ライフサイエンスコーパス: pyroglutamic acid

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1 s-1 (<Glu-Arg-Thr-Lys-Arg-MCA; where <Glu is pyroglutamic acid).

2 teins was used for the identification of the pyroglutamic acid.

3 cular colored compounds in the presence of l-pyroglutamic acid.

4 s of sterically constrained beta-substituted pyroglutamic acids.

5 to the diastereomerically pure 3-substituted pyroglutamic acids.

6 Coupling of amine 21 with pyroglutamic acid affords the naturally occurring tripep

7 -terminal and carboxyl-terminal residues are pyroglutamic acid and proline, respectively.

8 iate use for preparing various 3-substituted pyroglutamic acids and related amino acids (glutamic aci

9 e use for preparing various beta-substituted pyroglutamic acids and related compounds.

10 cally efficient approach to beta-substituted pyroglutamic acids and relevant compounds.

11 optically pure bromide 37, derived from (S)-pyroglutamic acid, and followed a similar sequence invol

12 ic acid at pH 6.2 and increased formation of pyroglutamic acid at pH 4 and pH 8.

13 rent pH values, showing minimal formation of pyroglutamic acid at pH 6.2 and increased formation of p

14 integrin structures reveal details including pyroglutamic acid at the beta2 N terminus and bending wi

15 s (-1858.96) and the subsequent formation of pyroglutamic acid at the new N-terminus Gln (-17.03).

16 However, the sum of glutamine and pyroglutamic acid concentrations in each sample remains

17 -mass spectrometry method could separate the pyroglutamic acid-containing light chains from the nativ

18 controlled by 3-phenyl or 4-benzyl groups in pyroglutamic acid derivatives 3 or 9, respectively.

19 with a catalytic amount of base to form the pyroglutamic acid derivatives.

20 mmetric phosphoramidite ligands derived from pyroglutamic acid for use in both oxidative and redox-ne

21 Pyroglutamic acid formation also occurs.

22 These variants were attributed to pyroglutamic acid formation and decarboxylation on the p

23 In this study, we investigated the pyroglutamic acid formation from N-terminal glutamic aci

24 ocated at the N-terminus of proteins undergo pyroglutamic acid formation in vitro.

25 method for the identification of N-terminal pyroglutamic acid formation will be discussed.

26 s such as oxidation, deamidation, N-terminal pyroglutamic acid formation, and glycosylation.

27 We identified the formation of pyroglutamic acid from N-terminal glutamic acid in the h

28 and chemical sequence analyses, where Pca = pyroglutamic acid, Hyp = hydroxyproline, Gla = gamma-car

29 l drops by up to 75% and, concomitantly, the pyroglutamic acid level increases proportionately.

30 onsidering the sum of apparent glutamine and pyroglutamic acid levels, obtained from the contemporary

31 e crystals of enantiomerically pure D- and L-pyroglutamic acid (PGA) are capable of recurring self-ac

32 or peptides have been reported to cyclize to pyroglutamic acid (pGlu) during liquid chromatography (L

33 of these was determined with the N-terminal pyroglutamic acid residue (pGlu1) and a complete C-termi

34 d-glucose model reactions with and without l-pyroglutamic acid revealed an increase of low molecular

35 s of cell density on succinate, proline, and pyroglutamic acid systems are also reported.

36 ues of pyochelin have been prepared from Boc-pyroglutamic acid-tert-butyl ester in 11 and 13 steps.

37 tified a surprising glutamine cyclization to pyroglutamic acid that occurs during protein removal.

38 fast occurring cyclization of l-glutamine to pyroglutamic acid, the typical amino-carbonyl reaction w

39 by the replacement of N-terminal proline by pyroglutamic acid; the long chains of gNaA and BngNAP1B

40 rbapenam carboxylic acid was prepared from L-pyroglutamic acid to unambiguously establish its absolut

41 beta-lactam scaffold 11 were prepared from L-pyroglutamic acid via substrate-controlled electrophilic

42 Closer investigations could prove that l-pyroglutamic acid was able to influence non-enzymatic br

43 A series of biologically intriguing pyroglutamic acids were synthesized in racemic form by e

44 the preparation of several beta-substituted pyroglutamic acids which include electron-releasing and

45 e-ketose transformation in the presence of l-pyroglutamic acid, which are signs of a faster proceedin

46 ymmetrical diketopiperazines from commercial pyroglutamic acid with control of product dictated by re

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