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1 st abundant abiotic amino acids, glycine and racemized alanine, dried and reconstituted MU soup was f
3 m mass spectrometry (CID-MS/MS) to elucidate racemized amino acid residues in immunoglobulin samples.
4 methodology successfully identified several racemized amino acid residues in the constant region of
6 iment that abiotically produced a mixture of racemized amino acids, we provide a definite proof that
8 4 may be recovered from the resolution step, racemized, and resubjected to enzymatic acylation to inc
10 be particularly elusive, and its ability to racemize as a peptide-bound residue (like asparagine and
12 Met)-dependent methylation of isomerized and racemized aspartyl residues in age-damaged proteins as p
16 nzymatically synthesized AdoMet was found to racemize at rates that were consistent with earlier stud
17 ved from allenes bearing beta-hydrogen atoms racemize at room temperature by reversible beta-hydride
19 igurationally stable at room temperature and racemizes at 199 degrees C with a half-time of about 11
21 Metallacycles derived from diarylallenes racemize by reversible thermal bond homolysis at 95 degr
23 The enantiomeric capsules can interconvert (racemize) by dissociation and recombination of their sub
26 mammalian enzyme can recognize spontaneously racemized d-aspartyl residues for conversion to l-aspart
27 r PIMT target site in H2B) was significantly racemized, exhibiting d/l ratios as high as 0.12, wherea
31 andem mass spectrometry (LC-MS/MS) to detect racemized peptides and elucidate the location of racemiz
34 tudies reveal that, while the parent amide 5 racemizes rapidly, for the sterically more hindered amid
35 l 2 is less configurationally stable than 1, racemizing rapidly in CHCl3 (t1/2(rac) = 1.9 h, rt), and
37 th as a reagent for detecting isomerized and racemized residues in damaged proteins and for possible
39 es; for 2m, 5600 degrees), but the molecules racemize slowly at room temperature (DeltaG++rac = 24 kc
42 nism where complex oligomeric catalysts both racemize the starting material and select one enantiomer
43 he single mutations were unable to invert or racemize the stereochemistry of hydride transfer even th
44 t the Pt-N bond of the phenanthridine ligand racemizes the complex, and the question arises as to whe
45 ugh heterochirality or by partially or fully racemizing the dendritic dipeptide destructively interfe
46 in both selecting different pathways and in racemizing the starting material via formation of an all
50 These results quantify the intermediacy of a racemized triplet biradical (3)16 on the major rearrange
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