ライフサイエンスコーパス: radical

1 , generating a carbazyl radical and an alkyl radical.

2 (TE)/gDM as measured by the assay with ABTS radical.

3 ometries for both the anions and the neutral radicals.

4 the reactions of the two carbamates with the radicals.

5 ion of the loaded initiator to generate free radicals.

6 heir scavenging capacity on DPPH and peroxyl radicals.

7 ate the surface with titanium oxyl (Ti-O(*)) radicals.

8 us to determine the ability to scavenge free radicals.

9 vity of anodically generated stilbene cation radicals.

10 lifetimes of the electrogenerated coreactant radicals.

11 ype of reaction by observing substrate-based radicals.

12 synthases and production of highly oxidative radicals.

13 o detoxify methylglyoxal and neutralize free radicals.

14 to UV irradiation induced generation of free radicals.

15 d to spin-orbit coupling (SOC) in the ECX(*) radicals.

16 sive autooxidation of hydroperoxyalkylperoxy radicals.

17 adicals, particularly oxygen-derived peroxyl radicals.

18 also participate in the inactivation of free radicals.

19 tissue prevents the formation of oxygen free radicals.

20 the antisymmetric stretching modes in ECX(*) radicals.

21 In dry, degassed acetone at 295 K, the radical 2 has a half-life, tau1/2 = 49 h (DeltaH(double

22 4'-pyridyl)-1,2,3,5-dithiadiazolyl (py-DTDA) radical, 2.

23 -fragmentation of the initially formed alkyl radical (8b) to form dA* and acetone.

24 olox equivalent antioxidant capacity, oxygen radical absorbance capacity and nitric oxide scavenging

25 e intake or total antioxidant intake (oxygen radical absorbance capacity).

26 he reduction process is proposed to occur by radical abstraction/hydrodehalogenation steps at rutheni

27 ds, aldehydes and ketones, as intermolecular radical acceptors.

28 ute to the cyclic 1,2,4,7-cyclooctatetraenyl radical accesses exotic reaction intermediates on the tr

29 Glycation and increased free radical activity underlie the pathogenesis of diabetic c

30 selectivity is complementary to conventional radical addition processes.

31 which the C-Si bond is formed through silyl radical addition to the heterocycle followed by subseque

32 tron transfer, hydrogen atom abstraction and radical adduct formation.

33 ented herein enable direct access to imidate radicals, allowing their first use for H atom abstractio

34 ve to the unpaired electrons in two hydroxyl radicals, amounts to 100 kcal/mol.

35 ted state of Li(carb), generating a carbazyl radical and an alkyl radical.

36 in reactions that were first-order in cation radical and first-order in nucleophile.

37 radicals formed between the stannane cation radicals and the neutral codonors, which thereby affect

38 intramolecular hydrogen migration of peroxy radicals and their bimolecular termination reactions.

39 the iron-catalyzed conversion of olefins to radicals and their subsequent use in the construction of

40 racterization of a naphthalene diimide (NDI) radical anion is presented.

41 e by direct detection of the 4,4'-bipyridine radical anion species localized in the plasmonic hot spo

42 angement and decarboxylation to form an aryl radical anion which is then oxidized by the [4Fe-4S](+2)

43 suggests the presence of a Co(I) bound to a radical anionic ligand.

44 d in an organic solvent (reaction with arene radical anions in glyme).

45 istically combines the favorable features of radical approaches, such as a facile remote C-H HAT step

46 zing an Ir photocatalyst, alpha-hydroxyalkyl radicals are generated from the single-electron oxidatio

47 Resonantly stabilized radicals are some of the most investigated chemical spec

48 oxidation of the trifluoroborates, and these radicals are subsequently engaged in a nickel-catalyzed

49 ductive umpolung cyclizations via aminoketyl radicals as a key step.

50 ith (*)OH, persistent DPPH(*) and galvinoxyl radical, as well as indigenous radicals of humic acids.

51 on are small and similar for the NF4 and LAF radicals, at the reaction temperatures, only the LAF rad

52 sis is proposed wherein free rotation of the radical-bearing carbon is prevented and the radical SAM

53 The synthesis of two new radical-bridged compounds [Co3(bptz)3(dbm)3].2toluene (1

54 lso describe the trapping of the captodative radical by replacing the vinylic carboxylic acid with an

55 The 1,2,4,7-cyclooctatetraenyl radical (C8 H7 ) has been synthesized for the very first

56 recombination efficiencies (FcP) of geminate radical cage pairs to the properties of the solvent.

57 ecursors and simple borohydride salts, alkyl radicals can be generated in aqueous solution.

58 nstabilized primary, secondary, and tertiary radicals can be used to install functional groups in a c

59 Thymidine radical cation (1) is produced by ionizing radiation and

60 in reaction, the oxidation of CPA 1 to amine radical cation 1(+*) by product radical cation 3(+*) (ge

61 A 1 to amine radical cation 1(+*) by product radical cation 3(+*) (generated using online electrochem

62 specific orientation of the sulfur-centered radical cation and a phenyl ring stabilized by the fibri

63 ducts in 67-89% yields via the corresponding radical cation and iminium ion intermediates, the reacti

64 in DNA, is significantly shifted toward the radical cation by a flanking dA.

65 ond formation proceeds through a key aminium radical cation intermediate that is generated via electr

66 The radical cation of N,N,N',N'-tetramethyl-p-phenylenediami

67 e approach reveals that an important part of radical cation population survives up to a few milliseco

68 A carotenoid radical cation signal was detected in the wild type, alt

69 lowed by mesolytic cleavage of the resulting radical cation species, which leads to the generation of

70 inic acid and ionization to diphenyl sulfide radical cation that in turn led to diphenyl sulfoxide.

71 probe the first two electronic states of the radical cation, and resolve the vibrational fine structu

72 asic conditions, the neutral network assumes radical cationic character without decomposing or changi

73 s method should be compatible with producing radical cations at defined positions within DNA.

74 n survives up to a few milliseconds, whereas radical cations produced by chemical oxidants in various

75 (2+) ions upon UV irradiation to form MV(+*) radical cations within the crystal structure with half-l

76 e neutral state and in the oxidized species (radical cations, dications and radical trications) has b

77 between the nitrogen lone pair and proximal radical center in angular 5,6-diethynylquinoxalines.

78 While radical chain halogenation reactions provide efficient a

79 Results were consistent with a free radical chain scission mechanism, supported by measureme

80 Surprisingly, we found an excess of radical changes in several of these lineages in comparis

81 ctive hydroxyl radicals (HO(*)) and chlorine radicals (Cl(*)) is an attractive alternative to UV alon

82 Radical clock and kinetic isotope experiments support a

83 ic isotope effects, stereochemical labeling, radical clock, and transient absorption studies support

84 l results in up to 30% decrease in the CH3O2 radical concentration while the HO2 concentration increa

85 upported by measurements of sub-muM hydroxyl radical concentrations.

86 resence of NO and it can be explained by the radical consumption by NO as SOx and NOx species share t

87 to the molecular oxygen with formation of a radical couple that recombines either as a peroxide anio

88 The ligand-centered radical couples antiferromagnetically with the Fe center

89 resence of dominant intralayer metal-organic radical coupling to give a magnetically ordered phase be

90 nteresting effect of a remote substituent on radical cyclization has also been presented.

91 ane-1,3-diones 2 followed by stereoselective radical cyclization of the resulting adducts 3 to provid

92 Highly selective dearomatizing radical cyclizations and cyclization cascades, triggered

93 Although radical cystectomy (RC) currently is viewed as the stand

94 As would be expected, the radicals' decay, specifically probed by the oxyl's subsu

95 stronger oxidant AgBF4 formed the metal-free radical dication L(.2+) .

96 a generalized pathway involving fast cation radical dimerization following electron transfer, follow

97 nes, the mono Au(I)-catalyzed pendant to the radical dimerization of nonconjugated alkyne units has n

98 Recently, BMCs associated with glycyl radical enzymes (GREs) were discovered; these are widesp

99 catalytic repertoire of Cbl-dependent AdoMet radical enzymes.

100 The formyl-radical equivalent then undergoes nickel-catalyzed subst

101 th-invariant oxidation potentials and cation radical excitation energies.

102 -2 addition (2->10:1), while softer tertiary radicals favor bond formation to C-4 (4.7->29:1).

103 inium salts are documented: harder secondary radicals favor C-2 addition (2->10:1), while softer tert

104 tide reductase (RNR) uses a diferric-tyrosyl radical (Fe(III)2-Y(*)) cofactor to initiate nucleotide

105 ed by intramolecular hydrogen atom transfer, radical fluorination, and ultimate restoration of the en

106 substrate double bond to form a captodative radical followed by rearrangement and decarboxylation to

107 -directed protein cross-linking and hydroxyl radical footprinting experiments.

108 materials for simple, thermal, Ni-catalyzed radical formation and subsequent trapping with either a

109 se of 266 nm light, we determined an initial radical formation time of 1.3 +/- 0.2 ps, which is ident

110 nation, amine arylation, and decarboxylative radical formation).

111 ed by the intermediacy of heterodimer cation radicals formed between the stannane cation radicals and

112 addition, copper(II) was also used to induce radical fragmentation reactions in the carboxylic acid p

113 inge modified similar sites on Notch1, while Radical Fringe modified a subset.

114 ial in situ generation of the diethoxymethyl radical from diethoxyacetic acid by a 4CzIPN-mediated ph

115 The chemical energy and radicals from an oscillating chemical reaction are used

116 s rely on the oxidative generation of iminyl radicals from simple oximes.

117 imary species, ejected electrons and guanine radicals, generated upon absorption of UV radiation dire

118 s established to elucidate the mechanisms of radical generation and mineral surface complexation.

119 Kinetic studies facilitated by photochemical radical generation reveal that Y731 changes conformation

120 rollable reactivity gives the carbon organic radical great potential as a versatile reducing agent th

121 The radical group (vs the conservative group) more often had

122 the formation of these tricarbontriphosphide radicals has been rationalized by a combination of exper

123 mmonium salts and three homologous nitroxide radicals have been prepared and characterized.

124 The pi bonds between organic radicals have generated excitement as an orthogonal inte

125 ation of a recalcitrant azo dye and hydroxyl radical (HO.) production.

126 ocess that produces highly reactive hydroxyl radicals (HO(*)) and chlorine radicals (Cl(*)) is an att

127 Hydroperoxyl radical (HO2) is a key species to atmospheric chemistry.

128 h as ozone (O3) and hydroxyl (OH) and peroxy radicals (HO2 + RO2), determines the lifetimes of reduce

129 ng ratio of hydroperoxyl radical to hydroxyl radical ([HO2]/[OH]) and increased [NO2]/[NO] with highe

130 ondary reaction between a dissociated iodine radical (I(*)) and an adjacent I3(-).

131 r that of the primary photoproduct, diiodide radical I2(*)(-), indicates that I4(*)(-) was formed via

132 Tomography has made a radical impact on diverse fields ranging from the study

133 plausible for the reaction with nitric oxide radical in all the solvents investigated.

134 The reaction appears to be radical in nature, with the addition of small quantities

135 extract showed antioxidant activity towards radicals in both environments, aqueous and hydrophobic,

136 drobenzo[e][1,2,4]triazin-4-yls (aka Blatter radicals) in moderate to good yields.

137 host cells to free fatty acid, leading to a radical increase in the esterification of free fatty aci

138 The stress-associated plant protein radical-induced cell death1 (RCD1) is one such hub, inte

139 ad also a protection effect against hydroxyl radical-induced DNA damage.

140 The koose inhibited radical-induced oxidative cellular and DNA damage.

141 onal food that can contribute to alleviating radical-induced oxidative stress.

142 nd EGF36 (added by Manic and Lunatic but not Radical) inhibited Notch1 activation from Jagged1.

143 , with the addition of small quantities of a radical initiator (azobis(isobutyronitrile)) increasing

144 a 2,2'-azobis[2-(2-imidazolin-2-yl)propane] radical initiator, of linoleic acid in sodium dodecyl su

145 served, consistent with a number of possible radical intermediates or hypercoordinate silicates.

146 ascade reactions that involve both ionic and radical intermediates.

147 the basic principles of using stable organic radicals involved in reversible exchange processes as fu

148 The radical-ion annihilation process is very efficient and c

149 applying stable hydrophilic and hydrophobic radicals is advantageous, especially for characterisatio

150 The cross-coupling of these radicals is catalyzed by copper via an out-of-cage mecha

151 In this regime, beta hydroxy peroxy radical isomers comprise approximately 95% of the radica

152 .1-7.9 x 10(3) M(-1) s(-1)) or with hydroxyl radicals (k(*)OH) (0.9 x 10(9) - 6.5 x 10(9) M(-1) s(-1)

153 Transition-metal complexes of radical ligands can exhibit low-energy electronic transi

154 SrTiO3, these one-electron intermediates are radicals located in Ti-O(*) (oxyl) and Ti-O(*)-Ti (bridg

155 sion of the quadricyclanes occurs via a free radical mechanism with very little contribution from pol

156 st that this reaction does not proceed via a radical mechanism, which is in contrast to classical Hun

157 This transformation operates via a hybrid Pd-radical mechanism, which synergistically combines the fa

158 e alkenes has been achieved via a photoredox radical mechanism.

159 DFT calculations revealed that radical mechanisms are preferred in reactions with steri

160 macromolecule-bound antioxidants in aqueous radical medium.

161 liberating an intermediate having a nitrogen radical moiety Fe(III)-N. and a phenoxyl anion.

162 With the exception of double radical MYBPC3 mutations, there is little data to guide

163 the incidence of CKD stage 4 or higher after radical (n=9759) or partial nephrectomy (n=4370) was 7.9

164 effectiveness of partial nephrectomy versus radical nephrectomy to preserve kidney function has not

165 ole that promotes catalysis through a methyl radical/Ni(ii)-thiolate intermediate.

166 nd galvinoxyl radical, as well as indigenous radicals of humic acids.

167 NO is a major source of atmospheric hydroxyl radical (OH), which impacts air quality and climate.

168 The detection of hydroxyl radicals (OH(*)) is typically accomplished by using reac

169 rbonaceous poison and combination with CH3CO radicals on adjacent Pd active sites.

170 tems from the promoted production of free OH radicals (on Ni active sites) which facilitate the oxida

171 tricyclic compounds are reported with either radical or cationic ground states stabilized by cyclic (

172 e of natural photosystems, and by metastable radical pair formation when photovoltaic reaction center

173 in statistics of the uncorrelated A(-*)-R(*) radical pair, where the initial charge separation yields

174 We conclude that the current model of radical-pair magnetoreception is unable to explain the f

175 e showed that the solid-state spectra of the radical pairs are very similar to those detected in solu

176 econd electronic spectra and kinetics of the radical pairs from various crystalline tetraarylacetones

177 ate, we were able to detect the intermediate radical pairs within the ca. 8 ns laser pulse of our las

178 rine concentration, suggesting scavenging of radicals participating in free chlorine chain decomposit

179 ino acids is correct as regards various free radicals, particularly oxygen-derived peroxyl radicals.

180 Consistent with a radical pathway, glutathione fully suppresses catalysis.

181 that the reaction likely proceeds through a radical pathway.

182 ate (GMA) by surface initiated atom transfer radical polymerization (SI-ATRP) and hexamethylene diami

183 ted electrochemically mediated atom transfer radical polymerization (SI-eATRP).

184 sized and chain extended using atom transfer radical polymerization from the model protein bovine ser

185 While switching of controlled radical polymerization has been achieve using light, app

186 that a tailored medium undergoing controlled radical polymerization is capable of forming giant polym

187 es for photoredox catalysis of atom transfer radical polymerization lies in their ability to minimize

188 MagLev) to characterize the kinetics of free-radical polymerization of water-insoluble, low-molecular

189 PTH", we demonstrate switching of controlled radical polymerization reactions using temperature "LOW"

190 was used as an efficient catalyst in living radical polymerization, yielding a well-defined polymer-

191 and thus the ability to realize a controlled radical polymerization.

192 covalently bound to graphene oxide via free-radical polymerization.

193 ls through cell surface-initiated controlled radical polymerization.

194 al isomers comprise approximately 95% of the radical pool, a much higher fraction than in the nascent

195 by NO as SOx and NOx species share the same radical pool.

196 , at the reaction temperatures, only the LAF radicals possess sufficient thermal stability to be viab

197 The radical possesses four mPEG-3 groups replacing four meth

198 The scope of the radical precursor includes alpha-iodo ketones, esters, n

199 The findings of this study suggest that the radicals present in soil can play an important role in n

200 s spectrometry, and products assessment from radical probes.

201 ntly incorporates molecular oxygen through a radical process.

202 rsened by 3 months for patients who received radical prostatectomy (36.2 [95% CI, 30.4-42.0]), extern

203 rachytherapy (LDR) alone, EBRT alone, and/or radical prostatectomy (RP) should be offered to eligible

204 aluated for variation in prostate biopsy and radical prostatectomy (RP) volume.

205 logic and biochemical outcomes after delayed radical prostatectomy (RP), using descriptive statistics

206 s occurred in 23 (33.8%) of 68 patients with radical prostatectomy and 16 (50%) of 32 patients previo

207 ancer (PCa) salvage radiotherapy (SRT) after radical prostatectomy are usually drawn in the absence o

208 Radical prostatectomy centres that closed were more like

209 ed 731 men with localized prostate cancer to radical prostatectomy or observation.

210 Regardless of radical treatment type (radical prostatectomy or radical radiotherapy), increasi

211 ohort of men with localized prostate cancer, radical prostatectomy was associated with a greater decr

212 t pelvic (99m)Tc-trofolastat SPECT/CT before radical prostatectomy with extended pelvic LN dissection

213 ogression to metastasis in patients choosing radical prostatectomy.

214 ssive prostate cancer involves a regiment of radical prostectomy, radiation therapy, chemotherapy and

215 greater 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical quenching potential (50% inhibitory concentratio

216 changes occurred more often in patients with radical radiotherapy treatment, positive (68)Ga-PSMA sca

217 cal treatment type (radical prostatectomy or radical radiotherapy), increasing comorbidity does not s

218 (50%) of 32 patients previously treated with radical radiotherapy.

219 ecular reaction rate constants with hydroxyl radicals ranged from (2.04 +/- 0.37) x 10(9) to (8.47 +/

220 irst comprehensive study on chlorine-derived radical reactions, and it provides mechanistic insight i

221 s study reports a method for correlating the radical recombination efficiencies (FcP) of geminate rad

222 y that precludes the possibility of safe and radical resection.

223 the rate of autoxidation for organic peroxy radicals (RO2) produced in the oxidation of a prototypic

224 In addition, neither solvent polarity nor radical rotation affects the correlation between FcP and

225 Radical S-adenosyl-l-methionine (SAM) enzymes are widely

226 Many cobalamin (Cbl)-dependent radical S-adenosyl-l-methionine (SAM) methyltransferases

227 ulated antiviral protein that belongs to the radical S-adenosylmethionine (SAM) enzyme family.

228 Radical S-adenosylmethionine (SAM) enzymes exist in orga

229 be formed using CysS, a cobalamin-dependent radical S-adenosylmethionine (SAM) methyltransferase.

230 nging to the emerging family of SPASM domain radical SAM enzymes, likely contains three [4Fe-4S] clus

231 Of particular interest are radical SAM enzymes, such as heme chaperones, that inser

232 radical-bearing carbon is prevented and the radical SAM machinery sits adjacent rather than opposite

233 sented that differs from other characterized radical SAM methyltransferases.

234 n conclusion, our findings indicate that the radical SAM protein family HemW/RSAD1 is a heme chaperon

235 Here, we report that a radical SAM protein, the heme chaperone HemW from bacter

236 aled a novel rRNA methylation mechanism by a radical SAM superfamily enzyme, indicating that two resi

237 activation of glutathione and ascorbate free radical scavenger systems.

238 SH) is a crucial intracellular reductant and radical scavenger, but it may also coordinate the soft C

239 control studies with and without oxygen and radical scavengers, we propose that boron-imidates form

240 ihydrocaffeates) exhibited relatively strong radical scavenging abilities.

241 We show that, while it has radical scavenging ability on par with other flavonoids

242 The DPPH radical scavenging activity of HG was quite stable over

243 Higher DPPH radical scavenging activity of pigmented cultivars was d

244 Compound 1 exhibited DPPH radical scavenging activity with an IC50 value of 20.02+

245 ma) and DPPH (2,2-Diphenyl-1-Picrylhydrazyl) radical scavenging assays.

246 ng of the cowpea pastes decreased their TPC, radical scavenging capacities and total quantified flavo

247 etermined using Folin-Ciocalteu method while radical scavenging capacities were by Trolox equivalent

248 Important aspects that may affect the radical scavenging capacity of carotenoids, such as syne

249 s, anthocyanins, proanthocyanidins, and free radical scavenging capacity were analysed.

250 re used to assess antioxidant activity, free radical scavenging capacity, protein-bound carbonyl grou

251 the fatty acids, total phenolic content and radical-scavenging activity were determined in the kerne

252 hich expressed 1.03+/-0.01 (mumolAAE/g) ABTS radicals-scavenging activity.

253 the protein containing flavin and tryptophan radicals shows kinetics that differ markedly from those

254 rface density of catalytically active oxygen radical sites on a MoVTeNb oxide (M1 phase) catalyst dur

255 ion of highly reactive and selective sulfate radical (SO4(*-)).

256 se synthesis of this hitherto elusive cyclic radical species 1,2,4,7-cyclooctatetraenyl via a single-

257 The radical species involved within the photocatalytic mecha

258 hieved, permitting the formation of reactive radical species that can engage in alkylations and aryla

259 coupling of photoredox-generated alpha-amino radical species with conjugated dienes using a unified c

260 azidation at the C2-position, whereas a less radical stabilizing group such as an alkyl or amide grou

261 A radical stabilizing group such as an ester or ketone moi

262 ein (MFP at 1, 8 and 20mg/mL) under hydroxyl radical stress.

263 lyoxylic acid and EPR shows the formation of radical structures.

264 ether our data may form the basis for a free radical substituent constant, sigmaQ*, analogous to the

265 This peptidomimetic/free radical system is a potentially excellent template for t

266 peridine (TEMPOH) was oxidized to the stable radical TEMPO by electron transfer to ferrocenium oxidan

267 he vinyl ether monomer-and a dithiocarbamate radical that is likely in equilibrium with the correspon

268 [Cu(II)(carb)3](-) serves as the persistent radical that is responsible for predominant cross-coupli

269 ly increases the local concentration of free radicals, thereby strongly influencing particle growth r

270 unprecedented capability to harness reactive radicals through discrete, single-electron transfer (SET

271 th an increased mixing ratio of hydroperoxyl radical to hydroxyl radical ([HO2]/[OH]) and increased [

272 nsfers: electron transfer from the substrate radical to the iron center followed by late ligand (Cl(-

273 e terminal alkyne and addition of a sulfonyl radical to the resultant vinyl azide.

274 ction involving the addition of the adenosyl radical to the substrate double bond to form a captodati

275 ments of the reaction products of the peroxy radicals to diagnose this complex chemistry.

276 es in the addition of secondary and tertiary radicals to pyidinium salts are documented: harder secon

277 Installation of the radical trap 3-amino tyrosine (NH2Y) by amber codon supp

278 ersatility compared to other highly reactive radical-trapping antioxidants (e.g., phenols, diarylamin

279 Regardless of radical treatment type (radical prostatectomy or radical

280 ized species (radical cations, dications and radical trications) has been investigated, allowing the

281 ctification ratio R = 99, but junctions with radical units have a new accessible state, a single-unoc

282 two pendant, chiral nitronyl nitroxide free radical units.

283 transfer process, generating viologen cation radical (V(*+)).

284 d all of these proteins generate an adenosyl radical via the homolytic cleavage of the S-C(5') bond o

285 n addition to Trp(233*+), a Cys(222)-derived radical was identified by electron paramagnetic resonanc

286 was found that the number of carbon centered radicals was dependent on the kind of starch and its che

287 ained from an independently generated aminyl radical, we assign it to the corresponding 1,3,-alkyl-am

288 The germane cation radicals were found to rapidly react with nucleophiles (

289 Benzyltrialkylgermane cation radicals were generated and spectroscopically characteri

290 However, it was found that hydroxyl radicals were produced proportionally to the Fe(II)-conc

291 Cu2 I2 (L(.) ) complex of a ligand-centered radical, whereas reaction with the stronger oxidant AgBF

292 ively cleaved to generate a 5'-deoxyadenosyl radical, which initiates turnover.

293 that by polarizing (13)C with photo-induced radicals, which can be subsequently annihilated using a

294 largely obscure class of cyclooctatetraenyl radicals, which have been impossible to access through c

295 that for both carbon- and nitrogen-centered radicals, which have relatively early and late transitio

296 es in the D/H ratios between the various CHx radicals whose polymerization is at the origin of the IO

297 012, which employs the reaction of iodoalkyl radical with molecular oxygen: for instance, CH2I + O2 -

298 n be synthesized through reaction of pyridyl radicals with 1,3-butadiene or sequentially with two ace

299 This opens a new way of generating stable radicals with fascinating electronic properties useful f

300 onducted for the reactions of the two N-oxyl radicals with toluene, which indicate that the HAT proce