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1 blackberry formation for a non-Mo-containing polyoxometalate.
2  now facilitate efforts to design functional polyoxometalates.
3 sport studies of magnetically functionalized polyoxometalates.
4 of molecular oxygen in reactions mediated by polyoxometalates.
5  {P2 W18 } (3), and {Mo12 O36 (HPO3 )2 } (4) polyoxometalates.
6 ns, flexibility and dynamic is possible with polyoxometalates.
7      Finally, inhibition of CD39 activity by polyoxometalate-1, a pharmacologic inhibitor of nucleosi
8  (31)P NMR shows that the Cu-NO2-substituted polyoxometalates act as oxygen donors to the C-C double
9 hesized gold nanoparticles (AuNPs) and alpha-polyoxometalate (alpha-POM) (K7PMO2W9O39 .
10 but less common than other Keggin isomers in polyoxometalate and polyoxocation chemistry.
11 r the screening and scale up of syntheses of polyoxometalates and manganese-based single-molecule mag
12 the process of the self-assembly of gigantic polyoxometalates and their subsequent molecular growth,
13 l and biological sciences, are a subclass of polyoxometalates and usually self-assemble in aqueous-ph
14 table redox states (e.g., metalloporphyrins, polyoxometalates, and C60) is more particularly discusse
15 clude aluminum polycations, transition-metal polyoxometalates, and the actinyl peroxide clusters have
16 2)Mo(18)O(62)](4-), and [S(2)W(18)O(62)](4-) polyoxometalate anions (POMs) and oxidation of water occ
17 including but not limited to combinations of polyoxometalate anions and redox-active cations, was con
18            Unlike metallo-organic catalysts, polyoxometalate anions are oxidatively stable and are re
19 show that equilibration reactions typical of polyoxometalate anions keep the pH of the system near 7
20                                              Polyoxometalates are anionic metal oxide clusters of a v
21                                              Polyoxometalates are clusters of metal-oxide units, comp
22                           The fuel cell uses polyoxometalates as the photocatalyst and charge carrier
23  to describe the synthesis of the core-shell polyoxometalates based on the monitoring results.
24               Two MOF-like but all-inorganic polyoxometalate-based networks, [Na7X2W18Sn9Cl5O68.(H2O)
25                                              Polyoxometalate-based open frameworks (POM-OFs) are exte
26                                   Meanwhile, polyoxometalates-based organic-inorganic hybrid material
27                                          Ru4-polyoxometalate bridges the gap between homogeneous and
28 o(2)O(2)S(2)}(2+) and {Mo(3)S(4)}(4+) toward polyoxometalate building blocks.
29 porating phosphorus(III)-based anions into a polyoxometalate cage, a new type of tungsten-based uncon
30                                  The reduced polyoxometalate can be reoxidized in fuel cells that con
31                 A typical type of core-shell polyoxometalates can be obtained through the Keggin-type
32  we describe how building block libraries of polyoxometalates can be used to construct systems with i
33                           In a similar vein, polyoxometalates can stabilize metal nanoparticles, lead
34 chemical warfare nerve agent simulant over a polyoxometalate catalyst.
35 munication describes a new method for the Pd/polyoxometalate-catalyzed aerobic olefination of unactiv
36                                              Polyoxometalate cluster anions (POMs) control formation
37 elope of both events and employ it for a new polyoxometalate cluster, Na6 [Mo120 Ce6 O366 H12 (H2 O)7
38 amolecular assembly of a series of nanoscale polyoxometalate clusters (from the same one-pot reaction
39                                       Uranyl polyoxometalate clusters are both fundamentally fascinat
40 nd have many common building blocks; in fact polyoxometalate clusters are perhaps the largest non-bio
41 hods for the grafting of peptide chains onto polyoxometalate clusters by the use of general activated
42 d to probe the mechanism of self-assembly of polyoxometalate clusters in solution.
43 lecular nanostructures like coordination and polyoxometalate clusters is extremely time-consuming sin
44                   Despite the vast number of polyoxometalate clusters now known, an ongoing and impor
45 zeolitic channels and on stronger acids HPW (polyoxometalate clusters on silica).
46                            Mn-Anderson based polyoxometalate clusters with different terminal groups
47 rometer-scale tubes and membranes built from polyoxometalate clusters.
48             Nanostructured inverse hexagonal polyoxometalate composite films were cast directly from
49 ns to produce an aqueous solution of reduced polyoxometalate compounds that can be used to generate p
50                            Herein, using the polyoxometalate H(3)PMo(1)(2)O(4)(0), we introduce the c
51  as an active catalyst, and iron(II) and the polyoxometalate H(5)PMo(10)V(2)O(40) (POM-V2) were ident
52                  A well-defined alpha-Keggin polyoxometalate, H(5)PV(2)Mo(10)O(40), can be viewed as
53 at all structural sites in two isostructural polyoxometalates, [H(x)Nb(10)O(28)]((6-x)-) and [H(x)Ti(
54                                          The polyoxometalate H5PV2Mo10O40 mediates the insertion of a
55 molecular water oxidation catalysts based on polyoxometalates have been reported that combine the adv
56                                  A series of polyoxometalates have been synthesized and evaluated for
57                                 Not only can polyoxometalates have gigantic nanoscale molecular struc
58 talyst development, and the possible uses of polyoxometalates in green energy science.
59 hould aid in the exploitation of these giant polyoxometalates in solution for various applications.
60                                  None of the polyoxometalates inhibited the binding of a specific CXC
61 enerally applicable strategy for integrating polyoxometalates into functional architectures and devic
62                                              Polyoxometalate ions (POMs) have structures similar to c
63 nd composition suggests reaction pathways in polyoxometalate ions will be highly variable even within
64 ared by pretreatment of the aqua-coordinated polyoxometalates (L = H2O) with NO2 or are formed in sit
65 based on redox-active (vanadate(V)-centered) polyoxometalate ligands, Na10[Co4(H2O)2(VW9O34)2].35H2O
66 c hybrid molecule comprising two Dawson-type polyoxometalates linked by a 2,2'-bipyridine unit, which
67  very similar to the unique self-assembly of polyoxometalate macroanions into single-layer, spherical
68 onstruct complex chemical systems based upon polyoxometalates, manipulating the templating/self templ
69 demonstrating the crucial role played by the polyoxometalate metal oxide cluster as an intermediary i
70 g a terminal aromatic pyrene platform with a polyoxometalate Mn-Anderson cluster as linker, demonstra
71  a nanoscale anion, the tetragonal Lindqvist polyoxometalate Mo6O19(2-).
72 been achieved using the ruthenium-containing polyoxometalate molecular catalyst, [{Ru4O4(OH)2(H2O)4}(
73    Here we show that a molybdenum(VI) oxide 'polyoxometalate' molecular nanocluster containing two em
74                                      Niobium polyoxometalates (Nb-POMs) are unique in the aqueous met
75 inorganic hybrid complexes between CB[n] and polyoxometalates not only display a surprisingly high st
76 noted L) and the trivacant [AsW(9)O(33)](9-) polyoxometalate (noted POM) has been investigated.
77 ptor anion, alpha-SiV(V)W(11)O(40)(5-) (1, a polyoxometalate of the Keggin structural class), was use
78                   Herein, we report a hybrid polyoxometalate organic-inorganic compound, Na2 [(HGMP)2
79 and programmed assembly of a dumbbell-shaped polyoxometalate-organic hybrid molecule comprising two D
80 with a 100% theoretical atom economy using a polyoxometalate oxygen donor has been found.
81 fter as (COD)Ir.POM(8-), where POM(9-) = the polyoxometalate, P2W15Nb3O62(9-)) under H2 is investigat
82                                          The polyoxometalate phosphotungstic acid has been used to se
83 een applied to the study of the reduction of polyoxometalate [PMo12O40](3-) adsorbed at a boron doped
84 imentally elusive delta-isomer of the Keggin polyoxometalate polyanion.
85 ed, dimeric, ZrIV-substituted Lindqvist-type polyoxometalate (POM) (nBu4N)6[{(mu-MeO)ZrW5O18}2], (TBA
86  report the encapsulation of a Ni-containing polyoxometalate (POM) [Ni4 (H2 O)2 (PW9 O34 )2 ](10-) (N
87 f pure approximately 0.75 nm size molybdenum polyoxometalate (POM) anions on 25 mug ( approximately 0
88 SS), [60]fullerene (C60), and Lindqvist-type polyoxometalate (POM) are used as building blocks to con
89          In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical Re
90   In this review we discuss the relevance of polyoxometalate (POM) chemistry to provide model objects
91                          In the wide area of polyoxometalate (POM) chemistry, diphosphate/diphosphona
92  hybrid molecules containing a large anionic polyoxometalate (POM) cluster and two C6 and C16 alkyl c
93 nteract with the conjugate anion in W and Mo polyoxometalate (POM) clusters and gaseous mineral acids
94                    Acid strengths for Keggin polyoxometalate (POM) clusters and zeolites, chosen beca
95 eactions on Bronsted acid catalysts based on polyoxometalate (POM) clusters are described in terms of
96 he contribution of building blocks of Keggin polyoxometalate (POM) clusters to redox processes are ch
97 a representative series of Keggin and Dawson polyoxometalate (POM) films in contact with a metallic (
98 lay an important structure-directing role in polyoxometalate (POM) growth in solution.
99 >30 coordination polymers incorporating this polyoxometalate (POM) ligand.
100 al core is stabilized by coordination of two polyoxometalate (POM) ligands.
101                 Here we show that core-shell polyoxometalate (POM) molecules can act as candidate sto
102 ance fuel cells that are catalyzed solely by polyoxometalate (POM) solution without any solid metal o
103                                              Polyoxometalate (POM) species-nanoscale inorganic anions
104  self-assembly of hydrophilic Keplerate-type polyoxometalate (POM) {Mo(72)Fe(30)} macroanions into si
105 anion size and charge allows the Keggin-type polyoxometalate (POM), [CuPW(11)O(39)](5-), a catalyst f
106 ecognition processes involving a Dawson-type polyoxometalate (POM), [P2W18O62](6-), a cationic electr
107   This strategy employs a single material, a polyoxometalate (POM), alpha(2)-[P(2)W(17)O(61)](10-), t
108  osmotically driven crystal morphogenesis of polyoxometalate (POM)-based crystals is investigated, wh
109 driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing remote terpyr
110  Wells-Dawson [alpha(2)-P(2)W(17)O(61)](10-) polyoxometalate (POM)-supported [Re(CO)(3)](+) complex c
111 ocation process of countercations around one polyoxometalate(POM)-organic hybrid anionic cluster at v
112                                              Polyoxometalates (POMs) are discrete clusters of redox-a
113        POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-t
114                     We report here that some polyoxometalates (POMs) favor polymerization of PrP 27-3
115                                              Polyoxometalates (POMs) have remarkable properties and a
116                                Nb-containing polyoxometalates (POMs) of the Wells-Dawson class inhibi
117 of mononuclear lanthanoid complexes based on polyoxometalates (POMs) that exhibit single-molecule mag
118 peroxoniobium compounds to the corresponding polyoxometalates (POMs), alpha(1)-K(7)[P(2)W(17)NbO(62)]
119 , enzymes, ...) and inorganic molecules like polyoxometalates (POMs), which have very interesting app
120   Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymm
121  catalyst hypothesis: (i) six vanadium-based polyoxometalate precatalysts, (n-Bu4N)4H5PV14O42, (n-Bu4
122                                          The polyoxometalates represent a class of polyanionic compou
123                     These redox reactions of polyoxometalates require protons, and thus such complexe
124 spinning NMR spectroscopy of six-coordinated polyoxometalate solids.
125 of 10-20 nm by post-process immersion into a polyoxometalate solution (phosphomolybdic acid, PMA) in
126         Here we investigate a nano-sized Ru4-polyoxometalate standing as an efficient artificial cata
127 rected assembly of a ring-shaped macrocyclic polyoxometalate structural building unit, {P(8)W(48)O(18
128 ew method to identify metallic nanoclusters (polyoxometalate structures) in solution at the single mo
129 ation to minimize steric clashes between the polyoxometalate subunits, in order to stabilize the corr
130         Recently we showed that V-containing polyoxometalates such as (n-Bu4N)7SiW9V3O40 or (n-Bu4N)9
131 s, is described using copper(II)-substituted polyoxometalates, such as {alpha2-Cu(L)P2W17O61}(8-) or
132 nner and outer faces of the gamma-CD for the polyoxometalate surfaces.
133 ates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical
134 in the reaction mechanism by protonating the polyoxometalate thereby enabling the activation of the m
135  where oxygen atoms are transferred from the polyoxometalate to the substrate.
136 id growth of tubes occurs from crystals of a polyoxometalate upon addition of an aqueous solution con
137 999, a catechol dioxygenase derived from a V-polyoxometalate was reported which was able to perform a
138 hat SMOF-1 adsorbs anionic Wells-Dawson-type polyoxometalates (WD-POMs) in a one-cage-one-guest manne
139 and water activation on multi-Ru-substituted polyoxometalates were studied using the B3LYP density fu
140 u(+) and Bu3Sn(+) cations coordinated to the polyoxometalate, which were also identified by ESI-MS.
141 y of ([UO2(O2)OH]60)(60-) (U60), an actinide polyoxometalate with fullerene topology, can be induced
142      The technique allows the measurement of polyoxometalates with over 2 orders of magnitude lower a
143 self-assembly of an equilibrated ensemble of polyoxometalates, with the heteropolytungstate anion [AI

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