ライフサイエンスコーパス: propylene oxide

1 ectively adsorb the (R)-propylene oxide ((S)-propylene oxide).

2 alicyclic (cyclohexene oxide) and aliphatic (propylene oxide).

3 G), glycerin, nicotine, ethanol, acetol, and propylene oxide.

4 eaction of the chiral anion with (S)- or (R)-propylene oxide.

5 y important epoxidation of propylene to form propylene oxide.

6 xposure to enantiomerically pure and racemic propylene oxide.

7 rate) by the carbonylative polymerization of propylene oxide.

8 n-bonding interactions between 2-butanol and propylene oxide.

9 ard the adsorption of the two enantiomers of propylene oxide.

10 reactions, starting from (R)-citronellal and propylene oxide.

11 The adsorption of propylene oxide, a chiral molecule, on a Pt(111) single-

12 The coverage of (R)-propylene oxide adsorbing on an (R)-2-butoxide-covered s

13 Propylene oxide adsorbs reversibly on Pd(111) at 80 K wi

14 cific equilibrium constants for (R)- and (S)-propylene oxide adsorption on the chiral Au nanoparticle

15 vity factor (s = k(fast)/k(slow)) of 370 for propylene oxide, allowing enantiomerically pure epoxide

16 In the absence of CO2, propylene oxide and 1,2-epoxybutane were isomerized to f

17 4e catalyzes the polymerization of propylene oxide and 2a catalyzes the polymerization of m

18 Cr(III)-catalyzed system for the coupling of propylene oxide and carbon dioxide reveal that although

19 on in the presence of complex 1, coupling of propylene oxide and carbon dioxide was found to occur by

20 Just add water: The copolymerization of propylene oxide and CO2 catalyzed by a cobalt complex is

21 he bipyridine ligands are "tailed" with poly(propylene oxide) and poly(ethylene oxide) oligomers.

22 .7H2O with N-methyl formamide as porogen and propylene oxide as initiator.

23 droxy-telechelic isotactic PPO using racemic propylene oxide as the monomer.

24 ar sequence) starting from d-mannose and (S)-propylene oxide as the source of the stereogenic centers

25 n of leptin with poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide), Pluronic P85 (P

26 xide/ethylene oxide copolymer (predominantly propylene oxide based, PPO/PEO) for polar solvents or wa

27 hthalate and a poly(ethylene oxide) and poly(propylene oxide) block copolymer, and they were implante

28 k copolymer, poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide), was covalen

29 lene (C(3)H(6)), suggesting the formation of propylene oxide (C(3)H(6)O), an important monomer used,

30 ificity with 2-butanol exposure suggest that propylene oxide can interact either with a single adsorb

31 alicyclic (cyclohexene oxide) and aliphatic (propylene oxide) carbon dioxide coupling is thought to b

32 clohexyl carbonate, under similar conditions propylene oxide/carbon dioxide produces mostly cyclic pr

33 that acetoacetate is the primary product of propylene oxide carboxylation and that beta-hydroxybutyr

34 astronomical detection of a chiral molecule, propylene oxide (CH3CHCH2O), in absorption toward the Ga

35 ence in the two concurrent reactions for the propylene oxide/CO(2) process (33 kJ.mol(-1)) accounts f

36 se of water as chain-transfer reagent in the propylene oxide/CO2 polymerization, poly(propylene carbo

37 drophilic-lipophilic balance values and poly(propylene oxide) contaminants, whereas this interaction

38 exhibits high catalytic activity for the CO2/propylene oxide coupling reaction and can be used as a r

39 catalyzed the CO2-dependent carboxylation of propylene oxide (epoxypropane) to form acetoacetate and

40 for hydrophobic/low polarity solvents and a propylene oxide/ethylene oxide copolymer (predominantly

41 ysteine selectively adsorb one enantiomer of propylene oxide from a solution of racemic propylene oxi

42 f (R)-3-methylcyclohexanone and (R)- and (S)-propylene oxides from the Cu(643)(R) and Cu(643)(S) surf

43 e enantioselective chemisorption of R- and S-propylene oxide has been measured either on clean Pd(111

44 alyst allows for the preparation of the poly(propylene oxide) in high yields with high turnover (TON>

45 racemic catalyst forms highly isotactic poly(propylene oxide) in quantitative yield.

46 onoxide and at room temperature in methanol, propylene oxide is converted to methyl 3-hydroxybutanoat

47 Propylene oxide is detected in the gas phase in a cold,

48 Production of the industrial chemical propylene oxide is energy-intensive and environmentally

49 rotation of polarized light by (R)- and (S)-propylene oxide is enhanced by interaction with Au nanop

50 olecule, specifically that the uptake of (S)-propylene oxide is larger than that of (R)-propylene oxi

51 antioselective chemisorption of (S)- and (R)-propylene oxide is measured on a Pd(111) surface chirall

52 )-propylene oxide is larger than that of (R)-propylene oxide on (S)-2-methylbutanoate adsorbed layers

53 nces in adsorption energetics of (R)- vs (S)-propylene oxide on the (S)-2-methylbutanoate/Pt(111) ove

54 the living, alternating copolymerization of propylene oxide (PO) and CO(2), yielding poly(propylene

55 TPD titrations of NEA-modified Pt(111) using propylene oxide (PO) as a chiral probe point to a relati

56 Statistical ethylene oxide (EO) and propylene oxide (PO) copolymers of different monomer com

57 fined alternating copolymers made of CO2 and propylene oxide (PO) or cyclohexene oxide (CHO) were ind

58 erizes lactide (L and rac) dissolved in neat propylene oxide (PO) to yield polylactide (PLA) terminat

59 The metal-free polymerization of propylene oxide (PO) using a special class of alkene-N-h

60 The enantioselective polymerization of propylene oxide (PO) using biaryl-linked bimetallic sale

61 ortant epoxide monomers ethylene oxide (EO), propylene oxide (PO), and butylene oxide (BO).

62 contains poly(ethylene oxide) (EO) and poly(propylene oxide) (PO) units with an approximate molecula

63 H(2))(9)CH(3), and O(2)C(CH(2))(6)CH(3), and propylene oxide, PO, have been studied in CDCl(3) and ha

64 opylacrylamide and poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (known as poloxame

65 , such as triblock poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) copo

66 phiphilic triblock poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) copo

67 of ethyl ether and poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) or P

68 -cyclodextrins and poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) trib

69 olymer of the form poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) helps seal electro

70 erized in random and triblock ethylene oxide/propylene oxide polyols using LC/CR/MS.

71 Hydroxy-telechelic poly(propylene oxide) (PPO) is widely used industrially as a

72 chelic supramolecular polymers based on poly(propylene oxide) (PPO), thymine (Thy), and diaminotriazi

73 eine (d-cysteine) selectively adsorb the (R)-propylene oxide ((S)-propylene oxide).

74 f propylene oxide from a solution of racemic propylene oxide, thus leaving an enantiomeric excess in

75 as temperature, pressure, and molar ratio of propylene oxide to catalyst have been investigated, and

76 m PLLA/Pluronic-P104 (poly(ethylene oxide-co-propylene oxide) triblock copolymer) blends in attempts

77 ynthesis of propylene carbonate from CO2 and propylene oxide under mild catalytic conditions; the per

78 rization of tricyclic anhydrides with excess propylene oxide using aluminum salen catalysts.

79 e atactic polymers are produced from racemic propylene oxide using chain shuttling agents and double-

80 dioxide with epoxides (cyclohexene oxide or propylene oxide) using the (salen)Cr(III)Cl complex as c

81 ing copolymerization of maleic anhydride and propylene oxide, using a functionalized primary alcohol

82 diation, chemical transformation (propene to propylene oxide), wastewater denitrification, as compone

83 Using enantiopure propylene oxide, we synthesized semicrystalline polyeste

84 ic isotactic PPO is synthesized from racemic propylene oxide with control of molecular weight using e

85 The alternating copolymerization of propylene oxide with terpene-based cyclic anhydrides cat