ライフサイエンスコーパス: reaction

1 re measured by quantitative polymerase chain reaction.

2 ated B cell responses in the germinal center reaction.

3 y, as well as altering the apparent order of reaction.

4 or as a hydrogen abstraction-Norrish Type II-reaction.

5 bition by the product of the chloroacylation reaction.

6 respectively, in an NTP-hydrolysis dependent reaction.

7 be influenced by atopy and type of clinical reaction.

8 ding are critical for the regulation of this reaction.

9 catalyst that is capable of catalyzing this reaction.

10 sis catalysed by RecN during the DNA pairing reaction.

11 turn is produced by the preceding enzymatic reaction.

12 nd attributed to the dynamics of elimination reactions.

13 for both epoxidation and H2O2 decomposition reactions.

14 s to desensitization of mice to IgE-mediated reactions.

15 catalyse specific enantioselective chemical reactions.

16 terials characterization and single-molecule reactions.

17 nd recoverability of their phototransduction reactions.

18 hol in inter- or intra-molecular Diels-Alder reactions.

19 ergies often associated with severe allergic reactions.

20 xisomes, organelles that sequester oxidative reactions.

21 may be used as templates in the cage forming reactions.

22 e transition state for activated bimolecular reactions.

23 eeds by sequential transnitrilation and SNAr reactions.

24 ivity) in Pd-catalyzed C-H functionalization reactions.

25 umed transition state in these glycosylation reactions.

26 e either through direct emissions or surface reactions.

27 y radicals and their bimolecular termination reactions.

28 r interactions often lead to exotic chemical reactions.

29 mful postvaccination immunologic (Koch-type) reactions.

30 bases have been reported to result from such reactions.

31 determine the kinetic course of nitrosation reactions, a systematic study of the nitrosation of ethy

32 substituted benzaldehydes and to compare the reaction acceleration relative to the bulk.

33 0 degrees C) exhibited high oxygen reduction reaction activity with an onset potential of 0.92 V, and

34 The reaction affords a variety of 2-oxindoles having quatern

35 odes becoming accessible to the ferricyanide reaction after nitrocellulose digestion by cellulase.

36 phoid sites for the study of germinal center reactions after vaccination in children.

37 The use of a one-pot reaction allowed us to overcome potential problems with

38 -) reduction of O2 to water, a key fuel-cell reaction also carried out in biology by oxidase enzymes,

39 selective photocatalysis, namely epoxidation reactions, among others.

40 a isolates was performed by polymerase chain reaction amplification of a fragment of tpi and bg genes

41 pathway, pyruvate:ferredoxin oxidoreductase reaction and anaplerotic pathways) and Re-citrate syntha

42 CD by triggering a robust neuroinflammatory reaction and degeneration of the nigral-dopaminergic neu

43 omote the enantioselective hydroalkoxylation reaction and form cyclic ethers.

44 analyzed with quantitative polymerase chain reaction and immunoblotting, respectively.

45 anic matter (DOM) affects mercury (Hg) redox reactions and anaerobic microbial methylation in the env

46 that targeted next-generation DNA sequencing reactions and in situ point mutation detection assays in

47 ntal conditions, it can participate in redox reactions and influence the sorption processes at surfac

48 ry and the heat flux dissipated by oxidation reactions and measured directly in water-in-oil emulsion

49 t score might be able to predict more severe reactions and merits further study.

50 allergy varies from mild to life-threatening reactions and often seems to depend on the route of expo

51 Visualization of metabolites, reactions and pathways in genome-scale metabolic network

52 quency entrainment, synchronized oscillatory reactions and pattern formation in space, as manifestati

53 d compartments are used to sequester harmful reactions and store useful compounds.

54 Azoxystrobin is biotransformed by various reactions, and 18 BTPs were identified.

55 teristics, development of early dermatologic reactions, and cause of treatment discontinuation were a

56 The reaction appears to be radical in nature, with the addit

57 d activation energy (Ea) for this hydrolysis reaction are detailed; the results demonstrate a direct

58 ls to implement selectivity in C-H oxidation reactions are briefly discussed.

59 , general criteria for solid-state explosive reactions are built upon both thermodynamics and kinetic

60 ee energies of activation for all elementary reactions are determined from density functional theory

61 The mechanisms of these SET reactions are discussed, and the ramifications are consi

62 Documented reactions are mild, involving mainly the skin, and, rare

63 The dynamics of chemical reactions are often governed by transient species, inclu

64 ctor, and then use the nuclease-based homing reaction as a form of gene drive to spread those genes t

65 s like triflates and mesylates for follow-up reactions as well as the comparison of different electro

66 4 mM) NaBAr(F)4 as compared with a very slow reaction at 125 degrees C in the absence of NaBAr(F)4.

67 eadily in a one-pot, two-step stoichiometric reaction at room temperature to form uranium(IV) siloxid

68 During charging, the oxidation reaction at significantly reduced charge potentials main

69 the characterization of photopolymerization reactions at elevated temperatures, which also widens th

70 We discuss the diverse array of reactions available involving omega-TAms and process con

71 ting step and provided close results for the reaction barriers of the two reaction steps.

72 talysts needed for five different photoredox reactions (beta-alkylation, beta-aminoalkylation, dehalo

73 e the evolution of droplet morphology during reaction between Al and SiO2.

74 a catalyst 3b activates the Michael addition reaction between malononitrile derivatives 2 and enamine

75 a palladium-catalyzed Ullmann cross-coupling reaction between the appropriate 2-iodocyclohex-2-en-1-o

76 he optimality of putative metabolic exchange reactions between heterocysts and vegetative cells.

77 ta(18)O anomalies, suggesting that explosive reactions between magma and coal during the Siberian flo

78 Reactions between nitric oxide (NO), nitrite (NO2-), and

79 the dielectric surface and not from chemical reactions between NO2 and the dielectric/semiconductor c

80 Reactions between phosphines with small cyclohexyl- (Cy)

81 d to catalyze abiological C-H bond amination reactions, but the yields of these reactions have been l

82 g that the classical mechanism involving SN2 reaction by Asp110 pertains.

83 vity toward aromatic diazonium ions and this reaction can be used to chemoselectively label proteins.

84 Kinetic data suggest thioether-Pd-catalyzed reactions can be as much as 800x faster than classic lig

85 ry is particularly well suited because these reactions can be performed in precise three-dimensional

86 diverse cellular functions, from serving as reaction catalysts to coordinating cellular propagation

87 The subsequent energy transfer to the reaction center is commonly rationalized in terms of exc

88 ptures solar energy and transports it to the reaction center, where charge separation occurs.

89 ry of a homodimer is broken in heterodimeric reaction-center structures, such as those reported previ

90 ophyll is coordinated with the production of reaction centre and light-harvesting polypeptides.

91 ygen-regulated pufQBALMX operon encoding the reaction centre-light-harvesting photosystem complex.

92 Each droplet then becomes a reaction chamber for PCR, which through the use of fluor

93 amic balance of the metal ligand cooperative reactions, changing the energetics of the process when d

94 (1)-C(5) cyclization to become a competitive reaction channel.

95 can also occur for alkynes held under CuAAC reaction conditions but again can be eliminated by addin

96 leterious acid-base side-reactions under the reaction conditions for homologation, leading to low ste

97 t ZnCu undergoes surface oxidation under the reaction conditions so that surface Zn transforms into Z

98 c acid (FDCA) using aerial oxygen under mild reaction conditions.

99 obtained with satisfactory yields under mild reaction conditions.

100 hyl sulfoxide as an oxidant under metal-free reaction conditions.

101 A single pot dipolar cycloaddition reaction/Cope elimination sequence was developed to acce

102 ible and LC-MS analyses showed that the fast reaction corresponds to beta-adduct formation (the kinet

103 mation (the kinetic product), while the slow reaction corresponds to the formation of the delta-adduc

104 The reaction could be viewed as an electron-transfer initiat

105 The reaction couples structured with TFMG/TE are annealed at

106 ger systems.The competition between chemical reactions critically affects our natural environment and

107 us, a subsequent LP solution subject to this reaction deletion constraint becomes a distinct EM.

108 l modes resulted in either Direct or Delayed reaction, depending on the vibrational mode.

109 cal environment or catalysis of an exergonic reaction, drives the system away from equilibrium.

110 SpyTag002 reaction enabled specific and covalent decoration of int

111 This reaction enables introduction of various aryl groups to

112 ition, a cascade of three aldolase-catalyzed reactions enables one-pot assembly of gamma-nitroketones

113 ss the predictive performance of our virtual reaction extraction tool, 38 potential substrates were t

114 0 coefficients of individual metabolites and reaction fluxes.

115 y is a potentially life-threatening allergic reaction following a honeybee, vespid, or ant sting.

116 The key signal amplification reaction for the checkpoint is the conformational conver

117 rbit[7]uril (CB[7]) can catalyse Diels-Alder reactions for a number of substituted and unreactive N-a

118 ous complexity with thousands of species and reactions for all but the very simplest of chemistries.

119 icant expansion to the scope of substitution reactions for the dodecaborate ion, whereby this cluster

120 The shell sequesters enzymatic reactions from the cytosol, analogous to the lipid-based

121 This reaction furnishes highly substituted and functionalized

122 ermal annealing, the hole-injection-assisted reactions happen at selective molecular sites controlled

123 of this catalyst during the electrochemical reaction has been proposed to be beneficial for its cata

124 Harnessing the reverse reaction has the potential to allow the versatile E. col

125 amination reactions, but the yields of these reactions have been limited by low chemoselectivity for

126 electrocatalysts for the hydrogen evolution reaction (HER) to cathode materials for batteries.

127 tate" becomes the most stable species on the reaction hypersurface.

128 ee's, ortho-tert-butoxyaniline our optimized reaction (i.e. solvent, temperature and catalyst study)

129 onversion of two rapid photoinduced ligation reactions, i.e., the light activation of o-methylbenzald

130 ated adverse events were infusion-associated reactions (IARs) (56%), which were grade 1/2 in 84% of p

131 oor units facilitates a visible light fusion reaction in >95% yield, whereas the cove-edge nature of

132 The ED05 is the dose that elicits a reaction in 5% of allergic subjects.

133 aterials for catalyzing the oxygen evolution reaction in acid-based electrolyzers must be guided by t

134 The reaction in chloroform at 100 degrees C under Rh2(OAc)4

135 The process is effectively a "reaction in the beaker", avoiding direct handling of hig

136 onclude by showing applications of the IEDDA reaction in the construction of biomaterials that are us

137 ment is potentially a conserved biosynthetic reaction in this molecular class.

138 ed atomistic understanding of transformation reactions in even larger systems.The competition between

139 be essential for the electron transfer (ET) reactions in NOSs.

140 s involved in 83% of all predicted enzymatic reactions in the tomato metabolic network.

141 ward oxygen evolution and hydrogen evolution reactions in water-alkali electrolyzers is pivotal for l

142 a covalent inhibitor that mimics one of the reaction intermediates, there is an overall decrease in

143 competition experiment established that the reaction involves formation of free alkynylboronate and

144 A rapidly emerging set of catalytic reactions involves intermediates that contain a copper-s

145 ramolecular atropselective aza Paterno-Buchi reaction involving atropisomeric enamide and imine funct

146 atalyzed Suzuki-Miyaura and Buchwald-Hartwig reactions involving cleavage of the C(acyl)-O bond of ar

147 unctional theory (DFT) calculations on these reactions, involving both cyclopentadienyl and carborany

148 The galvanic replacement reaction is a highly versatile approach for the creation

149 The reaction is both chemo- and regioselective, as only 4,6-

150 The reaction is catalyzed by an iridium complex generated fr

151 aracteristics during the photopolymerization reaction is desired.

152 A remarkable feature of the reaction is that the stronger Ph-O bond is cleaved rathe

153 The reaction is triggered by oxidative addition of an activa

154 lex I at which energy generated by the redox reaction is used to initiate proton translocation.

155 razole (4) by N-amination and N-azo coupling reactions is described.

156 acity of 1,327 mAh/(g of S), along with fast reaction kinetics and negligible polysulfide dissolution

157 vacancies and the mechanism determining the reaction kinetics are still unknown.

158 ynergistically combine to accelerate surface reaction kinetics by several orders of magnitude.

159 og unit for equilibrium constants of several reactions leading to halamines in water.

160 Accordingly, these reactions led to the construction of new classes of pyrr

161 us (specifically acute, Koch phenomenon-like reactions), lung function, or radiology attributable to

162 d spectroscopic studies confirmed that these reactions mainly proceeded by intramolecular electron tr

163 Such Mn(II)-phyllomanganate reactions may thus alter metal uptake by blocking key re

164 A new reaction mechanism for this thioesterification is propos

165 vides new insights into a potentially unique reaction mechanism.

166 We show that the photochemical reaction mechanisms for alpha-keto acids in aqueous solu

167 and theoretical studies of the C-H amination reaction mediated by the iron dipyrrinato complex ((Ad)

168 rmore, the assay can be used for fine-tuning reaction mixtures of various agents to enhance the overa

169 al safety of milk, but also induces Maillard reactions modifying for example proteins.

170 omatography-stable-isotope dilution-multiple-reaction monitoring-mass spectrometry.

171 ainful burn with blisters vs. practically no reaction, multivariable-adjusted RR = 1.01, 95% CI: 0.93

172 d in living systems by constructing chemical reaction networks (CRNs) with well-defined dynamic prope

173 Surface reaction networks involving hydrocarbons exhibit enormou

174 nder uncertainty for heterogeneous catalysis reaction networks using surrogate models that are traine

175 four oxidant precursors was used to initiate reactions (NOx photo-oxidation, photolysis of H2O2, ozon

176 These reactions occur with chemoselectivity for insertion of t

177 Our data demonstrate that the reaction occurs exclusively on the Pt surface.

178 onstrated, which explains how the conversion reaction occurs in alpha-MnO2 material.

179 (oxy)hydroxide (Ni(Fe)OxHy) oxygen evolution reaction (OER) catalysts, yet its precise role remains u

180 eduction reaction (ORR) and oxygen evolution reaction (OER) in fuel cells or metal-air batteries.

181 In the oxygen evolution reaction (OER), surface oxygen adsorption plays an indis

182 rbazole has been prepared by cyclomerization reaction of 4,5-bis(6-carbazole-9-yl-hexylsulfanil)phtha

183 cient, solvent-free, and eco-friendly domino reaction of 5/6-membered cyclic sulfamidate imines with

184 hiolate [Cu(II)]-SR intermediate formed upon reaction of an additional equiv thiol with [Cu(II)]-OH.

185 cations have also been synthesized from the reaction of an NHC with phenylethynyl bromide or 1,4-bis

186 The reaction of chiral N-tert-butanesulfinyl aldimines with

187 nanostructures at the MWCNT/Cu interface by reaction of diffused Cr atoms and amorphous carbon of MW

188 conformational change in the oxidative half-reaction of FMOs.

189 In contrast, the reaction of L(-) with CuI formed the unique, neutral Cu2

190 effect of oxalic acid (OxA) on NPF from the reaction of MSA and methylamine (MA) at 1 atm and 294 K

191 The unexpected reaction of one of these 1,4-oxazepanes in the presence

192 NO formation from thiols occurs from the reaction of RSNO and a copper(II) thiolate [Cu(II)]-SR i

193 oselective intramolecular Diels-Alder (IMDA) reaction of the camphanate-containing triene intermediat

194 A detailed study of the reaction of trifluoroacetylated acetylenes and aryl (alk

195 ic procedure involved two key steps: (1) the reaction of vinyl magnesium bromide with 2,2-dimethyl-6-

196 rlying thermodynamic factors controlling the reactions of 25 and its reaction partners, and a detaile

197 osphination and the retro-hydrophosphination reactions of [60]fullerene/phosphine borane compounds of

198 sition of water and methanol, as well as the reactions of CO and CO2 over TMC surfaces.

199 combination of ion intercalation with redox reactions of iodine allows for developing rechargeable i

200 This review covers the functionalization reactions of meso-arylcorroles, both at the inner core,

201 y theoretical calculations conducted for the reactions of the two N-oxyl radicals with toluene, which

202 In this study, the kinetics of SO2 reactions on MnO2 with different morphologies (alpha, be

203 thways that have been proposed for oxidation reactions on single supported atom.

204 and RuO2 catalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in fu

205 latinum, resulting from the oxygen reduction reaction (ORR) or hydrogen peroxide reduction on platinu

206 utions around the alkene strongly affect the reaction outcome.

207 ifferences in postoperative anterior chamber reaction (P = 0.7) or LPI area (P = 0.9) were noted betw

208 tors controlling the reactions of 25 and its reaction partners, and a detailed comparison was made wi

209 es and their interconversion rates along the reaction pathway of a bacterial homodimeric enzyme, fluo

210 The latter reaction pathway requires a C13=C14, C15=N double-isomer

211 breakdown is considered as the main Maillard reaction pathway, other reactive intermediates, often of

212 New insight is presented on the individual reaction pathways of the terpenes hydroxydammarenone and

213 ologies involving real-time polymerase chain reaction (PCR) assays that facilitate direct analysis of

214 by use of real-time immuno-polymerase chain reaction (PCR), to parasitemia limits of 0.02 parasite/m

215 d on parasite prevalence by polymerase chain reaction (PCR)- and the prevalence of antibodies to two

216 Prolonging the reaction period to 48-70 h led to successive gamma-C(sp(

217 most severe and frightening of the allergic reactions, placing patients at high risk and demanding p

218 These reactions proceed within 10 min at room temperature, whi

219 The reaction proceeds at room temperature under mild conditi

220 The reaction proceeds by sequential transnitrilation and SNA

221 The reaction proceeds through inter- and intramolecular C-C

222 The reaction proceeds through nucleation and growth of the n

223 evidence is presented that supports that the reaction proceeds via a Rh(III)-eta(3)-allyl.

224 The reaction proceeds via the generation of NHC-bound enolat

225 Since this reaction proceeds with a rate constant in the order of 1

226 e to dictate the preferred enantiomer of the reaction product.

227 ption revealed the presence of five possible reaction products (a-e).

228 at the extent of fission is increased as the reaction progresses, producing more compartments with in

229 While radical chain halogenation reactions provide efficient access to many halogenated m

230 The reaction provides a greener and more practical access to

231 The reaction provides a straightforward approach to pharmace

232 proximately 0.5-0.7), rate of particle-phase reaction (r(2) approximately 0.4-0.7), and sulfate (r(2)

233 on the effects of chloride concentration on reaction rate and indicate that the catalyst is subject

234 an a clinically negligible 6.0% breakthrough reaction rate in the cohort that received 5-hour intrave

235 order of magnitude and increases the overall reaction rate.

236 ive humidity (RH), and particle size control reaction rates and mechanisms.

237 I) ](2+) core through aromatic hydroxylation reactions represent a new domain for high-valent bis(mu-

238 tivity for hydroisomerization of n-hexane, a reaction requiring hydrogenation/dehydrogenation and mod

239 This reaction scheme introduces no addition time to the scan

240 s to polarized pi bonds occur within cascade reaction sequences to provide rapid access to a diverse

241 of space between tooth and bone, periosteal reaction, serpentine bone resorption, abscess formation,

242 ted to participate, irrespective of previous reaction severity.

243 Addition of water to the reaction showed a remarkable improvement and the isomeri

244 s defined as the combination of at least two reaction steps in a single reaction vessel without isola

245 results for the reaction barriers of the two reaction steps.

246 The KIEs measured for the enzymatic reaction suggest a similar mechanism of cyclization with

247 chasticity during pre-nucleation renders the reactions susceptible to perturbations by other molecule

248 igher mass activity for the oxygen reduction reaction than Pt/C, and twice the mass activity of the h

249 n parboiled rice as a result of the Maillard reaction that negatively affects consumers' acceptabilit

250 discuss the mechanistic hypotheses for those reactions that are currently active areas of investigati

251 u-NPs) to induce known thermal decomposition reactions that cleave peptides and proteins specifically

252 The r-process is a series of neutron capture reactions that synthesise many of the elements heavier t

253 d the invention of entirely new biocatalytic reactions that were previously unknown in Nature.

254 fibrinolysis that includes the main chemical reactions: the microscale model represents a single fibe

255 Because PutAs catalyze sequential reactions, they are good systems for studying how metabo

256 minant role in the formation of desmoplastic reaction through the synthesis of connective tissue and

257 ctivity to concomitant increases in saccadic reaction time (SRT).

258 fore, the new design allows a 30-fold longer reaction time and a 40-fold increase in pressure compare

259 were evaluated using the five-choice serial reaction time task (5-CSRTT) and delay discounting proce

260 ing, 6 loci shared between schizophrenia and reaction time, and 14 loci shared between schizophrenia

261 al synchrony during visual attention predict reaction time.

262 variability in search performance, such that reaction times were longer when distractors had a higher

263 Reaction times were prolonged in SCI participants compar

264 igm, which typically refers to a decrease of reaction times when subjects perform an action (e.g., a

265 ive to standard batch conditions, with short reaction times, increased safety profile, and potential

266 activation barrier for the highly exothermic reaction to a classical Lewis structure nevertheless mak

267 t is hard to give up" and also "an automatic reaction to a specific situation".

268 Here we report an electrically driven CE reaction to prepare individual nanostructures inside a t

269 djusted RR = 0.98, 95% CI: 0.92, 1.05), skin reaction to prolonged sun exposure (for painful burn wit

270 the PET/MRI examination well, and no adverse reactions to (18)F-FTC-146 were reported.

271 des underlying clinically significant tissue reactions to Co, Cr and Ti by analysing viable peri-pros

272 2 permeability and the exploitation of phase reactions to create a new conductive phase along the gra

273 esterone and the subsequent 17alpha,20-lyase reactions to form dehydroepiandrosterone (DHEA) and andr

274 catalyzed azide alkyne cycloaddition (CuAAC) reactions to synthesize heteromultivalent glycooligomers

275 of the already very versatile Suzuki-Miyaura reaction toward the synthesis of very electron-poor prod

276 Emphasis is placed on reaction types and catalytic mechanisms that showcase bo

277 prone to undergo deleterious acid-base side-reactions under the reaction conditions for homologation

278 rization formulation to constrain the set of reactions used to fill gaps in a metabolic network.

279 s work showcases a new catalytic cyclization reaction using a highly Lewis acidic borane with concomi

280 Iron-catalyzed cross-coupling reactions using alkynyl nucleophiles represent an attrac

281 n of at least two reaction steps in a single reaction vessel without isolation of the intermediates,

282 molecular Diels-Alder and hetero-Diels-Alder reactions via a single ambimodal transition state, and a

283 as the length of colored band formed on the reaction was also demonstrated.

284 The reaction was amenable to a variety of aryl boronic acids

285 In thermal reactions, we discuss the thermal decomposition of water

286 ative reverse transcriptase-polymerase chain reaction, Western blot, and immunohistochemistry were us

287 chemical transformations occur in two-phase reactions, which are widely used in chemical, pharmaceut

288 Pericyclic reactions-which proceed in a concerted fashion through a

289 ethionine, the reactive methyl donor, and by reaction with alkylating agents.

290 It was found that the reaction with alpha-substituted five- to seven-membered

291 en substituents geometrically positioned for reaction with halides in solution, halogen bonding was d

292 heterocycles were converted to C-Si bonds by reaction with hydrosilanes under the catalytic action of

293 at -70 degrees C is easy to achieve, whereas reaction with lithium-magnesium and lithium-zinc amides

294 For such a complex reaction with membranes, it has been difficult to uncove

295 In addition to reaction with O2, cis-[Pd(IPr)2(eta(2)-O2)] reacts at lo

296 N3-Methyladenine (3-MeA) is formed in DNA by reaction with S-adenosylmethionine, the reactive methyl

297 omplex of a ligand-centered radical, whereas reaction with the stronger oxidant AgBF4 formed the meta

298 , except for a higher rate of injection-site reactions with alirocumab.

299 n ozone and gaseous elemental mercury due to reactions with halogen atoms, influencing atmospheric co

300 nce for acid production from indoor chemical reactions with ozone was found.