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1 bstituent, solvent, and concentration on the reaction order.
2 s well as quantitation of rate constants and reaction order.
3  characterized for substrate specificity and reaction order.
4 r leads to the observed transition of the CO reaction order.
5 o catalyst systems have essentially the same reaction order and Arrhenius apparent activation energie
6     Intriguingly, we determine that both the reaction order and the enthalpy of activation of the two
7 ion results in differing values for both the reaction order and the rate constants.
8                               In particular, reaction orders and activation parameters for the two st
9                    This study determines the reaction orders and rate constant for Ce(III) oxidation
10 experimental design allows deduction of both reaction orders and rate constants in many cases.
11 advanced minimization algorithm to yield the reaction orders and rate constants.
12 scopic data to derive uncertainty-quantified reaction orders and rates for Michael attack, estimate t
13                        Further, the apparent reaction orders and the stretching frequency of CO adsor
14 D, turbidity, and calorimetry indicates high reaction order, and the heating rate dependence suggests
15                              Rate constants, reaction orders, and apparent activation energies were d
16 kinetic isotope effect, activation enthalpy, reaction orders, and dependence of rate on carboxylate p
17 *-A*) and, consequently, in erroneous rates, reaction orders, and identification of rate-determining
18               At high overpotentials, the CO reaction order approaches -1 due to enhanced CO adsorpti
19 s, apparent activation energies and apparent reaction orders at the SCR conditions, even on zeolite f
20  studies using (19)F NMR spectroscopy reveal reaction orders consistent with a transition structure o
21 ical quenching, deuterium labeling, KIE, and reaction order determination experiments were performed
22 ion order was 3.07, while above 2.0-2.5 bar, reaction orders diverged.
23 ntly, traditional descriptors of rate (e.g., reaction orders) do not reflect intrinsic kinetic inform
24                                              Reaction-order experiments show higher coverages of CO*
25 This is the first demonstration of a precise reaction order for a MAP2K.
26                                 The apparent reaction order for NO consumption by sGC is dependent on
27                             In contrast, the reaction order for the alkenes was 1.65, and for benzene
28                    For carbonate buffer, the reaction orders for hydroxide and carbonate anions were
29 or the experimentally observed change in the reaction order from thermal catalysis to hot-carrier-med
30 dition did increase the iodination rate, the reaction order in [Cl(-)] was fractional (<=0.36).
31   For catalase-catalyzed H2O2 breakdown, the reaction order in [H2O2] was somewhat greater than unity
32 he oxidation is inhibited by OH(-) ions; the reaction order in [Pt(II)Me] changes to 2, consistent wi
33 on and carbon dioxide pressure, reveals zero reaction order in carbon dioxide concentration, for pres
34 ntributing to high reactivity with near-zero reaction order in CO.
35 to relatively low reactivity with a positive reaction order in CO.
36 d mechanistic studies have revealed that the reaction order in HNO(3) is >2 and indicate that the (*)
37          The Tafel slope (40 mV dec(-1)) and reaction order in OH(-) (1) for the mixed Ni-Fe films (c
38                                          The reaction order in picolinic acid equals one for 1a and t
39 , contrary to the canonical understanding of reaction order in PKSs, that methylation can precede con
40 plex of NSMOA is consistent with a preferred reaction order in which flavin reduction and reaction wi
41                                              Reaction orders in [C(3)H(8)] and [catalyst] are essenti
42                                              Reaction orders in [HOBr](T) ranged from 1.09 (+/-0.17)
43                                              Reaction orders in [HOBr]tot were found to be 1.33 (+/-0
44 -mediated mechanisms explains the fractional reaction orders in both oxygen and hydroquinone, the tim
45 h a range of experimental findings including reaction orders in methane, water, and oxygen as well as
46                  At high concentrations, the reaction order increases from the previously reported fi
47                           This extraordinary reaction order is encompassed by a novel double nucleati
48        The current studies further show that reaction order is independent of phosphate concentration
49 research is the introduction of an automatic reaction order model reduction framework, designed to op
50  theoretical work accounts for the different reaction order observed in the gas phase and in some con
51 rst on Tyr-182 and then on Thr-180, the same reaction order observed previously in ERK2.
52 xosyl donor, as indicated by the nucleophile reaction order of 0.26, and supported by metadynamics ca
53    The title compound 2 reacted in a kinetic reaction order of 0.5 (square root of its concentration)
54 a rate law with a single rate constant and a reaction order of 0.61 with respect to {H(+)}: Rexp = 36
55                Our kinetic analyses reveal a reaction order of 1 in iodine, indicating that higher io
56 stic studies including the evaluation of the reaction order of each component by variable time normal
57 rsus 3alpha(OH)EA, indicative of a preferred reaction order of hydroxylation at C-1, followed by that
58                             Furthermore, the reaction order of O(2) is -1.4 in dark but reverses to 0
59 ion of Cu(I) by oxygen and by H(2)O(2) had a reaction order of one.
60 ata, we discovered information regarding the reaction order of the substrates and catalysts.
61                                          The reaction orders of .NO and cysteine are second and first
62 electrokinetic data, we demonstrate that the reaction orders of adsorbed CO at p(CO) <0.4 and >0.6 at
63  permitted the determination of the relative reaction orders of the protonation on the two faces of t
64 c chemistry, the mechanisms underlying their reaction order remain poorly understood and difficult to
65                     The models confirmed the reaction order, revealed processivity in the phosphoryla
66 physiological conditions, with an "apparent" reaction order somewhat greater than 1 owing to local in
67                                   A study of reaction orders supports the postulated cooperative cata
68 pressures less than 2.0-2.5 bar, the average reaction order was 3.07, while above 2.0-2.5 bar, reacti
69                                          The reaction order was determined for iodobenzene (zero orde
70       Based on the measured Tafel slopes and reaction orders, we demonstrate that the formation rates
71                     Two regions of differing reaction order were identified for the alkynes; at press
72      The various reaction rate constants and reaction orders were found to correlate with the differe
73         Kinetic studies established that the reaction order with respect to both the acid and the cat
74                                          The reaction order with respect to plutonium concentration w
75 ) WGSR apparent activation energy, and (iii) reaction orders with respect to CO, H2O, CO2, and H2.
76  The potential-dependent negative fractional reaction orders with respect to the CO partial pressures