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1 blackberry formation for a non-Mo-containing polyoxometalate.
2 now facilitate efforts to design functional polyoxometalates.
3 sport studies of magnetically functionalized polyoxometalates.
4 of molecular oxygen in reactions mediated by polyoxometalates.
5 {P2 W18 } (3), and {Mo12 O36 (HPO3 )2 } (4) polyoxometalates.
6 ns, flexibility and dynamic is possible with polyoxometalates.
8 (31)P NMR shows that the Cu-NO2-substituted polyoxometalates act as oxygen donors to the C-C double
11 r the screening and scale up of syntheses of polyoxometalates and manganese-based single-molecule mag
12 the process of the self-assembly of gigantic polyoxometalates and their subsequent molecular growth,
13 l and biological sciences, are a subclass of polyoxometalates and usually self-assemble in aqueous-ph
14 table redox states (e.g., metalloporphyrins, polyoxometalates, and C60) is more particularly discusse
15 clude aluminum polycations, transition-metal polyoxometalates, and the actinyl peroxide clusters have
16 2)Mo(18)O(62)](4-), and [S(2)W(18)O(62)](4-) polyoxometalate anions (POMs) and oxidation of water occ
17 including but not limited to combinations of polyoxometalate anions and redox-active cations, was con
19 show that equilibration reactions typical of polyoxometalate anions keep the pH of the system near 7
29 porating phosphorus(III)-based anions into a polyoxometalate cage, a new type of tungsten-based uncon
32 we describe how building block libraries of polyoxometalates can be used to construct systems with i
35 munication describes a new method for the Pd/polyoxometalate-catalyzed aerobic olefination of unactiv
37 elope of both events and employ it for a new polyoxometalate cluster, Na6 [Mo120 Ce6 O366 H12 (H2 O)7
38 amolecular assembly of a series of nanoscale polyoxometalate clusters (from the same one-pot reaction
40 nd have many common building blocks; in fact polyoxometalate clusters are perhaps the largest non-bio
41 hods for the grafting of peptide chains onto polyoxometalate clusters by the use of general activated
43 lecular nanostructures like coordination and polyoxometalate clusters is extremely time-consuming sin
49 ns to produce an aqueous solution of reduced polyoxometalate compounds that can be used to generate p
51 as an active catalyst, and iron(II) and the polyoxometalate H(5)PMo(10)V(2)O(40) (POM-V2) were ident
53 at all structural sites in two isostructural polyoxometalates, [H(x)Nb(10)O(28)]((6-x)-) and [H(x)Ti(
55 molecular water oxidation catalysts based on polyoxometalates have been reported that combine the adv
59 hould aid in the exploitation of these giant polyoxometalates in solution for various applications.
61 enerally applicable strategy for integrating polyoxometalates into functional architectures and devic
63 nd composition suggests reaction pathways in polyoxometalate ions will be highly variable even within
64 ared by pretreatment of the aqua-coordinated polyoxometalates (L = H2O) with NO2 or are formed in sit
65 based on redox-active (vanadate(V)-centered) polyoxometalate ligands, Na10[Co4(H2O)2(VW9O34)2].35H2O
66 c hybrid molecule comprising two Dawson-type polyoxometalates linked by a 2,2'-bipyridine unit, which
67 very similar to the unique self-assembly of polyoxometalate macroanions into single-layer, spherical
68 onstruct complex chemical systems based upon polyoxometalates, manipulating the templating/self templ
69 demonstrating the crucial role played by the polyoxometalate metal oxide cluster as an intermediary i
70 g a terminal aromatic pyrene platform with a polyoxometalate Mn-Anderson cluster as linker, demonstra
72 been achieved using the ruthenium-containing polyoxometalate molecular catalyst, [{Ru4O4(OH)2(H2O)4}(
73 Here we show that a molybdenum(VI) oxide 'polyoxometalate' molecular nanocluster containing two em
75 inorganic hybrid complexes between CB[n] and polyoxometalates not only display a surprisingly high st
77 ptor anion, alpha-SiV(V)W(11)O(40)(5-) (1, a polyoxometalate of the Keggin structural class), was use
79 and programmed assembly of a dumbbell-shaped polyoxometalate-organic hybrid molecule comprising two D
81 fter as (COD)Ir.POM(8-), where POM(9-) = the polyoxometalate, P2W15Nb3O62(9-)) under H2 is investigat
83 een applied to the study of the reduction of polyoxometalate [PMo12O40](3-) adsorbed at a boron doped
85 ed, dimeric, ZrIV-substituted Lindqvist-type polyoxometalate (POM) (nBu4N)6[{(mu-MeO)ZrW5O18}2], (TBA
86 report the encapsulation of a Ni-containing polyoxometalate (POM) [Ni4 (H2 O)2 (PW9 O34 )2 ](10-) (N
87 f pure approximately 0.75 nm size molybdenum polyoxometalate (POM) anions on 25 mug ( approximately 0
88 SS), [60]fullerene (C60), and Lindqvist-type polyoxometalate (POM) are used as building blocks to con
90 In this review we discuss the relevance of polyoxometalate (POM) chemistry to provide model objects
92 hybrid molecules containing a large anionic polyoxometalate (POM) cluster and two C6 and C16 alkyl c
93 nteract with the conjugate anion in W and Mo polyoxometalate (POM) clusters and gaseous mineral acids
95 eactions on Bronsted acid catalysts based on polyoxometalate (POM) clusters are described in terms of
96 he contribution of building blocks of Keggin polyoxometalate (POM) clusters to redox processes are ch
97 a representative series of Keggin and Dawson polyoxometalate (POM) films in contact with a metallic (
102 ance fuel cells that are catalyzed solely by polyoxometalate (POM) solution without any solid metal o
104 self-assembly of hydrophilic Keplerate-type polyoxometalate (POM) {Mo(72)Fe(30)} macroanions into si
105 anion size and charge allows the Keggin-type polyoxometalate (POM), [CuPW(11)O(39)](5-), a catalyst f
106 ecognition processes involving a Dawson-type polyoxometalate (POM), [P2W18O62](6-), a cationic electr
107 This strategy employs a single material, a polyoxometalate (POM), alpha(2)-[P(2)W(17)O(61)](10-), t
108 osmotically driven crystal morphogenesis of polyoxometalate (POM)-based crystals is investigated, wh
109 driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing remote terpyr
110 Wells-Dawson [alpha(2)-P(2)W(17)O(61)](10-) polyoxometalate (POM)-supported [Re(CO)(3)](+) complex c
111 ocation process of countercations around one polyoxometalate(POM)-organic hybrid anionic cluster at v
117 of mononuclear lanthanoid complexes based on polyoxometalates (POMs) that exhibit single-molecule mag
118 peroxoniobium compounds to the corresponding polyoxometalates (POMs), alpha(1)-K(7)[P(2)W(17)NbO(62)]
119 , enzymes, ...) and inorganic molecules like polyoxometalates (POMs), which have very interesting app
120 Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymm
121 catalyst hypothesis: (i) six vanadium-based polyoxometalate precatalysts, (n-Bu4N)4H5PV14O42, (n-Bu4
125 of 10-20 nm by post-process immersion into a polyoxometalate solution (phosphomolybdic acid, PMA) in
127 rected assembly of a ring-shaped macrocyclic polyoxometalate structural building unit, {P(8)W(48)O(18
128 ew method to identify metallic nanoclusters (polyoxometalate structures) in solution at the single mo
129 ation to minimize steric clashes between the polyoxometalate subunits, in order to stabilize the corr
131 s, is described using copper(II)-substituted polyoxometalates, such as {alpha2-Cu(L)P2W17O61}(8-) or
133 ates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical
134 in the reaction mechanism by protonating the polyoxometalate thereby enabling the activation of the m
136 id growth of tubes occurs from crystals of a polyoxometalate upon addition of an aqueous solution con
137 999, a catechol dioxygenase derived from a V-polyoxometalate was reported which was able to perform a
138 hat SMOF-1 adsorbs anionic Wells-Dawson-type polyoxometalates (WD-POMs) in a one-cage-one-guest manne
139 and water activation on multi-Ru-substituted polyoxometalates were studied using the B3LYP density fu
140 u(+) and Bu3Sn(+) cations coordinated to the polyoxometalate, which were also identified by ESI-MS.
141 y of ([UO2(O2)OH]60)(60-) (U60), an actinide polyoxometalate with fullerene topology, can be induced
142 The technique allows the measurement of polyoxometalates with over 2 orders of magnitude lower a
143 self-assembly of an equilibrated ensemble of polyoxometalates, with the heteropolytungstate anion [AI
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