ライフサイエンスコーパス: reaction rate

1 gated to the alkyne significantly retard the reaction rate.

2 hilicity of the N-Boc carbonyl group and the reaction rate.

3 lit protein and the process of enhancing its reaction rate.

4 arching goal being to accelerate the overall reaction rate.

5 with a barrier consistent with the observed reaction rate.

6 ce was remarkably slow, limiting the overall reaction rate.

7 order of magnitude and increases the overall reaction rate.

8 he effects of aroyl chloride substitution on reaction rate.

9 activation and transmetalation influence the reaction rate.

10 ion of its substrate, thereby increasing its reaction rate.

11 for simultaneous delivery and sensing of the reaction rate.

12 eptides, anthocyanin degraded at first-order reaction rate.

13 MD simulations and allows one to control the reaction rate.

14 he tracers and the catalyst as a function of reaction rate.

15 influence of added perturbant species on the reaction rate.

16 ides into close proximity and increasing the reaction rate.

17 without significantly affecting the forward reaction rate.

18 macrocycles are not enough to produce a high reaction rate.

19 ivity of nearly 40% at industrially relevant reaction rates.

20 ed electrodes to achieve high photocatalytic reaction rates.

21 oximation of quantum vibrational spectra and reaction rates.

22 location, and MRI type correlate with acute reaction rates.

23 to increased precursor emissions, not faster reaction rates.

24 n motif with catalytic reactions and uniform reaction rates.

25 om emissions, boundary conditions (BCs), and reaction rates.

26 article, DPPH) would reflect their relative reaction rates.

27 tration of enzymes and substrates to enhance reaction rates.

28 erformance has been disappointing due to low reaction rates.

29 liminate the interspecies differences in the reaction rates.

30 ucture coupled with differences in intrinsic reaction rates.

31 o analyze activation barriers that determine reaction rates.

32 y with measurably different efficiencies and reaction rates.

33 mitations imposed by realistic diffusion and reaction rates.

34 tes, competing metabolic reactions, and slow reaction rates.

35 roduce a plasma target, further enhanced the reaction rates.

36 limited by low component stability and slow reaction rates.

37 rving micro- and mesoporosity, and micropore reaction rates.

38 rates, while the polar effects will increase reaction rates.

39 tion front velocity ~ (thermal diffusivity x reaction rate)(1/2).

40 Most significantly, reaction rate acceleration has been demonstrated by expl

41 These results reveal the reaction rate accelerations possible under Coulombic con

42 Hypersensitivity reaction rate after allergy skin testing (17%; 95% CI: 7

43 Higher reaction rate after immunotherapy was associated with mo

44 Hypersensitivity reaction rate after switching GBCAs was 50% (95% CI: 21%

45 endrimer and surface group also affected the reaction rate and activation energy.

46 upported by the low-temperature limit of the reaction rate and by the H/D kinetic isotope effect.

47 ctive zone" within the hydrogel affected the reaction rate and byproduct selectivity, and it was depe

48 acteristic fingerprint pattern of changes in reaction rate and enantioselectivity.

49 the phosphoramidite dramatically influences reaction rate and enantioselectivity.

50 ntributions to the free energy and impacting reaction rate and equilibrium constants.

51 xy substituent showed a faster cross-linking reaction rate and higher ICL efficiency than the corresp

52 on the effects of chloride concentration on reaction rate and indicate that the catalyst is subject

53 The reaction rate and product branching fractions are measur

54 cyclopentadienyl (Cp(X)) ligand structure on reaction rate and selectivity has been viewed as a black

55 ups on the framework linkers, impacts on the reaction rate and the enantiomeric excess of the aldol p

56 orated by the linear correlation between the reaction rate and the reduction potential of the carbazo

57 Both the reaction rate and the selectivity to chain-lengthened pa

58 via H-bonding is key for the enhancement in reaction rate and yield, while stereocontrol is dependen

59 obtain a clear correlation between observed reaction rates and computationally derived activation en

60 The formation of this structure depends on reaction rates and conditions.

61 effectors is proposed to enhance biological reaction rates and efficiency.

62 ogeochemical cycles via accelerating various reaction rates and enabling biological processes at the

63 ermediates' stability and, therefore, in the reaction rates and mechanisms.

64 ive humidity (RH), and particle size control reaction rates and mechanisms.

65 GBCA reaction rates and other potential risk factors were exa

66 ss conversion reactions can lead to improved reaction rates and selectivities.

67 teomic and kinetic data available to predict reaction rates and steady-state concentrations of H2O2 a

68 mobilization are predicated on the values of reaction rates and surface area of calcite, adsorption s

69 rination of chlorinated solvents due to high reaction rates and the opportunity to inject reactive sl

70 alladium membrane reactor proceeds at faster reaction rates and with much higher voltage efficiency t

71 ew precatalysts 2F and 3F are showing higher reaction rates and yields for multigram-scale syntheses.

72 nts can be fine-tuned separately to increase reaction rates and/or selectivities.

73 mplications in overall reaction selectivity, reaction rate, and accessibility of off-cycle iron(I)-Sc

74 The small size of the reagent, the high reaction rate, and the easy synthesis make pyrrolyl alan

75 extend MCMC methods to efficiently estimate reaction rates, and delay distribution parameters, from

76 Different cages have different solubilities, reaction rates, and energies required for triggering.

77 OS, OS + P and COS + P followed second-order reaction rates, and sorption isotherms of all sorbents w

78 on kinetic parameters becomes weak when the reaction rate approaches the diffusion limit.

79 w within this system is laminar (Re < 1) and reaction rates are driven by enzyme kinetics (Pe = 100,

80 Different reaction rates are explained by the structural relations

81 Enhancements of reaction rates are found in comparison to literature pro

82 The reaction rates are much higher for these materials than

83 This is especially true for enzymes where reaction rates are typically diffusion limited.

84 reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes hig

85 a model for predicting the diffusion-limited reaction rate, as first discussed by von Smoluchowski.

86 lective catalysts, which can control at will reaction rates, as well as mechanistic crossovers, for t

87 e to account for the diffusion limitation on reaction rates associated with the altered layer.

88 some cases, in facilitating their enzymatic reaction rates at favorable reaction conditions.

89 trodes for overall water splitting with high reaction rates at low overpotentials, and supercapacitor

90 ass transport processes and electrocatalytic reaction rates at the electrode diffusion layer through

91 ectric field distribution in determining the reaction rates at the three-phase interface.

92 ibe our investigation into the effect on the reaction rate based on the structure of the iodoarene pr

93 ays including kinetic barriers, and computed reaction rates based on the microkinetic models.

94 on period is followed by a rapid increase in reaction rate before the rate decreases again as the rea

95 The reaction rate behaviors were examined with regard to sub

96 arrots, we report the first in situ apparent reaction rate beta between FC and amino acids in the ran

97 nterferometry, we quantify the difference in reaction rate between the crystal faces, the overall ran

98 s are uncommon, it is challenging to compare reaction rates between GBCAs and to determine risk facto

99 Purpose To compare reaction rates between the four GBCAs gadodiamide, gadob

100 ysteine conjugation reagents, increasing the reaction rate by >3 orders of magnitude.

101 d the molecules from loss and suppressed the reaction rate by an order of magnitude below the backgro

102 he two transport phenomena and the catalytic reaction rate by applying models from closely related fi

103 te and observed a modulation of the chemical reaction rate by three orders of magnitude as we tuned t

104 neglected processes enhance the triple-alpha reaction rate by up to an order of magnitude.

105 l on the cyclooctyne ring also increased the reaction rates by 3.5- to 6-fold.

106 b5 did not enhance reaction rates by decreasing the koff rates of any of th

107 ate extreme tunability of ultracold chemical reaction rates by inducing resonant dipolar interactions

108 with proton relays and these enhance overall reaction rates by orders of magnitude.

109 We find that the GSH reaction rates can generally be understood in terms of t

110 al observations, including enantioinduction, reaction rate, catalyst resting state, enolate crossover

111 ctively, which demonstrates that bimolecular reaction rate coefficients can be quantified using merge

112 s to estimate the pseudo first-order abiotic reaction rate coefficients in diffusion-dominated intact

113 The apparent reaction rate coefficients obtained in different experim

114 The measured second order reaction rate coefficients of CPA with OH were: 3.6 +/-

115 lectivity toward AA production at volumetric reaction rates comparable to homogeneous processes.

116 Labeling proceeded with reaction rates comparable to or higher than the most oft

117 nd lactate dehydrogenase, respectively, with reaction rates comparable to that of the native cofactor

118 rk is that it relies on experimental data in reaction rate computations.

119 Here, we prove that cytometry of reaction rate constant (CRRC) can facilitate such analys

120 Cytometry of Reaction Rate Constant (CRRC) uses time-lapse fluorescen

121 The first (1)O(2) bimolecular reaction rate constant for a RiPP, the thiazole-containi

122 ave now measured the creatine kinase forward reaction rate constant in BD.

123 ificant reduction in creatine kinase forward reaction rate constant in the BD group (F = 4.692, p = .

124 A reaction rate constant is determined for every cell, and

125 In apple and orange juices, the reaction rate constant of glucosone formation was found

126 adical-cations (k(H)) of 10(5) s(-1) and the reaction rate constant of the phenoxy radicals (k(R)) in

127 The system was robust to reaction rate constant perturbations.

128 at 4T and quantified creatine kinase forward reaction rate constant using (31)P magnetization transfe

129 th direct and indirect photodegradation, the reaction rate constant with (1)O(2) alone resulted in a

130 d be developed solely using the second order reaction rate constant with ozone (kO3).

131 ults are largely independent of the specific reaction-rate constant values, and depend on the topolog

132 thocyanins followed first-order kinetics and reaction rate constants (k values), which were obtained

133 The reaction rate constants (km) for the dissolution of uran

134 With the exoskeleton, we increased in the reaction rate constants as much as 21-fold by running th

135 the temperature-dependence of the respective reaction rate constants complied with the Arrhenius equa

136 The derived reaction rate constants for the heterogeneous loss of EH

137 The derived reaction rate constants for the heterogeneous loss of tr

138 The reaction rate constants implied that the kynurenic acid

139 Reaction rate constants of DEET and caffeine with the re

140 Calculated pseudo-first order reaction rate constants were in the following order; kCy

141 The estimated reaction rate constants were within 1 order of magnitude

142 ainly formed from 1-deoxyglucosone with high reaction rate constants while glyoxal formed through glu

143 Bimolecular reaction rate constants with hydroxyl radicals ranged fr

144 literature-reported experimentally measured reaction rate constants, kexp, for 22 chlorine-derived i

145 tides and measured their (1)O(2) bimolecular reaction rate constants, showing slow photooxidation und

146 o rank these antioxidants according to their reaction rate constants.

147 ced elementary reaction mechanisms and their reaction-rate constants.

148 Yet, pronounced reaction rate decrease for benzyl alcohol alkylation wit

149 Over time, the reaction rate decreased and eventually plateaued to a ra

150 ransitions between discrete states, with the reaction rates defined by an underlying free energy land

151 anism differ significantly, since elementary reaction rates depend on the product of the rate coeffic

152 such sites may or may not impact the overall reaction rate depending on reaction conditions: the meta

153 We find that the reaction rate depends critically on the molecular config

154 fic reaction elementary steps to the overall reaction rate depends on the preferred reaction pathways

155 on enabled testing of several models for the reaction rate distance dependence.

156 confounding factors potentially influencing reaction rates (e.g., evaporation, charge, and size).

157 Significant reaction rate enhancements of a difluorinated SNO-OCT de

158 Human P450 17A1 reaction rates examined are enhanced by the accessory pr

159 The experimentally determined reaction rates exponentially correlate with the computat

160 Results The breakthrough reaction rate for 5-hour intravenous prophylaxis was 2.5

161 -tert-butylphenols showed a 15-fold enhanced reaction rate for [Ni(III)(ONO2)(L)] compared to [Ni(III

162 Reaction rate for degradation of betalains, L( *), Hue a

163 The reaction rate for this system was also theoretically det

164 ligands are separated to reduce the kinetic reaction rates for better control over the crystallizati

165 Understanding and predicting reaction rates for bioconjugation reactions is fundament

166 the three-component system leads to similar reaction rates for copolymerization and ROP and therefor

167 Breakthrough reaction rates for macrocyclic (36%; 95% CI: 25%, 48%; 2

168 Herein, we report glutathione (GSH) reaction rates for N-phenyl acrylamides with varied subs

169 The reaction rates for the mononuclear rearrangement of the

170 The reaction rates for the nucleophilic aromatic substitutio

171 groups reacting by an S(N)1 mechanism, while reaction rates for the worse leaving groups are limited

172 Current estimation techniques for inferring reaction rates frequently rely on marginalization over u

173 upramolecular catalyst where the increase in reaction rate from solvent-driven pre-organization of th

174 neat reagents caused an acceleration in the reaction rate, giving birth to what has been called "on-

175 ((Fl)DAB)Rh(OAc)(eta(2)-C2H4) shows that the reaction rate has a dependence on catalyst concentration

176 The reaction rate has first order dependence in the catalyst

177 ed a novel type of smart probes with tunable reaction rates, high fluorescence turn-on ratio, and eas

178 p to 91% of O(2) yield); it exhibits initial reaction rates identical with those of its protio analog

179 e alkylation reagents, including accelerated reaction rates, improved stability, and robust ionizatio

180 em gives a four-fold increase in the initial reaction rate in comparison to a stirred biphasic medium

181 s able to produce an 18-fold increase in the reaction rate in relation to crown ether catalysis only.

182 This raises the questions of what the reaction rate in supernova outflows is, and how changes

183 an a clinically negligible 6.0% breakthrough reaction rate in the cohort that received 5-hour intrave

184 C10 stereochemistry in stereoselectivity and reaction rate in the Michael addition was observed.

185 of Cu to significantly influence the oxygen reaction rate in wine.

186 The latter requirement indicates that reaction rates in ionic liquids are limited by some fact

187 r alignment of catalytic linkers can enhance reaction rates in MOFs.

188 sequence and structure context can modulate reaction rates in order to direct precursors along speci

189 applications and calculate expected nuclear reaction rates in the D(d,n) and (12)C(p,gamma) systems

190 A multipronged systematic analysis of the reaction rates in the OADHc pathway, supplemented with r

191 e flux becomes rate-limiting, explaining why reaction rates in vivo can be independent on enzyme conc

192 like state, and this results in the observed reaction rate increase.

193 ses from 10 to 1 mum, whereas the total MPST reaction rate increases ~7-fold.

194 reproduce experimentally observed effects on reaction rate, induced by electronically different subst

195 r constituents affect the E(H)-dependence of reaction rates involving oxide-bound Fe(2+) as a reducta

196 rolled by C-C bond formation even though the reaction rate is dictated by the protonation step.

197 Although the reaction rate is found to be independent of RH, the reac

198 Remarkably, the reaction rate is increased by more than two orders of ma

199 n the obese resting heart, the myocardial CK reaction rate is increased, maintaining ATP delivery des

200 The reaction rate is independent of the cryogenic temperatur

201 ent temperature up to over 70 degrees C, and reaction rate is insensitive to the electronic character

202 It was also found that the ring-expansion reaction rate is more than 1 order of magnitude faster w

203 ole of elastic strain in modifying catalytic reaction rates is crucial for catalyst design, but exper

204 two types of active sites with different OER reaction rates: k'(fast) (MnO(x) )=1.21 s(-1) and k'(slo

205 formation of hairpin stems, finding that the reaction rate kon is increased by the crowding effect, w

206 domains are known to shape diffusion-limited reaction rates, less is understood about how these facto

207 ed enzymes, whole cells suffer from inherent reaction rate limitations due to transport resistance im

208 conditions (90 degrees C temperature), fast reaction rates (<4 h), compatibility with air moisture,

209 The combination of electrochemical reaction rate measurements and density functional theory

210 be expressed as a combination of microscopic reaction rates, Michaelis-Menten constants, and biochemi

211 e in-medium contribution to the triple-alpha reaction rate must be present at high densities, this ef

212 fore contrast-enhanced CT has a breakthrough reaction rate noninferior to that of a 13-hour oral prem

213 at reactivity varies widely among PFASs, but reaction rates observed for individual PFASs in AFFF are

214 ayed only one kinetic behavior with a faster reaction rate of 1.72 s(-1) .

215 f the lipid rafts that sharply increases the reaction rate of biomolecules by guiding them to form di

216 We find that the ratio of the effective reaction rate of calcite to that of dolomite decreases w

217 determine if the allergic-like breakthrough reaction rate of intravenous corticosteroid prophylaxis

218 The effect of macrocyclic ring size on the reaction rate of oxidative aromatization was investigate

219 f detectable high-valent metal states if the reaction rate of process (ii) outweighs that of (i).

220 This study aimed to investigate the relative reaction rate of protein and lipid oxidation in differen

221 effects provided by the substituents and the reaction rate of the described process.

222 The exceptionally high reaction rate of this ligation minimizes label concentra

223 libration curve was created by measuring the reaction rate of various samples with different ratios o

224 We obtain ground-state reaction rates of 2.19 x 10(11) s(-1) at 150 K and 0.63

225 oded tetrazine amino acids in proteins reach reaction rates of 8 x 10(4) M(-1) s(-1) with sTCO reagen

226 Reaction rates of both solvent-free and solvent-stabiliz

227 Inspired by the rapid reaction rates of cyclophellitol and cyclophellitol azir

228 sed for CL because of the differences in the reaction rates of DEPC and HDX.

229 Here we demonstrate that reaction rates of individual reactions in the network ca

230 ncompatible with hydrolysis, explain the low reaction rates of mononucleotides and suggest two distin

231 dology to simultaneously assess the relative reaction rates of multiple antioxidant compounds in one

232 the long-standing conundrum of why apparent reaction rates of oxygen in aquifers are typically small

233 The concentrations and reaction rates of the oxidised states accumulated during

234 However, the reaction rates of vinyl cations are affected only half a

235 The reaction rates of VOCs with O(3), OH radicals, and nitra

236 l observations, such as no dependency of the reaction rate on the HO(t)Bu concentration, no observabl

237 fer predicts a bell-shaped dependence of the reaction rate on the reaction free energy.

238 the temperature sensitivity of an enzymatic reaction rate or a physiological process due to an incre

239 Use of the water adduction reaction rate or the unreactive ratio provides two separ

240 ate production was quantified as an apparent reaction rate, or k(PL), and normalized lactate ratio (n

241 hat water has a near-zero or mildly positive reaction rate order over Pd/Pt catalysts.

242 Based on reported measurements of reaction rates, our results indicate neither time-averag

243 Purpose To determine the GBCA breakthrough reaction rate overall and according to GBCA class and to

244 es, introducing excess ethylene can increase reaction rate owing to faster catalyst initiation.

245 r hand, experimental studies reveal that the reaction rates per surface area for the slowest step (FF

246 drance of Py and FA largely dictates the HDF reaction rate, pointing to an inner-sphere electron tran

247 This leads to an inverted parabolic reaction rate profile and slower reactions with more aci

248 ver, current densities, related to catalytic reaction rates, ranged from 15 to 50 mA cm(-2) mM(-1) co

249 ind that 1) nucleotidase confinement reduces reaction rates relative to an open (bulk) system, 2) the

250 gests that this effect of electronics on the reaction rate results from an unusual trend of faster ox

251 Steady state reaction rates reveal two regimes of catalytic performan

252 neously forms phosphorus-carbon bonds, has a reaction rate sensitive to the aryl diazonium substituen

253 As moats grow in width, diffusion and hence reaction rate slow down.

254 itical descriptor of its chemistry-impacting reaction rates, solubility, chemical speciation, and hom

255 The larger reaction rate suppresses the production of heavy proton-

256 ero-order kinetics, displaying a much higher reaction rate than observed for the conventionally therm

257 t reactions whilst barely perturbing forward reaction rates: the introduction of mismatches within th

258 While being one of the most popular reaction rate theories, the applicability of transition

259 chromatin competitive binding using chemical reaction rate theory and are able to derive the physical

260 supply driven mainly by intensified anammox reaction rates, thereby providing a quantitative link be

261 plementary (positive) charges to ATP enhance reaction rates, though the impact of these contributions

262 An optimum CuRu catalyst presents a reaction rate threefold higher than that for Ru and fort

263 of CO(2) in the gas stream and regulate the reaction rate through the current density.

264 d reveals a proportional relationship of SCR reaction rate to [surface VO(x) concentration](2) , impl

265 This suggests substrate-limited reaction rates to be common.

266 i), which compares observed enzyme-catalyzed reaction rates to characteristic substrate diffusion tim

267 f PDI, we created PDI variants with a slowed reaction rate toward substrates.

268 e repair mechanism is modeled by an expanded reaction-rate two-lesion kinetic model, which were calib

269 Accelerations on reaction rate up to 177% were observed for ketimines red

270 eposition, this had a moderate effect on the reaction rate (up to two-fold enhancement).

271 By coordinating reaction rate using a protease-based oscillator in E. co

272 interaction potentials and the alteration of reaction rates using quantum statistics.

273 ntribution of enzymatic O2 activation to the reaction rate varies for different nitroaromatic substra

274 ow, for the first time, that electrochemical reaction rates vary significantly across an individual A

275 tly, but both AQDS and Fe(III) increased the reaction rate, via the production of AH2QDS and/or Fe(II

276 First order reaction rate was 3.31 x 10(-3) +/- 9.1 x 10(-4) min(-1)

277 The overall breakthrough reaction rate was 39% (95% confidence interval [CI]: 30%

278 The breakthrough reaction rate was compared by using the Farrington and M

279 c membrane, up to 15-fold enhancement in the reaction rate was reached.

280 Up to 60-fold increase in TCE reaction rates was observed upon sulfidation treatment,

281 From the calculated reaction rates we find that at low pH the OH(-) anion nu

282 The "surface" and "strongly-retained" water reaction rates well correlate with the rye content in th

283 Breakthrough reaction rates were determined with random-effects model

284 sulfidation relative to iron reduction, TCE reaction rates were found to depend strongly on sulfur t

285 reated with a panel of phosphine probes, and reaction rates were measured.

286 Surprisingly, the quenching reaction rates were more than 3 orders of magnitude fast

287 Overall reaction rates were not significantly lower in omalizuma

288 rly Earth ocean-air interface, yields higher reaction rates when compared to bulk solution, thus over

289 ifferences of antibody affinity and chemical reaction rate, which are characterized to guide probe de

290 the coupling of diffusion anisotropy and the reaction rate, which indicates a new type of bifurcation

291 er does not change the methanol steady state reaction rate, while it has a substantial inhibiting eff

292 xy group to 2,6-dimethylphenol will decrease reaction rates, while the polar effects will increase re

293 nly specific, intermediate, residence times (reaction rates) will both produce and release N2O to the

294 ting substituents substantially impacted the reaction rate with (1)O(2) as well as the one-electron o

295 UV/Vis and mass spectrometric techniques and reaction rates with cyclohexane carboxaldehyde (CCA) are

296 Trends of experimental initial reaction rates with MOF topology and PC regioisomer are

297 The sigmoidal dependence of initial reaction rates with pH resembles the dissociation curve

298 potential physical mechanism for regulating reaction rates within organelle network structures.

299 , such as studies of the competition between reaction rates within the bulk and at the surface of con

300 d the template ions on the self-condensation reaction rate, yield, and stereoselectivity was examined