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1 the coordinated thiirane becomes the cyclic polysulfide.
2 ffinity than hydrogenase I for both S(0) and polysulfide.
3 ) and S(2-) ) to sulfite and thiosulfate via polysulfide.
4 ellent physical properties displayed by many polysulfides.
5 pper CSEM inhibitor intercepts the migrating polysulfides.
6 d in a carbon host, which serve to sequester polysulfides.
7 tion kinetics and better trapping of soluble polysulfides.
8 tributing Li(2)S and in sequestering lithium polysulfides.
9 ellent physical properties displayed by many polysulfides.
10 enzymatic oxidation of hydrogen sulfide and polysulfides.
11 ) as well as solid-phase associated S(0) and polysulfides.
12 thiosulfate with transitory accumulation of polysulfides.
13 nce of graphite and sulfite, thiosulfate, or polysulfides.
15 duplication of a denture anchor in stone via polysulfide, addition silicone, and polyether impression
17 ectly between Li(2)S and electrolyte without polysulfide and (b) lithium-ion diffusion in Li(2)S.
19 d due to a synergetic effect of both lithium polysulfide and lithium nitrate as additives in ether-ba
20 effect of the mediating effect of dissolved polysulfide and the fast diffusion of Mg ion in the amor
21 lectrodes over planar film electrodes toward polysulfide and triiodide reduction, which suggests a st
22 strong dipole-dipole interaction between Li polysulfides and Li-S cathode materials originates from
24 eferential adsorption of higher order liquid polysulfides and subsequent conversion to lower order so
25 new simple synthetic method for binary metal polysulfides and sulfides was developed by utilizing an
26 ion-pi interactions between Li(+) of lithium polysulfides and the negatively charged cyclopentadienyl
27 study, quinonoid imine is proposed to anchor polysulfides and to facilitate the formation of Li2 S2 /
28 accompanied by the dissolution of long-chain polysulfide, and solid-state transition from short-chain
29 10(-4) mA cm(-2) , a rapid redox reaction of polysulfide, and therefore improved sulfur utilization a
30 ring lithiation, dissolution of intermediate polysulfides, and low ionic/electronic conductivity.
31 ron reductant, resulting in the formation of polysulfide anions, such as HS2(-), which were confirmed
36 ation for future grid energy storage.Lithium polysulfide batteries suffer from the precipitation of i
37 st time the occurrence of surface-associated polysulfides being the main oxidation products in the pr
38 need for material structures with effective polysulfide binding capability and well-defined surface
39 lculations, it was determined that effective polysulfide binding originates from favorable cation-pi
40 te coated with polyaniline (PANI) polymer as polysulfide block to achieve high sulfur utilization, hi
42 rrier is found to be the phase nucleation of polysulfides, but the amplitude of barrier is mainly due
43 the reduction of elemental sulfur (S(0)) and polysulfide by hydrogenase I and hydrogenase II, and bot
45 particles) into the cathode, the heteropolar polysulfides can be anchored within the cathode due to t
47 nts and theoretical calculations reveal that polysulfide capture by the oxides is via monolayered che
48 /flavoprotein oxidoreductase system restores polysulfide-carrying hemoglobin derivatives to ferrous h
49 e a dendrite-free Mg anode with a reversible polysulfide cathode and present a truly reversible Mg/S
51 use of lithium sulfide cathodes and lithium polysulfide catholytes, as well as recent burgeoning eff
55 ghly conductive coating layer for stabilized polysulfide chemistry, is accomplished by the combinatio
57 n of the poorly soluble and insulating short polysulfide compounds was evidenced, thus leading to the
60 propose that mitochondria export glutathione polysulfide, containing glutathione and persulfide, for
61 tion by zinc acetate, the surface-associated polysulfides could be precipitated as zerovalent sulfur
63 urable network of mobile anions and restrict polysulfide diffusion from mesoporous carbon hosts by an
65 G coating) on a Celgard separator suppresses polysulfide diffusion through its physical and chemical
66 s that the hybrid electrolyte limits lithium polysulfide dissolution and is, thus, ideally suited for
68 materials are shown to completely eliminate polysulfide dissolution and shuttling between lithium an
69 an inherent mechanism for preventing lithium polysulfide dissolution and shuttling during electrochem
72 ss of sulfur cathode material as a result of polysulfide dissolution causes significant capacity fadi
73 otection prevents mechanical degradation and polysulfide dissolution in lithium-sulfur battery chemis
74 ed ionic liquid (IL) significantly mitigates polysulfide dissolution, and therefore the parasitic red
77 phene Oxide composite electrode, and sulfide/polysulfide electrolyte deliver power conversion efficie
78 mprovements studied, use of a methanol-based polysulfide electrolyte results in a particularly dramat
79 ormance of QDSCs, the 30% deionized water of polysulfide electrolyte was replaced with methanol to im
80 raction between graphene oxide and sulfur or polysulfides enabled us to demonstrate lithium/sulfur ce
83 ite their potential relevance, the extent of polysulfide formation and its relevance for product form
84 Varying the Fe/S ratio revealed that surface polysulfide formation only becomes dominant when the rem
85 iate at the junction between thiosulfate and polysulfide formation, coordinates ferric hemoglobin and
86 identified in thicker films, resulting from polysulfide generation, but are shown not to improve the
92 together show phosphorene as a highly potent polysulfide immobilizer for lithium-sulfur batteries, en
95 le for reversible storage/delivery of mobile polysulfides in lithium-sulfur (Li-S) batteries to contr
98 systematic strategy for the introduction of polysulfides in the synthesis of epipolythiodiketopipera
99 S to a mixture of thiosulfate and iron-bound polysulfides in which the latter species predominates.
100 sed to show that ring closure to form cyclic polysulfide incorporated inversion of stereochemistry ve
101 to reversibly form different soluble lithium polysulfide intermediates and insoluble lithium sulfides
102 ntent/loading, arising from the shuttling of polysulfide intermediates between the cathode and anode
104 l capacity while inhibiting the formation of polysulfide intermediates that lead to parasitic shuttle
107 at human RBCs convert garlic-derived organic polysulfides into hydrogen sulfide (H(2)S), an endogenou
108 on the electrolyte due to the dissolution of polysulfides into the electrolyte, along with the format
110 MNCS/CNT), which can strongly adsorb lithium polysulfides, is now reported to act as a sulfur host.
112 e electrode to chemically reduce in situ the polysulfide Li2S6 in liquid electrolyte to insoluble Li2
114 valuation of the reactions regarding lithium polysulfide, lithium nitrate and lithium metal, and prov
117 for aerobic carbon monoxide (CO) oxidation, polysulfide metabolism and hydrogen utilization were ide
118 which the formation and chain-shortening of polysulfide occur at early stage accompanied by the diss
119 ite enable the effective trapping of lithium polysulfides on electroactive sites within the cathode,
121 electrodes, which prevent the dissolution of polysulfides on the cathode and reduction of polysulfide
122 2Fe-2S] cluster may generate a protein-bound polysulfide or persulfide that serves as the immediate S
124 class of PTP inhibitors based upon a cyclic polysulfide pharmacophore that forms a reversible covale
125 two-phase reaction pathway, where the liquid polysulfide phase in the sulfide electrode is thermodyna
126 ediment surface; and high pore water sulfide-polysulfide promotes Mo fixation in pyrite while promoti
127 al effects of their intermediate byproducts, polysulfides (PS), have to be resolved to realize these
131 for growth in high sulfide concentrations; a polysulfide reductase-like complex operon, psrABC (CT049
132 )H-dependent coenzyme A disulfide reductases/polysulfide reductases (CoADR/Psr) have been proposed to
133 thermore, during cycling the bulk of soluble polysulfides remains trapped within the cathode matrix.
134 ing of natural micropores function well as a polysulfide reservoir in Li/dissolved polysulfide cells.
135 only provide excellent electron pathways and polysulfide reservoirs, but they can also be used as a s
138 lved sulfide on the production of sulfur and polysulfide (S-PS) and associated iron corrosion was inv
139 sulfur species (i.e., bisulfide (HS(-)) and polysulfides (S(n)(2-))) and dissolved organic matter (D
143 ry technology, and controlling the inherent "polysulfide shuttle" process has become a key research t
145 problems arising from insulating sulfur and polysulfide shuttles as well as remarkably increasing th
146 e for growth of new materials: the potassium polysulfides spanning K(2)S(3) and K(2)S(5), which melt
147 t discharge plateau, S is reduced to soluble polysulfide species concurrently with the formation of a
149 nstrate preferential adsorption of a soluble polysulfide species, formed during discharge process, to
151 problems are mainly caused by the dissoluble polysulfide species, which are a series of complex reduc
152 roposed mitochondrial pathway because it has polysulfides, that is, disulfide and trisulfide, as inte
153 With adsorbed additives, like LiNO3 and polysulfide, the lithium deposits are strongly textured,
154 e from a high-order polysulfide to low-order polysulfides through solid-liquid two-phase reaction pat
155 r experiences phase change from a high-order polysulfide to low-order polysulfides through solid-liqu
156 and solid-state transition from short-chain polysulfide to magnesium sulfide occurs at late stage.
157 e II, and both enzymes preferentially reduce polysulfide to sulfide rather than protons to H(2) using
158 This design with CSEM allows the dissolved polysulfides to be localized and the electrochemical rea
161 electrolyte as a separator, which blocks the polysulfide transport towards the Li-metal, also has hig
166 al approach to immobilize sulfur and lithium polysulfides via the reactive functional groups on graph
171 ing the reaction between lithium and lithium polysulfide, which has long been considered as a critica
172 showed that DUF442 speeds up the reaction of polysulfides with glutathione to produce glutathione per
173 sulfides; rhodanese enhances the reaction of polysulfides with glutathione to produce GSSH; PDO oxidi
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