ライフサイエンスコーパス: pulegone

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1 uct (+)-menthofuran and its intermediate (+)-pulegone).

2 from the commercially available terpene (S)-pulegone.

3 uran itself might influence the reduction of pulegone.

4 -methylcyclohex-2-ene-1-one (1) from (R)-(+)-pulegone (3), proceeding in 44% overall yield, is descri

5 Menthol, menthone, pulegone and eucalyptol were identified as the major com

6 ential oil were isomenthone, neo-isomenthol, pulegone and isomenthol, constituting 34.07%, 7.65%, 19.

7 mulation of the branchpoint intermediate (+)-pulegone and the side product (+)-menthofuran.

8 coumarin, estragole, methyl-eugenol, (R)-(+)-pulegone and thujone were EU-regulated substances detect

9 Similarly, the reaction of triply labeled pulegone clearly shows that the label in the product is

10 r decreased reductase activity and increased pulegone content.

11 n prepared by dynamic kinetic reduction of a pulegone-derived beta-keto ester.

12 From a pulegone-derived building block, a key propellane interm

13 t of menthofuran, such that menthofuran, and pulegone increased, or decreased, in concert.

14 (+)-Pulegone is a central intermediate in the biosynthesis o

15 a demonstrate that the metabolic fate of (+)-pulegone is controlled through transcriptional regulatio

16 scrambled, whereas the label in the starting pulegone is retained.

17 The ability to reduce both menthofuran and pulegone levels is of commercial significance in improvi

18 To elucidate regulation of pulegone metabolism, we modified the expression of mfs u

19 ter the acute ingestion, identified 18 ng of pulegone per mL and 1 ng of menthofuran per mL.

20 of (+)-menthofuran on the branchpoint enzyme pulegone reductase (PR) were assumed.

21 uced to (-)-menthone en route to menthol, by pulegone reductase (PR), or oxidized to (+)-menthofuran,

22 tain biosynthetic enzyme concentrations [(+)-pulegone reductase and (+)-menthofuran synthase], wherea

23 ed to secretory cell mitochondria, while (+)-pulegone reductase labeling occurred only in secretory c

24 iperitenol dehydrogenase, and peppermint (+)-pulegone reductase.

25 s in all transformed plants, the flux of (+)-pulegone through PR correlated negatively with the essen

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