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1 , resulting in an overall disproportionation reaction with 1 equiv of ethyl arene formed for each equ
2 scence intensity enhancement at 435 nm after reaction with 1 equiv of H2S due to the inhibition of PE
3 of acetic acid from CH4 and CO2 is an ideal reaction with 100 % atom economy, but it is almost impos
4 az, which showed extensive biotransformation reactions with 18 BTPs detected that were mainly formed
5 and the inverse electron-demand Diels-Alder reactions with 3,6-bis(trifluoromethyl)tetrazine were an
6 enation/hydrogenolysis, and cyclization upon reaction with 4-bromobutanal to give the tricyclic skele
9 tion-state calculations for a concerted SNAr reaction with a bromine nucleofug, gives correlations su
14 on of methyl 5-hydroxynicotinate followed by reaction with a diene in the presence of triethylamine a
15 in fact effective in catalyzing the reverse reaction with a kcat of 11 +/- 0.4 s(-1) We also quantif
16 allel kinetic resolution (PKR) strategy upon reaction with a pseudoenantiomeric mixture of lithium (R
17 herol and BHT) antioxidants were measured by reaction with a series of 4-alkanoyloxyTEMPO radical pro
18 lo-enolcarbenes was successfully extended to reaction with a stable benzylidene dichlororuthenium com
20 OPA was also found to produce BrC in aqueous reactions with a broad spectrum of amino acids and amine
21 r organ and also an important site of immune reactions with a high density of dendritic cells (DCs),
23 id activates the substrate toward sequential reactions with a nucleophile (epoxide ring-opening by ch
24 nistic studies indicate a complex network of reactions with a number of possible intermediates and me
25 as electrocatalysts or catalysts for various reactions, with a focus on the enhanced performance rela
26 report a single ribozyme that performs both reactions, with a nucleobase serving as initial acceptor
28 nexpensive reagents, and reacts in the title reaction with acetonitrile, sodium chloride, and sodium
29 chemiluminescence (MF-CL) methods (based on reactions with acidic permanganate enhanced by formaldeh
30 atalyzed carbomagnesiation of cyclopropenes, reaction with acylsilanes, and addition of THF as cosolv
31 generated kinetin and its isomer, while its reaction with adenosine generated kinetin riboside, as c
32 med with moderate to good yields, while upon reaction with aldehydes, the initial addition product (6
37 eagents examined gave exclusive 1,4-addition reactions with alpha,beta-gamma,delta-unsaturated thiol
40 s to trigger the onset of the auto-oxidation reaction with an apparent turnover frequency of 440 s(-1
41 roethanesulfonyl fluoride is made via a neat reaction with an aqueous, nearly saturated potassium bif
42 using digital quantitative polymerase chain reaction with an independent cohort of 63 RRMS patients
43 oop-mediated isothermal amplification (LAMP) reaction with an initial number of DNA strands as low as
45 of a lactam to a thioiminium ion followed by reaction with an organocopper (RCu) reagent and final re
46 as employed in a 2-fold neopentylic coupling reaction with an organolithium reagent derived from the
48 PO) derivatives of variable lipophilicity in reactions with antioxidant Trolox, and as pyrene-fluores
49 ility to additional sulfur incorporation via reaction with aqueous sulfide increased with increasing
51 anes undergo a stereospecific cross-coupling reaction with aromatic halides in the presence of a pall
54 then undergoes nickel-catalyzed substitution reactions with aryl halides and triflates and vinyl brom
58 tion of free diethylnitrosamine, whereas the reaction with azide results in N2O formation; these prod
59 ared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides the cyanoborane derivati
60 (COOLi) and in determining the course of the reaction with bases and alkyl halides 3 are discussed.
61 reactivity as demonstrated in cross-coupling reactions with benzoyl chloride that produce ketones.
63 pable of finding indirectly dead-end-related reactions with biological importance for the target orga
64 generated from the neutral precatalyst upon reaction with Boc2O, is proposed as the catalytically ac
65 tho-substituted 8-aryl BODIPY derivatives by reaction with borontrifluoride etherate, an overall proc
67 n two bottom quarks (b) causes the analogous reaction with bottom quarks () to have a much larger ene
68 oited for multifold C-C coupling cyclization reactions with C-C cleavage using symmetrical bisindolyl
69 s is shown to affect C-N bond scission while reactions with C6Cl4O2 or (tht)AuCl afford formal oxidat
71 ng interphase, which minimizes the corrosion reaction with carbonate electrolytes and suppresses dend
72 elf-assembly of an anticipated hexagram upon reaction with Cd(2+) or Fe(2+); however, unexpected pent
73 to metal carboxylate and methane coproducts, reactions with CdMe2 produce surface bound methyl groups
74 he authors show a reactivation strategy by a reaction with cheap sulfur powder under stirring and hea
76 Family studies, long-range polymerase chain reaction with cloning, and complementary DNA sequencing
78 forming of methane (DRM), two key industrial reactions with common elementary steps and intermediates
79 onalized NPs were radiolabeled via a "click" reaction with copper-64 ((64)Cu)-1,4,7-triazacyclononane
80 ough this Communication focuses primarily on reactions with cyanide as nucleophile, preliminary exper
84 r offers a probe having selective, sensitive reaction with cysteine to rapidly produce a reporter who
89 ining polymers underwent click-type coupling reactions with dialkynes, while the (iso)cyanate-contain
91 catalyst was used in batch aerobic oxidation reactions with different primary alcohols and shown to b
94 For gross adulteration levels (>25.0%, w/w) reaction with diphenylamine-sulfuric acid was found adeq
98 embrane protects the metal against parasitic reactions with electrolyte and, for fundamental reasons,
99 se in the formation of Li dendrites and side reactions with electrolyte components, thus potentially
100 pi-system of benzene is highly resistant to reactions with electron-rich and negatively charged orga
101 ess, copper-catalyzed/mediated C-H amination reactions with electron-rich anilines remain an unsolved
102 of forming stable nonvolatile compounds upon reaction with elemental halogens may partially mitigate
106 1-aza- and 2-aza-derivatives in Diels-Alder reactions with ethylene and fumaronitrile were investiga
109 ns in hydrogen-atom and oxygen-atom transfer reactions, with faster rates corresponding to weaker equ
112 logue to a common fungal metabolite, and its reaction with ferrihydrite and goethite under variable p
115 for secondary covalent cross-linking and for reaction with fluorophores for in vitro and in vivo imag
117 Galp-(1-->6)-d-Glcp are formed from acceptor reactions with free Glc and not by rearrangement of Glc
123 based radical species that accumulate during reaction with H2O2 Our results suggest that catalase-ina
124 en substituents geometrically positioned for reaction with halides in solution, halogen bonding was d
125 n ozone and gaseous elemental mercury due to reactions with halogen atoms, influencing atmospheric co
126 ersible during the catalytic process because reaction with HBpin is faster than beta-hydrogen elimina
127 N-Boc-alpha-amino aldehydes in cross-benzoin reactions with heteroaromatic aldehydes is demonstrated.
128 salts and a tertiary amine base promote the reaction with high site-selectivity for either the 3'-po
129 esulting enzyme catalyses a reversible aldol reaction with high stereoselectivity and tolerates a bro
130 oth Mukaiyama-Mannich and oxocarbenium aldol reactions with high efficiency and enantioselectivity.
133 ver, realization of these goals will require reactions with high specificity and precise control.
134 obtained efficiencies of up to 90% for these reactions with high throughput processing up to 120muL o
135 ly involved in the subsequent C-H activation reactions with hydrocarbon solvents reported for some of
138 heterocycles were converted to C-Si bonds by reaction with hydrosilanes under the catalytic action of
140 l sensitizers and DOM isolates revealed that reactions with hydroxyl radicals dominated the transform
141 l glyoxal loss processes such as photolysis, reactions with hydroxyl radicals, and aerosol uptake wer
142 an oxygen-dependent prolyl hydroxylase (PHD) reaction, with hypoxia-inducible factor alpha (HIFalpha)
143 mplex 3 also forms more crowded complexes in reactions with I2, PhCl, and Al2Me6, which generate (C5M
144 rhodium-catalysed asymmetric Suzuki-Miyaura reaction with important partners including aryls, vinyls
145 f advanced catalysts toward oxygen reduction reaction with improving activity and stability is signif
146 rapped, these molecules can undergo chemical reactions with increased rates and with stereoselectivit
147 atures are that mechanochemistry facilitates reactions with insoluble reactants, enables high-yieldin
148 opper(I) sulfide (Cu2 S) NCs through a redox reaction with iodine molecules (I2 ), which formed vacan
149 ct as an unambiguous nucleophile through its reactions with iodomethane, benzophenone and N,N'-di-iso
151 ever, the integration of a DNA amplification reaction with its associated detection in a low-cost, po
152 ch will be involved in the second pericyclic reaction with juglone to construct the tetracyclic core
154 en which can generate a reactive peroxide by reaction with [KOt-Bu]4 as indicated by density function
156 isubstituted selenourea precursors and their reaction with lead oleate at 60-150 degrees C to form ca
157 e actors, audiences may experience autonomic reactions, with less distance, or may have to distance p
159 f 3.12 and 1.16 the activation energy of the reaction with Lipozyme(R) RM IM and Novozym(R) 435, resp
160 at -70 degrees C is easy to achieve, whereas reaction with lithium-magnesium and lithium-zinc amides
161 um coatings also undergo reversible alloying reactions with lithium ions, facilitating design of high
162 cycloaddition is considered to be a "click" reaction with many applications in chemical biology and
163 hnique to monitor spatially confined surface reactions with mass spectrometry under ambient condition
165 robes are capable of performing amalgamation reactions with metal cations, which avoid unwanted side
166 ications are based on whether the elementary reactions with methane proceed by chain or nonchain reac
167 lar, CHA reactions are defined as elementary reactions with methane that result in a discrete methyl
168 ast, CHO reactions are defined as elementary reactions with methane where the carbon atom of the prod
172 ep to modulate its volume expansion and fast reaction with methylammonium iodide (MAI)/formamidinium
173 rsity of reactions, namely Wittig reactions, reactions with methylene active compounds, formation of
175 ur results illustrate Cr(VI) generation from reaction with Mn oxides within structured media simulati
176 e use of (2-arylcyclopropyl)ethanones in the reactions with model 4-bromophenylhydrazine hydrochlorid
180 F performs a sequential ordered bi-substrate reaction with MVAPP as the first substrate, consistent w
181 ound to exhibit aromatic C-H activation upon reaction with N,N-diethylaniline, naphthalene, and even
182 N-monochlorovaline, with a slower subsequent reaction with N-monochlorovaline to form N,N-dichloroval
183 ical species acts as an intermediate in this reaction, with NADH and NADPH (the reduced forms of nico
186 results point to HAT as implausible for the reaction with nitric oxide radical in all the solvents i
187 yrrolidines were synthesized by 1,4-addition reactions with nitroalkanes, followed by reduction and c
188 itu, is exemplified by dipolar cycloaddition reactions with nitrones to give highly substituted 4-nit
190 hetero)aromatic amines-essentially a one-pot reaction with no isolation of intermediates; (ii) the al
194 e resulting eta(2)-arenium species undergoes reactions with nucleophiles at the adjacent meta carbon.
196 meaningful exposures focuses on adducts from reactions with nucleophilic loci of blood proteins, part
197 e 3 featuring a Si=O-->B interaction through reaction with O2 , N2 O, or CO2 , and formation of silan
199 ropose that the partial reversibility of the reaction with O2 results from the four-electron reductio
200 functions as the sensory module, undergoing reaction with O2 that leads to conversion to a [2Fe-2S]
203 widely used herbicide, and its heterogeneous reaction with OH radicals is important for assessing its
206 es photodegradation by direct photolysis, by reactions with (*)OH and CO3(*-), and possibly also with
207 hoton-generated cyclooctynes undergo a SPAAC reaction with organic azides, yielding the expected tria
209 etection limit of 60ng/ml and shows no cross-reaction with other analogous organophosphates or metal
211 in a GSH and GSSG mixture via a 1,4-addition reaction with p-benzoquinone (BQ), followed by enzymatic
214 ypes of reactive species involved in primary reactions with PFOA showed that hydroxyl and superoxide
215 mples demonstrating such selectivity include reactions with: phenolics, through dearomatizing ortho-s
216 re pyrrolidine-based carbonate was used, the reaction with phenols proceeds via a bicyclic aziridiniu
218 olkit and the frequent failure of even these reactions with polar and functionalized substrates.
219 sign principles for programmable biochemical reactions with potential applications to autonomous sens
220 negative charge at the oxygen end that upon reaction with PPh3 and benzoic acid afford Ph3P horizont
223 and [IMesH][C14H8O2B(C6F5)2] (12), while the reactions with quinuclidine and DMAP afforded the specie
225 Anaphylaxis is a serious systemic allergic reaction with rapid onset and potentially life-threateni
226 f iron oxide particles as a result of either reaction with reducing moieties, light-mediated ligand t
228 N3-Methyladenine (3-MeA) is formed in DNA by reaction with S-adenosylmethionine, the reactive methyl
236 ute configuration was determined by chemical reactions with sodium borohydride, hydrogen peroxide, al
237 led that radical mechanisms are preferred in reactions with sterically hindered coupling partners wit
238 outliers to the Bronsted correlation are the reactions with sterically hindered pyridines, which appa
239 tion between neutral and anionic phases upon reaction with stoichiometric amounts of halide or pseudo
243 ttributed to direct electron transfer and to reactions with surface-bound reactive chlorine species.
244 the free energy DeltaG degrees PCET for the reaction with TEMPO (-48.4 kJ mol(-1)) are very similar
246 eduction to the corresponding aldehydes, and reaction with tert-butyl (triphenylphosphoranylidene)ace
247 trofurans undergo intramolecular Diels-Alder reactions with tethered electron-poor dienophiles more r
248 2 + 2] cycloaddition-retroelectrocyclization reaction with tetracyanoethylene (TCNE) and 7,7,8,8-tetr
254 erent rates: kobs1, which corresponds to its reaction with the deprotonated form of the substrate, an
255 iron(II)-SciOPP complexes are consumed upon reaction with the electrophile with concomitant generati
256 an forge interstrand DNA-DNA cross-links via reaction with the exocyclic amino group on a nearby 2-de
257 etention of oscillatory behavior for the B-Z reaction with the formation of giant vesicles bring a ne
260 g CPP precursor was used for the Diels-Alder reaction with the parent benzyne or 3,6-dimethoxybenzyne
261 bstrate, and kobs2, which corresponds to its reaction with the protonated form of the substrate.
262 oxidative removal of Mn(II) from solution by reaction with the reactive oxidant species produced thro
264 ng a regio- and stereoselective oxyamination reaction with the same nitrene reagent generated in stoi
265 omplex of a ligand-centered radical, whereas reaction with the stronger oxidant AgBF4 formed the meta
266 the release of phenylalanine amino acid in a reaction with the yeast enzyme of phenylalanine ammonia
267 AA caused by chlorine follows a second-order reaction, with the rate constant k1 is 5.0 x 10(4) M(-1)
269 substituted alkenes through cross-metathesis reactions with the commercially available, inexpensive a
273 s for the design of new amide cross-coupling reactions with the N-C(O) amide bond cleavage as a key s
274 has inspired original methodologies to probe reactions, with the aim to rationalize unknown mechanism
275 is and low-temperature water-gas shift (LTS) reactions, with the choice of precursor phase strongly i
276 followed by a description of stoichiometric reactions, with the competition between the C-H and C-F
277 been available on early Earth from prebiotic reactions, with the goal of making the model less discon
278 ides and aliphatic carboxylic acids based on reactions with TMMS and one or two CAD experiments.
281 a key role in atmospheric chemistry through reactions with trace species that can lead to aerosol pa
284 r substrate radicals was observed during the reaction with Trp or any molecule within a tested panel
285 ilms that are powered by DNA strand exchange reactions with two different domains that can respond to
286 can participate in 1,3-dipolar cycloaddition reactions with two maleimides that differ in the relativ
289 o decades, the demand for new chemoselective reactions with unique abilities, and those compatible wi
291 about the formation of CO2 adducts from its reaction with various amine-functionalized SBA-15 contai
292 without cleavage of the 1,2,3-dithiazole by reaction with various nucleophiles, giving access to 4-[
294 Compound 6 can be used directly in SN2@P reactions with various nucleophiles to yield valuable P-
295 indicate that carbamates can undergo direct reactions with various radical species, oxidizing themse
296 amine-squaramide catalyzed C-C bond forming reactions with vinyl ketones or Morita-Baylis-Hillmann-t
297 lar ratios of >/=0.3, effectively eliminates reaction with water, but retains significant reactivity
299 hiral ligands for transition-metal-catalyzed reactions with well-defined reaction mechanisms but mult
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