineC-N-C(O) units deviate significantly from planarity with dihedral angles around the imide group re
126 maticity: energetic (stability), structural (planarity with equal bond lengths), and magnetic (negati
127 ements of the peripheral vinyl groups toward planarity with the heme macrocycle by cyt b 5 but away f
128 corrole ring showed a large distortion from planarity, with the Th(IV) and U(IV) ions residing unusu
129 pocket that permit the heme to relax toward planarity, yielding the signaling-competent NO-bound con
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