ライフサイエンスコーパス: reaction mechanism

1 ights and unexpected findings for the unique reaction mechanism.

2 deepen the understanding of the solid-state reaction mechanism.

3 perimental analysis of the H(2)O(2)-mediated reaction mechanism.

4 d through gas chromatography to validate the reaction mechanism.

5 cated the adsorption controlled irreversible reaction mechanism.

6 lecular mechanics (QM/MM) to investigate its reaction mechanism.

7 r docking simulations, unveiled the enzyme's reaction mechanism.

8 ion identity impacts multiple aspects of the reaction mechanism.

9 mediates were performed to shed light on the reaction mechanism.

10 ture-activity relationships and to propose a reaction mechanism.

11 experiments were conducted to postulate the reaction mechanism.

12 ,2-metalate shifts as a critical part of the reaction mechanism.

13 actions, there are only scant details of the reaction mechanism.

14 e nature of active sites for the ORR and the reaction mechanism.

15 is a complete description of the underlying reaction mechanism.

16 gnment and molecular-level insights into the reaction mechanism.

17 vides new insights into a potentially unique reaction mechanism.

18 taining peptide we could postulate a general reaction mechanism.

19 conducted to gain detailed insight into the reaction mechanism.

20 alculations shed light on the intermolecular reaction mechanism.

21 1 nm Ptmetal clusters but share an identical reaction mechanism.

22 tion through either the Friedel-Crafts or E2 reaction mechanism.

23 on rhodium(111), we identify the most likely reaction mechanism.

24 -mu-oxo-[Fe(IV)](2) unit) is involved in the reaction mechanism.

25 the aldehyde dehydrogenase lead to a revised reaction mechanism.

26 ectroscopy, which reveals key aspects of the reaction mechanism.

27 form of the oxidant plays a key role in the reaction mechanism.

28 amines plausibly via a ligand-free Heck-type reaction mechanism.

29 us providing crucial information about their reaction mechanism.

30 that laid the foundation for unraveling its reaction mechanism.

31 ore plausible than the alternative gas-phase reaction mechanism.

32 calculations were performed to elucidate the reaction mechanism.

33 er of electrons and protons in the reduction reaction mechanism.

34 sted to identify unambiguously the operative reaction mechanism.

35 providing insights on substrate binding and reaction mechanism.

36 ntermediate supports an interrupted Pummerer reaction mechanism.

37 rol reactions are conducted to establish the reaction mechanism.

38 ried out in them and produces changes in the reaction mechanism.

39 retical calculations performed for proposing reaction mechanisms.

40 e place directly on surfaces through unusual reaction mechanisms.

41 us interfacial charge-transfer phenomena and reaction mechanisms.

42 is still impeded by the lack of knowledge of reaction mechanisms.

43 ids to rationalize the underlying electronic reaction mechanisms.

44 de use in simulating heterogeneous catalytic reaction mechanisms.

45 of this method for time-resolved studies of reaction mechanisms.

46 gests the possibility of substrate-dependent reaction mechanisms.

47 ates, which facilitates the comprehension of reaction mechanisms.

48 e considered in the study of mechanochemical reaction mechanisms.

49 x proteins and enhance our knowledge of PCET reaction mechanisms.

50 magnetite provides further insight into its reaction mechanisms.

51 radical reactions, with a focus on the main reaction mechanisms.

52 s (EAOPs), due to the neglect of alternative reaction mechanisms.

53 e debate over the size-dependent microscopic reaction mechanisms.

54 homogeneous kinetics, radical lifetimes, and reaction mechanisms.

55 ineate the most likely reaction pathways and reaction mechanisms.

56 ds, which shed light on their reactivity and reaction mechanisms.

57 is is devoted to a detailed consideration of reaction mechanisms.

58 sibility of the hydrolytic and nonhydrolytic reaction mechanisms.

59 Studies of the reaction mechanism aimed at illuminating the singular ef

60 alysis of byproducts, we suggest a plausible reaction mechanism and a possible regeneration of the ch

61 sights into nature's choice of metal ion and reaction mechanism and allows for finer control of the e

62 al transformation of H2 and protons, yet the reaction mechanism and composition of intermediates are

63 We will further illustrate each reaction mechanism and describe characteristic substrate

64 ature of this synthetic protocol is that the reaction mechanism and formation of the products depend

65 oice of base has a significant effect on the reaction mechanism and its energetics.

66 The proposed reaction mechanism and key elementary reaction acts were

67 chanistic studies provided insights into the reaction mechanism and observed regioselectivity/diaster

68 Computational studies into the reaction mechanism and origins of enantioselectivity, in

69 fundamental understanding of the underlying reaction mechanism and parameters determining the CO(2)R

70 support a previously proposed in-line attack reaction mechanism and show a distinct variability of me

71 ive analysis of the FAO superfamily based on reaction mechanism and substrate recognition.

72 s are consistent with the proposed ping-pong reaction mechanism and suggest plausible routes by which

73 , we discuss the elucidation of this cascade reaction mechanism and the constraints for the byproduct

74 revents a straightforward elucidation of the reaction mechanism and the design of new and better cata

75 The elucidation of the reaction mechanism and the intermediate evolutionary pro

76 By studying the reaction mechanism and the intermediates formed, and in

77 thanks to our enhanced understanding of the reaction mechanism and the modes by which SBiz imidates

78 on an unknown glycal, provide insight on the reaction mechanism and the role of distant protecting gr

79 pread use of this synthesis method, both the reaction mechanism and the surface state of the obtained

80 rosslinked product provide insights into the reaction mechanism and underlying protein dynamics that

81 We observed two different reaction mechanisms and analyzed the role of the residue

82 l trajectory simulations reveals fundamental reaction mechanisms and facilitates an intimate understa

83 w to use in silico approaches to extract the reaction mechanisms and kinetic parameters for complex c

84 it is practical to extract from such RMD the reaction mechanisms and kinetics information needed to d

85 Factors such as different reaction mechanisms and masking of isotope fractionation

86 or chemical reactions for the elucidation of reaction mechanisms and measurement of kinetics.

87 Additionally, the cathodic reaction mechanisms and pathways of ECR are described al

88 ations and mixtures, identifying the various reaction mechanisms and products, and propose designs fo

89 Different reaction mechanisms and rates for Ag-O and Ag-S emerge.

90 hensive model was developed to elucidate the reaction mechanisms and simulate reaction kinetics of UV

91 Here, we investigated the reaction mechanisms and structures of tryptophan 6-halog

92 However, the reaction mechanisms and the origins of the selectivity a

93 licit solvent model, confirming the proposed reaction mechanisms and the role of kinetic controls in

94 xplicit solvent model confirmed the proposed reaction mechanisms and the role of kinetic controls on

95 ions were performed to confirm the suggested reaction mechanisms and to elucidate the origin of the e

96 reactions is important to better understand reaction mechanisms and to separate the influence of pH

97 The reaction mechanism, and the peculiar contribution of the

98 f the I fluorescent state, the time-resolved reaction mechanism, and the role of the counterion clust

99 he resulting conclusions about organolithium reaction mechanisms, and (3) perspectives on the concept

100 xidation processes tend to have very complex reaction mechanisms, and models containing over 150 step

101 However, due to their complex reaction mechanisms, and often, their poor optical signa

102 lculations revealed intricate details of the reaction mechanisms, and strong synergies between ESI-MS

103 the accessibility of specific active sites, reaction mechanisms, and the selectivity of desirable pr

104 taining to catalysis, stereoselectivity, and reaction mechanism are discussed.

105 All steps of the KOA reaction mechanism are studied, for the first time, in d

106 ogy, activity and stability improvement, and reaction mechanisms are discussed in detail.

107 The reaction mechanisms are elucidated by identifying the ex

108 uggests that separate concerted and stepwise reaction mechanisms are operating, depending upon the mi

109 The reaction mechanisms are reviewed based on CO2 capture li

110 These fundamental reaction mechanisms are valuable to facilitate an unders

111 Our results clarify the reaction mechanism at high potentials in conventional la

112 Here we investigate the reaction mechanism behind CdSe QD synthesis, the most wi

113 etals, implying a possible difference in the reaction mechanism between transition-metal dichalcogeni

114 only provides insights into the cooperative reaction mechanism but also aids the design of oxidation

115 -metal-catalyzed reactions with well-defined reaction mechanisms but multiple stereocontrolling trans

116 Here, we report a surface reaction mechanism by computational modeling and simulat

117 The WGS reaction mechanism by the CuCrFeO (x) catalyst has been

118 d confirm an inverting mannosyl-transferring reaction mechanism by the enzyme complex.

119 The reaction mechanism by which the shelterin protein POT1 (

120 ons that predict novel, energetically viable reaction mechanisms by which Al-O and Si-O bonds rapidly

121 s brought into question many of the proposed reaction mechanisms by which these multicarbon alcohols

122 The reaction mechanisms by which these processes take place

123 normally transient intermediate of the TOP2 reaction mechanism called the TOP2-DNA covalent complex.

124 half-lives, as intrinsic differences in the reaction mechanism can amplify the importance of seconda

125 conclude that enzymes with distinct primary reaction mechanisms can form a completely separate netwo

126 proteasome and HslV, a classical proteasomal reaction mechanism could be inferred from the covalent b

127 To obtain a closer insight into the reaction mechanism, cyclic voltammetry was performed.

128 f individual PCE-RdhAs rather than different reaction mechanisms determine the extent of PCE isotope

129 deally suited to, e.g., elucidating chemical reaction mechanisms, determining the distribution of com

130 y, we highlight research needs in clarifying reaction mechanisms, developing analytical methods for b

131 e and electrolyte has been observed to alter reaction mechanisms differently, resulting in a diverse

132 We visualize this previously hypothetical reaction mechanism, directly observing formation of a th

133 y and decisive information to understand the reaction mechanism during such reactions in batch photor

134 PSs leading to a distinct carbocation-driven reaction mechanism en route to the 5,7-trans-fused bicyc

135 thermore, we gather unique insights into the reaction mechanism, enabled by a specifically designed c

136 To obtain a reliable description of the reaction mechanisms, energy profiles of the entire catal

137 ydrogenation of propane (ODHP) reaction, the reaction mechanisms, especially regarding radical chemis

138 thway E1) was found to be the most plausible reaction mechanism, exhibiting an overall activation ene

139 A reaction mechanism explaining these results is proposed,

140 Results reveal that the reaction mechanism follows general base (in contrast to

141 center of C1 and an intricate intramolecular reaction mechanism for activation of C1r and C1s, induce

142 h triethylamine and pyridine to validate the reaction mechanism for different amine catalysts.

143 2.4 +/- 0.1 to 3.6 +/- 0.1) suggest a common reaction mechanism for different PCE-RdhAs.

144 al theory calculations determined a probable reaction mechanism for NDMA reduction, where the rate-li

145 We have identified the most likely reaction mechanism for oxidizing heptafulvenes to the co

146 e-reflectance infrared spectra, we propose a reaction mechanism for photoreduction of CO(2) via Bi-ba

147 ontrolled experiments, we propose a possible reaction mechanism for the case in which N-hydroxyphthal

148 Investigation of the reaction mechanism for the CPA-controlled glycosylations

149 ional theory (DFT) calculations illustrate a reaction mechanism for the formation of 2-propanol, prop

150 rearrangement which occurs through a unique reaction mechanism for the installation of the C17 amino

151 he basis of control experiments, a plausible reaction mechanism for the selective formation of 3-aryl

152 A new reaction mechanism for this thioesterification is propos

153 We show that the photochemical reaction mechanisms for alpha-keto acids in aqueous solu

154 nderstanding of the subtle variations in the reaction mechanisms for C-H functionalization reactions

155 ith both insertion/extraction and conversion reaction mechanisms for lithium storage.

156 and it provides mechanistic insight into the reaction mechanisms for the development of an elementary

157 alculations that evaluate the energetics and reaction mechanisms for the dimerizations of two differe

158 The reaction mechanisms for the heavy alkali metals were inv

159 ey flavonol compound degraded by competitive reactions mechanism forming such kinetic branches, which

160 A redox reaction mechanism has also been established, where Cu i

161 t substrates (alkynes versus allenes) on the reaction mechanism has been discussed in detail.

162 d on these results, greater insight into the reaction mechanism has been gained.

163 The reaction mechanism has been investigated through control

164 read use in the pharmaceutical industry, the reaction mechanism has not been determined.

165 ligand classes, as well as studies of their reaction mechanisms, has resulted in dynamic progress in

166 Plausible cationic reaction mechanisms have been discussed.

167 e literature of the last 40 years, and their reaction mechanisms have been emphatically discussed.

168 ement of both polar and radical steps in the reaction mechanisms have been implicated.

169 demonstrate significant variations in their reaction mechanisms, highlighting both the extraordinary

170 An electrolyte-dependent reaction mechanism in delta-MnO(2) is identified.

171 lso be utilized as a diagnostic tool for the reaction mechanism in differentiating between single and

172 ugh a fundamental understanding of the redox reaction mechanism in Li2 MnO3 , Na(Li1/3 Mn2/3 )O2 is d

173 of selective species and reveal its internal reaction mechanism in the carbonate electrolyte.

174 antum dynamics frameworks to investigate the reaction mechanism in the diterpene synthase CotB2, comm

175 , two molecules of TosMIC participate in the reaction mechanism in two different ways, with the secon

176 We propose a reaction mechanism in which His-257 acts as a general ba

177 rroborate the "loose-bolt" postulate for the reaction mechanism in Wulff-type boronic acids.

178 compelling illustration of generality across reaction mechanisms in asymmetric catalysis.

179 to systematically analyze the corresponding reaction mechanisms in details.

180 ovide a unique opportunity to directly study reaction mechanisms in heterogeneous catalysts, a proble

181 erature various intercalation and conversion reaction mechanisms in MnO(2) have been reported, but it

182 An in-depth understanding of the reaction mechanisms in play is essential to being able t

183 he potential to provide unique insights into reaction mechanisms in the liquid phase that involve cha

184 is mechanism is in contrast to the gas-phase reaction mechanisms in which the organic acid either ser

185 The reaction mechanism includes a rare azaphilic [4 + 2]-cyc

186 and oxygenates is to determine the detailed reaction mechanism including kinetics and product select

187 The reaction mechanism including the ortho C-H bond activati

188 is still a lack in understanding of how the reaction mechanism influences the macromolecular structu

189 efly described, with special emphasis on the reaction mechanisms involved.

190 rimental and computational studies support a reaction mechanism involving a crucial E-to-Z vinyl-Pd i

191 A possible reaction mechanism involving a pai-allyl iridium interme

192 The enzyme has an unusual cooperative reaction mechanism involving an active site that spans t

193 ction products were elucidated and support a reaction mechanism involving cycloaddition followed by a

194 Only the reaction mechanism involving DMSO as a nucleophilic reac

195 rn in trans double bonds, we have proposed a reaction mechanism involving excitation of the double bo

196 quasi Mars-van Krevelen (quasi-MvK) surface reaction mechanism involving extracting and refilling th

197 ons and experimental observations revealed a reaction mechanism involving the reversible formation an

198 Experimental insights implicate a reaction mechanism involving the selective protonation o

199 The key step in the reaction mechanism is a 1,3-chlorine shift to a cationic

200 abundance, indicating that the biosynthetic reaction mechanism is cobalamin dependent.

201 The feasibility of this reaction mechanism is confirmed from DFT calculations, a

202 The proposed new reaction mechanism is corroborated by the experimental r

203 he effect of acceptor nucleophilicity on the reaction mechanism is described and steric, conformation

204 The possible reaction mechanism is discussed.

205 rongly enhances the selectivity and that the reaction mechanism is fundamentally different for nanopa

206 On the basis of this agreement, a possible reaction mechanism is presented.

207 egraded the studied antibiotics and that the reaction mechanism is principally related to attack by h

208 A possible reaction mechanism is proposed and strongly supported by

209 A reaction mechanism is proposed and used to rationalize h

210 hydrogen evolution reaction, an alternative reaction mechanism is proposed for nanomaterials based o

211 trile were identified as main products and a reaction mechanism is proposed.

212 ery in catalysis, but the proposed gas-phase reaction mechanism is still open to discussion.

213 A Lederer-Manasse type reaction mechanism is suggested, with dehydration of the

214 The reaction mechanism is unveiled by comprehensive spectros

215 structural evolution, electrochemical redox, reaction mechanism, kinetics, and degradation.

216 Reaction mechanisms leading both to methane and methanol

217 nvolving subsurface hydrogen are the primary reaction mechanisms leading to methanol.

218 Nevertheless, the basic reaction mechanisms leading to the formation of even the

219 To elucidate the reaction mechanism, [{LSi(N(SiMe(3))(2))}{(eta(4)-P(5))F

220 ine the similarities and differences between reaction mechanisms mediated by modified biocatalysts an

221 Due to the nature of the branched reaction mechanism, monoterpene synthases often produce

222 To provide the basis for the reaction mechanism, novel forms of these cations were is

223 Recently, the reaction mechanism occurring in these materials was char

224 understanding of the reversible ring-opening reaction mechanism of 1,3-benzoxazine with thiols.

225 In this study, we investigated the reaction mechanism of 6:2 fluorotelomer sulfonate (6:2 F

226 s the first study that describes the use and reaction mechanism of aforementioned modifiers for enhan

227 s simulations allow elucidating the dominant reaction mechanism of an intermediate hydrogen-bonded co

228 Reaction mechanism of apiosidase from Aspergillus aculea

229 The reaction mechanism of indenone formation proceeds first

230 Herein, the reaction mechanism of methanol decomposition over Pt(1)/

231 d in turn facilitate investigations into the reaction mechanism of nitrogenases.

232 desulpho (ds)-Gl SOTs and to understand the reaction mechanism of plant SOTs, we determined the firs

233 calculated potential energy surface shows a reaction mechanism of six steps controlled by enthalpy (

234 battery platform for unraveling the complex reaction mechanism of sulfur chemistries and for explori

235 Furthermore, a possible reaction mechanism of the Sn4P3/C composite as PIB anode

236 To clarify the reaction mechanism of this critical reaction, we decided

237 conjunction with our earlier studies on the reaction mechanism of this enzyme and on the basis of th

238 ined to monitor the kinetics and unravel the reaction mechanism of this industrially relevant reactio

239 ary organic aerosols (SOA), the kinetics and reaction mechanisms of superoxide (O(2)(*-)) formation a

240 By exploring these reaction mechanisms of the phenyl radical with biphenyl/

241 ese reagents, very little is known about the reaction mechanisms of their syntheses, which has hamper

242 s published to date, while the difference in reaction mechanisms offers a potential answer to the lon

243 The reaction mechanism on nanoparticles is complex and invol

244 A unified low-temperature reaction mechanism on the formation of acenes, phenacene

245 n the present study finally resolves the WGS reaction mechanism on the industrial-type high-temperatu

246 new insights towards understanding the ODHP reaction mechanisms over boron-based catalysts.

247 ons from naphthalene and anthracene indicate reaction mechanism pathways that use oxidized alcohol an

248 lectronic structure methods for studying the reaction mechanisms promoted by 3d transition metal mole

249 DFT studies indicate a light-initiated chain reaction mechanism propagated by (.) Mn(CO)5 .

250 The reaction mechanism proposed in that work contained some

251 A DFT study of the reaction mechanism provides a rationale for the observed

252 Further, insight into the reaction mechanism provides an unprecedented observation

253 ing to the NMR and DFT investigations of the reaction mechanism, pyrroles and dihydropyrazines are fo

254 ites, nature of the active sites during MDA, reaction mechanisms, rate-determining step, kinetics and

255 The reaction mechanism, reaction intermediates, and final de

256 avoid this nonspecific reaction in MGL, the reaction mechanism remains unknown.

257 the lack of fundamental understanding of the reaction mechanism renders designing a selective catalys

258 Overall, the reaction mechanism resembles a Hock-like rearrangement.

259 t also as a crucial component in the overall reaction mechanism responsible for averting the formatio

260 Computational investigations of the reaction mechanism reveal an unexpected, concerted SNAr

261 Computational modeling of the reaction mechanism reveals a principal role of the rever

262 rous NDMA precursors, essential parts of the reaction mechanism such as the incorporation of molecula

263 mputational investigation of the cyclization reaction mechanism suggests facile C-N bond formation in

264 than the oxidized form, from which we derive reaction mechanisms supported by density functional theo

265 The reaction mechanism, supported by DFT calculations, invol

266 A representative, low-temperature gas-phase reaction mechanism synthesizing polyacenes via ring annu

267 ylation selectivity in SyrB2 is related to a reaction mechanism that involves two asynchronous transf

268 e observe that haematite is able to access a reaction mechanism that is third order in surface-hole d

269 labeling study clearly reveals that, in the reaction mechanism, the initial C-H activation step via

270 Despite showing the same major reaction mechanism, the three main CA families are evolu

271 This work has led to the discovery of reaction mechanisms, the invention of new methods, and t

272 Critical information on metal-dependent reaction mechanisms, the key intermediates, the dynamics

273 Different from conventional battery reaction mechanisms, this battery revolutionarily synchr

274 report a comprehensive study describing the reaction mechanism through kinetic studies, isotope-labe

275 Our investigations on the reaction mechanism to account for regioselectivity on th

276 Assigning a defined reaction mechanism to affinity binding interactions is c

277 A plausible reaction mechanism to explain the formation of this prod

278 ach based on the recently developed complete reaction mechanism to identify non-transition-metal (NTM

279 ngth of XPEEM to solve challenging interface reaction mechanisms via post mortem measurements.

280 The amination cyclization reaction mechanism was examined employing nuclear magnet

281 ve quantum mechanical simulation, a coherent reaction mechanism was identified matching the experimen

282 The reaction mechanism was investigated experimentally by de

283 The reaction mechanism was investigated to understand the va

284 The reaction mechanism was investigated using tandem mass sp

285 In the case of the t-Bu derivative, the reaction mechanism was probed using stoichiometric react

286 A possible reaction mechanism was proposed and supported by deuteri

287 The reaction mechanism was proposed for gallic acid degradat

288 A possible reaction mechanism was proposed from the experimental ou

289 Even though the general reaction mechanism was thoroughly investigated, studies

290 To study the reaction mechanism, we have synthesized and characterize

291 To obtain molecular insights into reaction mechanisms, we determined crystal structures of

292 Some of the proposed reaction mechanisms were tested by examining additional

293 The underlying reaction mechanisms were unravelled through the combinat

294 suggests the possibility of a nonhydrolytic reaction mechanism when the catalytic base aspartic acid

295 nts were carried out to get insight into the reaction mechanism which shows that the nickel and the c

296 Here we report an original Eley-Rideal reaction mechanism, which permits direct O2 formation in

297 servations have unveiled key elements of the reaction mechanism, which proceeds along nucleofilaments

298 Reaction mechanisms, which were analyzed with the help o

299 etailed quantum chemical calculations of the reaction mechanism with different computational setups s

300 They are essential to understanding reaction mechanisms, yet many of their properties remain