ライフサイエンスコーパス: propyne

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1 tion of C(6)H(5)NH(2) and C(6)D(5)NH(2) with propyne.

2 reaction between cyclopentene and 1-phenyl-1-propyne.

3 lene, carbon dioxide, and 3-bromo-1-phenyl-1-propyne.

4 addition (X = Br, Cl, F) to alkynes (ethyne, propyne, 2-butyne, trifluoromethylethyne, trimethylsilyl

5 The hydroxyl propyne (48) and butyne (23) were among the most potent

6 7-Propyne-7-deaza-2'-deoxyguanosine is a promising lead an

7 s with three and four substitutions of the 7-propyne-7-deaza-2-amino-2'-deoxyadenosine exhibited a 2-

8 The 7-propyne and 7-iodo nucleosides were incorporated into an

9 th the model reaction of acetone addition to propyne and allene, the addition of acetone and acetophe

10 ers synthesized by their click reaction with propyne carboxyfluorescein are seen to accumulate around

11 BrCH2Cl, CH3CH2OH, CH3CN, CH3NO2, I2), and a propyne clathrate (CH3CCH@Me,H,SiMe2.2CHCl3), have been

12 C or G of a CpG dinucleotide with 5-OH-dC, 5-propyne-dC, furano-dT, 1-(2'-deoxy-beta- d-ribofuranosyl

13 synthesis of 1,3-disubstituted allenes, the propyne derivatives containing either a allyl(tert-butyl

14 analysis point to the unique ability of C-5 propyne dU ODNs to selectively bind to RNA within cells

15 C-5 propyne dU phosphorothioate ODNs bind selectively and wi

16 The incorporation of the propyne group at the 5 position gives rise to a very lar

17 In the propynylated duplexes, the propyne group stacks on the aromatic ring of the 5'-base

18 pplications, like the production of MMA from propyne, hydroesterification seems to have an advantage

19 inking acetylene moiety was confirmed, and a propyne link was preferred over a butyne link.

20 '-deoxyuridine or 2'-deoxycytidine through a propyne linker.

21 s in a fully solvated system showed that the propyne modification leads to substantial conformational

22 the potency, specificity, and utility of C-5 propyne modified antisense ONs as biological tools and i

23 The increased NMR spectral dispersion of the propyne-modified duplex allowed a larger number of exper

24 To investigate effects of the propyne nucleotide on triplex structure and the factors

25 We demonstrate that C-5 propyne ONs as short as 11 bases retained 66% of the pot

26 ly inactivated the antisense ON and that C-5 propyne ONs have a biologically active half-life in tiss

27 ver 20-fold, we show that the potency of C-5 propyne ONs is unaffected by changes in the expression l

28 sphorothioate-modified oligonucleotides (C-5 propyne ONs), we have utilized a HeLa line that stably e

29 e targeted with equivalent potency using C-5 propyne ONs.

30 Selective semi-hydrogenation of propyne over ceria nanocubes yields hyperpolarized prope

31 observed in the hydrogenation of propene and propyne over ceria nanocubes, nano-octahedra, and nanoro

32 C5-propyne phosphodiester and phosphorothioate compounds we

33 The oligomers contained C-5-propyne (prC), 2'-O-methyl (2'-O-Me) or 2'-OH (RNA) grou

34 xazine bases into a previously optimized C-5 propyne pyrimidine modified 7-mer phosphorothioate oligo

35 We evaluate C-5 propyne pyrimidine modified phosphorothioate antisense o

36 of short (7 and 8 nt) ONs modified with C-5 propyne pyrimidines and phosphorothioate internucleotide

37 extracts by the mechanism-based inactivator propyne, suggesting that it is the catalytic component a

38 Cu nanoparticles semihydrogenate 1-phenyl-1-propyne to cis-beta-methylstyrene (20 bar H2, 40 degrees

39 Removing a single propyne two base pairs away from a mismatch in a PrODN:R

40 common features, it was weakly inhibited by propyne with an apparent Km value of 340 microM.

41 The hydroesterification of propyne with their Pd(OAc)2/PN/HA (PN = (2-pyridyl)diphe

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