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1 so far unprecedented reaction is proposed to proceed via 1,2-dioxane derivatives, which decompose und
3 ively mild reaction conditions, are found to proceed via a "frustrated Lewis pair" mechanism in which
4 T calculations revealed that these reactions proceed via a bimolecular mechanism in which either the
5 eaction with (2R, 3S)-8 is predicted to also proceed via a C2 radical intermediate, but no enzyme ina
6 ty acids 22:6n-3 and 22:5n-6 are believed to proceed via a circuitous biochemical pathway requiring r
7 C-C cleavage and C-H hydroxylation pathways proceed via a common key intermediate, i.e., an alpha-pe
8 types of reactions shows that all reactions proceed via a common rate-determining step, the nucleoph
9 sted that linker exchange reactions in ZIF-8 proceed via a competition between dissociative and assoc
11 ates containing a pyracyclene subunit should proceed via a cyclobutyl mechanism, and appropriate benz
12 dots, and we establish that these reactions proceed via a dark surface prereduction step prior to ph
16 T) calculations show that C-H activation can proceed via a heteroatom-directed process that involves
17 culations show that the nitrofuran reactions proceed via a highly asynchronous transition state allow
20 Mechanistic studies suggest the reaction to proceed via a nonstabilized, aliphatic, cyclic oxocarben
21 teractions between E-cadherin molecules, and proceed via a nucleation process in which protrusion and
22 number of human diseases, and is thought to proceed via a nucleation-dependent polymerization mechan
23 idue, such that the translocase reaction can proceed via a nucleophilic attack of the phosphate moiet
25 of p-X-DTBP indicates that the HAT reactions proceed via a partial transfer of charge rather than a c
27 w that, for the wide range of catalysts that proceed via a radical intermediate, a unifying framework
28 studies suggest that this reaction does not proceed via a radical mechanism, which is in contrast to
30 and were especially unstable, the reactions proceeded via a "dead-end" polymerization mechanism, and
31 ashi catalyst, copper iodide, and Hunig base proceeded via a multicascade route, affording the title
32 VO2(+), HxV4O12+x((4+x)-) (V4), and HVO4(2-) proceeded via a one-electron transfer, while that of Nax
35 reversible deaggregation, with the reaction proceeding via a disolvated-monomer-based transition str
36 ort a conceptually novel borylation reaction proceeding via a mild photoinduced decarboxylation of re
37 ar 1,2-carboamination of unactivated alkenes proceeding via a Pd(II)/Pd(IV) catalytic cycle has been
39 arbonate was used, the reaction with phenols proceeds via a bicyclic aziridinium intermediate leading
40 etones with N-propargyl-substituted ynamides proceeds via a cascade of several pericyclic reactions t
42 ng in 1,1,1,3,3,3-hexafluoropropan-2-ol that proceeds via a chelated radical-anion coupling mechanism
44 ltimately triggers tetramer dissociation; it proceeds via a cob(III)alamin intermediate, which then f
45 suggest that carbon-fluorine bond formation proceeds via a concerted transition state rather than a
47 xperimental data suggested that the reaction proceeds via a covalent intermediate using a ping-pong m
54 e mechanism of E/Z isomerization of nitrones proceeds via a diradical bimolecular process involving a
55 anine ligase by the antibiotic D-cycloserine proceeds via a distinct phosphorylated form of the drug.
56 echanistic studies suggest that the reaction proceeds via a distinctive O-benzoylhydroxylamine-promot
57 processivity studies demonstrate that NTMT1 proceeds via a distributive mechanism for multiple methy
59 vocate that the cis-trans isomerization step proceeds via a dual Au(III) push-pull assisted intermedi
61 ies reveal that the metal-free C-H insertion proceeds via a frustrated Lewis pair mechanism involving
63 as been widely accepted that membrane fusion proceeds via a hemifusion step before opening of the pro
66 tric boronate addition to o-quinone methides proceeds via a Lewis acid catalyzed process through a cl
68 ur experiments reveal that the pore assembly proceeds via a membrane-bound prepore intermediate state
69 -N bond-forming reductive elimination, which proceeds via a mixed-valent Ni(II) -Ni(III) intermediate
70 and that the synthesis of stealthin C likely proceeds via a nonenzymatic S-N-type Smiles rearrangemen
71 studies show that this diamination reaction proceeds via a nucleophilic amino cyclization followed b
74 lves formation of overall four C-C bonds and proceeds via a palladium-catalyzed oxidative transformat
75 the protonation of reduced NiFe dithiolates proceeds via a previously undetected isomer with enhance
81 he palladacycle with secondary alkyl iodides proceeds via a rarely precedented concerted oxidative ad
82 f lipid leaflets, suggesting that adsorption proceeds via a rate-limiting structure with negative cur
87 at the transformation of the precursor anion proceeds via a series of intermediate structures charact
89 (DFT) calculations showed that the reaction proceeds via a six-membered transition structure (TS) in
90 mechanistic studies reveal that the reaction proceeds via a stepwise pathway involving a novel covale
92 ells bearing higher-affinity immunoglobulins proceeds via a stereotyped pattern whereby B cells migra
94 echanistic studies suggest that the reaction proceeds via a tandem catalysis mechanism in which both
98 or retaining mechanisms, the latter of which proceeds via a two-step mechanism that includes formatio
102 ontroversial proton transfer step, which may proceed via Aggarwal's or McQuade's proposals, was evalu
103 vated amide C-N bond to a Ni(0) catalyst and proceeds via alkene insertion into a Ni(II)-acyl bond.
110 udies reveal that initiation and propagation proceed via an external alkoxide attack on the coordinat
111 catalyzed methodologies that are believed to proceed via an inner-sphere-type mechanism, with an emph
112 t the reactions with CO and aryl isonitriles proceed via an insertion of CO and isonitrile carbon int
113 Evidence is provided that these reactions proceed via an intramolecular abstraction of a beta-H of
115 NMR monitoring suggested that the reaction proceeded via an initial acylation step followed by an i
117 The data also suggest that C-H cleavage proceeds via an acetate-assisted mechanism with the carb
118 hosphino)pyrrole as the ligand, the reaction proceeds via an alkoxy palladium intermediate that incre
120 that the diastereoselective alkylation step proceeds via an alpha-substituted malonate-imidazolidino
121 w demonstrate that the initial cycloaddition proceeds via an ambimodal transition state that can lead
122 atalyzed methylenecyclopropane rearrangement proceeds via an argento-stabilized biradical or whether
124 t a concerted pathway for this reaction that proceeds via an early transition state with little bond
126 protecting/directing group, meta borylation proceeds via an electrostatic interaction and a secondar
129 (DFT) calculations reveal that the reaction proceeds via an inner-sphere mechanism-nucleophilic atta
131 tingly, we found that the adsorption of PhOH proceeds via an intermediate, weakly bound state in whic
132 t the aggregation of mutant huntingtin exon1 proceeds via an intramolecular collapse of the expanded
135 mino-oxygenation reaction is reported, which proceeds via an iron-nitrenoid generated by the N-O bond
137 tic investigations suggest that the reaction proceeds via Au(I)-catalyzed hydrofunctionalization of t
140 umarins with excellent regioselectivity, and proceeds via C-H bond activation proven by deuterium inc
144 tic experiments, the reaction is proposed to proceed via catalytic P(III)/P(V) horizontal lineO cycli
145 tic experiments, the reaction is proposed to proceed via catalytic P(III)/P(V) horizontal lineO cycli
146 employ diphosphate-activated donors and each proceed via cationic species: allylic cations and oxocar
147 r intermediates) revealed that this reaction proceeds via chairlike transition state and is exothermi
148 ciphering if biodegradation will most likely proceed via cometabolism (ROI < 1) or direct metabolism
149 radiation damage in crystalline solids often proceeds via complex dynamic annealing processes, involv
150 ich toxin clustering happened in seconds and proceeded via condensation of EqtII dimer units formed u
152 m calculation demonstrates that the reaction proceeds via conrotatory ring closure in the triplet exc
153 cently been used in catalytic C-H activation proceeding via coordination of an internal sulfoxide to
154 tic investigations suggest that fluorination proceeds via copper acetylides and that cationic species
156 de genetic evidence that the omega-7 pathway proceeds via Delta(9) desaturation of palmitoyl-ACP foll
159 that the mechanism of S-oxygenation does not proceed via direct attack at the thiolate sulfurs; the a
161 pending on GB character, the SCM is found to proceed via dislocation slipping in the <100> or <110> m
163 We conclude that the methanation reaction proceeds via dissociation of CO2, followed by reduction
164 cording to the DFT calculations the reaction proceeds via dissociation of the metal-bound complex of
165 stituted styrenes indicate that the coupling proceeds via double C-H addition of a styrene molecule,
166 r findings suggest that mycobacterial HR can proceed via DSB unwinding and protein capture of the dis
167 d biological nitrogen fixation is thought to proceed via either a sequence of proton and electron tra
169 H2Ph)](py) (7) which Fukui analysis shows to proceed via electrophilic insertion of the nitride into
170 rizations of 1,n-enynes catalyzed by gold(I) proceed via electrophilic species with a highly distorte
172 the mass spectrometer, the cluster formation proceeded via essentially one-to-one acid-base addition
173 otential energy profile, Paths 5 and 6 which proceed via extrusion of p-nitrophenylisocyanate and the
175 Long-term bacterial evolution is known to proceed via few, nonsynonymous, positively selected muta
176 sses these compounds by a distinct mechanism proceeding via fluoride abstraction, migratory insertion
177 Topoisomerase 2 (TOP2) DNA transactions proceed via formation of the TOP2 cleavage complex (TOP2
180 se, 5-hydroxymethylfurfural formation mainly proceeded via fructofuranosyl cation dehydration rather
181 s an environmental niche where evolution can proceed via generation of improved mutant chromosomes du
184 This suggests more generally that evolution proceeds via hard sweeps if resistance is unlikely and v
185 ion of prFMN is light-dependent and probably proceeds via high-energy intermediates but is independen
186 we report the first Heck reaction of amides proceeding via highly chemoselective N-CO cleavage catal
187 I complexes, interference by TtCsm does not proceed via initial base pairing by a seed sequence.
189 tion of B(C6F5)3 with 1,6-enynes is shown to proceed via initial cyclopropanation and formal 1,1-carb
190 echanistic studies suggest that the reaction proceeds via initial C-H activation followed by a novel
193 onal and organoleptic attributes of oils can proceed via interesterification of oils blends catalyzed
194 e diboration remains unclear but it does not proceed via intermediacy of hydroboration products or vi
195 tions (B3LYP/6-311+G(d,p)) the rearrangement proceeds via intermediate formation of a diazo compound,
197 sed wherein the alternating copolymerization proceeds via intermediates that have carboxylate ligatio
200 of the mupirocin biosynthetic pathway, which proceeds via major (10,11-epoxide) and minor (10,11-alke
201 In contrast, the reaction with precatalyst 2 proceeded via Me2NH-BH2-NMe2-BH3 (6) as the key intermed
204 ur kinetic analysis reveals that aggregation proceeds via monomeric assembly into small oligomers, an
208 d shows the transition from AF to FM regions proceeds via nucleation of small vortex structures, whic
210 nce, shows that the (CF3)2CFCN + OH reaction proceeds via OH addition to -C( identical withN), follow
211 ng the damaged base, replication past it may proceed via one of two DNA damage tolerance (DDT) pathwa
212 bic degradation and reductive dechlorination proceeding via outer sphere mechanisms), in studies of i
213 ch suggest that pyrrole, or furan, formation proceeds via oxazine formation, followed by a boryl rear
214 d oxygen-dependent JmjC KDMs, respectively), proceeds via oxidation of the N-methyl group, resulting
215 -) (M = Ni (5a), Pd (5b)) with allyl acetate proceed via oxidative addition to give M(IV) species [(C
216 alculations indicate that H2 activation at 2 proceeds via oxidative cleavage at Ru with concomitant h
218 ein, we present an orthogonal approach which proceeds via photochemically catalyzed isomerization of
220 ynthesis of which has recently been shown to proceed via post-translational modification of ribosomal
222 )-substituents facilitates the reaction that proceeds via pseudopericyclic 1,5-electrocyclization of
226 catalyzed cyclization of heterocyclic dienes proceeded via regiodivergent 5-exo or 6-endo pathways de
227 ediated by the phosphonite PPh(catechyl) and proceeds via regioselective cycloaddition with an in sit
228 m-catalyzed C-H amination is hypothesized to proceed via Rh2-nitrene intermediates in either the Rh2(
229 in many aquifers, Fe(III) reduction may thus proceed via S(0)-mediated electron-shuttling pathways.
230 We suggest that this transformation, which proceeds via saturated and unsaturated fluorotelomer car
232 l-catalyzed activation of amide N-C(O) bonds proceeds via selective metal insertion into the carbon-n
233 These results suggest that oxygen activation proceeds via similar mechanisms at the Mn/Fe and Fe/Fe c
234 duct nanoparticles, including CsOH and CsCl, proceeded via SiO2 condensation over aggregates of Zn-Fe
235 y, it is clear that the air-exposed reaction proceeds via slight, endothermic rearrangements of cryst
236 hough it has been proposed that the reaction proceeds via substrate-based radical intermediates.
237 er transition takes place at ca. 58(2) K and proceeds via subtle changes of intra- and interstack int
239 icle catalysts, zirconia-based growth should proceed via surface-bound kinetics, and we propose a gro
241 s unusual direct transformation was shown to proceed via the adenylation of CDG, which activates it t
244 inary studies suggest that this reaction may proceed via the catalytic formation of highly electrophi
246 anism of this process, the reaction does not proceed via the direct formation of the corresponding ca
248 ypically catalyse oxygenation reactions that proceed via the formation of substrate radical intermedi
249 I)-catalyzed C-H activation that is shown to proceed via the formation of the catalytically active Pd
250 alkyl shift proceeds more slowly and cannot proceed via the intermediacy of the aryne intermediate.
251 ymer backbone forces acene polymerization to proceed via the less reactive noncentral benzene rings.
252 n step by Fe(IV) horizontal lineO species to proceed via the pi-type pathway, and thus the usual ener
253 ion (TID) mechanism is observed to initially proceed via the so-called "typical" (CID) dissociation r
257 of 2-bromoenals with heterocyclic C-H acids proceeding via the alpha,beta-unsaturated acyl azolium i
260 version of zeaxanthin to crocetin dialdehyde proceeds via the C30 intermediate 3-OH-beta-apo-8'-carot
264 Cyclic voltammetry shows that this reaction proceeds via the formation of a silylone radical anion i
267 t a model in which polymerization activation proceeds via the induction of a conformational change in
268 duct, nitrogen dioxide (NO2), in AN solution proceeds via the initial formation of a trans-ONO-NO2 di
269 esults, indicates that the detection pathway proceeds via the initial step of a five-membered ring fo
270 he most stable dioxide species, [M(x)O2](-), proceeds via the less stable peroxo species, [M(x)(+)...
271 t that the pathway for the electron transfer proceeds via the leucine 69 (Leu(69)) and valine 68 (Val
274 rmation of the enantiomerically pure product proceeds via the nonracemizing rotation around the sigma
275 evidence shows this transformation initially proceeds via the oxidative addition of a C(sp(3) )-H bon
276 st during the reaction, which preferentially proceeds via the Pd(II)/Pd(II) redox-neutral electrophil
281 l three-state folding mechanism, which might proceed via transient structural changes rather than req
282 ns revealed that these Diels-Alder reactions proceed via transition state structures of similar energ
284 cycle is stepwise understandable by DFT, and proceeds via turnover-limiting H(2) delivery to surface
285 of sterically hindered enediynes is known to proceed via two competing mechanisms in solution: a clas
290 brinogen and that Efb-N binding to platelets proceeds via two independent mechanisms: fibrinogen-medi
293 pincer-Ir catalyzed alkane dehydrogenation, proceeds via two mechanistically distinct pathways in th
296 ines and nitrate esters, whose decomposition proceeds via unimolecular reactions both in the gas and
298 al studies imply the CO activation processes proceed via very similar mechanisms to those previously
300 of homogeneous lipid monolayers is known to proceed via wrinkling/buckling, followed by folding into
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