ライフサイエンスコーパス: reaction mechanism

1 vides new insights into a potentially unique reaction mechanism.

2 ion intermediates and to shed light into the reaction mechanism.

3 of its unique, catalytic tyrosine-dependent reaction mechanism.

4 (d,p) level were employed to investigate the reaction mechanism.

5 taining peptide we could postulate a general reaction mechanism.

6 n of the substrate scope, and a study of the reaction mechanism.

7 investigation was performed to elucidate the reaction mechanism.

8 boronate amines, are proposed as a plausible reaction mechanism.

9 conducted to gain detailed insight into the reaction mechanism.

10 imetry supports a key role of Lys-232 in the reaction mechanism.

11 studies have been performed to elucidate the reaction mechanism.

12 o-metal charge transfer (LMCT) via a complex reaction mechanism.

13 ing the influence of different thiols on the reaction mechanism.

14 DFT calculations provide insight into the reaction mechanism.

15 crucial importance to correctly unravel the reaction mechanism.

16 sive for the nature of an observed enzymatic reaction mechanism.

17 the first irreversible chemical step in the reaction mechanism.

18 s offer valuable facts for understanding the reaction mechanism.

19 on catalyst activation and shed light on the reaction mechanism.

20 n the solid state provide information on the reaction mechanism.

21 ation of the catalyst, its performances, and reaction mechanism.

22 gy and provides invaluable insights into the reaction mechanism.

23 s well studied in terms of its structure and reaction mechanism.

24 are useful for defining features of the ADAR reaction mechanism.

25 ng group, providing further insight into the reaction mechanism.

26 ngle domain with a metal dependent retaining reaction mechanism.

27 etal sulfides and provide insight into their reaction mechanism.

28 for the required inline hammerhead ribozyme reaction mechanism.

29 o address the various stages involved in the reaction mechanism.

30 re, little is known about the details of the reaction mechanism.

31 nce is highly consistent with the identified reaction mechanism.

32 M function, and allow us to propose a likely reaction mechanism.

33 1/Trp160/His251 and their involvement in the reaction mechanism.

34 omputational approaches to establish a novel reaction mechanism.

35 he origin of key product atoms and propose a reaction mechanism.

36 1 nm Ptmetal clusters but share an identical reaction mechanism.

37 tion through either the Friedel-Crafts or E2 reaction mechanism.

38 on rhodium(111), we identify the most likely reaction mechanism.

39 the aldehyde dehydrogenase lead to a revised reaction mechanism.

40 ectroscopy, which reveals key aspects of the reaction mechanism.

41 form of the oxidant plays a key role in the reaction mechanism.

42 amines plausibly via a ligand-free Heck-type reaction mechanism.

43 the system leads to a new description of the reaction mechanism.

44 and computational studies shed light on the reaction mechanism.

45 nd provides insight into its metal-dependent reaction mechanism.

46 mediates or contribute to the elucidation of reaction mechanisms.

47 action and Cl-adduct formation are the major reaction mechanisms.

48 generation and authenticating the implicated reaction mechanisms.

49 nvolved in their biosynthesis, or to similar reaction mechanisms.

50 studied to various degrees in terms of their reaction mechanisms.

51 and will be a valuable tool for the study of reaction mechanisms.

52 radical, in contrast to previously proposed reaction mechanisms.

53 s (EAOPs), due to the neglect of alternative reaction mechanisms.

54 physicochemical effects while investigating reaction mechanisms.

55 rimary tool for describing and rationalizing reaction mechanisms.

56 bles able to track a wide range of different reaction mechanisms.

57 ein fold, but employ fundamentally different reaction mechanisms.

58 e debate over the size-dependent microscopic reaction mechanisms.

59 homogeneous kinetics, radical lifetimes, and reaction mechanisms.

60 ions is fundamental for the understanding of reaction mechanisms.

61 rylketones takes place through two competing reaction mechanisms-a 5-exo-dig or a 6-endo-dig cyclizat

62 alkali-ion batteries owing to their distinct reaction mechanism, abundant active sites and shortened

63 confirms product formation by an Eley-Rideal reaction mechanism and accounts for inelastic energy los

64 sights into nature's choice of metal ion and reaction mechanism and allows for finer control of the e

65 aillard reaction by a reversible bimolecular reaction mechanism and also to evaluate the compatibilit

66 ; however, many questions remain about their reaction mechanism and biological function.

67 riments allowed us to get insights about the reaction mechanism and characterize CB[5], CB[6], CB[7],

68 al transformation of H2 and protons, yet the reaction mechanism and composition of intermediates are

69 Yeast and human Top1 share a common reaction mechanism and domain structure.

70 The reaction mechanism and driving forces behind noncovalent

71 rovide a great opportunity to understand the reaction mechanism and fabricate a better catalyst.

72 structure has a significant influence on the reaction mechanism and has important implications for th

73 which support the experimentally determined reaction mechanism and provide cohesive mechanistic insi

74 The reaction mechanism and regioselectivity were then system

75 hieve this, leading to key insights both for reaction mechanism and strategies to enhance function.

76 r lithium-ion batteries categorized by their reaction mechanism and structural dimensionality.

77 metalloproteins, but also shed light on the reaction mechanism and structural features responsible f

78 s are consistent with the proposed ping-pong reaction mechanism and suggest plausible routes by which

79 revents a straightforward elucidation of the reaction mechanism and the design of new and better cata

80 The cyclization reaction mechanism and the enantiomeric composition of t

81 thanks to our enhanced understanding of the reaction mechanism and the modes by which SBiz imidates

82 DFT calculations provide insights into the reaction mechanism and the rationale for this unusual ch

83 pread use of this synthesis method, both the reaction mechanism and the surface state of the obtained

84 mass spectrometry (ESI-TOF-MS) to derive the reaction mechanism and to obtain the stoichiometry facto

85 al studies have begun to reveal the detailed reaction mechanisms and kinetics for gas-phase O3, NO3,

86 otocatalysts and surrounding solvent dictate reaction mechanisms and pathways, but are not readily ac

87 f metal oxides and identify common themes in reaction mechanisms and research strategies for catalyst

88 We review reaction mechanisms and the role of the corrinoid and Fe

89 erstanding of the radical-induced elementary reaction mechanisms and their reaction-rate constants.

90 d to understand biodegradation processes and reaction mechanisms and to assess the efficiency of trea

91 ions were performed to confirm the suggested reaction mechanisms and to elucidate the origin of the e

92 In order to assess the underlying reaction mechanisms and to obtain stoichiometry factors

93 s an unexpected electrochemical mass storage reaction mechanism, and may provide a strategy for the d

94 he resulting conclusions about organolithium reaction mechanisms, and (3) perspectives on the concept

95 results of quantum mechanical studies of the reaction mechanism are also discussed.

96 e nature of the active site and the possible reaction mechanism are discussed.

97 potential of the nitro group and a putative reaction mechanism are discussed.

98 Computational analyses of the reaction mechanism are reported.

99 e a clear understanding of each subcategory, reaction mechanisms are discussed.

100 cribed for the reaction in solution, but the reaction mechanisms are noticeably different.

101 Various reaction mechanisms are possible for the carbon-carbon b

102 The reaction mechanisms are reviewed based on CO2 capture li

103 The reaction mechanisms are supported by density functional

104 -dimensional NMR spectroscopy to interrogate reaction mechanisms as they occur.

105 heimer molecular dynamics simulations of the reaction mechanisms associated with hydrogen-assisted CO

106 In a solid electrolyte, neither the reaction mechanism at the cathode nor the nature of the

107 ry depend on a complex interplay between the reaction mechanism at the cathode, the chemical structur

108 lipid-derived reactive carbonyl but not the reaction mechanism because the Ea of formation of both 2

109 Here we investigate the reaction mechanism behind CdSe QD synthesis, the most wi

110 etals, implying a possible difference in the reaction mechanism between transition-metal dichalcogeni

111 -metal-catalyzed reactions with well-defined reaction mechanisms but multiple stereocontrolling trans

112 The solvent plays a key role in the reaction mechanism by protonating the polyoxometalate th

113 Contrary to a previous proposal for the reaction mechanism, C-methylation is the preferred pathw

114 spectroscopy (IR) data, the electrochemical reaction mechanism can be explained by the reversible tr

115 Knowledge of chemical reaction mechanisms can facilitate catalyst optimization

116 nt structural insight into the adenylylation reaction mechanism catalyzed by Fic domains.

117 er, the origin of this effect is a change of reaction mechanism compared the uncatalyzed reaction.

118 A plausible reaction mechanism comprising the bidentate ligand-aided

119 proteasome and HslV, a classical proteasomal reaction mechanism could be inferred from the covalent b

120 deally suited to, e.g., elucidating chemical reaction mechanisms, determining the distribution of com

121 y, we highlight research needs in clarifying reaction mechanisms, developing analytical methods for b

122 The reaction mechanism, due to the HMDS symmetrical structur

123 y and decisive information to understand the reaction mechanism during such reactions in batch photor

124 additives with a chemical conversion as the reaction mechanism, e.g., CuS and FeS2, can increase the

125 PSs leading to a distinct carbocation-driven reaction mechanism en route to the 5,7-trans-fused bicyc

126 Met) radical chemistry; the remainder of the reaction mechanism, especially the source of the sulfur,

127 molecular interactions, property trends, and reaction mechanisms, etc.

128 Results reveal that the reaction mechanism follows general base (in contrast to

129 center of C1 and an intricate intramolecular reaction mechanism for activation of C1r and C1s, induce

130 investigate the effects of sugar type on the reaction mechanism for formation of acrylamide and 5-hyd

131 The data are consistent with a common reaction mechanism for indoleamine 2,3-dioxygenase-catal

132 ld and experimental systems suggest a common reaction mechanism for nucleating the mineral.

133 ular dynamics simulations, a novel catalytic reaction mechanism for plant PPOs is proposed.

134 Investigation of the reaction mechanism for the CPA-controlled glycosylations

135 A chemical reaction mechanism for the decarboxylation of 5-carboxyv

136 The isolation of 2 and 3 confirmed the reaction mechanism for the formation of 1.

137 rearrangement which occurs through a unique reaction mechanism for the installation of the C17 amino

138 A reaction mechanism for the reversible decarboxylation in

139 he basis of control experiments, a plausible reaction mechanism for the selective formation of 3-aryl

140 A new reaction mechanism for this thioesterification is propos

141 ions about the enzyme and propose a possible reaction mechanism for TsdA.

142 We show that the photochemical reaction mechanisms for alpha-keto acids in aqueous solu

143 Early-stage reaction mechanisms for aragonite-promoting systems are

144 nderstanding of the subtle variations in the reaction mechanisms for C-H functionalization reactions

145 ith both insertion/extraction and conversion reaction mechanisms for lithium storage.

146 and it provides mechanistic insight into the reaction mechanisms for the development of an elementary

147 alculations that evaluate the energetics and reaction mechanisms for the dimerizations of two differe

148 utational techniques to identify low-barrier reaction mechanisms for the formation of large furans an

149 By simulating different reaction mechanisms, from simple EC' catalysis to more s

150 A redox reaction mechanism has also been established, where Cu i

151 A possible reaction mechanism has also been proposed.

152 t substrates (alkynes versus allenes) on the reaction mechanism has been discussed in detail.

153 The reaction mechanism has been elucidated with the help of

154 ntified in Streptococcus thermophilus, and a reaction mechanism has been proposed.

155 read use in the pharmaceutical industry, the reaction mechanism has not been determined.

156 ement of both polar and radical steps in the reaction mechanisms have been implicated.

157 The originally proposed reaction mechanism (Houk) involves a highly peri-, regio

158 We unveil the reaction mechanism in a low-temperature scanning tunneli

159 ugh a fundamental understanding of the redox reaction mechanism in Li2 MnO3 , Na(Li1/3 Mn2/3 )O2 is d

160 recombination-activating gene (RAG) complex reaction mechanism in real time.

161 The structures provide key evidence for the reaction mechanism in the stereospecific addition for th

162 electivity, and for the determination of the reaction mechanism in the two situations.

163 Our results are consistent with a reaction mechanism in which a catalyst molecule simultan

164 xperimental and computational data support a reaction mechanism in which cis,syndio-selectivity is a

165 ified that are responsible for the different reaction mechanisms in CH-FkbO and CH-Hyg5.

166 a quantum computer can be used to elucidate reaction mechanisms in complex chemical systems, using t

167 Mitigation strategies based on the reaction mechanisms in each unit of the CO2 capture syst

168 ovide a unique opportunity to directly study reaction mechanisms in heterogeneous catalysts, a proble

169 how quantum chemistry can directly establish reaction mechanisms in intuitive terms and unprecedented

170 The variety of different reaction mechanisms in lanthanide chemistry appear to be

171 and oxygenates is to determine the detailed reaction mechanism including kinetics and product select

172 e obtained mutants allow the study of VKORc1 reaction mechanisms, inhibition by warfarin, and the hig

173 reviously and provides some insight into the reaction mechanism involved in PTR.

174 The proposed reaction mechanism involves a borinylium radical 1(*+) w

175 The results suggest that the most favorable reaction mechanism involves formation of a gem-diol inte

176 rimental and computational studies support a reaction mechanism involving a crucial E-to-Z vinyl-Pd i

177 A bimolecular reaction mechanism involving a Mn(IV)-hydroxo based inte

178 A reaction mechanism involving a palladium hydride, genera

179 cture of the molybdenum center, we propose a reaction mechanism involving direct hydride transfer fro

180 rn in trans double bonds, we have proposed a reaction mechanism involving excitation of the double bo

181 mputational modeling are consistent with the reaction mechanism involving rate-limiting formation of

182 we offer evidence in favor of an alternative reaction mechanism involving the acid-catalyzed reaction

183 Reaction mechanisms involving the evolution of the prima

184 In this case, two different reaction mechanisms, involving either the scenario with

185 These exotic chemical reaction mechanisms, involving roaming H2 molecules, are

186 This reaction mechanism is a consequence of relativistic effe

187 A plausible reaction mechanism is also proposed.

188 The proposed reaction mechanism is characterized by a rate-determinin

189 The feasibility of this reaction mechanism is confirmed from DFT calculations, a

190 The possible reaction mechanism is discussed.

191 Evidence concerning the reaction mechanism is obtained taking into account the s

192 demonstrates that the liquid-solid two-phase reaction mechanism is promising in addressing the kineti

193 A reaction mechanism is proposed in which (a) C-C and C-O

194 A reaction mechanism is proposed to explain the variety of

195 A reaction mechanism is proposed, in which combined kineti

196 trile were identified as main products and a reaction mechanism is proposed.

197 bsence of spin-orbit coupling, the predicted reaction mechanism is qualitatively different.

198 Most of our current understanding of reaction mechanisms is based on hand specimen and labora

199 is understood about the underlying chemical reaction mechanism leading to monomer formation and subs

200 Reaction mechanisms leading both to methane and methanol

201 nvolving subsurface hydrogen are the primary reaction mechanisms leading to methanol.

202 Nevertheless, the basic reaction mechanisms leading to the formation of even the

203 Their enzyme-based reaction mechanisms may be genetically tailored for envi

204 These structures support a reaction mechanism model with at least four states and i

205 rtance of energy landscapes to understanding reaction mechanisms, most experiments do not directly me

206 Armed with an understanding of the reaction mechanisms, much of the known chemistry within

207 understanding of the reversible ring-opening reaction mechanism of 1,3-benzoxazine with thiols.

208 The data support the proposed four-step reaction mechanism of ACDs, coupling acyl-CoA thioesters

209 s the first study that describes the use and reaction mechanism of aforementioned modifiers for enhan

210 the hydrogen bond provided by Asn-169 to the reaction mechanism of AMSDH, we created Ala, Ser, Asp, a

211 vided significant insight into the enzymatic reaction mechanism of AvLOx and presented a novel approa

212 pattern can be used to deduce aspects of the reaction mechanism of enzymes still to be identified.

213 The reaction mechanism of etherification of beta-citronellen

214 kinetic model was constructed and reveals a reaction mechanism of four elementary steps: (i) formati

215 We have investigated the reaction mechanism of glycosylation of a donor modified

216 sed on the crystal structures, the enzymatic reaction mechanism of IMPases is accustomed to fit the d

217 teine persulfide enzyme adducts, whereas the reaction mechanism of Ncs6 remains unknown.

218 potentials to examine the detailed atomistic reaction mechanism of OER at the IrO2 (110) surface.

219 enesis data provide useful insights into the reaction mechanism of OsDHAR against ROS-induced oxidati

220 desulpho (ds)-Gl SOTs and to understand the reaction mechanism of plant SOTs, we determined the firs

221 The reaction mechanism of protocatechuate 3,4-dioxygenase is

222 , 6, or 8)] were designed to probe the "ene" reaction mechanism of singlet oxygen at the air-water in

223 The reaction mechanism of solid-acid-catalyzed phenol alkyla

224 d in vivo approaches, we identify a role and reaction mechanism of the reductase sulfiredoxin (Srxn1)

225 Furthermore, a possible reaction mechanism of the Sn4P3/C composite as PIB anode

226 present a molecular-level description of the reaction mechanism of the spirotetronate cyclase AbyU, a

227 conjunction with our earlier studies on the reaction mechanism of this enzyme and on the basis of th

228 ing atomistic mechanistic insights about the reaction mechanism of tryptophan 7-halogenase is vital a

229 y screening reaction conditions and studying reaction mechanisms of biphasic nanocrystal ligand-excha

230 d the reactivity of oxygenated radicals, the reaction mechanisms of chlorine-derived radicals have no

231 ce spectroscopy to investigate the molecular reaction mechanisms of Galphai1.

232 To evaluate the reaction mechanisms of these different reduction routes

233 ions explain well the selectivity tuning and reaction mechanism on STO with different surface termina

234 ention of this work is to (i) understand the reaction mechanisms on the microscopic level and (ii) co

235 can be trapped at low temperatures the same reaction mechanism operates in both POR A and POR B.

236 ow-temperature ethanol steam reforming (ESR) reaction mechanism over a supported Rh/Pt catalyst has b

237 DFT analysis of the reaction mechanism pointed to the importance of both rep

238 ns in the molecule are implicated in a given reaction mechanism, position-specific fractionation occu

239 ints to a Langmuir-Hinshelwood surface-based reaction mechanism possibly involving semiquinone radica

240 DFT studies indicate a light-initiated chain reaction mechanism propagated by (.) Mn(CO)5 .

241 Reaction mechanism proposal is discussed.

242 ing to the NMR and DFT investigations of the reaction mechanism, pyrroles and dihydropyrazines are fo

243 c transamination and/or addition-elimination reaction mechanisms, rather than hydride abstraction pat

244 The reaction mechanism, reaction intermediates, and final de

245 ental and engineered degradation, underlying reaction mechanisms remain elusive.

246 tment for over four decades, yet their exact reaction mechanism remains elusive.

247 ucture; however, the precise electrochemical reaction mechanism remains unknown.

248 the lack of fundamental understanding of the reaction mechanism renders designing a selective catalys

249 t also as a crucial component in the overall reaction mechanism responsible for averting the formatio

250 Computational investigations of the reaction mechanism reveal an unexpected, concerted SNAr

251 Repulsion (VSEPR) model to the most esoteric reaction mechanism routinely rely on the notion that ele

252 ifferent classes of phosphine ligands on the reaction mechanism(s), and deliver a methodology that sh

253 ansferases suggest that FUT1 uses a SN2-like reaction mechanism similar to that of protein-O-fucosylt

254 tion, and low-efficiency TIR rejoining using reaction mechanisms similar to those used by vertebrate

255 Highlights on the reaction mechanism (strictly dependent on the CMH of cho

256 Alternative reaction mechanisms, successive and concerted, were obse

257 rous NDMA precursors, essential parts of the reaction mechanism such as the incorporation of molecula

258 d show that different MbetaLs share the same reaction mechanism, suggesting new strategies for drug d

259 Our interrogation of the reaction mechanism suggests a disulfide radical anion as

260 Detailed scrutiny of the reaction mechanism suggests the involvement of C-centere

261 guides the two substrate types into a shared reaction mechanism that catalyzes their cleavage by an e

262 ssolution-reprecipitation may be a universal reaction mechanism that controls both silicate glass cor

263 hydrocarbons and alcohols, but the atomistic reaction mechanism that controls the product distributio

264 'Roaming' is a new and unusual class of reaction mechanism that has recently been discovered in

265 nd directly above the Cbl, consistent with a reaction mechanism that involves the formation of a cova

266 ylation selectivity in SyrB2 is related to a reaction mechanism that involves two asynchronous transf

267 We found evidence for a reaction mechanism that involves unusual dinuclear coppe

268 We identified a chemical reaction mechanism that is thermodynamically favorable i

269 s improve our understanding of autooxidation reaction mechanisms that are routinely used to predict f

270 In the proposed reaction mechanism the enzyme facilitates the transfer o

271 insight into the rate limiting steps in the reaction mechanism, the effect of first-coordination sph

272 Despite some uncertainty in the reaction mechanisms, the model accurately predicted rate

273 f amyloid formation bind to and where in the reaction mechanism they act.

274 ationships and a deeper understanding of the reaction mechanism, this review comprehensively overview

275 We present a plausible reaction mechanism to explain the observed reaction outc

276 m complexity and quantitatively characterize reaction mechanisms to an extent that is infeasible for

277 alculations are used to support the proposed reaction mechanism, to understand why decarbonylation do

278 cal computer simulations used to probe these reaction mechanisms, to significantly increase their acc

279 uction in dimensionality that makes chemical reaction mechanisms transferrable to seemingly arbitrari

280 The understanding of this reaction mechanism under the synthesis conditions should

281 ed to provide a comprehensive picture of the reaction mechanism using Ru(bpy)3Cl2 as a photocatalyst

282 We now have a new way to reformulate reaction mechanisms using an experimentally determined d

283 of phosphonium enolate intermediates in the reaction mechanism was indicated through reaction monito

284 The Ga4L6(12-) cage-mediated reaction mechanism was investigated by UV/vis absorption

285 The reaction mechanism was proposed for gallic acid degradat

286 The oxidative addition reaction mechanism was studied using density functional

287 The sensor reaction mechanism was verified by various experimental

288 To study the reaction mechanism, we have synthesized and characterize

289 To probe the reaction mechanism, we synthesized a SAM analogue (SAMCA

290 To obtain molecular insights into reaction mechanisms, we determined crystal structures of

291 The primary steps in the reaction mechanism were shown to include oxidation of ca

292 radicals, and in particular, silyl radicals, reaction mechanisms were proposed for each.

293 little is known about its effectiveness and reaction mechanisms when reacting with hormones.

294 These studies suggest a FEN1 reaction mechanism where junctions are bound and 5'-flap

295 Instead, we present a completely different reaction mechanism, where hOGG1 initially targets the ri

296 f isotope fractionation is a function of the reaction mechanism, where reduction of Cr(VI) to Cr(III)

297 oemission spectroscopy, the surface-assisted reaction mechanism, which is different from that in solu

298 Here we report an original Eley-Rideal reaction mechanism, which permits direct O2 formation in

299 oselectivity of the reaction is dependent on reaction mechanism with many substrates able to engage i

300 o expedite the development of completely new reaction mechanisms, with particular emphasis placed on