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1 steep gradients in solute concentrations and redox potential.
2 ing Cd(II) as this metal has a more negative redox potential.
3 s complex displayed a lower and irreversible redox potential.
4 for free and Brine Releasable (BR) VSCs and redox potential.
5 , and pheomelanin possesses a more oxidative redox potential.
6 of matrix superoxide/H2O2 production at this redox potential.
7 heir flexibility in tuning the Fe(3+)/Fe(2+) redox potential.
8 cathepsins through modulation of the lumenal redox potential.
9 ts oxidation level into large changes in its redox potential.
10 ified susceptible neurons by their increased redox potential.
11 esidues in the gamma subunit influence thiol redox potential.
12 ata to calculate their Gibbs free energy and redox potential.
13 gical agents modulating mitochondrial pH and redox potential.
14 , the concentrations of ions, the pH and the redox potential.
15 (-1) s(-1), respectively, and correlate with redox potentials.
16 olor changes, is achieved by tuning external redox potentials.
17 itu determination of reduced ZnO nanocrystal redox potentials.
18 l straddle the water oxidation and reduction redox potentials.
19 d water, with respect to vacuum and to water redox potentials.
20 nment between the solid band edges and water redox potentials.
21 presence of Sec is not tied to unusually low redox potentials.
22 while allowing sensitivity to drugs with low redox potentials.
23 3)6(3+) and Fe(CN)6(3-), which have resolved redox potentials.
24 aid in the detection of molecules with high redox potentials.
25 resulting catalysts, when exposed to extreme redox potentials.
26 l radicals, as well as their electrochemical redox potentials.
27 bit relatively low solubility and inadequate redox potentials.
28 duce multiple bonds without unreasonably low redox potentials.
29 ommunity compete for hydrogen in soil at low redox potentials.
30 n CH3CN), multiple electron transfers at low redox potentials (-1.7 and -1.9 V versus Ag/Ag(+)), and
31 OleTJE heme iron has an unusually positive redox potential (-103 mV versus normal hydrogen electrod
32 ed similar affinities for Cu(2+) (12-31 nM), redox potentials (242 and 251 mV), and electron paramagn
33 d the relationship between mitochondrial pH, redox potential, [2Fe-2S] clusters and Fech activity, we
34 st specific capacity (3861 mAh/g) and lowest redox potential (-3.04 V vs standard hydrogen electrode)
37 ysis to a shift in the distal [Fe4S4](2+/1+) redox potential, a previously experimentally inaccessibl
38 rategies the most important properties, i.e. redox potentials, absorption and emission maxima or fluo
39 pplied potentials are believed to affect the redox potential across the cell membrane and disrupt red
43 thereby anodically shifting the metal ion's redox potential and (ii) optimizes the bond strength bet
44 py, and 3) nicotinamide adenine dinucleotide redox potential and adenosine triphosphate/adenosine dip
46 sing roGFP2 and HyPer showed a rapid loss of redox potential and an increase in H2O2 of mitochondrial
50 drenocortical cell line resulted in impaired redox potential and increased reactive oxygen species (R
52 ated with an oxidising shift in the GSSG/GSH redox potential and is inhibited by the antioxidants ebs
54 alysis and established relationships between redox potential and O2-adsorption strength, we conclude
56 igration, while soil characteristics such as redox potential and surface salinity developed later in
58 erenol (0.1 muM) decreased the mitochondrial redox potential and the ratio of reduced to oxidated glu
59 e result of a clear correlation between heme redox potential and the strength of electronic coupling
60 he modified ATP synthase has a more reducing redox potential and thus remains predominantly oxidized
61 is thought to be crucial for maintenance of redox potential and vitality of the cell but is poorly u
64 st-principles calculations of proton-coupled redox potentials and magnetizations reveal that the Ni-o
65 lustrate structural effects on their various redox potentials and on the p Ka values of the correspon
67 APBA; however, the binding did not alter the redox potentials and the apparent diffusivities of ions.
68 lems caused by energy mismatch between water redox potentials and the band edges of hematite and many
69 s between these binding modes modulate the Q redox potentials and the rate of electron transfer (eT)
70 ation by peak cU(aq), we reanalyzed measured redox potentials and total concentrations of aqueous ura
71 omposition, (iii) reducing agent, (iv) metal redox potential, and (v) addition of surfactants for con
72 lts for the number of electrons transferred, redox potential, and diffusion coefficient are in good a
73 e from this system feature very high pH, low redox potential, and low ionic concentrations, making it
75 ity, defects in neuronal function, decreased redox potential, and reduced numbers of presynaptic mito
77 and the effect of sorbent concentration, pH, redox potential, and the sulphite and iron content of th
78 be converted into each other by changing the redox potential, and this redox switch caused a major al
79 tudies of the ground electronic state (GES), redox potentials, and C-H amination of [Rh2(II,III)(O2CC
80 Cu(II) as these metals have relatively high redox potentials, and microbial electrolysis cells for r
81 PeT + w) values from experimentally measured redox potentials, and validate the voltage sensitivities
82 , between the pro-oxidant parameters and the redox potentials, antioxidant capacities and lipophilici
83 ) ), this Mn-oxide is predicted to show high redox potentials ( approximately 4.2 V vs Na/Na(+) ) wit
86 ve as the reservoir for electrons, but their redox potentials are tuned by the choice of ligand at Mn
87 ations indicate that both UQ and MQ have low redox potentials around -260 and -230 mV, respectively,
90 ed to be a consequence of increased cellular redox potential as judged by an elevated ratio of oxidiz
91 e NAD(+) or NADH at about the same operating redox potential as the NADH/NAD(+) pool and comprise the
93 o has a significant impact on Co(III)-Co(IV) redox potential, as revealed by the change in the lithiu
95 hondrial metabolic potential and an abnormal redox potential, associated with reduced nicotinamide ad
97 king at physiological or neutral pH, the GOx redox potentials at pH 7.4 and pH 7.0 are of main intere
98 the redox couple, the OCP deviates from the redox potential because of additional background half re
100 hors show that cobalt moieties have a higher redox potential, bind oxygen more weakly and are less ac
101 for measuring the intracellular glutathione redox potential by direct and quantitative measurement o
102 polymers (Os-EDPs) with specifically adapted redox potential by means of chemical co-deposition.
104 cannot be explained in terms of distance or redox potential change between donor and acceptor but in
105 tion state of the polymer, in the absence of redox potential change, resulting in increased emission.
106 terrestrial environments subject to periodic redox potential changes such as peatlands, marshes, and
107 pecies within this group, we identified that redox potential changes with diet and is the main factor
108 This is similar to isolated catalyst 2, with redox potentials comparable to the [-Ru(b)-OH(2)](2+) si
112 en spectroscopically characterized and their redox potentials, determined by cyclic voltametry, revea
113 ties, i.e., its (electro)chemical stability, redox potential, diffusion coefficient and the influence
115 stic conductance, determine the shift in the redox potential due to mechanical stretching of the meta
117 ents of photon capture, electron fluxes, and redox potentials during photosynthesis cause reactive ox
119 20H2), a stronger reductant with a mid-point redox potential (E'0) of -360 mV; E'0 of NAD(P)H is -320
121 roGFP-based specific bioprobe of glutathione redox potential (E(GSH); Grx1-roGFP2) and measured subce
122 end of the basin, anomalies in water column redox potential (E(h)) were detected close to the seaflo
124 allow the quantification of the glutathione redox potential (EGSH) in the cytoplasm and the mitochon
126 tammetry, where several parameters including redox potential, electron transfer rate, and surface cov
128 I (NADH:ubiquinone oxidoreductase) uses the redox potential energy from NADH oxidation by ubiquinone
129 tailored to be responsive to pH variations, redox potential, enzymatic activation, thermal gradients
131 e examples reveals that solvent, spin state, redox potential, external co-reductants, and ligand arch
132 n-SOD, interacts with Cu(2+), which provides redox potential for catalytic removal of O2[Symbol: see
133 ely 1 nM; from the experimentally determined redox potential for CBP21-Cu(2+) of 275 mV using a therm
135 ated Cu(II) ATSM-F3 displays the appropriate redox potential for selective accumulation in hypoxic ce
136 ere measured that reveal that changes in the redox potential for the Cu(III)/Cu(II) couple are only p
139 he strong oxidant diamide, implying that the redox potential for the thiol/disulphide transition in g
141 ot only to a much broader range of available redox potentials for the resulting phenanthro[9,10-d]imi
143 compounds have been examined, and reversible redox potentials have been compared with results obtaine
147 hile either the macrophyte or SMFC increased redox potential in sediments, redox potentials near the
148 ted potent antiproliferative activity having redox potentials in a range accessible to biological red
149 sing the pKa values and Ni(II/I) and Ni(I/0) redox potentials in a thermochemical cycle, the free ene
150 "sets" signaling at distinct, nonoverlapping redox potentials in support of multiplexing and error co
151 o [4Fe-4S] clusters adjacent to the Cbl have redox potentials in the range expected for Cbl reduction
153 oredoxin)-based buffers regulate the ambient redox potentials in the various intracellular compartmen
154 al expansion" (i.e., a further separation of redox potentials) in single-pyridinium EPs (4, 5), where
155 xplicit solvation into account and show that redox potentials increase over the whole range of forces
156 risons reveal that for C-terminal motifs the redox potentials increased between 20-25 mV when the sel
157 A comparison of calculated acidities and redox potentials indicates that pyridinium cations behav
158 d 4-chlorobenzonitrile, having two different redox potentials indicates that the reaction does not in
159 ce in driving force is opposite the trend in redox potentials, indicating that basicity is a key fact
163 sors, which however do not allow quantifying redox potentials, lack specificity, and the possibility
164 edox states, precise control of a molecule's redox potential, leading to a single output voltage in a
165 se complexes, the phosphonate groups provide redox-potential leveling through charge compensation and
166 nformation and oxidation state in catalysis, redox potential modulation of the metal site, and cataly
167 SMFC increased redox potential in sediments, redox potentials near the anode (approximately 6 cm dept
169 vious approaches to measuring the biological redox potential noninvasively in real time are limited t
175 logical effects are consistent with the high redox potential of 5-Me-PCA, which distinguishes it from
176 eveals that a mechanical force can shift the redox potential of a molecule, change its redox state, a
177 he position of the wave is determined by the redox potential of a redox relay when intramolecular ele
179 AHSP binding also dramatically reduces the redox potential of alpha-subunits, from +40 to -78 mV in
180 , through a mechanism that also involved the redox potential of catechins to maintain l-5-MTHF in its
182 lly favorable reaction, with a less negative redox potential of CoxB (E'0 = -231 mV) as compared with
187 We provide information on how changes in the redox potential of either reaction partner significantly
188 lla oneidensis could potentially control the redox potential of environments relevant to the geologic
190 ion in M. oryzae, we measured the amount and redox potential of glutathione (E(GSH)), as the major cy
193 DeltaEm_b can be markedly increased, and the redox potential of one of the hemes can stay above the l
194 ulted in higher oxidative shift in mycothiol redox potential of PknG mutant compared with the wild ty
195 which is much higher than the thermodynamic redox potential of SmI2(H2O)n determined by electrochemi
196 s of L2 results in significant shifts in the redox potential of the [2Fe-2S] cluster and orders of ma
197 dentified based on the Bronsted basicity and redox potential of the active site, explaining the chang
198 electronics, where careful attention to the redox potential of the backbone relative to the organic
199 uctive half-reaction and have determined the redox potential of the bound flavin to be -123 +/- 7 mV.
200 proposed manner in which CobA increases the redox potential of the cob(II)alamin/cob(I)alamin couple
201 and might play a key role in adjusting a low redox potential of the FADH(*)/FAD pair required for fer
202 Fc(+) and adsorbed Fe(II) increases with the redox potential of the ferrocene derivative, as expected
203 undamental parameters were obtained: (i) the redox potential of the haem-containing centre of the enz
204 NAD(+), total NAD contents, and NAD(+)/NADH redox potential of the healthy human brain were revealed
205 tions at these residues are sensitive to the redox potential of the internal solution, providing evid
206 The charge separation is directed by the redox potential of the involved bases and thus controlle
208 shell control the catalytic activity via the redox potential of the metal oxide and of the OCl(-).
211 the 'OFF' state, and show that the mid-point redox potential of the redox switch affords it sensitivi
212 group to a histidine nitrogen positions the redox potential of the tyrosine between those of P680(*+
213 d to confirm that the membrane potential and redox potential of the ubiquinone pool could be measured
214 ectron transfer reactions, yet the effective redox potential of these powerful reductants has not bee
217 thalpies, free energies of reaction, and the redox potentials of Ar-X/Ar-H couples, were investigated
220 en shown to have a significant effect on the redox potentials of compounds such as 1,4-dinitrobenzene
221 ey to rechargeability lies in exploiting the redox potentials of Cu to reversibly intercalate into th
222 t was then calculated from the difference in redox potentials of cytochrome c and ubiquinone pool usi
223 nd an excited fluorophore is governed by the redox potentials of each moiety according to a Rehm-Well
227 can be explained by differences in predicted redox potentials of PSII electron acceptors that control
228 erns the motifs' reactivity, we measured the redox potentials of Sec-containing motifs and their corr
230 olecular dynamics simulations to compute the redox potentials of the 10 hemes of MtrF in aqueous solu
232 terconversion of succinate and fumarate, the redox potentials of the biologically available ubiquinon
233 into how the intervening protein matrix and redox potentials of the electron donor and acceptor dete
234 Further, DFT-based investigations of the redox potentials of the Li-bound quinone derivatives pro
236 ive force while simultaneously measuring the redox potentials of the NADH/NAD(+) and ubiquinol/ubiqui
238 fine-tuning of the electronic properties and redox potentials of the photocatalyst in both the excite
239 ndependent of material and controlled by the redox potentials of the photogenerated charge carriers,
240 l selection by LOX and the adjustment of the redox potentials of their protein-bound catalytic metals
245 aluated the dependency of a disulfide bond's redox potential on a pulling force applied along the sys
246 dency of the reduction mechanism and the GOx redox potential on the presence of halides, especially o
247 nstant, regardless of the proteins' in vitro redox potentials or their putative positions in the aero
249 tumor microenvironment like low pH, elevated redox potential, over-expressed enzymes and hyperthermia
251 NN up to 172 cm(-1)), decreases the Fe(0)-N2 redox potential, polarizes the N-N bond, and enables -N
253 y designed to target different areas of this redox potential range and are monitored by surface-enhan
254 f -470 to +130 mV vs NHE, which includes the redox potential range occupied by cells in a state of ox
255 racellular nanosensors to cover a much wider redox potential range of -470 to +130 mV vs NHE, which i
256 re synthesized and the respective Ru(II/III) redox potentials (ranging from DeltaE = +0.46 to +1.04 V
257 ere, we tested whether cytosolic NADH/NAD(+) redox potential regulates NCX activity in adult cardiomy
259 d organs can be ischemic, the measurement of redox potential (RP) in blood serum reflects the prooxid
260 2 (TRPM2) channel is known to be a cellular redox potential sensor that provides an important pathwa
261 which reports at a distinct, nonoverlapping redox potential, serving as a drift-correcting reference
262 to the bioreactor, that is, by maintaining a redox potential set-point value, appeared to be ineffect
263 lculated affinity change associated with the redox potential shift observed for [4Fe4S] cluster prote
264 Ga(Sbx)N1-x are found to straddle the water redox potentials showing excellent suitability for solar
265 old constitute reference electrodes having a redox potential similar to that of Ag/AgCl in physiologi
268 show that slow oscillations in mitochondrial redox potential stimulated by 10 mm glucose are in phase
269 he same exposed Trp-164 responsible for high redox potential substrate oxidation (as shown by activit
271 ed to differentiate species with overlapping redox potentials, such as dopamine/Fe(CN)6(3-) and ferro
272 ristic sigmoid plots when represented versus redox potential suggesting that all changes are the resu
275 mation of a single disulfide bond with a low redox potential that can be efficiently reduced by the N
277 lytes) with the necessary combination of (1) redox potentials that exceed the potential limits of wat
278 ctroscopic determination of the one-electron redox potentials that have been difficult to establish v
280 Binding of ligands to iron modifies its redox potential, thereby permitting iron to transfer ele
281 ion of free radicals from energy stored in a redox potential through a 2e(-)/1H(+) transfer process,
282 m of NCX regulation by cytosolic NADH/NAD(+) redox potential through a ROS-generating NADH-driven fla
283 obial metabolism markedly reduces gut pH and redox potential through the production of short-chain fa
284 he Mn(IV) at site 1 is necessary to tune the redox potential to a value similar to that of the tyrosi
285 forces to be likely to tune the disulfide's redox potentials to an extent similar to the tuning with
286 stors, the electrical/optical "dual-function redox-potential transistors", which is solution processa
287 tive to glycation, albumin concentration, or redox potential, unlike other methods to quantify HSA-bo
288 jury, and in situ mapping of the hepatic GSH redox potential using a redox-sensitive green fluorescen
289 sed dyes by nine ferrocene derivatives whose redox potentials vary by 0.85 V, resulting in 54 differe
290 receptor, Aer, monitors cellular oxygen and redox potential via FAD bound to a cytosolic PAS domain.
291 on of glycolytic ATP production and cellular redox potential via HDAC3-mediated PGK1 deacetylation.
293 catalytic activity were maintained, and its redox potential was reduced modestly by 20 mV possibly d
294 a variety of aryl halides, and, owing to its redox potential, was found to be the first organic donor
296 O2 exceptional availability and high O2/H2O redox potential, which may in particular allow highly en
297 and do not follow the trend in one-electron redox potentials, which appear to dominate HAT reactivit
299 the entropic and enthalpic contributions to redox potentials with Q and with the identity and hydrop
300 nt enzymes to ROS scavenging and glutathione redox potential within each intracellular compartment.
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