ライフサイエンスコーパス: reaction order

1 bstituent, solvent, and concentration on the reaction order.

2 s well as quantitation of rate constants and reaction order.

3 characterized for substrate specificity and reaction order.

4 o catalyst systems have essentially the same reaction order and Arrhenius apparent activation energie

5 Intriguingly, we determine that both the reaction order and the enthalpy of activation of the two

6 In particular, reaction orders and activation parameters for the two st

7 experimental design allows deduction of both reaction orders and rate constants in many cases.

8 advanced minimization algorithm to yield the reaction orders and rate constants.

9 Further, the apparent reaction orders and the stretching frequency of CO adsor

10 D, turbidity, and calorimetry indicates high reaction order, and the heating rate dependence suggests

11 Rate constants, reaction orders, and apparent activation energies were d

12 kinetic isotope effect, activation enthalpy, reaction orders, and dependence of rate on carboxylate p

13 s, apparent activation energies and apparent reaction orders at the SCR conditions, even on zeolite f

14 studies using (19)F NMR spectroscopy reveal reaction orders consistent with a transition structure o

15 ion order was 3.07, while above 2.0-2.5 bar, reaction orders diverged.

16 This is the first demonstration of a precise reaction order for a MAP2K.

17 The apparent reaction order for NO consumption by sGC is dependent on

18 In contrast, the reaction order for the alkenes was 1.65, and for benzene

19 For catalase-catalyzed H2O2 breakdown, the reaction order in [H2O2] was somewhat greater than unity

20 he oxidation is inhibited by OH(-) ions; the reaction order in [Pt(II)Me] changes to 2, consistent wi

21 on and carbon dioxide pressure, reveals zero reaction order in carbon dioxide concentration, for pres

22 The Tafel slope (40 mV dec(-1)) and reaction order in OH(-) (1) for the mixed Ni-Fe films (c

23 The reaction order in picolinic acid equals one for 1a and t

24 , contrary to the canonical understanding of reaction order in PKSs, that methylation can precede con

25 plex of NSMOA is consistent with a preferred reaction order in which flavin reduction and reaction wi

26 Reaction orders in [HOBr](T) ranged from 1.09 (+/-0.17)

27 Reaction orders in [HOBr]tot were found to be 1.33 (+/-0

28 h a range of experimental findings including reaction orders in methane, water, and oxygen as well as

29 At high concentrations, the reaction order increases from the previously reported fi

30 This extraordinary reaction order is encompassed by a novel double nucleati

31 The current studies further show that reaction order is independent of phosphate concentration

32 theoretical work accounts for the different reaction order observed in the gas phase and in some con

33 rst on Tyr-182 and then on Thr-180, the same reaction order observed previously in ERK2.

34 The title compound 2 reacted in a kinetic reaction order of 0.5 (square root of its concentration)

35 Our kinetic analyses reveal a reaction order of 1 in iodine, indicating that higher io

36 rsus 3alpha(OH)EA, indicative of a preferred reaction order of hydroxylation at C-1, followed by that

37 ion of Cu(I) by oxygen and by H(2)O(2) had a reaction order of one.

38 ata, we discovered information regarding the reaction order of the substrates and catalysts.

39 The reaction orders of .NO and cysteine are second and first

40 permitted the determination of the relative reaction orders of the protonation on the two faces of t

41 The models confirmed the reaction order, revealed processivity in the phosphoryla

42 physiological conditions, with an "apparent" reaction order somewhat greater than 1 owing to local in

43 A study of reaction orders supports the postulated cooperative cata

44 pressures less than 2.0-2.5 bar, the average reaction order was 3.07, while above 2.0-2.5 bar, reacti

45 The reaction order was determined for iodobenzene (zero orde

46 Two regions of differing reaction order were identified for the alkynes; at press

47 The various reaction rate constants and reaction orders were found to correlate with the differe

48 The reaction order with respect to plutonium concentration w

49 ) WGSR apparent activation energy, and (iii) reaction orders with respect to CO, H2O, CO2, and H2.