ライフサイエンスコーパス: pseudorotation

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1 he guanidinium promoted activation energy of pseudorotation.

2 cdG deoxyribose exhibited the O4'-exo (west) pseudorotation.

3 further evidence suggests a role for ribosyl pseudorotation.

4 through a low-lying TBP transition state for pseudorotation.

5 Comparative pseudorotation analyses of the J-coupling data for this

6 analytically described using the concept of pseudorotation, and for RNA and DNA they are dominated b

7 The two populations differed in the pseudorotation angle of the sugar ring for the 5'-neighb

8 kbone conformational variables such as sugar pseudorotation angles and BI/BII state equilibria and th

9 The altered sugar pseudorotation at A6 appears to be common to both bay re

10 hanisms involving two, four, and three Berry pseudorotations at phosphorus, respectively.

11 the south (B form) sugar pucker to the east pseudorotation barrier are lower in pyrimidines as compa

12 ded RNAs to sample a wider spectrum of their pseudorotation conformations.

13 only the relative stability of the different pseudorotation conformers, but also the main transition

14 graphy, and their structures (which span the pseudorotation coordinate between trigonal bipyramidal a

15 nts, a free energy landscape of the complete pseudorotation cycle of nucleic acids in solution has re

16 Results show that the east pseudorotation energy barrier involves a decrease in the

17 calculated the free energy surface of ribose pseudorotation in guanosine and 2'-deoxyguanosine.

18 Pseudorotation in the all-cis boat isomer (3) proceeds w

19 cal mol(-1), ruling out a mechansm via Berry pseudorotation involving equatorial halides.

20 However, the O4'-exo pseudorotation of the S-cdG deoxyribose perturbed the he

21 ular dynamics (MD) simulations using the two pseudorotation parameters directly as the collective var

22 ne following the 5'-5' linkage, the C3'- exo pseudorotation phase angle of the alpha-nucleotide, and

23 through the selenium center and for various pseudorotation processes.

24 amer was used to re-evaluate the deoxyribose pseudorotation profile and the Lennard-Jones nonbonded e

25 steep distance-dependent form, a deoxyribose pseudorotation profile with reduced energy barriers betw

26 f the atoms in the furanose ring in terms of pseudorotation puckering amplitude (q) and the pseudorot

27 ters, including the diffusion coefficient D, pseudorotation puckering amplitude q, and the form of th

28 eudorotation puckering amplitude (q) and the pseudorotation puckering phase phi.

29 he north and south ranges of the deoxyribose pseudorotation surfaces have been located, allowing char

30 est energy structure, which can rearrange by pseudorotation through the T geometry.

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