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1 plete or partial thermal isomerization via a rearrangement reaction.
2 ould act as general acid-base catalysts in a rearrangement reaction.
3 s that are converted to imines via a Beckman rearrangement reaction.
4 antly to the lowering of the barrier for the rearrangement reaction.
5 tion but has little effect on the subsequent rearrangement reaction.
6 amolecular Mitsunobu, and tandem epoxidation/rearrangement reactions.
7 -addition reactions, and in some cases, ring rearrangement reactions.
8 strand refolding is a novel mechanism in DNA rearrangement reactions.
9 rsity of 5'-deoxyadenosylcobalamin-dependent rearrangement reactions.
10 es mediate a wide range of important genetic rearrangement reactions.
11 uring the hydrogen atom transfer and radical rearrangement reactions.
12 lsilyl groups for product formation in these rearrangement reactions.
13 s facilitating disulphide bond formation and rearrangement reactions.
14 f the p-terphenyl systems was susceptible to rearrangement reactions.
15 nd of the cofactor, leading to radical-based rearrangement reactions.
16 tions and appear to reflect isomerization or rearrangement reactions.
17 l insights into how enzymes catalyze complex rearrangement reactions.
18 asymmetric Pauson-Khand reaction, an Overman rearrangement reaction, a ring-closing metathesis reacti
19 f the route outlined herein include specific rearrangement reactions and a retro-aldol cleavage of ri
20 sound, and that this allows us to accelerate rearrangement reactions and bias reaction pathways to yi
21 evidenced by their formal [1,3]-sigmatropic rearrangement reactions and the rapid additions of oxyge
22 e ratio can be operated such that structural rearrangement reactions and/or CID are achieved as a fun
24 ange from ligand release to isomerization or rearrangement reactions at high urea concentrations.
25 boron compounds are readily synthesized via rearrangement reactions between Lewis acidic B(C6F5)3 an
26 lations that predict rate enhancement of the rearrangement reaction by the interaction of the migrati
27 Here we report that the complex cyclization/rearrangement reaction catalyzed by abietadiene synthase
29 of a cascade click cycloaddition and a ring rearrangement reaction, followed by a reductive step.
30 en atom, thereby retarding the ring cleavage/rearrangement reaction generally encountered with relate
32 0'Rxn, were determined for the net reduction/rearrangement reaction, His82-Fe3+-His18 + e- --> Met80-
35 tions change little during the course of the rearrangement reaction, in contrast to the large conform
37 example of a biocatalytic [2,3]-sigmatropic rearrangement reaction involving allylic sulfides and di
41 Under these conditions, no strain-induced rearrangement reactions occur, delivering p-phenylene un
42 rithm is able to cope with general molecular rearrangement reactions occurring during EI in GC/MS mea
43 to occur via the facile and reversible F/Ph rearrangement reaction of 1 to cis-[(Ph(3)P)(2)Rh(Ph)(Ph
45 es is reported through a Lewis acid mediated rearrangement reaction of enol ethers bearing an Co-alky
47 formed from the tandem cyclopropanation/Cope rearrangement reaction of vinylcarbenes with dienes.
51 The mechanisms of the BF3-catalyzed Meinwald rearrangement reactions of five epoxides in dichlorometh
53 controlled cyanate-to-isocyanate sigmatropic rearrangement reactions of the corresponding allyl carba
54 This process is followed by acid-promoted rearrangement reactions of the formed homoallenic halohy
56 ed by sare1259, catalyzes multiple oxidative rearrangement reactions on 34a-deoxyrifamyin W to yield
57 ochemically complementary to related Claisen rearrangement reactions--processes that typically delive
58 2)-fold slower rate of the substrate radical rearrangement reaction relative to k(obs), and the rever
59 n "short circuit" complex cyclization and/or rearrangement reactions, resulting in the production of
61 hemical models consistent with each of these rearrangement reactions that account for the formation o
62 a- and beta-thujone can undergo two distinct rearrangement reactions that could, in principle, serve
63 ondary amines, undergo a fascinating thermal rearrangement reaction to afford Z-alpha,beta,gamma,delt
64 owers the propensity for the photo-Favorskii rearrangement reaction to occur and opens the reaction p
65 se subsequently undergo phospha-Claisen type rearrangement reactions to give the respective substitut
66 The sulfonamide 4c predominantly undergoes a rearrangement reaction under acidic and neutral conditio
67 ergo the combined C-H functionalization/Cope rearrangement reaction via an s-cis/boat transition stat
68 An enantioselective alkoxylation/Claisen rearrangement reaction was achieved by a strategic desym
70 ing materials by Lewis acid induced skeletal rearrangement reactions was studied under stable ion con
73 g the course of these studies, several novel rearrangement reactions were encountered while attemptin
74 in a tandem ammonium ylide generation/[2,3]-rearrangement reaction, which formally represents a pall
75 and photolytic cycloaddition/1,5-sigmatropic rearrangement reactions with 11a-d with N(2) retention t
76 he conversion of DHHA to PCA, probably via a rearrangement reaction yielding the more reactive 3-oxo
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