ライフサイエンスコーパス: racemic

1 s viable and that natural paracaseolide A is racemic.

2 mparable) sugar acids and sugar alcohols are racemic.

3 nce, the self-assembly of the helicates from racemic 1 proceeds in a completely narcissistic self-sor

4 etylation of the 5R configured enantiomer of racemic 1,2-O-isopropylidene-myo-inositols possessing ch

5 Treatment of racemic 1-aryl-2-tetralones with a chiral quinidine-deri

6 99% enantiomeric excess) and contrasted with racemic 1-octen-3-ol formed in reaction of linoleate 10S

7 Racemic 19d showed a remarkable in vitro phenotypic resp

8 Racemic 2,3-diaryl-1,4-diazabicyclo[2.2.2]octane (DABCO)

9 Racemic 2,3-dihydro-1-phenylbenzo[b]phosphole was obtain

10 During recrystallization of TETROL from racemic 2- and 3-methylcyclohexanone, some preference is

11 es of dinuclear bis-propagators derived from racemic 2-4 was used to attenuate the rate of reversible

12 In this way, the Pd(0)-catalyzed coupling of racemic 2-triflates with aryl boroxines using a TADDOL-d

13 The racemic 3-(4-oxo-3,4-dihydroquinazolin-2-yl)-N-[1-(pyrid

14 GAT107, the (+)-enantiomer of racemic 4-(4-bromophenyl)-3a,4,5,9b-tetrahydro-3H-cyclop

15 Racemic 4-hydroxycyclopentenone, readily derived from fu

16 to the enhanced fibril formation propensity, racemic Abeta42 was less prone to form soluble oligomers

17 Diastereomeric salts of racemic acids (RS)-1 and (RS)-2 with biologically active

18 lay oxidative Heck reaction using achiral or racemic acyclic alkenols and boronic acid derivatives is

19 Racemic acyclic diols as well as trans-cycloalkane-1,2-d

20 RhCl(CS-L)]2 were employed in 1,2-additions, racemic addition products were observed, suggesting a C

21 aimed to assess the effectiveness of inhaled racemic adrenaline as compared with inhaled saline and t

22 t of acute bronchiolitis in infants, inhaled racemic adrenaline is not more effective than inhaled sa

23 ized, controlled trial that compared inhaled racemic adrenaline versus saline.

24 ted viruses modified the response to inhaled racemic adrenaline.

25 oscopy predominantly to study aggregation of racemic adsorbates.

26 , as well as chiral amines directly from the racemic alcohol precursors in up to >97 % ee, releasing

27 ively, lipase-catalyzed acetylation of these racemic alcohols, and the complementary hydrolysis of th

28 tereoselectivities in the reaction between a racemic aldehyde and an allyl alcohol, catalyzed by usin

29 A short convergent route to the racemic alkaloid is described which comprises only eight

30 lifam, as well as to a cross-coupling with a racemic alkyl electrophile; in the latter process, the c

31 ckel-catalyzed stereoconvergent couplings of racemic alkyl electrophiles are emerging as a powerful t

32 of Rh(I) catalysts enables the conversion of racemic allene to enantiopure cyclopentenone product in

33 ronic acids better results are obtained with racemic allyl bromides.

34 ing method that couples arylboronic acids to racemic allyl chlorides.

35 With a racemic allylboronate reagent that contains an allylic s

36 The racemic allylic alcohol substrates can be converted to t

37 r-catalyzed cross-coupling between branched, racemic allylic alcohols and simple olefins is described

38 via direct iridium-catalyzed substitution of racemic allylic alcohols with enamines generated in situ

39 diates in allylic substitutions of branched, racemic allylic alcohols with various nucleophiles.

40 dditions of alkylzirconocene nucleophiles to racemic allylic halide electrophiles were conducted usin

41 We developed reaction conditions where racemic allylic phosphates are suitable substrates using

42 ve formation of substituted spiroketals from racemic, allylic carbonates is reported, which enables t

43 A serendipitous kinetic resolution of racemic alpha-arylamino hydrazones is also described.

44 1,3-Diketones react with racemic alpha-branched amines to furnish the correspondi

45 gent Negishi arylations and alkenylations of racemic alpha-bromosulfonamides and -sulfones that furni

46 unprecedented stereodivergent resolution of racemic alpha-chiral carboxylic acids, thus providing ac

47 alkyl fluorides through Negishi reactions of racemic alpha-halo-alpha-fluoroketones, which represents

48 t alkyl-alkyl couplings of readily available racemic alpha-haloboronates with organozinc reagents und

49 (3)-umpolung addition of alpha,beta-enals to racemic alpha-keto esters, forming gamma-butyrolactones

50 alyzes the umpolung addition of aldehydes to racemic alpha-keto esters.

51 Here, the enantioselective conversion of racemic alpha-tosyloxy ketones to optically enriched alp

52 With that purpose a series of racemic amines and prochiral ketones have been synthesiz

53 ch, the classical kinetic resolutions of the racemic amines have been investigated using Candida anta

54 etones) or an amine acceptor (deamination of racemic amines).

55 Several racemic analytes including pharmaceutical products were

56 Racemic and asymmetric propargylations are described.

57 Various racemic and enantioenriched (trans)-X,Y-dihydroxy-X,Y-di

58 A series of racemic and enantiopure analogues of CJ-16,264 was desig

59 er, and toluene do not differentiate between racemic and enantiopure dimers and also suggest that the

60 s of lundurines A-C has been accomplished in racemic and enantiopure forms in 11-13 and 12-14 steps,

61 d highly stereocontrolled total syntheses of racemic and enantiopure frog alkaloid 205B (1) were acco

62 phenyl packing motifs between some groups of racemic and enantiopure structures, although they show v

63 Both racemic and enantioselective approaches have been report

64 naccessible complex crystalline systems from racemic and homochiral building blocks.

65 ordered phases coexist at 60 K, most likely racemic and homochiral phases.

66 ple and unpredicted synthetic pathway toward racemic and scalemic tetrahydrodibenzoimidazoazepines ha

67 nces observed in the (1)H NMR spectra of the racemic and the enantio-enriched compounds in an achiral

68 X-ray structures of both the racemic and the enantiopure natural products 9, 11, and

69 Enantiomerically rich, racemic, and achiral compositions undergo deracemization

70 The active enantiomers of these racemic antagonists were even more potent, with IC50 val

71 vided an efficient and direct preparation of racemic arnottin II.

72 A series of racemic aryl-substituted phenylalanines was synthesized

73 y enantioenriched 2-arylphenethylamines from racemic aziridines.

74 , we describe a strategy for eliminating the racemic background reaction in asymmetric [2 + 2] photoc

75 remaining Bronsted acid and thus inhibit the racemic background reaction.

76 tions has been the difficulty of controlling racemic background reactions that occur by direct photoe

77 ination in which one of the enantiomers of a racemic benzylic amine substrates undergoes faster aryl

78 Racemic benzylic amines undergo kinetic resolution via b

79 inetic asymmetric transformations (DyKAT) of racemic beta-bromo-alpha-keto esters by direct aldolizat

80 aryl etherase pathway in order to cleave the racemic beta-ether linkages that are present in the back

81 A series of racemic beta-fluoroamines was resolved in a kinetic reso

82 cting good yield and diastereoselectivity in racemic beta-lactone formation.

83 ent arylation reactions of boronic acids and racemic beta-stereogenic alpha-keto esters have been dev

84 The addition of terminal alkynes to racemic beta-stereogenic alpha-keto esters was achieved

85 dynamic kinetic asymmetric transformation of racemic biaryl substrates on the basis of axial-to-centr

86 r-catalyzed enantioselective fluorination of racemic, branched allylic trichloroacetimidates with Et3

87 ionalized amino acids (FAAs) 1 skeleton from racemic butadiene monoepoxide as a starting material and

88 luding enantiopure R and S branched alkyls, "racemic by mixture", "racemic by synthesis", n-octyl, an

89 tures of right- and left-handed columns from racemic by mixture, racemic by synthesis, other combinat

90 nd S branched alkyls, "racemic by mixture", "racemic by synthesis", n-octyl, and n-dodecyl groups was

91 left-handed columns from racemic by mixture, racemic by synthesis, other combinations of R and S, and

92 ts 2,3-dihydro isomer 2, which is chiral and racemic, by base-catalyzed olefin isomerization followed

93 The racemic carbonate complex [Co(en)2 O2 CO](+) Cl(-) (en=1

94 We also showed that racemic carvedilol and the non-beta-blocking carvedilol

95 onstrate that illumination of dispersions of racemic CdTe NPs with right- (left-)handed circularly po

96 cid and wilforol A were prepared en route to racemic celastrol.

97 Non-racemic chiral boronic esters are recognised as immensel

98 A new and short synthesis of racemic cis-clavicipitic acid was achieved by taking adv

99 lysis shows that host-guest interactions and racemic cocrystallization allow for controlling the soli

100 he nematic elasticity to predefine chiral or racemic colloidal superstructures in nematic colloids.

101 enantiopure (-)-beflubutamid rather than the racemic compound may therefore be advantageous from an e

102 tereoselective interaction of a benzothiazol racemic compound that acts as a positive allosteric modu

103 nsitivity of crystallized forms (enantiopure/racemic compound/polymorphs) to both conditions and subs

104 Deracemisation of racemic compounds is still the most important strategy t

105 more, we were able to resolve several of the racemic compounds via chiral HPLC and assign the absolut

106 In contrast, heterochiral and racemic compounds yield disordered crystals, amorphous s

107 improve on the therapeutic promise of other racemic compounds, including the development of safer th

108 which has at least two enantiopure and three racemic crystal polymorphs, reveals that there are many

109 The previously reported racemic crystal structure of a magainin 2 derivative dis

110 The racemic crystal structure of BTD-2 solved at 1.45 A reve

111 allows the analysis of 13 enantiopure and 30 racemic crystal structures of 21 (F/Cl/Br/CH3/CH3O) subs

112 Four racemic crystal structures of this previously un-crystal

113 lain the (largely) predominant occurrence of racemic crystallization from racemic solution.

114 Both structures resulted from racemic crystallization of a peptide corresponding to th

115 ructural analysis providing insight into the racemic crystallization process as well as structural de

116 vincing evidence of the applicability of the racemic crystallization technique to DNA through the stu

117 rystals containing ferric enterobactin using racemic crystallization, a method that involves cocrysta

118 ork highlights the utility of small-molecule racemic crystallography for obtaining elusive structures

119 termined the X-ray structure of ShK toxin by racemic crystallography, in the course of which we disco

120 llo-ShK and determine its X-ray structure by racemic crystallography.

121 Racemic crystals are predominantly, but not exclusively,

122 es were not suitable for resolution of these racemic cyclic nitrogenated amines, alternative chemoenz

123 The racemic cyclopropane-linked compounds showed PLK4 affini

124 efer homochirality, even when assembled from racemic D,L mixtures.

125 Racemic diacetate 21 showed a strong activity against KB

126 The reaction of racemic diarylmethylamines, (Ar(1)Ar(2)CHNR2), where Ar(

127 nd 5-O-triethylsilyl derivatives of the four racemic diastereomers of 6-(2-ethyl-1,3-dioxolan-2-yl)-5

128 mplexes existing in solution as pairs of two racemic diastereomers.

129 With a racemic dienyl alcohol, the reaction proceeds via a kine

130 meric esters or by kinetic resolution of the racemic diol 2a using lipase from Candida rugosa (CRL).

131 oss-coupling strategy to kinetically resolve racemic diols with aromatic and aliphatic alcohols, yiel

132 Ketorolac is a racemic drug.

133 gamma-addition of a racemic nucleophile to a racemic electrophile; through the choice of an appropria

134 specifically, enantioconvergent couplings of racemic electrophiles-that substantially enhances the al

135 costeroids, and more recently with nebulized racemic epinephrine and hypertonic saline.

136 ations, we developed a kinetic resolution of racemic epoxides, which proceeds with high selectivity (

137 sed, beta-lactones were first synthesized in racemic fashion via the NCAL process with excellent dias

138 e enantiomers showed their colocalization in racemic fibrils.

139 dendrimer, contains a combination of chiral-racemic fluorinated and achiral hydrogenated dendrons (R

140 Two Janus dendrimers contain either chiral-racemic fluorinated dendrons and a green fluorescent dye

141 ules contain environmentally friendly chiral-racemic fluorinated dendrons in their hydrophobic part (

142 Dose-response curves of racemic fluoxetine (IC50 = 39 muM) and its optical isome

143 rpene natural products curcusones I and J in racemic form were achieved.

144 gainin 2 (S8A, G13A, G18A), obtained for the racemic form, features a dimerization mode that has prev

145 molecules (i.e., Nutlin-3) provided only the racemic form, with enantiomers being enriched by chromat

146 tem ultimately led to the three alkaloids in racemic form.

147 ulated to the ABC-core, has been prepared in racemic form.

148 While racemic forms had previously been utilized, a scalable a

149 h no distinction between the enantiopure and racemic forms.

150 Total syntheses of racemic gamma-indomycinone and kidamycinone were achieve

151 ensation reaction of (R)-phenylglycinol with racemic gamma-subtituted delta-oxoesters, in a process t

152 The racemic helicand, reacting with Cu(I), forms dimetallic

153 Racemic heptahelicene on the Ag(100) surface shows a tra

154 The Pd(0)-catalyzed coupling of racemic heterobiaryl bromides, triflates, or nonaflates

155 From racemic hit 4, optimization work led to the preparation

156 of 134 pairs of diastereoisomers and of 279 racemic-homochiral pairs were retrieved from the Cambrid

157 A biomimetic total synthesis of racemic homodimericin A was achieved in seven steps, inc

158 ylinders in the presence of small amounts of racemic hydrophobic amino acid auxiliaries, which are kn

159 oth 4-OH-PCB 95 and 5-OH-PCB 95 changed from racemic (i.e., 0.50) to 0.62 and 0.46, respectively.

160 nlike 5-OH-PCB95, 5-OH-PCB91 remained nearly racemic in most tissues of whole poplars during 10 day e

161 tuted cyclopentanones, which can be prepared racemic (in six steps) or optically pure (in ten steps)

162 ved in the alkynylation of widely available, racemic isochroman and chromene acetals to deliver alpha

163 lins, and we enantioselectively crystallized racemic jasmonic acid, whose absolute configuration had

164 s efficient conversion of readily available, racemic ketals into high-value enantioenriched isochroma

165 Secondary alcohols were dimerized into racemic ketones by a dehydrogenative Guerbet reaction wi

166 Each cycle of mFOLFOX6 consisted of racemic leucovorin 200 mg/m(2) or 400 mg/m(2), according

167 The ligands do not self-sort (racemic ligands form a near-statistical mixture of homol

168 of two general and simple procedures for the racemic lithiation/trapping of N-Boc piperazines.

169 ency 180-fold relative to the unsubstituted, racemic macrocycle and improved selectivity.

170 Additionally, the starting racemic material, adamantane-oxazolidine-2-one, was reso

171 a stereoconvergent oxidative dimerization of racemic materials in a transformation that likely coinci

172 The enantiodifferentiation of a racemic metabolite in a millimolar aqueous solution usin

173 ed employing a stereodivergent reaction of a racemic mixture (stereodivergent RRM) involving [4+2] cy

174 By enantioselective HPLC, we solved the racemic mixture and ascertained that the two enantiomers

175 studied in detail the effects of lubeluzole (racemic mixture and single isomers), the aforementioned

176 Solid-phase extraction of a racemic mixture by using Cu(GHG) as the extractive phase

177 issistic self-sorting was demonstrated for a racemic mixture consisting of both short and long alleno

178 cile crystal formation occurred from a quasi-racemic mixture consisting of glycosylated L-protein and

179 a mono- and a disubstituted derivative as a racemic mixture has been performed, which confirms the i

180 tereoselective metabolism within the body, a racemic mixture in wastewater suggests a nonconsumed dru

181 Dosing with (+)-pioglitazone instead of the racemic mixture may result in higher levels of brain exp

182 In contrast, a racemic mixture of building blocks gives the near-quanti

183 The racemic mixture of each hemicryptophane host can be read

184 d either an intravenous saline infusion or a racemic mixture of ketamine (100 ng/ml) separated by at

185 (+)- and S-(-)-enantiomers and the R,S-(+/-) racemic mixture of LA or lipoamide, we identified the bi

186 structure of the complex between dCK and the racemic mixture of our new lead compound indicated that

187 rpenetrating, lock-and-key dimers that are a racemic mixture of positive and negative chiralities.

188 A racemic mixture of the protein enantiomers L-Ser-CCL1 an

189 2-substituted cyclohexanediamine) contains a racemic mixture of the R,R and S,S enantiomers.

190 Building on recent studies with a racemic mixture of the synthetic tetrahydroprotoberberin

191 line systems showed that each conjugate is a racemic mixture of two atropisomers resulting from the a

192 y observed in the kite C4 structure and as a racemic mixture of two cyclochiral conformers, which are

193 lity crystals were readily obtained from the racemic mixture of {D-DKP ester insulin + L-DKP ester in

194 attractive to P. longispinus males than the racemic mixture or the (R)-(-)-enantiomer.

195 le into their individual assemblies in their racemic mixture solution.

196 The racemic mixture was separated by chiral preparative HPLC

197 ogical activities of the two enantiomers and racemic mixture were tested in a New Zealand vineyard.

198 The synthesized molecules, as a racemic mixture, were assayed for their EcDXR inhibitory

199 the high load of fluoxetine was present as a racemic mixture, which is typical for fluoxetine in disp

200 mantadine has always been characterized as a racemic mixture.

201 istry, homodimericin A occurs naturally as a racemic mixture.

202 38 enabled facile crystallization of the D/L-racemic mixture.

203 trolled in an enantiodivergent reaction on a racemic mixture.

204 wing question based on available data: in 2D racemic mixtures adsorbed on surfaces, is there a clear

205 e of 1S and 1R with respect to resolution of racemic mixtures of 1-phenyl-1-propanol (PP) was studied

206 inside poplar tissues, in contrast to nearly racemic mixtures of 5-OH-PCB95 remaining in hydroponic s

207 Furthermore, racemic mixtures of chemically synthesized SLs and their

208 In 3D, racemic mixtures of chiral molecules tend to aggregate i

209 uid crystals (NLCs) of achiral molecules and racemic mixtures of chiral ones form flat films and show

210 ntres from prochiral substrates or resolving racemic mixtures of enantiomers.

211 Polydisperse and racemic mixtures of helical fragments of variable compos

212 It has previously been shown that the use of racemic mixtures of naturally chiral macromolecules such

213 Stereodynamic probes typically consist of racemic mixtures of rapidly interconverting enantiomeric

214 Six racemic mixtures, 8, 23-25, 31, and 33, were separated a

215 ipids, but these studies were performed with racemic mixtures, and the role of stereochemistry remain

216 umed that chemical reactions produced 50:50 (racemic) mixtures of enantiomers, as evidenced by common

217 In the presence of racemic ML309, 2-HG levels drop rapidly.

218 n beta-etherase assays were conducted with a racemic model substrate, beta-guaiacyl-alpha-veratrylgly

219 ing a cationic cyclization process, into the racemic modification of the unusual uleine alkaloid gilb

220 A total synthesis of the racemic modification, (+/-)-2, of the tazettine-type alk

221 and this could be readily elaborated to the racemic modifications of the alkaloids uleine, dasycarpi

222 H, (2)H and (13)C NMR spectra of mixtures of racemic mono- and prochiral bis-deuterated glycine-2-(13

223 transition from homochiral nuclei to larger racemic motifs, although the extended homochiral phase e

224 Racemic mTFD-MPAB enhanced the equilibrium binding of [(

225 dl-Serine was converted to a racemic N,N-dibenzyl-protected gamma-amino-alpha,beta-un

226 Eudistidine C (1) is a racemic natural product composed of a tetracyclic core s

227 iversity of lignin's monomeric units and the racemic nature of lignin polymers, we propose that bacte

228 e one-step bicyclization of 10-oxocitral to (racemic) nepetalactone in diastereomerically pure form.

229 rticipants, likely due in part to its use of racemic nicotine hapten, (+/-)-3'-AmNic.

230 etry operators are neither ubiquitous in the racemic nor patently superior to first-order operators i

231 yze the stereoconvergent gamma-addition of a racemic nucleophile to a racemic electrophile; through t

232 he term flavonolignin is recommended for the racemic oligomers and polymers of monolignols that start

233 aration of alpha-aminoboronic acids in their racemic or in their enantiopure form.

234 rylene (CTV) crowns substituted with chiral, racemic, or achiral peripheral alkyl chains, including e

235 lity from a complex mixture of many possible racemic partners.

236 ngenic wild type (WT) mice were treated with racemic PCB 136, and levels and chiral signatures of PCB

237 ranging from aggregates made of natural and racemic peptides and DNA, through artificial functional

238 We show that both homochiral and racemic perylene bisimide compounds, including a mixture

239 In a Leishmania donovani mouse model, two racemic phenylpyridines (71 and 93) were superior, with

240 parable amyloid-lowering capabilities to the racemic pioglitazone in an in vitro AD model.

241 When mice were dosed with racemic pioglitazone, the concentration of (+)-pioglitaz

242 compared to those from an equivalent dose of racemic pioglitazone.

243 The crystal structures of fluorinated racemic PNA monomers reveal interesting base pairing of

244 ature (T(g)) of 15 degrees C compared to the racemic polymer, suggesting potential future application

245 A straightforward approach using a common racemic precursor was employed to obtain the desired opt

246 complexes, whereas other substrates provide racemic product mixtures.

247 f the nonaxially chiral derivatives from the racemic products were found to be optically stable under

248 by the fact that the substrates contained a racemic propargyl alcohol that could affect the selectiv

249 pranolol (5-HT1A/1B receptor antagonist), or racemic propranolol in both male and female rats.

250 te to hydroxy-telechelic isotactic PPO using racemic propylene oxide as the monomer.

251 These atactic polymers are produced from racemic propylene oxide using chain shuttling agents and

252 telechelic isotactic PPO is synthesized from racemic propylene oxide with control of molecular weight

253 erformed on a large scale, and the resulting racemic protected Fmoc-DSA subunit was separated by supe

254 of the Ts3 protein molecule, and the use of racemic protein crystallography to determine the folded

255 tic ester insulin molecule was determined by racemic protein X-ray crystallography to a resolution of

256 (i) enantioselective transesterification of racemic proxyphylline with vinyl acetate as well as (ii)

257 cross-coupling, specifically, reactions of a racemic pyrrolidine-derived nucleophile with cyclic alky

258 Racemic (R/S)-guaifenesin (1) was identified as a potent

259 ver exhibited the highest deviation from the racemic ratio, indicating enantiomer-selective metabolis

260 carbon stereocenters from achiral or chiral racemic reactants via transition metal catalysis.

261 omerization to rac-C2-L, which then gave the racemic [RhCl(rac-C2-L)]2 complex.

262 gly, NMR and X-ray analysis gave exclusively racemic (RR/SS)-1,2-disilane 3a, indicating a stereospec

263 nctional theory calculations reveal that the racemic RS dimer is more stable than the RR dimer as a r

264 The racemic salt contains only one independent donor in the

265 In the chiral analysis of racemic samples, exemplified for warfarin, the signal-to

266 alpha-chiral tert-butanesulfinylamines from racemic secondary alcohols and Ellman's chiral tert-buta

267 of alkenyl triflates and acyclic primary or racemic secondary alkenols.

268 gs of arylzinc reagents with CF3-substituted racemic secondary alkyl halides, a process that necessit

269 omplexes derived from 2-lithio furan and non-racemic secondary and tertiary alkyl or aryl boronic est

270 bes an organocatalytic kinetic resolution of racemic secondary nitroallylic alcohols (2) combined wit

271 rein describe the asymmetric fluorination of racemic, secondary allylic electrophiles with Et3N.3HF u

272 d with a new environmentally friendly chiral racemic semifluorinated alkyl group and with AB3 miniden

273 o allows highly enantioselective addition to racemic seven-membered-ring allyl chlorides for the firs

274 A variety of substituted racemic silyl ketene imines have been transformed into h

275 Unmodified racemic sites on heterogeneous chiral catalysts reduce t

276 t occurrence of racemic crystallization from racemic solution.

277 py measurements indicate that inkjet-printed racemic solutions of amino acids can produce nanocrystal

278 ibes the preparation of a series of 17 novel racemic spirocyclic scaffolds that are intended for the

279 China show smaller deviations from those of racemic/standard compound, indicating the DDT residues t

280 sformation--involves the transformation of a racemic starting material into a single enantiomer produ

281 n enantioconvergent mechanism transforms the racemic starting material into a single product enantiom

282 se when there is a kinetic resolution of the racemic starting material, and its magnitude is correlat

283 reospecific for a given beta-enantiomer in a racemic substrate; LigE and LigP beta-etherase homologue

284 amic kinetic asymmetric transformation using racemic substrates and alkyl nucleophiles.

285 espite complications arising from the use of racemic substrates.

286 s reported and extends our first-generation (racemic) synthesis of this alkaloid family.

287 ng enantiopure reference compounds of eleven racemic TAGs with C12-C22 fatty acids with 0-2 double bo

288 butyl 3,4-dihydroxybutanoate carbonate) from racemic-tert-butyl 3,4-epoxybutanoate (rac-(t)Bu 3,4-EB)

289 alyzed method for coupling readily available racemic tertiary alkyl chloride electrophiles with amine

290 Pavine NMT converted racemic THP to laudanosine, but the enzyme showed a pref

291 nitial hit 2, resulting in identification of racemic-trans-(3-((4-(aminomethyl)-6-(trifluoromethyl)py

292 A range of racemic transformations of alpha-oxo gold carbene interm

293 Enantiomers of racemic triacylglycerol (TAG) mixtures were separated us

294 otal synthesis of the published structure of racemic trichodermatide A is reported.

295 The first reported twisted bis-lactam, a racemic Troger's base (TB) analogue (2), was resolved in

296 loited in developing a kinetic resolution of racemic unsaturated amides via halocyclization.

297 ation, and was dose-dependently inhibited by racemic warfarin at a physiologically relevant concentra

298 st one of the polypeptides in the mixture is racemic, which disrupts backbone hydrogen-bonding networ

299 K analogue proteins were determined by quasi-racemic X-ray crystallography and were similar to wild-t

300 ed by Cu-catalyzed [3 + 2] cycloadditions of racemic (Z)-2-benzylidene-5-oxopyrazolidin-2-ium-1-ides