ライフサイエンスコーパス: reductive

1 cation, sulfate respiration, methanogenesis, reductive acetogenesis and anoxygenic phototrophy.

2 lide respiration, methanogenesis and H2 /CO2 reductive acetogenesis.

3 Methanogens and reductive acetogens correlated with detrital volume and

4 Our results reconcile the required reductive activation of a metal hydride and the resistan

5 Upon reductive activation, they cleave the substrate and prom

6 rs H2O2-dependent Bip oxidation through Ero1 reductive activation, which inhibits glutathione import

7 nsfer (PCET) reactions, (v) SOD activity and reductive activity toward both oxygen and superoxide, an

8 posed of Fe(0) and Cu(0), and exhibited good reductive activity toward Cr(VI).

9 amples were further subjected to Accelerated Reductive aging (AR) and analyzed for free and Brine Rel

10 This enantioselective reductive alkenylation proceeds under mild conditions an

11 copper-catalyzed azidation or amination and reductive alkylation of benzylazide by a helicenyl dichl

12 we developed this concept by performing the reductive alkylation reaction in monolayer CVD graphene

13 The reductive aminase from Aspergillus oryzae (AspRedAm) was

14 report the discovery of an NADP(H)-dependent reductive aminase from Aspergillus oryzae (AspRedAm, Uni

15 cells primarily assimilated ammonia through reductive amination catalyzed by glutamate dehydrogenase

16 Reductive amination chemistry was used to synthesize all

17 The asymmetric ruthenium-catalyzed reductive amination employing ammonia and hydrogen to pr

18 Reductive amination is one of the most important methods

19 The highly efficient and direct asymmetric reductive amination of arylacetones catalyzed by an irid

20 monstrated through a deprotection and double-reductive amination sequence to give 4,5,6,7-tetrahydrop

21 four garlic organosulfur compounds (OSCs) by reductive amination with (13)C, D2-formaldehyde, and dev

22 e, we immobilized glycoproteins on resin via reductive amination, modified alpha2,6-linked sialic aci

23 e bond formation, Suzuki cross-coupling, and reductive amination, the Buchwald-Hartwig-Ullmann-type a

24 ormaldehyde and sodium cyanoborohydride, the reductive amination-based method can be utilized to gene

25 A sequence of oxidative cleavage/reductive amination/reductive cleavage enables the prepa

26 ation on an aldehyde-active solid support by reductive amination; (ii) stabilization of fragile siali

27 We also demonstrate preparative scale reductive aminations with wild-type and Q240A variant bi

28 intramolecular bisboronate homocoupling and reductive aromatization by H2 SnCl4 .

29 efficient and versatile palladium-catalyzed reductive azo cleavage is disclosed for the synthesis of

30 This method is based on adsorptive/reductive behaviour of ETTA at an in situ plated bismuth

31 e use of the present bimetallic scaffold for reductive bioinspired activation of a range of inert sma

32 lkaline conditions (pH approximately 12) and reductive C-Cl bond cleavage by cast zerovalent iron, Fe

33 oup has been developed that allows catalytic reductive C-H silylation of sterically hindered phenols.

34 Such a pathway precedes CO2 fixation via the reductive C1 metabolic pathway in C. thermocellum These

35 ctor and through its ability to catalyze the reductive carbon-carbon coupling of small carbon compoun

36 ovides a distinct advantage over traditional reductive carbonylation in that no carbon monoxide, pres

37 amine to generate citrate and lipids through reductive carboxylation (RC) of alpha-ketoglutarate (alp

38 ched TCA cycle, in which glutamine-dependent reductive carboxylation cooperates to the production of

39 Loss of reductive carboxylation disrupts redox balance and incre

40 The capacity for reductive carboxylation in RPE exceeds that of all other

41 tive damage, suggesting that deficiencies of reductive carboxylation may contribute to RPE cell death

42 lysis can provide carbon for anaplerosis and reductive carboxylation to citrate.

43 s cycle, proline is used to make citrate via reductive carboxylation.

44 Cs and contributes to lipid biosynthesis via reductive carboxylation.

45 leus must downscale in size with progressive reductive cell divisions.

46 Three different red wines with reductive character have been treated with two different

47 t-range charge-transfer processes, including reductive charge shift reactions between the two electro

48 ric oxide metabolites measured by tri-iodide reductive chemiluminescence.

49 We expect that this biocompatible reductive chemistry will be broadly useful to practition

50 ce of oxidative cleavage/reductive amination/reductive cleavage enables the preparation of N-substitu

51 H-bonding interaction as a prerequisite for reductive cleavage is highlighted.

52 ition of Fc* (2 equiv overall required), O-O reductive cleavage occurs, giving water, Fe(III), and Cu

53 lation of arenes and heteroarenes as well as reductive cleavage of C-O bonds in aryl ethers and C-S b

54 Nitrogenase enzymes mediate the six-electron reductive cleavage of cyanide to CH4 and NH3 .

55 r reducing conditions that would promote the reductive cleavage of SAM, 6-CP is turned over to 6-deox

56 ich use a reduced [4Fe-4S] cluster to effect reductive cleavage of the 5' C-S bond of SAM to form a 5

57 dase enzymes, includes the critical O-O bond reductive cleavage step.

58 to form an oxa-osmacyclopentane, which upon reductive cleavage via hydrogen transfer from the second

59 hese lignins upon derivatization followed by reductive cleavage, a degradative method that cleaves be

60 Tafel analysis suggests reductive CO coupling as a rate determining step for C2

61 Reductive condensations of alcohols with aldehydes/keton

62 , Uniprot code Q2TW47) that can catalyse the reductive coupling of a broad set of carbonyl compounds

63 and, diisophosphaethynolate, is reported via reductive coupling of a Sc-OCP precursor.

64 le light photoredox-catalyzed beta-selective reductive coupling of alkenylpyridines with carbonyl or

65 reduction of electron-poor olefins, and the reductive coupling of benzyl bromide via photoredox cata

66 by SEGPHOS catalyze the 2-propanol-mediated reductive coupling of branched allylic acetates 1a-1o wi

67 report a mechanistic investigation into the reductive coupling of CO, which provides new fundamental

68 ylzinc iodides were prepared by Fe-catalyzed reductive coupling of terminal arylalkynes with alkyl io

69 dox-assisted catalytic system for the direct reductive coupling of two carbon electrophiles.

70 nsymmetrical alkenes from the intermolecular reductive coupling of two different aldehydes is describ

71 on is hyponitrite (N2O2(2-)), the product of reductive coupling of two NO molecules.

72 We report the first reductive coupling of unactivated alkenes with N-methoxy

73 as a more robust catalyst for regioselective reductive coupling of ynoates and aldehydes with triethy

74 and class, nickel-catalyzed enantioselective reductive coupling reactions of aldehydes and alkynes ha

75 biological iron and/or copper mediated NO(g) reductive coupling to give N2O(g) is discussed.

76 Related 2-propanol mediated reductive couplings also are described.

77 Here, we review catalytic intermolecular reductive couplings of unactivated and activated olefin-

78 g-term study, aquifer sediments subjected to reductive Cr(VI) immobilization under different biogeoch

79 An asymmetric Ni-catalyzed reductive cross-coupling has been developed to prepare e

80 An asymmetric Ni-catalyzed reductive cross-coupling of (hetero)aryl iodides and ben

81 A Ni-catalyzed reductive cross-coupling of styrenyl aziridines with ary

82 This reductive cross-electrophile coupling is the first to us

83 The stereospecific reductive cross-electrophile coupling reaction of 2-viny

84 was an unprecedented NaBH4-promoted one-pot reductive cyclization cascade that efficiently yielded a

85 lation was accompanied by diastereoselective reductive cyclization in situ; reductive N-methylation t

86 is based on the quantitative intramolecular reductive cyclization of an oligo(diyne) with a low-vale

87 e natural products 2-7 have been prepared by reductive cyclization of the relevant 2-arylcyclohex-2-e

88 Nickel-catalyzed reductive cyclization of this alkynylaldehyde, to constr

89 aminoketyl radicals can undergo reduction or reductive cyclization pathways, providing a powerful met

90 iodo-2-cyclohexen-1-one, engaged in a tandem reductive cyclization process upon exposure to hydrogen

91 A cross-coupling/reductive cyclization protocol has been employed in a un

92 ne 4, the product of a Raney-cobalt mediated reductive cyclization reaction, was readily converted in

93 Mechanistic studies of the reductive cyclization suggest a hydride insertion pathwa

94 e enantiomeric C12-fragment (R)-30 underwent reductive cyclization to provide the desired product in

95 4-phenylbut-2-enoate and diastereoselective reductive cyclizations of gamma-amino ketones as the key

96 In reductive cycloaromatization reactions, such crossings d

97 eoisomerization, oxidation, dehydrogenation, reductive debromination, and ring opening.

98 ment based on Dehalococcoides mccartyi (Dhc) reductive dechlorination activity remains a cornerstone

99 diment column indicating that both anaerobic reductive dechlorination and aerobic degradation occurre

100 ulfate, C-Cl bond cleavage in Fe(0)-mediated reductive dechlorination and E1CB elimination mechanism

101 Inhibition by acetylene of reductive dechlorination and methanogenesis in the enric

102 Both nucleophilic substitution and reductive dechlorination are the proposed mechanisms for

103 Here, we show that reductive dechlorination by a methanogenic, mixed cultur

104 (17 +/- 2 and 13.0 +/- 0.8, respectively) vs reductive dechlorination by Fe(0) (8 +/- 2) establish a

105 ic vs metabolic) and their interactions with reductive dechlorination in relation to riverbed sedimen

106 the dynamics of successful and unsuccessful reductive dechlorination of chlorinated ethenes in groun

107 reen rusts, GRs) are promising reactants for reductive dechlorination of chlorinated solvents due to

108 is a carcinogen generated in groundwater by reductive dechlorination of chloroethenes.

109 ovide multiple lines of evidence for in situ reductive dechlorination of MCB to benzene.

110 2 (1.3 mM) concentrations reversibly inhibit reductive dechlorination of TCE by Dehalococcoides mccar

111 Although reductive dechlorination of TCE by Dehalococcoides mccar

112 existing aerobic ethenotrophic and anaerobic reductive dechlorination pathways.

113 gradation processes at the OAI and that high reductive dechlorination potential suppresses developmen

114 y ethenotrophs in low-TOC sediments with low reductive dechlorination potential.

115 mproved predictive understanding of a site's reductive dechlorination potential.

116 The microbial reductive dechlorination process is robust at circumneut

117 lum spp. are key contributors to in situ PCE reductive dechlorination under low pH conditions.

118 is a valid tool for describing transport and reductive dechlorination.

119 black carbon, while DDE degradation involves reductive dechlorination.

120 o biodegradation, and particularly anaerobic reductive dechlorination.

121 dent dealkylation of alkylcobalamins and the reductive decyanation of cyanocobalamin.

122 Faster kinetic rates of reductive degradation were observed with increased molec

123 ter of groundwater among the samples with VC reductive dehalogenase gene (bvcA and vcrA) abundances r

124 roph functional genes (etnC and etnE) and VC reductive dehalogenase genes (bvcA and vcrA) were strong

125 ccartyi strain 195 showed genes encoding for reductive dehalogenases (e.g., tceA) were not affected d

126 summarize current knowledge about catabolic reductive dehalogenases and the electron transfer chain

127 of quinone-dependent and quinone-independent reductive dehalogenases that are distinguishable at the

128 Fe-S cluster-containing, membrane-associated reductive dehalogenases.

129 y further aid in understanding the bacterial reductive dehalogenation at the molecular level.

130 Although reductive dehalogenation is key to their environmental a

131 etention times have rarely been explored for reductive dehalogenation of chlorinated ethenes.

132 enetically diverse microorganisms couple the reductive dehalogenation of organohalides to energy cons

133 to a full electron transfer as start of the reductive dehalogenation.

134 fractionation in all natural and engineered reductive dehalogenations reported to date suggesting th

135 The subsequent reductive deoxygenation of the Diels-Alder adducts with

136 pic oxidation of Ag to AgCl concomitant with reductive deposition of small Pt clusters on the NS surf

137 Cycloaddition followed by aryl migration and reductive deprotonation is presented as a new reaction s

138 The reductive desulfonylation of the monoalkylated and selec

139 We report a novel reductive desulfurization reaction involving pi-acidic n

140 nce by employing Overman's samarium mediated reductive dialkylation procedure.

141 been successfully synthesized via a one-pot reductive diazotation approach.

142 An intermolecular, three-component reductive dicarbofunctionalization of alkenes is present

143 Optimization of a reductive diene cyclization led to the development of an

144 r thousand (anaerobic C-Cl bond cleavage via reductive dihaloelimination).

145 ation method of substituted azoxybenzenes by reductive dimerization of nitrosobenzenes.

146 erformed in the presence of silyl triflates, reductive disproportionation is arrested by silylative e

147 ] reacts with two molecules of CO2 to effect reductive disproportionation to CO and carbonate ([CO3 ]

148 solvent molecules producing halide ions via reductive dissociation, which is followed by anion excha

149 hydrite promoted 2,6-DMHQ oxidation both via reductive dissolution and heterogeneous catalysis while

150 on of reactive organic carbon, including the reductive dissolution and transformation of ferric iron

151 At zero PO4(3-) loading, reductive dissolution appears to be constrained by the r

152 tion, which makes ferrihydrite more prone to reductive dissolution by the 2,6-DMBQ/2,6-DMHQ redox cou

153 torically contaminated coastal soils through reductive dissolution of arsenic-bearing mineral oxides

154 The results also suggest that while the reductive dissolution of Fe(III) oxides reduced the numb

155 echanisms: at low DO in water (<4 mg L(-1)), reductive dissolution of ferric Fe oxides was associated

156 is primarily controlled by a combination of reductive dissolution of ferrihydrite, arsenic incorpora

157 del approaches to represent and quantify the reductive dissolution of iron oxides, the concomitant re

158 provide conditions which facilitate optimal reductive dissolution of schwertmannite.

159 (-1), commensurate with some of the reported reductive dissolution rates of goethite, suggesting Fe(I

160 With the exception of Mn, which underwent reductive dissolution, CWs were sinks for the studied me

161 to reducing conditions, jarosite may undergo reductive dissolution, thereby releasing As, Sb, and Fe(

162 C compared to 4 degrees C due to accelerated reductive dissolution.

163 als starts with a precise 3D choreography of reductive divisions of the fertilized egg, known as clea

164 reduction, where two electrons come from H2 reductive elimination and the other two come from iron o

165 le-metal two-electron oxidative addition and reductive elimination are common fundamental reactions f

166 that undergoes at -90 degrees C accelerated reductive elimination enantioselectively and exclusively

167 We report a C-F reductive elimination from a characterized first-row ary

168 between the two aryl rings result in faster reductive elimination from Ar-Au(X)-Ar and lead to the p

169 ry of a borane-catalyzed formal C(sp(3))-CF3 reductive elimination from Au(III) that accesses these c

170 nd and conformational freedom on the rate of reductive elimination from diaryl-gold(III) species.

171 For the first time, the C(sp(2))-N reductive elimination from isolated amidoaryl Pd(IV) com

172 ermore, rare examples of C(sp(3))-Br and -Cl reductive elimination from Pd(II) as well as transfer hy

173 Reductive elimination from the presented nickel(III) com

174 The rates of reductive elimination from these C-bound fluoroenolate c

175 The ensuing reductive elimination furnishes the desired arylated pro

176 ce two protons into two hydrides, from which reductive elimination generates H2.

177 s that nitrenes are not generated and thus a reductive elimination has occurred.

178 roamides, and difluoroacetonitrile underwent reductive elimination in high yields.

179 Reductive elimination is accelerated by electron-donatin

180 the interplay between oxidative addition and reductive elimination is key for a potential catalytic c

181 mide], the energies for the regiocontrolling reductive elimination is predicted to be more in favor o

182 An unprecedented concerted reductive elimination mechanism for benzoxazole formatio

183 with an oxidative addition/olefin insertion/reductive elimination mechanism for each regioisomeric p

184 reaction proceeds via an oxidative addition/reductive elimination mechanism involving a Ni(IV) inter

185 The oxidative addition-reductive elimination mechanism via an unstable Cu(III)

186 These enzymes catalyze the reductive elimination of a halide and constitute the ter

187 a-Si elimination but either ethylene loss or reductive elimination of cis-disposed aryl and SiMe3 moi

188 key in the binding and activation of N2 via reductive elimination of H2 .

189 1,3,5-benzenetricarboxylate) via bimetallic reductive elimination of H2 from putative [M(IV)6(mu3-O)

190 ion that drives the re/oa equilibrium toward reductive elimination of H2 with N2 binding/reduction.

191 propose a mechanism involving the homolytic reductive elimination of hydrogen.

192 I)-Me complex (DPEphos)RhMeI2 (1) results in reductive elimination of MeI.

193 conditions were employed to investigate the reductive elimination of RuPhos (2-dicyclohexylphosphino

194 dly, its exposure to UV light affords, after reductive elimination of the entire PCO group, the unpre

195 FeMo-cofactor through a mechanism involving reductive elimination of two [Fe-H-Fe] bridging hydrides

196 to the one suggested by spectroscopy, with a reductive elimination of two hydrides just before nitrog

197 l transformation of the compound by means of reductive elimination or other mechanisms and is therefo

198 transformation follows an oxidative addition-reductive elimination pathway.

199 inant removal, such as (i) dechlorination by reductive elimination rather than hydrogenolysis and (ii

200 clopropylcarbinyl)nickel complex, which upon reductive elimination releases the cyclopropane.

201 ts inability to catalyze C-H silylation; the reductive elimination step to form the silylation produc

202 ugated alkenes involving a C(sp(3))-C(sp(3)) reductive elimination step.

203 e elimination and facilitate transmetalation/reductive elimination steps.

204 (-) and [Cu(III)](C6F5)(OPh) unstable toward reductive elimination to [Cu(I)](solvent) and PhO-C6F5.

205 de abstraction, migratory insertion, and C-F reductive elimination to achieve a net C-C bond construc

206 (III) complexes can undergo facile C(aryl)-P reductive elimination to afford phosphonium salts, which

207 cterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridini

208 ching), alkyl halide oxidative addition, and reductive elimination to enable alkyl-alkyl fragment cou

209 ed Ni(II) complexes, upon oxidation, undergo reductive elimination to form carbon-halogen bonds.

210 m the silylation product is much slower than reductive elimination to form the alkene hydroarylation

211 IV) species, which then undergoes facile C-C reductive elimination to form the final product.

212 tive addition can be shown to be followed by reductive elimination to give an N- (or O-)borylated pro

213 the reactivity of the arene and changes from reductive elimination to pi-complexation for arenes bear

214 a vinylgold(III) intermediate that undergoes reductive elimination to provide the heterocyclic coupli

215 ergoes a second alkyne insertion followed by reductive elimination to yield pyrrole and a Ti(II) spec

216 This tendency to undergo reductive elimination was exploited in the investigation

217 Reductive elimination was faster from complexes containi

218 Each Ni(III) undergoes separate, but fast reductive elimination, giving rise to Ni(I) species.

219 metallic reactions, i.e. oxidative addition, reductive elimination, insertion and elimination reactio

220 upling reactions, including C-C bond-forming reductive elimination, represents a significant challeng

221 to Ni(III) , however, is required to trigger reductive elimination.

222 ide ligand prior to an inner-sphere SN2-type reductive elimination.

223 ting step from C-H oxidative addition to C-B reductive elimination.

224 , and directly delivers the intermediate for reductive elimination.

225 merization and a carbon-halogen bond-forming reductive elimination.

226 -C bond, followed by migratory insertion and reductive elimination.

227 ated to a metal ion of possible relevance to reductive elimination/oxidation addition reaction chemis

228 ociated with changes in the share of ATP and reductive equivalent supply for isoprene synthesis.

229 xylase or by limited supply of energetic and reductive equivalents.

230 estigation of host-pathogen interactions and reductive evolution in one of the most medically and eco

231 enome content and sub-cellular structures by reductive evolution.

232 xplanation is oxidation of sorbed Fe(II) and reductive Fe(II) release coupled 1:1 by electron conduct

233 ent metalloprotein nitrogenase catalyzes the reductive fixation of atmospheric dinitrogen into bioava

234 -state and time-resolved measurements of the reductive fluorescence quenching of five fluorophores ("

235 are often considered beneficial in promoting reductive functionalizations.

236 Reductive glutamine metabolism was highly dependent on c

237 ed formation of D-2HG and reactive oxygen, a reductive glutamine metabolism, and modifications of the

238 ich is then assimilated into biomass via the reductive glycine pathway.

239 nto the understanding of basic principles of reductive graphene functionalization and will serve as a

240 acterization to a rapid kinetic study of the reductive half-reaction (the reaction of formate with ox

241 The catalytic process of Tmm consists of a reductive half-reaction and an oxidative half-reaction.

242 In the reductive half-reaction, FAD is reduced and a C4a-hydrop

243 C bond formation, thus providing examples of reductive heterocyclizations where hydrogen embedded wit

244 Competing reductive homocoupling of the carbonyl component is supp

245 the ultrathin superconducting NbSe2 by polar reductive hydrazine molecules triggers a slight elongati

246 ntribute to the enzyme isotope effect on the reductive hydride transfer reaction, but their contribut

247 d AC, the preferred reaction pathway was the reductive hydrodechlorination.

248 rfaces are highly selective in promoting the reductive hydrolysis of aromatic ethers in aqueous phase

249 Reductive immobilization to Cr(III) is a treatment optio

250 roxyl groups on the GONR were removed by the reductive MB.

251 This report describes a catalytic reductive methylenecyclopropanation reaction of simple o

252 ereoselective reductive cyclization in situ; reductive N-methylation then gave 3-deoxy-(+)-preussin B

253 Reductive N-N bond cleavage provided the N,N-diprotected

254 First, reductive O2 activation induces selective oxidative clea

255 formate serves as a CO2 entry point into the reductive one-carbon (C1) metabolism, and internalizes C

256 The activity of the sulfate reductive pathway key enzyme, adenosine 5'-phosphosulfat

257 Inhibition of this reductive pathway prevents the correct folding and secre

258 on in Salicornia and Sarcoconia: the sulfate reductive pathway that generates Cys and l-Cys desulfhyd

259 Herein, reductive pathways of MoO(S2)2bpy (Mo-bpy) (bpy = 2,2'-b

260 ons will have implications for the design of reductive processes involving Sm(II)-mediated reduction

261 istress in ROS-rich environments and require reductive protection from NRX1 for optimal activity.

262 Reductive quenching also occurs in strongly acidic solut

263 erent diastereoselectivity observed during a reductive radical cascade cyclization process.

264 A reductive radical cyclization cascade was utilized to bu

265 that, under solar irradiation, forms highly reductive radicals in the presence of an electron donor,

266 In deeper layers, however, abiotic non-reductive release of Fe (desorption, dissolution) from p

267 on through aldehyde modification followed by reductive removal of the beta-lactam carbonyl moiety.

268 hat phosphate complexation could enhance the reductive removal of vanadium(V) and inhibit the reoxida

269 the use of iron-sulfur cluster cofactors in reductive ring opening and hydroxy-group elimination.

270 e derivatives were synthesized via benchmark reductive routes using graphite intercalation compounds

271 inal components to dioxygen and nitric oxide reductive scavenging pathways in these organisms.

272 ester species is proposed to account for the reductive selectivity observed.

273 Notably, the PknG mutant exhibited a reductive shift in mycothiol redox potential and comprom

274 strategy helps minimize energy losses in the reductive, short-range charge shift from C60 to C70.

275 the development of better catalysts for the reductive side of hydrogen fuel cells.

276 General reductive silylation of the UO2(2+) cation occurs readil

277 Outer-sphere reductive single electron transfer (OS-SET) has been pro

278 malate importantly controls the chloroplast reductive status and, thereby, affects isoprene emission

279 n was associated with enhanced chloroplastic reductive status that suppressed light reactions of phot

280 but also catalytic processes that require a reductive step for the turnover of the catalytic cycle.

281 one Oxidoreductase (FaEO) catalyses the last reductive step in the biosynthesis of 4-hydroxy-2,5-dime

282 A new iridium-catalyzed reductive Strecker reaction for the direct and efficient

283 While systems to manage reductive stress are well-established, how cells cope wi

284 We propose that reductive stress in the ER inhibits the Ost3-dependent N

285 Depletion of JB12 during reductive stress or by shRNA from Huh-7 cells was associ

286 ons appropriate to the needs of the ER under reductive stress.

287 of Sil1, but not of Lhs1, is diminished upon reductive stress.

288 ssociated chaperone that was destabilized by reductive stress.

289 onor-acceptor cyclopropanes with the Zn-AcOH reductive system was developed.

290 ratio) has been extensively studied for the reductive transformation of chlorinated or nitroaromatic

291 The reductive transformation of ferrihydrite [Fe(OH)3] to na

292 n eight-month period triggered the aging and reductive transformation of Gallionella-like ferrihydrit

293 We report full details of a method for 1,3-reductive transposition of alpha-alkoxy-alpha,beta-unsat

294 y chiral biphenols, results in an asymmetric reductive transposition of the in situ generated allylic

295 After reductive treatment for 1 year, sediments were exposed t

296 hat biogeochemical conditions present during reductive treatment, and the potential for buildup of re

297 eservoir of reduced species generated during reductive treatment.

298 Here we report practical, catalyst-free, reductive trifluoroethylation reactions of free amines e

299 ving Sm(II)-mediated reduction of amides and reductive umpolung cyclizations via aminoketyl radicals

300 expressing the gene vcrA (or bvcA) encoding reductive vinyl chloride dehalogenases are important to

301 amolecular Suzuki-Miyaura cross-couplings or reductive Yamamoto homocouplings.