ライフサイエンスコーパス: reaction rate

1 eptides, anthocyanin degraded at first-order reaction rate.

2 MD simulations and allows one to control the reaction rate.

3 he tracers and the catalyst as a function of reaction rate.

4 influence of added perturbant species on the reaction rate.

5 Kinetic studies revealed a first-order reaction rate.

6 energy barrier, which rationalizes the high reaction rate.

7 with increasing substrate concentration and reaction rate.

8 order of magnitude and increases the overall reaction rate.

9 for simultaneous delivery and sensing of the reaction rate.

10 he effects of aroyl chloride substitution on reaction rate.

11 activation and transmetalation influence the reaction rate.

12 y with measurably different efficiencies and reaction rates.

13 tes, competing metabolic reactions, and slow reaction rates.

14 roduce a plasma target, further enhanced the reaction rates.

15 ambient conditions with unprecedentedly high reaction rates.

16 to increased precursor emissions, not faster reaction rates.

17 is complicated by the spatial variability of reaction rates.

18 id conformational sampling and slow chemical reaction rates.

19 ing both acceptable enantioselectivities and reaction rates.

20 can provide information about differences in reaction rates.

21 entials permits continuous adjustment of the reaction rates.

22 s suffers from low energy densities and slow reaction rates.

23 ociation reactions, activation barriers, and reaction rates.

24 n motif with catalytic reactions and uniform reaction rates.

25 om emissions, boundary conditions (BCs), and reaction rates.

26 article, DPPH) would reflect their relative reaction rates.

27 erformance has been disappointing due to low reaction rates.

28 liminate the interspecies differences in the reaction rates.

29 ucture coupled with differences in intrinsic reaction rates.

30 o analyze activation barriers that determine reaction rates.

31 e of the droplet both strongly contribute to reaction rate acceleration, suggesting that the reaction

32 yme before inhibitor dissociation; vs is the reaction rate after dissociation of the inhibitor.

33 Higher reaction rate after immunotherapy was associated with mo

34 Significantly faster reaction rates allow chlorine radicals to expedite oxida

35 endrimer and surface group also affected the reaction rate and activation energy.

36 upported by the low-temperature limit of the reaction rate and by the H/D kinetic isotope effect.

37 f the spatial distribution of the pore scale reaction rate and conservative component concentration i

38 The reaction rate and efficiency is comparable to previously

39 the phosphoramidite dramatically influences reaction rate and enantioselectivity.

40 acteristic fingerprint pattern of changes in reaction rate and enantioselectivity.

41 ulting in a dramatic increase in the surface reaction rate and equilibrium binding.

42 ntributions to the free energy and impacting reaction rate and equilibrium constants.

43 ovide a new class of catalysts for improving reaction rate and increasing product diversity during me

44 on the effects of chloride concentration on reaction rate and indicate that the catalyst is subject

45 (MIMs) - in particular, rotaxanes - its slow reaction rate and narrow substrate acceptance limit its

46 Protein denaturation increased the reaction rate and reduced the number of binding sites fo

47 cyclopentadienyl (Cp(X)) ligand structure on reaction rate and selectivity has been viewed as a black

48 l. demonstrated a strong correlation between reaction rate and the carbonyl stretching frequency of a

49 s reveal an inverse relationship between the reaction rate and the concentration of BQ, suggesting th

50 ups on the framework linkers, impacts on the reaction rate and the enantiomeric excess of the aldol p

51 orated by the linear correlation between the reaction rate and the reduction potential of the carbazo

52 via H-bonding is key for the enhancement in reaction rate and yield, while stereocontrol is dependen

53 tion with transition-path sampling to obtain reaction rates and analysis via Markov state models, we

54 The formation of this structure depends on reaction rates and conditions.

55 s solutions of NPP model, using the infinite reaction rates and constant ligand concentration assumpt

56 Higher reaction rates and conversion yields were observed with

57 Molecular crowding modifies biochemical reaction rates and decreases macromolecule diffusion.

58 In vivo biochemical reaction rates and equilibria might differ significantly

59 composite significantly increased the anodic reaction rates and facilitated the electron transfer fro

60 High reaction rates and full conversion were observed, with t

61 ive humidity (RH), and particle size control reaction rates and mechanisms.

62 icinity of transition states are critical to reaction rates and product distributions, but direct exp

63 We rationalize why models often underpredict reaction rates and show that, despite the uncertainty be

64 mobilization are predicated on the values of reaction rates and surface area of calcite, adsorption s

65 rination of chlorinated solvents due to high reaction rates and the opportunity to inject reactive sl

66 ew precatalysts 2F and 3F are showing higher reaction rates and yields for multigram-scale syntheses.

67 h the assistance of US irradiation, both the reaction rates and yields of selenenylation, sulfenylati

68 nts can be fine-tuned separately to increase reaction rates and/or selectivities.

69 mplications in overall reaction selectivity, reaction rate, and accessibility of off-cycle iron(I)-Sc

70 rder reaction rate constants, probe compound reaction rates, and experiments in buffered Cl(-) soluti

71 tion between Pd-NZVI aggregate sizes and TCE reaction rates, and is explained by cryo-transmission el

72 he effect of thermodynamic driving forces on reaction rates, and lead to equations relating rate cons

73 of geometries, energies, transition states, reaction rates, and spectroscopic properties of molecule

74 on kinetic parameters becomes weak when the reaction rate approaches the diffusion limit.

75 ion between a clean catalyst surface and the reaction rate are in agreement with a homotopic catalyti

76 Bimolecular reaction rates are at least an order of magnitude faster

77 w within this system is laminar (Re < 1) and reaction rates are driven by enzyme kinetics (Pe = 100,

78 Different reaction rates are explained by the structural relations

79 In the bulk material, reaction rates are limited by diffusion depending on pha

80 ors do not have an integer kinetic order and reaction rates are strongly temperature-dependent.

81 This is especially true for enzymes where reaction rates are typically diffusion limited.

82 s of equivalents of H2 produced and relative reaction rates) are provided throughout the discussion.

83 reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes hig

84 is control strategy: continuous variation of reaction rates as a function of the magnitude of externa

85 a model for predicting the diffusion-limited reaction rate, as first discussed by von Smoluchowski.

86 butyl group does not have a strong effect on reaction rate, as shown by the similar second order reac

87 e to account for the diffusion limitation on reaction rates associated with the altered layer.

88 trodes for overall water splitting with high reaction rates at low overpotentials, and supercapacitor

89 g initial concentrations and after examining reaction rates at the individual molecule level.

90 ays including kinetic barriers, and computed reaction rates based on the microkinetic models.

91 on period is followed by a rapid increase in reaction rate before the rate decreases again as the rea

92 The reaction rate behaviors were examined with regard to sub

93 g pH-stat experiments appeared to affect the reaction rate, being higher when KOH is added to the rea

94 ed measurements and models of biogeochemical reaction rates, benthic fluxes, and in-sediment nutrient

95 nterferometry, we quantify the difference in reaction rate between the crystal faces, the overall ran

96 n rate, as shown by the similar second order reaction rates between desethyl-terbuthylazine (DET; k =

97 by measuring the absolute Penning ionization reaction rates between hydrogen isotopologues and metast

98 atic discrepancies in experimentally derived reaction rates between other sCIs and SO2 and water vapo

99 olution and can reduce the average effective reaction rate by an order of magnitude.

100 b5 did not enhance reaction rates by decreasing the koff rates of any of th

101 on of the geometric phase modifies ultracold reaction rates by nearly two orders of magnitude.

102 Accordingly, significant acceleration of reactions rates by orders of magnitude is obtained.

103 t the temperature dependence of native redox reaction rates can be well described by the thermal acti

104 eviates the exponential decrease in chemical reaction rates caused by lowering of the temperature.

105 erally confirmed the newly found behavior of reaction rate changes from batch to column.

106 The OH reaction rate coefficient follows the Arrhenius trend (2

107 ctively, which demonstrates that bimolecular reaction rate coefficients can be quantified using merge

108 low-pressure termolecular dependence of the reaction rate coefficients for N2 and CO bath gases.

109 The apparent reaction rate coefficients obtained in different experim

110 The measured second order reaction rate coefficients of CPA with OH were: 3.6 +/-

111 nd lactate dehydrogenase, respectively, with reaction rates comparable to that of the native cofactor

112 decreased the weight normalized dehydration reaction rate compared to that of the parent HBEA, which

113 We show that the second-order forward reaction rate constant (k(on)) depends on both linker ar

114 Enzyme reaction rate constant (k) was placed in the 0-4 min mod

115 ion, multivariate analysis, determination of reaction rate constant and of Arrhenius plot) are illust

116 orrelation was observed between the observed reaction rate constant and the (31)P NMR chemical shift

117 composed of a reaction pathway generator, a reaction rate constant estimator, a mechanistic reductio

118 composed of a reaction pathway generator, a reaction rate constant estimator, and a KMC solver.

119 Pd sites and decreasing the TCE degradation reaction rate constant from 0.191 h(-1) to 0.027 h(-1).

120 ave now measured the creatine kinase forward reaction rate constant in BD.

121 ificant reduction in creatine kinase forward reaction rate constant in the BD group (F = 4.692, p = .

122 the second-order kinetics with an estimated reaction rate constant of 200 +/- 24 (mmol betaE2/g mine

123 The reaction rate constant of surface Co(IV) on oxygen-evolv

124 at 4T and quantified creatine kinase forward reaction rate constant using (31)P magnetization transfe

125 f 100 mug/L graphene, the pseudo-first-order reaction rate constant was increased ~50 times.

126 d be developed solely using the second order reaction rate constant with ozone (kO3).

127 ults are largely independent of the specific reaction-rate constant values, and depend on the topolog

128 thocyanins followed first-order kinetics and reaction rate constants (k values), which were obtained

129 Reaction rate constants (kcat/KM) were calculated for ne

130 The reaction rate constants (km) for the dissolution of uran

131 The various reaction rate constants and reaction orders were found t

132 the temperature-dependence of the respective reaction rate constants complied with the Arrhenius equa

133 Reaction rate constants did not change with the number o

134 Reaction rate constants for myoglobin, hemoglobin, neuro

135 yst of the reduction of GA, and fourth-order reaction rate constants kcat/KGAKXKGua.

136 The pseudo-first-order reaction rate constants of Co(III) and Co(IV) with water

137 Reaction rate constants of DEET and caffeine with the re

138 The chemical kinetic model together with the reaction rate constants that were determined in this wor

139 onding yields as well as forward and reverse reaction rate constants through fluorescence quenching a

140 reactants and their associated second-order reaction rate constants were estimated to be 6 to 9 orde

141 Calculated pseudo-first order reaction rate constants were in the following order; kCy

142 Reaction rate constants were obtained through least-squa

143 Reaction rate constants were smaller with lower pH, intr

144 The estimated reaction rate constants were within 1 order of magnitude

145 ainly formed from 1-deoxyglucosone with high reaction rate constants while glyoxal formed through glu

146 Bimolecular reaction rate constants with hydroxyl radicals ranged fr

147 ns and physicochemical properties (including reaction rate constants) to Northern Hemisphere (NH) and

148 literature-reported experimentally measured reaction rate constants, kexp, for 22 chlorine-derived i

149 be negligible based on measured second-order reaction rate constants, probe compound reaction rates,

150 Developed using the estimated reaction rate constants, the linear free energy relation

151 o rank these antioxidants according to their reaction rate constants.

152 ys and rate limiting steps by estimating the reaction rate constants.

153 ced elementary reaction mechanisms and their reaction-rate constants.

154 coupling of lithium composition and surface reaction rates controls the kinetics and uniformity duri

155 kynes or highly acidic carboxylic acids, the reaction rate could be increased.

156 dly over long (>15 A) distances, but usually reaction rates decrease with increasing donor-acceptor d

157 Over time, the reaction rate decreased and eventually plateaued to a ra

158 e range of 10-70 degrees C revealed that the reaction rate decreased with increasing temperature.

159 It was found that the reaction rate decreases when the number of water molecul

160 tration rather than molecule counts, because reaction rates depend on concentrations.

161 anism differ significantly, since elementary reaction rates depend on the product of the rate coeffic

162 such sites may or may not impact the overall reaction rate depending on reaction conditions: the meta

163 tress-driven reaction dynamics show that the reaction rate depends both on the bond being broken and

164 We find that the reaction rate depends critically on the molecular config

165 fic reaction elementary steps to the overall reaction rate depends on the preferred reaction pathways

166 on enabled testing of several models for the reaction rate distance dependence.

167 L-ascorbic acid proceeded with a first-order reaction rate during storage (40 degrees C for 5 days in

168 ic acid (0.050%) degraded with a first-order reaction rate during storage (40 degrees C/7days in ligh

169 determine whether there was a difference in reaction rates during the 4 years of the study was perfo

170 confounding factors potentially influencing reaction rates (e.g., evaporation, charge, and size).

171 onsuming and a macroscopic description using reaction rate equations (RREs) is no longer accurate.

172 Human P450 17A1 reaction rates examined are enhanced by the accessory pr

173 The reaction rate, extent of dehydrogenation, and reaction m

174 Results The breakthrough reaction rate for 5-hour intravenous prophylaxis was 2.5

175 -tert-butylphenols showed a 15-fold enhanced reaction rate for [Ni(III)(ONO2)(L)] compared to [Ni(III

176 Reaction rate for degradation of betalains, L( *), Hue a

177 te was 75 per minute, 63% of the ATP-coupled reaction rate for the nitrogenase complex under optimal

178 acrylamides, we determined glutathione (GSH) reaction rates for a family of N-arylacrylamides indepen

179 the three-component system leads to similar reaction rates for copolymerization and ROP and therefor

180 final selectivity is dependent on different reaction rates for radical formation from each epimer.

181 nel is the lack of experimentally determined reaction rates for sCIs formed from isoprene ozonolysis

182 We quantify reaction rates for these two products and describe catal

183 upramolecular catalyst where the increase in reaction rate from solvent-driven pre-organization of th

184 neat reagents caused an acceleration in the reaction rate, giving birth to what has been called "on-

185 ((Fl)DAB)Rh(OAc)(eta(2)-C2H4) shows that the reaction rate has a dependence on catalyst concentration

186 ed a novel type of smart probes with tunable reaction rates, high fluorescence turn-on ratio, and eas

187 Ideal bioorthogonal reactions with high reaction rates, high selectivity, and high stability wou

188 s been widely used to measure in vivo enzyme reaction rates (i.e., metabolic flux) in microorganisms.

189 Reaction rate in patients who were 6-15 months, 15-30 mo

190 an a clinically negligible 6.0% breakthrough reaction rate in the cohort that received 5-hour intrave

191 C10 stereochemistry in stereoselectivity and reaction rate in the Michael addition was observed.

192 was catalytically competent, giving the same reaction rate in the productive reaction as the Pd(II)/x

193 n, highlighting the importance of associated reaction rates in controlling N2O accumulation.

194 The latter requirement indicates that reaction rates in ionic liquids are limited by some fact

195 r alignment of catalytic linkers can enhance reaction rates in MOFs.

196 Kramers' theory frames chemical reaction rates in solution as reactants overcoming a bar

197 by introducing the j factor to describe the reaction rates in the cyclization process.

198 cceleration; this was confirmed by decreased reaction rates in the presence of a surfactant.

199 ntifying CO2 transport and average effective reaction rates in the subsurface is essential to assess

200 id-catalyzed reactions proceeded with higher reaction rates in the triplet manifold.

201 e flux becomes rate-limiting, explaining why reaction rates in vivo can be independent on enzyme conc

202 ecessitate the determination of all of these reaction rates in vivo.

203 Not only does the reaction rate increase with increasing KOH, but the rati

204 like state, and this results in the observed reaction rate increase.

205 presence of free chlorine and the oxidation reaction rates increase with free chlorine concentration

206 pH dependence studies show that the reaction rate increases with Fe(II) adsorption and is ma

207 reproduce experimentally observed effects on reaction rate, induced by electronically different subst

208 All quality indicators, except TVBN, showed reaction rates inversely proportional to the temperature

209 nergy of 32.5 kJ/mol, showing that the redox reaction rate is approximately 10(15) times slower at li

210 Furthermore, the reaction rate is controlled by the rate of Ag(I)-C-H act

211 rolled by C-C bond formation even though the reaction rate is dictated by the protonation step.

212 ugh a wave-pinning mechanism if the chemical reaction rate is fast enough.

213 Although the reaction rate is found to be independent of RH, the reac

214 Within the pH range of 6.5-9, the reaction rate is greatest at pH 7.

215 Benznidazole related cutaneous reaction rate is high, and it was produced by a delayed

216 ent temperature up to over 70 degrees C, and reaction rate is insensitive to the electronic character

217 For weak coupling to the solution, the reaction rate is limited by the rate at which the soluti

218 It was also found that the ring-expansion reaction rate is more than 1 order of magnitude faster w

219 ole of elastic strain in modifying catalytic reaction rates is crucial for catalyst design, but exper

220 On the basis of IC50 and reaction rates (k), beta-carbolines (norharman and harma

221 ere able to overcome the adsorption kinetics reaction rate-limiting mechanism, which is diffusion-con

222 is study also demonstrated that an effective reaction rate may be faster in transport systems than th

223 The combination of electrochemical reaction rate measurements and density functional theory

224 be expressed as a combination of microscopic reaction rates, Michaelis-Menten constants, and biochemi

225 discrepancy related to uncertainties in the reaction rate model and its parameters.

226 with a thermally activated, stress-assisted reaction rate model.

227 fore contrast-enhanced CT has a breakthrough reaction rate noninferior to that of a 13-hour oral prem

228 The DFT calculations suggest that the higher reaction rates observed in TFA and TFE compared with CH2

229 The specific reaction rate of 2.8 molCO.h(-1).gAu(-1) at a temperatur

230 ficant microwave-specific enhancement of the reaction rate of an organic chemical reaction can be obs

231 f the lipid rafts that sharply increases the reaction rate of biomolecules by guiding them to form di

232 We find that the ratio of the effective reaction rate of calcite to that of dolomite decreases w

233 determine if the allergic-like breakthrough reaction rate of intravenous corticosteroid prophylaxis

234 This result implies a ratio of the reaction rate of ISOPOO with HO2 to that with NO of appr

235 The effect of macrocyclic ring size on the reaction rate of oxidative aromatization was investigate

236 f detectable high-valent metal states if the reaction rate of process (ii) outweighs that of (i).

237 This study aimed to investigate the relative reaction rate of protein and lipid oxidation in differen

238 ating effect of Tb4O7NPs, which increase the reaction rate of the system, shortening analysis times.

239 libration curve was created by measuring the reaction rate of various samples with different ratios o

240 Inspired by the rapid reaction rates of cyclophellitol and cyclophellitol azir

241 Here we demonstrate that reaction rates of individual reactions in the network ca

242 dology to simultaneously assess the relative reaction rates of multiple antioxidant compounds in one

243 A comparison of the reaction rates of O-deallylation and ester reduction dem

244 However, the reaction rates of vinyl cations are affected only half a

245 This method relies on differences in HDX reaction rates of Zn-bound and Zn-free His residues.

246 The dependence of the reaction rate on the electrochemical potential generally

247 fer predicts a bell-shaped dependence of the reaction rate on the reaction free energy.

248 gh an unusual second-order dependence of the reaction rate on the ruthenium catalyst concentration.

249 articular interest is the role of individual reaction rates on the stability of the network output.

250 the temperature sensitivity of an enzymatic reaction rate or a physiological process due to an incre

251 Use of the water adduction reaction rate or the unreactive ratio provides two separ

252 ules in live cells have been limited by slow reaction rates or low component selectivity and stabilit

253 Based on reported measurements of reaction rates, our results indicate neither time-averag

254 w conditions offer considerable increases in reaction rate over prior art and allow a significant dec

255 us allowing measurement of the PLD-catalyzed reaction rate parameters.

256 drance of Py and FA largely dictates the HDF reaction rate, pointing to an inner-sphere electron tran

257 hotochemical transformation processes into a reaction rate prediction model improved the description

258 Steady state reaction rates reveal two regimes of catalytic performan

259 neously forms phosphorus-carbon bonds, has a reaction rate sensitive to the aryl diazonium substituen

260 We find that substituent effects on reaction rates show a linear Hammett correlation for ort

261 As moats grow in width, diffusion and hence reaction rate slow down.

262 R chemical shifts of the acrylamide with GSH reaction rates, suggesting that NMR chemical shifts may

263 ero-order kinetics, displaying a much higher reaction rate than observed for the conventionally therm

264 1a compared to 1a, and also explains why the reaction rate then drops with increasing KOH concentrati

265 While being one of the most popular reaction rate theories, the applicability of transition

266 chromatin competitive binding using chemical reaction rate theory and are able to derive the physical

267 From reaction rate theory, we predict that a class of modulat

268 An optimum CuRu catalyst presents a reaction rate threefold higher than that for Ru and fort

269 g limits on the suppression of hybridization reaction rates through the use of hairpins and offering

270 This suggests substrate-limited reaction rates to be common.

271 Enzymes enable life by accelerating reaction rates to biological timescales.

272 i), which compares observed enzyme-catalyzed reaction rates to characteristic substrate diffusion tim

273 ectrons and holes, we link the high observed reaction rates to the anisotropic structure, which favor

274 ied Ca(2+) diffusion coefficients and buffer reaction rates to tune the autocorrelation properties of

275 f PDI, we created PDI variants with a slowed reaction rate toward substrates.

276 phile electrostatic interactions dictate SN2 reaction rate trends.

277 e repair mechanism is modeled by an expanded reaction-rate two-lesion kinetic model, which were calib

278 Accelerations on reaction rate up to 177% were observed for ketimines red

279 d utilizing alkynyl dienophiles enhances the reaction rates up to 10(5)-fold.

280 ion parameters and experimentally determined reaction rates, validating the use of such methodology f

281 ntribution of enzymatic O2 activation to the reaction rate varies for different nitroaromatic substra

282 ow, for the first time, that electrochemical reaction rates vary significantly across an individual A

283 tly, but both AQDS and Fe(III) increased the reaction rate, via the production of AH2QDS and/or Fe(II

284 The breakthrough reaction rate was compared by using the Farrington and M

285 Grade 1/2 infusion reaction rate was low (5% EBd) and mitigated with premed

286 f temperature (294-328 K) on the degradation reaction rate was measured using ball-milled metallic gl

287 lectronic influence of the substrates on the reaction rate was quantified by Hammett plots.

288 Up to 60-fold increase in TCE reaction rates was observed upon sulfidation treatment,

289 The "surface" and "strongly-retained" water reaction rates well correlate with the rye content in th

290 sulfidation relative to iron reduction, TCE reaction rates were found to depend strongly on sulfur t

291 reated with a panel of phosphine probes, and reaction rates were measured.

292 Overall reaction rates were not significantly lower in omalizuma

293 h high efficacy rate (98%) and a low adverse reaction rate when compared with oral administration.

294 in the degree of dissolution with an overall reaction rate which is approximately 14 times lower than

295 e presence of graphene greatly increased the reaction rate while not changed the products.

296 nly specific, intermediate, residence times (reaction rates) will both produce and release N2O to the

297 The reaction rate with dihydroanthracene (k2 = 8.1 M(-1) s(-

298 urthermore, the simulations predict relative reaction rates with different sulfonamides, which is suc

299 droxyl radicals differ considerably in their reaction rates with humic acids (k (sulfate radical + hu

300 Trends of experimental initial reaction rates with MOF topology and PC regioisomer are