ライフサイエンスコーパス: reaction kinetics

1 nfluencing the gluconeogenic and anaplerotic reaction kinetics.

2 n mechanism and accurately measure electrode reaction kinetics.

3 es, but a significant limitation is its poor reaction kinetics.

4 transfer (smFRET) study of the dimerization reaction kinetics.

5 t indoor temperatures and RHs did not affect reaction kinetics.

6 n be modelled using stress-assisted chemical reaction kinetics.

7 tamin A but with a lower affinity and slower reaction kinetics.

8 mediated strand displacement for controlling reaction kinetics.

9 en heat transfer, fluid dynamics and surface reaction kinetics.

10 classical mass-action principles in modeling reaction kinetics.

11 unclear exactly how microorganisms influence reaction kinetics.

12 foundational knowledge regarding its surface reaction kinetics.

13 into the holding coil to accelerate the slow reaction kinetics.

14 er a period of 12h both followed first order reaction kinetics.

15 mediate, consistent with the analysis of the reaction kinetics.

16 P), k(CT), k(-CT)) and used to model overall reaction kinetics.

17 ation, regulate barrier height, and modulate reaction kinetics.

18 Temperature changes affect reaction kinetics.

19 rates, and analysis of steady-state and half-reaction kinetics.

20 racentrifugation, and steady-state and rapid-reaction kinetics.

21 el up to 5 mM had a negligibly effect on the reaction kinetics.

22 n interpreted in terms of simple bimolecular reaction kinetics.

23 we used this probe to monitor single Pb(2+) reaction kinetics.

24 of molecular oxygen was not a factor in the reaction kinetics.

25 acetonitrile has a significant impact on the reaction kinetics.

26 to wild-type EGFR, and they exhibit distinct reaction kinetics.

27 e cycling, sample archiving, and controlling reaction kinetics.

28 substrate turnover are consistent with bulk-reaction kinetics.

29 crofluidic flow-flash, for measuring protein reaction kinetics.

30 ad52-promoted annealing follows second-order reaction kinetics.

31 iation with a mathematical model of chemical reaction kinetics.

32 ture-function relationships in heterogeneous reaction kinetics.

33 articularly suited for in situ monitoring of reaction kinetics.

34 icals commonly used for sGC purification and reaction kinetics.

35 y to allow numerical analysis of proteolysis reaction kinetics.

36 inating the constraints of diffusion-limited reaction kinetics.

37 sis method was used to delineate the complex reaction kinetics.

38 unting for the gain-of-function and improved reaction kinetics.

39 diate products, time-dependent processes and reaction kinetics.

40 making it possible to estimate the observed reaction kinetics.

41 etect RNA reactivity could bias the observed reaction kinetics.

42 ntrol over heat and mass transfer to control reaction kinetics.

43 played an important role in the ring-opening reaction kinetics.

44 in-8, cannot be explained by simple chemical reaction kinetics.

45 similarity in reactivity is due to very fast reaction kinetics.

46 f ligands to the NC surface, and the surface reaction kinetics.

47 TPs demonstrated reaction kinetics 37.6 times faster than MBs, resulting

48 exhibit high affinity for analytes and fast reaction kinetics, allowing detection of single nucleoti

49 the diiron complex taken as an example, the reaction kinetics analysis, including the H/D isotope ef

50 Informed by reaction kinetics analysis, relevant dinuclear Pd(III) c

51 The sensor has improved reaction kinetics and a K(d) ideal for imaging Ca(2+) in

52 omplex process exhibiting multiphase "gated" reaction kinetics and a striking sigmoidal temperature p

53 Study of the reaction kinetics and aggregation behaviour suggests a m

54 Moreover, we use the system to determine reaction kinetics and argue how the multipoint detection

55 greater resistance to pulverization, faster reaction kinetics and better trapping of soluble polysul

56 The reaction kinetics and catalyst composition were studied

57 ve compositions of Pd-Co which suggests fast reaction kinetics and chemical reversibility during the

58 py, we observed deuteroxyl radical (OD) + CO reaction kinetics and detected stabilized trans-DOCO, th

59 Reaction kinetics and DFT calculations shed light on the

60 E to yield a variant (TES148C) with improved reaction kinetics and gain-of-function processing of an

61 e interfacial reaction area, leading to fast reaction kinetics and high reaction reversibility.

62 es with 2-aminoimidazole results in superior reaction kinetics and improved yields of primer extensio

63 Analysis of reaction kinetics and inhibitor stability revealed that

64 rate constant, k, measures intracellular CK reaction kinetics and is independent of myocyte number w

65 rmination of substrates with unknown surface reaction kinetics and large topographical features.

66 mum active region suggests that the surface reaction kinetics and lateral electron transport on the

67 strategies, including improved control over reaction kinetics and low synthesis temperatures, afford

68 r results provide a strong case of different reaction kinetics and mechanisms of reactions occurring

69 Reaction kinetics and mechanistic studies for ethylene-i

70 Although the reaction kinetics and molecular recognition of a few ind

71 thesis, involving initiation, control of the reaction kinetics and molecular structures, functionaliz

72 acity of 1,327 mAh/(g of S), along with fast reaction kinetics and negligible polysulfide dissolution

73 ligation with a focus on factors that affect reaction kinetics and on the identification of intermedi

74 coefficient measurements are needed, such as reaction kinetics and particle size determinations.

75 Understanding the potential reaction kinetics and pathways of Cr(VI) remediation pro

76 Analysis of reaction kinetics and product distribution in channel mu

77 insights into the mechanism of this process, reaction kinetics and products were determined employing

78 This transformation exhibits bimolecular reaction kinetics and represents a key step in a propose

79 We have examined the rapid reaction kinetics and spectroscopic properties of the mo

80 ng turnover, providing a signal to determine reaction kinetics and study cooperativity.

81 the kinetic mechanism of SsuD through rapid reaction kinetics and substrate binding studies.

82 ystem, both mechanisms operate; however, the reaction kinetics and the antioxidant efficacy depend on

83 heoretical support for the simplification of reaction kinetics and the approximation of reactive zone

84 antioxidant compounds followed a first-order reaction kinetics and the degradation rate constants (k)

85 A method for monitoring photochemical reaction kinetics and the dynamics of molecular excitati

86 lation, we need to understand GTP hydrolysis reaction kinetics and the GTP cap size.

87 Changes in the reaction kinetics and the ionic/nonionic nature of the T

88 degree, on which the interaction between the reaction kinetics and the network structure organise the

89 tions is controlled by the interplay between reaction kinetics and the rate of mass transfer to the r

90 Degradation followed first-order reaction kinetics and the temperature-dependence of the

91 is known about how these assemblies modulate reaction kinetics and the ultimate propagation of signal

92 00% H2 to varying degrees and with different reaction kinetics and then exhibits stable, reversible c

93 ductance switching allows the study of redox reaction kinetics and thermodynamics at single molecular

94 is in a lifeless environment are dictated by reaction kinetics and thermodynamics, so concentrations

95 oparticle surface, both of which control the reaction kinetics and thus enable the selective synthesi

96 parameters to quantitatively manipulate the reaction kinetics and thus the lower and upper limits th

97 ically elucidating parameters that influence reaction kinetics and total conversion, and highlighting

98 rface sedimentary environments, despite slow reaction kinetics and uncertainty as to the actual degra

99 Through the control of reaction kinetics and vascular delivery rate, we filled

100 zacyclooctynone (BARAC) that has exceptional reaction kinetics and whose synthesis is designed to be

101 e catalytic mechanism of the enzyme by rapid reaction kinetics and x-ray crystallography using the po

102 d mutants of ERK and MKP3, binding analyses, reaction kinetics, and chemical cross-linking studies we

103 sarily limited by the size of the electrode, reaction kinetics, and duration of the rest period.

104 rt of O(2-) anions, drastically improves the reaction kinetics, and enables the electrolysis at low t

105 e reagent and sample consumption, accelerate reaction kinetics, and enhance the sensitivity and speci

106 ide improved reaction safety and accelerated reaction kinetics, and have synthesised several active p

107 by computational modeling and a study of the reaction kinetics, and is also consistent with observed

108 r also results in phenomenologically simpler reaction kinetics, and overall these features have facil

109 s supported by the reaction products formed, reaction kinetics, and quantum mechanical calculations.

110 ffusion, molecular transport and biochemical reaction kinetics, and regulation of biomolecular intera

111 enables a closed form solution for ITP-aided reaction kinetics, and reveals a new characteristic time

112 ectroscopy, which directly measured FcP from reaction kinetics, and the second method (referred to he

113 Reaction kinetics are described by a rapid, low-fraction

114 The experimentally obtained reaction kinetics are discussed in light of molecular mo

115 The reaction kinetics are found to have a strong chiral depe

116 vacancies and the mechanism determining the reaction kinetics are still unknown.

117 (1) and DeltaS() = -25.9 (9.7) eu, while the reaction kinetics are zero-order in [amine] and first-or

118 These experiments measure reaction kinetics as a function of applied force.

119 with BaOCH3(+) Further investigations of the reaction kinetics as a function of collision energy over

120 Modeling the reaction kinetics as a series of irreversible steps allo

121 ITP accelerates the reaction kinetics as the ionic spacer concurrently separ

122 lay an important role in determining overall reaction kinetics as well as the distribution of ion/ion

123 date a variety of single-cell, deterministic reaction kinetics as well as various stochastic division

124 Multiphase reaction kinetics at gaseous ozone concentrations of 131

125 0.1), that greatly improved oxygen reduction reaction kinetics at intermediate to low temperatures.

126 In addition, an examination of the reaction kinetics at lower pH reveals that for Cu-DAHP s

127 We successfully applied a reaction kinetics based combined hydrolysis factor (CHFX

128 A reaction kinetics based modeling of the edge-oriented 3D

129 In this paper, we present a reaction kinetics-based technique that solves this probl

130 er density and accelerated surface oxidation reaction kinetics become the key points for improved pho

131 immunosensor was developed to elucidate the reaction kinetics between a protein of unknown function

132 However, the reaction kinetics between a solution-phase mediator and

133 Analysis of reaction kinetics between CCl(4) and AA revealed an over

134 y hydrogen and fluorine plasmas, much slower reaction kinetics between the chlorine plasma and graphe

135 Through the combination of reaction kinetics (both catalytic and stoichiometric) an

136 Through the combination of reaction kinetics (both stoichiometric and catalytic), s

137 Removal of nitrite does not alter reaction kinetics, but modulates reaction products, with

138 that an aprotic organic solvent affects the reaction kinetics by changing the stabilization of the a

139 ss has been made toward analyzing more rapid reaction kinetics by ITC, the capabilities and limitatio

140 rbon surface, which synergistically promotes reaction kinetics by providing more exposed active sites

141 ynergistically combine to accelerate surface reaction kinetics by several orders of magnitude.

142 echanism of an enzymatic catalytic cycle and reaction kinetics can be engineered by modification of p

143 The reaction kinetics can be followed by monitoring the blea

144 whole statistical mechanical description of reaction kinetics can be re-formulated via a mechanical

145 The reaction kinetics consisted of a pre-steady-state burst

146 scan rate(1/2) (nu), indicative of electrode reaction kinetics controlled by mass transport (semi-inf

147 etic resolution, how chemical anisotropy and reaction kinetics coordinate to generate highly ordered

148 action, we demonstrated that its first-order reaction kinetics could be accurately determined from th

149 e, mutagenesis combined with single-turnover reaction kinetics demonstrate that point mutations in th

150 However, differences in the reaction kinetics demonstrate that the mechanism of Pu(V

151 Measured reaction kinetics demonstrates that the higher reaction

152 -ligand pair is determined by monitoring the reaction kinetics, demonstrating that silicon nanowire f

153 Reaction kinetics depend heavily on template length and

154 the diaurated intermediates with the overall reaction kinetics determined by NMR spectroscopy.

155 A novel DFT-based Reaction Kinetics (DFT-RK) simulation approach, employed

156 Reaction kinetics differ significantly between the K- an

157 networks: the continuous approach, based on reaction-kinetics differential equations, and the Boolea

158 ubstrate (C4b2) combined with more favorable reaction kinetics drive the formation of the C3 converta

159 copy is frequently used in the monitoring of reaction kinetics, due to its nondestructive nature and

160 ese volatiles was performed to compare their reaction kinetics during storage in differently sterilis

161 itory effect of hydrogen was observed on the reaction kinetics, effectively raising the apparent acti

162 We investigated NO reaction kinetics, effects on arterial NO signaling, and

163 main numerical model to effectively describe reaction kinetics either with distinctive apparent rate

164 Appropriate control of reaction kinetics enables the 2D morphology of the NPLs

165 nderstanding the synthesis mechanism and the reaction kinetics enables the rational, template-free sy

166 odel based on protonation-dependent chemical reaction kinetics established previously.

167 An analysis of the reaction kinetics established the kinetic competence of

168 The observed reaction kinetics exhibited a time lag prior to the rapi

169 nctional theory (DFT-GGA-PW91) calculations, reaction kinetics experiments on a SiO2-supported Pd cat

170 y of model parametrizations of heterogeneous reaction kinetics focus on the population average of aer

171 The reaction kinetics follow steady-state equilibrium behavi

172 Reaction kinetics for complex, highly interconnected kin

173 ty to develop quantitative approximations of reaction kinetics for fusion.

174 The ability to examine real-time reaction kinetics for multimeric enzymes in their native

175 the freeze-concentration effect in altering reaction kinetics for processes occurring in environment

176 Reaction kinetics for the conversion of 7-DHC into 7-DHP

177 The mechanism involves first-order reaction kinetics for the conversion of either the (C7-R

178 elaxation of the standard constraints on the reaction kinetics for the Turing instability, increasing

179 S setup, we describe how one can extract the reaction kinetics from diffusion-coupled correlation cur

180 ease of K(m) for cytochrome c and shifts the reaction kinetics from hyperbolic to sigmoidal such that

181 served, and indirect determinations of their reaction kinetics gave derived rate coefficients spannin

182 Controlling the reaction kinetics gives rise to enhanced separation effi

183 Mechanistic studies, involving reaction kinetics, Hammett analysis, kinetic isotope eff

184 hase solid-solution pathway with exceptional reaction kinetics has been predicted to increase with de

185 ycloheptene) have been investigated, and the reaction kinetics have been analyzed.

186 uct can be advantageous in terms of improved reaction kinetics, higher yields, and selectivity.

187 n CO concentration was observed in the rapid reaction kinetics, however, suggesting that CO initially

188 Reaction kinetics in a cell or cell membrane is modeled

189 mental confirmation to the theory describing reaction kinetics in a segregated flow system.

190 nce of facet capping, surface diffusion, and reaction kinetics in controlling the morphologies of bim

191 kinetics are more robust against changes in reaction kinetics in HCT-116 and HeLa than in DLD-1 cell

192 ons or molecular interpretation of localized reaction kinetics in stretched polymers may require expl

193 rgies to some key reaction intermediates and reaction kinetics in the HER process.

194 Cyclopropene exhibited fast reaction kinetics in the photoclick reaction and allowed

195 We propose the slowing of enzyme reaction kinetics in the smaller droplets was the result

196 itions, we have further characterized intein reaction kinetics in this system.

197 was developed with real time measurement of reactions kinetics in bulk reactors in mind, and was che

198 Its reaction kinetics indicate that it uses different mechan

199 stability in this regime, in which catalytic reaction kinetics interact with heat transfer and mechan

200 necessary to couple the physical chemistry, reaction kinetics, ion flow, heat generation, et cetera,

201 control through the synthesis conditions and reaction kinetics is an effective route to manipulate NC

202 The reaction kinetics is E1, first order in the haloalkylcar

203 modified to accommodate situations where the reaction kinetics is known to be more complicated than s

204 rofluidic approach for the quantification of reaction kinetics is presented.

205 Reaction kinetics is studied by elevating the temperatur

206 ically active phases, which is controlled by reaction kinetics, is different.

207 Evaluation of reaction kinetics, isotope effects, and commitment-to-ca

208 Reaction kinetics, isotope exchange, and mass spectrosco

209 reduced steric hindrance, Sph exhibited fast reaction kinetics (k2 up to 34,000 M(-1) s(-1)) in the p

210 xchange or alkene insertion, as supported by reaction kinetics, kinetic isotope effects, and isotopic

211 139.2 kJ/mol), these catalysts display rapid reaction kinetics, leading to relatively low polydispers

212 ermore, thermodynamic computations show that reaction kinetics likely played a significant role in ou

213 This suggests that reaction kinetics may be a limiting factor, especially s

214 Gas-phase reaction kinetics measurements in conjunction with first

215 Along with numerical simulation of a reaction kinetics model, the assay permits quantitative

216 We used a molecularly detailed reaction-kinetics model of the chemotaxis pathway in Esc

217 transformation pathways in combination with reaction kinetics models.

218 Enzyme-substrate reaction kinetics of AAO were described using Michaelis-

219 The reaction kinetics of apoA-I with DMPC LUVs was monitored

220 We measured reaction kinetics of calf intestinal alkaline phosphatas

221 The method is used to describe the reaction kinetics of certain HiPco SWNTs upon reaction w

222 The reaction kinetics of cyclohexene epoxidation using aqueo

223 nalytical description of the equilibrium and reaction kinetics of DNA multiplex hybridization has bee

224 In this study, the reaction kinetics of Fe(3+)-saturated montmorillonite ca

225 hodology we use is measuring a change in the reaction kinetics of ferro-ferricyanide redox couple at

226 Singlet oxygen ((1)O2) reaction kinetics of individual photooxidizable residues

227 A new method to investigate the reaction kinetics of intermediates in solution by electr

228 ution of cofactor binding to reactivity, the reaction kinetics of isolated, recombinant human HDACs 1

229 ics of SHIP1 phosphorylation were similar to reaction kinetics of other early signals and returned to

230 We used the assay to compare the reaction kinetics of preparations of sGC from a commerci

231 III) bioreduction, we investigated the redox reaction kinetics of reduced flavin mononucleotide (i.e.

232 arget sequence specificity, selectivity, and reaction kinetics of Streptococcus pyogenes Cas9 activit

233 The transient decay reaction kinetics of the 1,1,2,2-(2)H(4)-aminoethanol ge

234 The reaction kinetics of the copolymerization of carbon diox

235 of the gradient is achieved by measuring the reaction kinetics of the coupling agent with the surface

236 The reaction kinetics of the dimer dissociation in a Zeonex

237 The reaction kinetics of the E. coli KDO8P synthase was also

238 Here, we report production and reaction kinetics of the next larger Criegee intermediat

239 effective WNV inhibitors, we reexamined the reaction kinetics of the NS2B-NS3 protease and the inhib

240 ts from two apparent effects: (1) the faster reaction kinetics of the phosphorus precursor compared t

241 The temperature dependence of the reaction kinetics of the Rubisco enzyme implies that, at

242 . coli RNase P, we compared the steady state reaction kinetics of two ptRNAs that differ at sequences

243 The rapid reaction kinetics of wild-type xanthine dehydrogenase fr

244 d provide insight into the dependence of the reaction kinetics on Cl content in the products.

245 Herein we report detailed reaction kinetics on low-temperature standard NH3-SCR, s

246 Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologie

247 R measurements suitable for determination of reaction kinetics on time scales of 100 ms or longer hav

248 mbustion reaction and verifies that chemical reaction kinetics play a major role in determining the g

249 of experimental samples based upon their own reaction kinetics rather than those of artificial standa

250 ventually intended to study enzyme-catalyzed reaction kinetics related to free radical and oxidative

251 On-protein reaction kinetics reveal a rapid reaction with rate cons

252 The reaction kinetics reveal that Msh2-Msh6 binds a variety

253 Hammett analysis of the reaction kinetics revealed positive charge accumulation

254 on the Keggin surfaces, its influence on the reaction kinetics seems minimal as the carbon content di

255 Assessment of the reaction kinetics showed zero-order in both the aziridin

256 reactions, together with its practical side (reaction kinetics simulations of real experimental condi

257 Thus, the reaction kinetics slow by a factor of 25 when substituen

258 reveal that compressive stresses change the reaction kinetics so that preferential lithiation occurs

259 led level the observed chemistry in terms of reaction kinetics, structure, and reactivity, and thus f

260 e:isoalloxazine rings in TftC and sequential reaction kinetics suggest that the reduced FAD leaves Tf

261 y manipulating crystal shape and solid-state reaction kinetics suggests that photoreactive molecular

262 n but also accelerated the surface oxidation reaction kinetics, synergistically contributing to the i

263 ty with TcO4(-) and CrO4(2-) and much slower reaction kinetics than those measured in studies with bi

264 itions, the networks necessarily have cyclic reaction kinetics that are maintained by sustained const

265 rovide an additional channel to describe the reaction kinetics that lead to ECL; good agreement was f

266 s have finally allowed to implement in-vitro reaction kinetics (the so called enzyme based logic) whi

267 By carefully controlling the reaction kinetics, the newly formed Ag atoms could be di

268 To quantify the reaction kinetics, the products of the primer extension

269 To determine the reaction kinetics, the responses from the different dens

270 phosphine probe because, despite their slow reaction kinetics, they remain the best-performing reage

271 well-controlled conditions, thereby allowing reaction kinetics to be followed and Arrhenius activatio

272 es of preconcentration, mixing, and chemical reaction kinetics under ITP.

273 ze, neutral charge, long half-life, and fast reaction kinetics under physiologic conditions.

274 We report a method to control reaction kinetics using electrochemically responsive het

275 t absolute binding free energies and analyze reaction kinetics using Markov state models and Perron-c

276 ct of particle mixing state on heterogeneous reaction kinetics using the N2O5 reactive uptake coeffic

277 tal reconstitution experiments examining the reaction kinetics using Zn2+, Cd2+, Cu2+, Co2+, Mn2+, an

278 Real-time evaluation of the reaction kinetics was accomplished by monitoring change

279 flow microreactor a detailed analysis of the reaction kinetics was performed.

280 Both the EPR spectrum and the reaction kinetics were altered by the R product-inducing

281 Reaction kinetics were analyzed by selected reaction mon

282 s a function of time were quantified and the reaction kinetics were modeled using KinTekSim simulatio

283 Biexponential reaction kinetics were observed for all pressures, consi

284 e-turnover kinetic measurements, multiphasic reaction kinetics were observed for several uracil sites

285 Reaction kinetics were studied to quantify the effects o

286 irborne merged microdroplets to, e.g., study reaction kinetics when reaction times are short relative

287 9-promoted DNA annealing follows first-order reaction kinetics, whereas Rad52-promoted annealing foll

288 Our data enabled quantitative modeling of reaction kinetics, which revealed that dynamic competiti

289 of the metal oxide, follow Mars-van Krevelen reaction kinetics, which utilize lattice oxygen atoms to

290 ht mass spectrometer, which permits study of reaction kinetics with a time between reaction initiatio

291 cle simulation package combining off-lattice reaction kinetics with arbitrary particle interaction fo

292 al propagons by comparing the multiplication reaction kinetics with controlled seeding data.

293 and UV/H(2)O(2) exhibited pseudo-first-order reaction kinetics with half-lives ranging from 3.0 to 9.

294 The oxime ligation demonstrates tunable reaction kinetics with pH and buffer strength, which ind

295 let oxygen ((1)O2) and analyzed the oligomer reaction kinetics with reverse transcription quantitativ

296 ffusion and adsorption of the gas during its reaction kinetics with the sensitive film itself.

297 Hammett analysis of reaction kinetics with these substrates is consistent wi

298 en investigated using steady-state and rapid reaction kinetics, with pH, substrate and solvent deuter

299 tensive characterization of enzyme-inhibitor reaction kinetics within a single experiment by tracking

300 ysts was investigated using a combination of reaction kinetics, X-ray crystallography, NMR spectrosco