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1 zenoid compounds (2500 cm(-1) for the M = CN radical anion).
2 been reduced to a paramagnetic endofulleride radical anion.
3 cation and scanning the tip to generate the radical anion.
4 eroxide, to produce SOD-Cu(II) and carbonate radical anion.
5 ectron transfer to generate a free iodoarene radical anion.
6 issociation of chloride from the chloroarene radical anion.
7 structure for the 1,7-di-trans-[12]annulene radical anion.
8 he nonadiabatic ET step for reduction to the radical anion.
9 mation involves rearrangement of the initial radical anion.
10 ration of the neutral at the geometry of the radical anion.
11 cal, which decarboxylates to yield a formate radical anion.
12 al state to be a Au(I) complex with a ligand radical anion.
13 ot appear to further stabilize the generated radical anion.
14 to stabilize the electrochemically generated radical anion.
15 ground-state CH3O anion or an adsorbed CH2O radical anion.
16 iconductors assembled with the TCNQ(.delta-) radical anion.
17 cal moieties in SOMO-HOMO converted distonic radical anions.
18 tron transfer, with generation of detectable radical anions.
19 F core as revealed in the EPR spectra of the radical anions.
20 romagnetically coupled to bis(imino)pyridine radical anions.
21 se substrates is the short lifetime of their radical anions.
22 reas the latter are easily reduced to afford radical anions.
23 y this species as the precursor of carbonate radical anions.
24 nds antiferromagnetically coupled to chelate radical anions.
25 hange spiral tubes of S = (1/2) (C14H10)(*-) radical anions.
26 ably arising from the production of distonic radical anions.
27 and then allowed to react with fluoranthene radical anions.
28 om SOMOs of the three- to five-membered ring radical anions.
29 er reactions between these siloles and their radical anions.
30 studied, water-soluble fullerenols as stable radical anions.
31 epend markedly on the presence of superoxide radical anions.
32 s of aromatic stabilization in forming their radical anions.
33 ncy in the corresponding quinone-semiquinone radical anions.
34 bond alternation significantly less for the radical anions.
35 he solvent used to generate lithium aromatic radical anions.
36 ty relationships when comparing nitrobenzene radical anions.
37 uction of GO by electrogenerated naphthalene radical anions.
38 re strongly bound than in isolated fullerene radical anions.
39 The optical spectra of nine dinitroaromatic radical anions (1,2- and 1,4-dinitrobenzene, 1,5- and 2,
41 ndicating the formation of the corresponding radical anion 2(*-), which was further characterized by
42 reduction of the neutral forms led first to radical anions (2(*-) and 3(*-)) and then to a bis(radic
45 n the formation of the N-nitrosodiethylamine radical anion (5) and nitric oxide (NO) via a triplet ex
48 e, having an inverted charge distribution (T radical anion, A radical cation), is not able to repair
49 ron oxidation of guanine in DNA by carbonate radical anions, a decomposition product of peroxynitroso
52 l electron transfer between an anthraquinone radical anion and a triarylamine radical cation in three
53 fluoride from the hexafluorocyclohexadienone radical anion and deprotonated hydroxypentafluorocyclohe
54 ersion of the formazanate complexes to their radical anion and dianion forms occurred at less negativ
56 -based simultaneous monitoring of superoxide radical anion and hydrogen peroxide provides the basis f
57 elet CD36 signaling by increasing superoxide radical anion and hydrogen peroxide through a mechanism
58 monitoring cellular production of superoxide radical anion and hydrogen peroxide using hydropropidine
59 erved in the reaction between benzoylnitrene radical anion and NO2, forming benzoate ion and nitrous
62 tion leading from the neutral species to the radical anion and subsequently to the dianion was achiev
63 ve reactions of the further reduction of the radical anion and the formation of lithium ethylene dica
64 rvation by ESR spectrometry of the disulfide radical anion and the spin trapping of the primary thiyl
65 n well before reaching the generation of the radical anion and was more intense on Au than on Pt.
67 f adjacent, electrochemically generated, NDI radical anions and dianions bind strongly to K(+), Li(+)
68 of PPNs--the ability of their reduced forms (radical anions and dianions) to interact with small radi
69 alino[2,3-b]phenazine) were reduced to their radical anions and dianions, employing either potassium
70 ce unactivated benzenes to the corresponding radical anions and display original selectivities in pre
71 hermal ET with most NDIs, generating NDI(*-) radical anions and NDI(2-) dianions in aprotic solvents,
72 e crystal X-ray structures of three of their radical anions and of three of their dianions were obtai
73 phenyl to naphthalene was determined for the radical anions and radical cations of molecules with the
74 o measure the proton affinities of all three radical anions and the electron affinities of o- and m-b
75 derive the heats of formation of each of the radical anions and their corresponding carbenes (i.e., a
76 l measurements were carried out on all three radical anions and their hydrogen-atom affinities, proto
77 uted energetic and ESR data for [12]annulene radical anions and their valence isomers suggest that 4a
79 of oxidative stress and source of superoxide radical anion (and indirectly, a causative of lipid pero
80 pounds (but by 450 cm(-1) for the M = C(CN)2 radical anion), and by 1000-1400 cm(-1) for the benzenoi
82 hotogeneration of singlet oxygen, superoxide radical anion, and photo-oxidation of added lipids and p
83 lculated spectra for the triplet flavin, the radical anion, and the most stable hydroflavin radical.
84 on the heptalene radical anion, [16]annulene radical anion, and tri-trans-[12]annulene radical anion
87 ssociation rates for a series of aryl halide radical anions (ArX-: X = Cl, Br) in NMP were measured a
88 operating in this case with the formation of radical anion as a critical step, followed by heterolyti
89 the reaction mechanism suggests a disulfide radical anion as the active species capable of cleaving
91 (3)MLCT(SQ) state (Ru(III) phen-semiquinone radical anion) as the predominant nonradiative decay pat
93 , the presence of adjacent covalently linked radical anions at a fixed location relative to each of t
95 ecomposition of the resulting disulfide bond radical anion breaks the C-S bond at the side chain of C
97 ion and noncovalent stabilization of organic radical anions by C-H hydrogen bonding in pi-stacked pai
99 This highly reactive and very short-lived radical anion can be produced both via photochemical and
100 generation of localized radical cations and radical anions capable of generating ECL upon annihilati
101 ion of the polymer and the other involving a radical anion-catalyzed chemical reaction of the polymer
102 diphenylanthracene are 330% and 470% for the radical anion-cation and radical anion-dication annihila
105 clerosis SOD1 mutants and that the carbonate radical anion (CO(3)) is responsible for oxidation of DC
106 or transitions from the ground state of each radical anion, (CO)n(*-) to the lowest singlet and tripl
108 by oxidation of (bi)carbonate to a carbonate radical anion (CO3*) by a bound hydroxyl radical-like sp
114 GPDI quadruplex suggests the formation of a radical anion delocalized over the neighboring PDI units
116 oxidation products were generated by SO4(*-) radical anions derived from the photolysis of S2O8(2-) a
117 nerating porphyrin radical cations and C(60) radical anions, detected by transient absorption spectro
123 has a significant electron affinity, and its radical anion expels chloride in a facile manner to give
124 of characteristic PTZ radical cation and ANQ radical anion features upon excitation in the transient
125 nitially reduced by one electron to form the radical anion (Fl(rad)(*-)) at E(0)(f) = -1.22 V versus
126 suggest a nucleophilic attack of superoxide radical anion followed by TNT denitration through an as
127 the oxaziridines to generate a copper-bound radical anion, followed by hydrogen atom abstraction and
132 ulated reduction potentials corresponding to radical anion formation are close to the experimental po
133 The cyclizations proceed by the trapping of radical anions formed by electron transfer reduction of
137 addition of an electron to the quinone, the radical anion forms strong H-bonded complexes with the v
138 ng constants (Kb) for binding of a series of radical anions from para- and ortho-substituted nitroben
140 e optical spectrum of 2,7-dinitronaphthalene radical anion generated by Na(Hg) reduction in acetonitr
141 otoelectron (NIPE) spectrum of the (CO)5(*-) radical anion gives an electron affinity of EA = 3.830 e
143 delta-) (7,7',8,8'-tetracyanoquinodimethane) radical anion has afforded molecular materials that beha
146 adiene undergo Cope cyclization, whereas the radical anions having substituents such as the fluoro, n
148 identified the coherently formed tetraiodide radical anion (I4(*)(-)) as a reaction intermediate.
149 Cope cyclization of 2,5-phenyl-1,5-hexadiene radical anions in a flowing afterglow triple quadrupole
152 ed by generating the (CO)5(*-) and (CO)6(*-) radical anions in the gas phase, using electrospray vapo
153 ibited by charge-delocalized dinitroaromatic radical anions in the solvents THF, HMPA, and DMPU (dime
154 ne radical anion, and tri-trans-[12]annulene radical anion indicate that electron spin resonance (ESR
155 in enhancing the inherent reactivity of the radical anion intermediate formed after electron transfe
156 ng electron density patterns in the putative radical anion intermediate involved in these reactions.
157 transfer from Sm(II) by stabilization of the radical anion intermediate rather than by solely promoti
158 2) as an acceptor of an electron to create a radical anion intermediate which is rapidly protonated,
159 ion proceeds via the formation of a silylone radical anion intermediate, which is further confirmed b
162 electron reduction of the coumarin to form a radical-anion intermediate, which is protonated by the m
168 rganization energy for ring opening of these radical anions is believed to be small because the negat
169 zation in the cross-conjugated, mixed-valent radical anions is proportional to the ferromagnetic cont
170 ch ultimately leads to the formation of host radical anions is responsible for the doping effect.
171 lkyl and vinyl phenyl thioethers by aromatic radical anions is shown to be the most general method ye
174 gy than the singlet ground state, and the pi radical anion lies 45.1 kcal/mol lower in energy than th
175 of the corresponding phenyl thioether by the radical anion lithium 1-(dimethylamino)naphthalenide (LD
177 New physical evidence to support a ketyl radical-anion mechanism for the [3,3]-sigmatropic rearra
178 on transfer/transport in the ground state of radical-anion mixed-valence derivatives occurring betwee
180 a nitrogen dioxide, (*)NO(2)) and superoxide radical anion (O(2)(*)(-)) promote Ras guanine nucleotid
181 specific reactive oxygen species (superoxide radical anion (O(2)(-)), hydroxyl radical (HO()) and hyd
183 shows distinctive EPR spectra for superoxide radical anion (O2(*-)) compared to other biologically re
184 t incorporates high reactivity to superoxide radical anion (O2(*-)), more persistent superoxide adduc
190 31+G* level, a nearly planar, bond-equalized radical anion of 1,7-di-trans-[12]annulene (4a(*-)) is l
193 ure the nu(C identical withN) IR band of the radical anion of a CN-substituted fluorene in tetrahydro
194 paramagnetic resonance (EPR) spectra of the radical anion of a tetrakis(silylalkynyl) DCF, generated
196 tive ion photoelectron (NIPE) spectra of the radical anion of cyclopropane-1,2,3-trione, (CO)3(*-), h
198 ten used for both ETD and PTR reactions; the radical anion of fluoranthene (m/z 202) for ETD and the
199 tive ion photoelectron (NIPE) spectra of the radical anion of meta-benzoquinone (MBQ, m-OC6H4O) have
200 the radical cation of phenothiazine and the radical anion of phenylquinoline shows good agreement wi
206 reaction between protonated peptide ions and radical anions of 1,3-dinitrobenzene formed exclusively
207 The Class III (delocalized) intervalence radical anions of 1,4-dinitrobenzene, 2,6-dinitronaphtha
210 cies in acetonitrile at 233 K, including the radical anions of m- and p-iodonitrobenzene, o-bromonitr
214 ped by Mathivanan, Johnston, and Wayner, the radical anions of several cyclopropyl- and oxiranyl-cont
216 calculations, on the single-electron reduced radical anions of the isosceles triangles confirm the se
217 eniently, alkyl halides with either aromatic radical-anions of lithium or lithium metal in the presen
218 nt oxidation pathway via sulfite and sulfate radical anions on droplets possibly via the direct inter
221 pable of assisting in the protonation of the radical anion or the expulsion of the leaving group.
222 lkyl chlorides, by either preformed aromatic radical anions or by lithium metal and an aromatic elect
223 olysis of alkynylcyclobutenones, can display radical, anion, or electrophilic character because of th
225 tion not only by bending the C-F bond of the radical anion out of planarity but also by increasing th
226 ansport of the electrogenerated nitrobenzene radical anion over macroscopic distances within the flow
227 ch leads to the formation of the semiquinone radical anions (P)-(+)-1(*-) and (M)-(-)-1(*-), respecti
229 es (intersystem crossing: ISC) and/or to the radical-anion (photoelectron transfer from the diene to
230 rgy (~1 eV) electrons (ECD), or with reagent radical anions possessing an electron available for tran
233 , only its decay product, the triply charged radical anion [Py(SO(3))(4)](*3-), as well as the triply
235 TPP(+)PDI(-) radical ion pairs, in which the radical anion rapidly migrates to PDI molecules that are
236 n the Re(I)(CO)3(py)(bpy-Ph)-perylenediimide radical anion (Re(I)-bpy-PDI(-*)) dyad, a prototype mode
237 the second system examined, the benzophenone radical anion reacted with the radical cation of either
241 e (stable neutral species (blue) or unstable radical anion (red)), and (iii) two-electron fully reduc
242 well as the spin density plots of the c-PFA radical anions reveal that the "extra" electron is large
243 a set is used to rationalize the kinetics of radical anion ring opening in a general context by using
245 ate-based, resulting in a bis(imino)pyridine radical anion (S(PDI) = 1/2) antiferromagnetically coupl
248 tion of the compound to an isolable triazole radical anion (see structure: C gray, H white, N blue, B
249 trostilbene (1-) and 4,4'-dinitrotolane (2-) radical anions show the narrow band widths and partially
250 e simple alkyne bridge in 4,4'-dinitrotolane radical anion shows two distinct bands, providing proof
252 (DMPO), hydroxyl radical ((*)OH) and sulfate radical anion (SO4(*-)) were measured from ultrasonic ac
256 ings include the probable bent nature of the radical anion species in ammonia, the likelihood that th
257 e by direct detection of the 4,4'-bipyridine radical anion species localized in the plasmonic hot spo
258 bserved that can be attributed to 8, an acyl radical-anion species resulting from a [3,3]-rearrangeme
260 ht account for the existence of a long-lived radical-anion state that permits lateral electron hoppin
261 on point for other systems involving the NDI radical anion, such as systems claimed to perform the ox
263 hough crystals could not be obtained for the radical anion [TCBT]*-, the electrochemistry (E degrees
264 For example, in the presence of a preformed radical-anion, tert-butyl phenyl sulfide cleaves signifi
265 ,4,6-tricyanobenzene, TCB, forms an unstable radical anion that immediately undergoes dimerization at
266 TCT, results in the formation of an unstable radical anion that undergoes immediate dimerization at a
267 ducing multiple species including the phenyl radical anion, the phenyl radical, and the benzyne dirad
269 ong the possible termination pathways of the radical anion, thermodynamically the most favorable is t
270 e neutral Ar'SnSnAr', 8, or ArSnSnAr, 9, the radical anions [(THF)(3)Na[rSnSnAr]], 10, [K(THF)(6)][Ar
271 utane thymine dimer and thymine dinucleotide radical anion, thymidylyl(3'-->5')thymidine, can be dire
273 bsequent electron transfer from the formed E radical anion to the neutral Z starting material the ove
274 rum of 1,2,4,5-tetraoxatetramethylenebenzene radical anion (TOTMB(*-)) shows that, like the hydrocarb
275 the minimal structural reorganization in the radical anions upon reduction during cyclic voltammetric
276 of a pseudo-para-dinitro[2.2]paracyclophane radical anion using Marcus-Hush theory reveals that its
277 ping of the captodative radical and the aryl radical anion using radical triggered C-Br fragmentation
278 is that the reduced VC decomposes to form a radical anion via a barrier of about 20 kcal/mol, which
279 ed to their corresponding radical cations or radical anions via electron abstraction or addition proc
281 In one, the energies of species (alkyne, radical anion, vinyl radical, vinyl anion, dianion, and
286 capturing and studying unstable anions and a radical anions when encapsulated by size-complementary a
287 ssociation spectrum of C(5)H(5)N-CO(2)(-), a radical anion which is closely related to the key interm
288 angement and decarboxylation to form an aryl radical anion which is then oxidized by the [4Fe-4S](+2)
289 radical species especially the negative side radical anion, which dominates the cycling stability of
290 ntrinsic properties of the para-benzoquinone radical anion, which serves as the prototypical electron
291 eases, except for the 1,5-dinitronaphthalene radical-anion, which has a coupling similar to that of 9
293 tructurally and electronically complex C(60) radical anion with a molecular formula of Na(+)(n)[C(60)
294 could proceed via combination of a nitroaryl radical anion with a neutral nitrosoaryl radical, follow
295 also were synthesized by reacting o-benzyne radical anion with carbon dioxide and electron ionizatio
296 xciton coupled singlet excited state, 3) the radical anion with strong through-space interactions bet
297 stem involves the reaction of the anthracene radical anion with the radical cation of 4,N,N-trimethyl
299 died for a series of nitrobenzene derivative radical anions, working as large guest anions, and subst
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