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1 easured in a single alignment medium that is rhombic.
4 e orientation of the riboses relative to the rhombic alignment tensor of the molecule studied, a stem
6 entify an unusual EPR signal with very small rhombic anisotropy and g values of 2.02, 1.99, and 1.96.
9 controlled by the His-Fe-His vector, and the rhombic axes are controlled by the mean of the imidazole
10 several Raman bands revealed an increase of rhombic B(1g) distortion with respect to native HRP in w
11 ifferent molecular environments, including a rhombic Be2 X2 (X=C, N) core, a vertical Be-Be axis in a
13 ), g-strain and broadening from the possible rhombic character of the Zeeman interaction are small.
14 tical spectrum; (2) its EPR spectrum showing rhombic character to its Type 1 center and nitrite pertu
15 eutral radical, the g-matrix has significant rhombic character, but this is significantly decreased i
16 We observe twinning of two-dimensional (2D) rhombic colloidal crystals of hard Brownian rhombic plat
17 ulation of these spectra yield the axial and rhombic components of the Mn(2+) (S = (5)/(2)) zero-fiel
19 is key feature, which is not readily seen in rhombic crystals of square colloids, facilitates observa
20 uidistant between two 'anchor' metal ions: a rhombic dipolar interaction tensor, T approximately [T,
22 he coupling of band III to modes with strong rhombic distortion of the heme macrocycle calls into que
25 ll {110}-faceted gold nanostructures, namely rhombic dodecahedra (RD) and triangular bipyramids (BPs)
27 l-regulated crystal orientation not only for rhombic dodecahedra all of whose facets are equivalent,
29 ra, {100}-truncated rhombic dodecahedra, and rhombic dodecahedra are approximately 200, 140, 270, and
30 the three-dimensional Pt anisotropy of Pt-Ni rhombic dodecahedra can be tuned by controlling the rati
34 corner-truncated octahedra, {100}-truncated rhombic dodecahedra, and rhombic dodecahedra are approxi
35 the shapes of spheres, cubes, octahedra and rhombic dodecahedra, we investigate the entire self-asse
41 l, {100}-truncated rhombic dodecahedral, and rhombic dodecahedral structures have been synthesized.
42 ncated rhombic dodecahedral, {100}-truncated rhombic dodecahedral, and rhombic dodecahedral structure
45 r-truncated octahedral, all-corner-truncated rhombic dodecahedral, {100}-truncated rhombic dodecahedr
46 on of ultrasonic irradiation afforded hollow rhombic-dodecahedral crystals of the C-methylcalix[4]res
47 gh the 14 axes to the 24 edges such that the rhombic dodecahedron becomes a Pt-rich frame enclosing a
48 At the micrometer scale, the anisotropic rhombic dodecahedron crystal habit couples with photonic
49 ubic habit from cube-shaped nanoparticles, a rhombic dodecahedron habit from octahedron-shaped nanopa
50 ies defined by the mesoscale crystal (here a rhombic dodecahedron) by controlling the spacing between
51 esults in Pt segregation to the 14 axes of a rhombic dodecahedron, forming a highly branched, Pt-rich
54 polyhedrons, namely, truncated octahedrons, rhombic dodecahedrons, hexagonal prisms, cubes, gyrobifa
55 pectra for ferrous N694G and an intermediate rhombic electron paramagnetic resonance (EPR) signal for
56 is from a transient species that displays a rhombic electron paramagnetic resonance (EPR) signal wit
57 es a novel Ni(p)(+) species (A(red)*) with a rhombic electron paramagnetic resonance spectrum (g valu
60 rk, the change from "large g(max)" to normal rhombic EPR signal occurs between axial ligand plane dih
61 ation (under argon) the H cluster exhibits a rhombic EPR signal that is not seen in the as-purified e
62 t of the enzyme results in conversion of the rhombic EPR signal to a g = 6 signal, consistent with fo
63 over many similar sites, the A-center has a rhombic EPR signal with a g-tensor, g(A) = [2.248(4), 2.
66 structures with apical oxo ligands, exhibit rhombic EPR spectra, and 3-5 are electrochemically reduc
70 -band EPR spectrum of the radical exhibits a rhombic g tensor with dual gx values (2.00550 and 2.0060
73 the [4Fe-4S](+) of PFL-AE, changing it from rhombic (g = 2.02, 1.94, 1.88) to nearly axial (g = 2.01
74 O(2) to generate an intermediate (H) with a rhombic, g < 2 EPR spectrum; (2) a form of the enzyme wi
75 en well documented, has the highest level of rhombic heme (41-fold greater than for HbA(0)), even tho
78 dandelion-like assemblages from Pt NCs, and rhombic/hexagonal platelet assemblages from PdS NCs and
79 e with two or three cysteinate ligands and a rhombic high spin (S = 2) Fe(II) center (E/D = 0.28, D =
80 active site iron center in oxidized SOR from rhombic high-spin ferric (S = 5/2) to axial-like low-spi
82 weak signal at g = 4.3, which we ascribe to rhombic iron and a free radical signal at g(ave) = 2.01.
84 kwise, from the average pointing axis of the rhombic lattice yielding a form of nonlocal chiral symme
85 which have higher symmetry but can also form rhombic lattices at high densities, each rhombic particl
86 s are more frequently expressed in the lower rhombic lip (LRL) and embryonic dorsal brainstem than in
88 ield that adjoins a germinal zone, the lower rhombic lip (LRL), functions as a progenitor domain by c
90 imordium contains two germinative zones, the rhombic lip (RL) and the ventricular zone (VZ), which ge
98 eal molecular organization of the cerebellar rhombic lip and introduce Lmx1a as an important regulato
99 Math1 expression delimits the extent of the rhombic lip and is required for the generation of the hi
101 cification of cerebellar cell types from the rhombic lip and its upregulation inhibits their producti
102 indbrain, arise from precursors in the lower rhombic lip and migrate anteroventrally to reach their f
103 that DCN neurons in mice are produced in the rhombic lip and migrate rostrally in a subpial stream to
104 Our results suggest that UBCs arise from the rhombic lip and migrate via novel pathways to their fina
106 of Lmx1a, these cells precociously exit the rhombic lip and overmigrate into the anterior vermis.
107 1 is the defining molecule of the cerebellar rhombic lip and Pax6 is downstream in the Math1 pathway.
108 associated with premature regression of the rhombic lip and posterior vermis hypoplasia in Lmx1a(-/-
109 hl1 homeobox gene is highly expressed by the rhombic lip and rhombic lip-derived migratory neurons.
111 ere derived from neuronal progenitors of the rhombic lip and that cerebellar ectopia were derived fro
113 arate progenitor pools located mainly in the rhombic lip and the cerebellar ventricular zone, respect
114 existence of spatial compartmentation in the rhombic lip and the interplay between Wls, Math1, and Pa
118 Thus, proliferating precursors within the rhombic lip are specified to be granule cells very early
119 the earliest granule cell progenitors at the rhombic lip as they separate from the ventricular zone o
120 g granule cell progenitors isolated from the rhombic lip at E14 or from the external germinal layer a
121 nce for an hCPe contribution directly by the rhombic lip at late embryonic stages when hRPe is no lon
122 ansformed our understanding of the embryonic rhombic lip by revealing the inductive cues, regional or
124 introduce Lmx1a as an important regulator of rhombic lip cell-fate decisions, which are critical for
125 ggests that Sef may normally function in non-rhombic lip cells and prevent them from responding to FG
127 When transplanted into younger neural tube, rhombic lip cells maintain their characteristic molecula
130 n hindbrain specification and generate upper rhombic lip derivatives on exposure to bone morphogeneti
131 trin orchestrates the migration of hindbrain rhombic lip derivatives to form the precerebellar nuclei
134 more than one cell type, indicating that the rhombic lip does not consist of a homogeneous population
135 ull mice have embryonic abnormalities of the rhombic lip due to loss of mesenchyme-secreted signaling
137 ulture experiments, Tbr2+ UBCs migrated from rhombic lip explants directly into the developing white
139 d in grafted progenitors: transplanted early rhombic lip fails to subsequently produce granule cell p
141 Thus, we demonstrate that the cerebellar rhombic lip gives rise to multiple cell types within rho
144 ence of Wls-positive cells in the Math1-null rhombic lip indicates that Wls expression is independent
150 ve cells and their progeny that arise in the rhombic lip of the cerebellar primordium during embryoge
151 zone precursors and glutamatergic cell from rhombic lip precursors, mirroring distinct origins for t
152 ental progression has been assumed, with the rhombic lip producing non-mitotic hRPe, and seemingly un
153 e neural tube, derivatives of early and late rhombic lip progenitors display patterns of migration an
155 addition, Lmx1a is expressed in a subset of rhombic lip progenitors which produce granule cells that
157 nterplay between Wls, Math1, and Pax6 in the rhombic lip provides novel views of early cerebellar dev
158 dbrain dorsal interneurons that comprise the rhombic lip relay sensory information and coordinate mot
159 ker of the cells in the interior face of the rhombic lip throughout normal mouse cerebellar developme
161 granule cell precursors are generated at the rhombic lip together with neurons of the lateral pontine
163 red gene interactions during the presence of Rhombic lip versus the presence of distinct internal gra
164 2+ UBCs appeared to migrate out of the upper rhombic lip via two cellular streams: a dorsal pathway i
166 blishment of a neural progenitor population (rhombic lip) that gives rise to multiple hindbrain struc
167 ated protein kinase pathway is active in the rhombic lip, a germinal zone that generates diverse type
168 iferative state, order of emergence from the rhombic lip, and molecular profile of either the constit
169 mutant mice, Tbr2+ UBCs accumulated near the rhombic lip, consistent with impaired migration through
171 d along the dorsal-most region of the caudal rhombic lip, gives rise to the cochlear and precerebella
172 Sef is expressed immediately adjacent to the rhombic lip, overlapping with FGF15 and FGFR1, which is
174 rsors of cerebellar granule neurons from the rhombic lip, the dorsal aspect of the midbrain/hindbrain
175 erivatives is intrinsically specified at the rhombic lip, the orderly temporal transition in cell typ
176 which gives rise to isthmic nuclei, and the rhombic lip, which generates deep cerebellar nuclei and
177 enitor zones, the ventricular zone and upper rhombic lip, which give rise to distinct cell types in t
178 n orientated, active migration away from the rhombic lip, which is apparently independent of either g
181 which have a severe cerebellar malformation, rhombic lip-derived cells migrated to the NTZ, despite r
182 nd positioning of fissures, whereas in upper rhombic lip-derived cells the genes are more important i
184 -lateral coordinates into the adult, whereas rhombic lip-derived granule cells undergo lateral to med
185 ineage appears to be unique among the varied rhombic lip-derived lineages in its proliferative respon
187 ctive deficit occurs without affecting other rhombic lip-derived nuclei, despite expression of Math1
188 poptosis, indicating that VZ/SVZ-derived and rhombic lip-derived progenitor cells show differential r
204 selective knock-out of P/Q-type channels in rhombic-lip-derived neurons including the PF and MF path
205 use many precerebellar nuclei originate from rhombic lips, the first analysis of neuronal migrations
206 esponsible for the strong positive axial and rhombic magnetic anisotropy of the high-spin Co(II) ion
211 ignificantly contributes to constructing the rhombic nanoporous network, whereas carboxylic acid amph
214 orm rhombic lattices at high densities, each rhombic particle has a distinguishable bidirectional poi
215 ioheme I, and the known essentially constant rhombic perturbation of heme pocket sites on the hyperfi
216 han that of the axial His, that modulate the rhombic perturbation to the heme's in-plane electronic a
217 -order transition between the square and the rhombic phase and different regimes of elasticity, as we
219 ncated icosahedron or soccer ball--and the 2 rhombic polyhedra reported by Johannes Kepler in 1611.
222 Fe-NO adduct of FeSOD (NO-FeSOD) exhibit two rhombic S = 3/2 signals of comparable population; E/D =
226 ituted ImiS demonstrated the appearance of a rhombic signal after 10 ms that is assigned to a reactio
227 For the paral-[FeOMTPP(1-MeIm)(2)]Cl, a rhombic signal with g(1) = 1.54, g(2) = 2.51, and g(3) =
228 ](+) exhibits both "large g(max)" and normal rhombic signals, suggesting the presence of both "perpen
229 present different shapes, such as hexagonal, rhombic, six-cornered star, dumbbell, or dendritic.
231 of the component spins of the triplets have rhombic symmetry because of electron spin delocalization
233 n I-II-helix VIII dimers interact to form a "rhombic" tetramer via an interface involving residues fr
234 surface occupy the positions of atoms in the rhombic triacontahedral cluster, the building block of t
236 2D nanoporous molecular networks containing rhombic voids are demonstrated to be accessible from low
237 allel = 98 x 10(-4) cm(-1), and another more rhombic, with a smaller A parallel value of 69 x 10(-4)
238 /- 2 cm(-1) (where D and E are the axial and rhombic zero-field splitting parameters, respectively) a
240 The fast QTM rate suggested a significant rhombic ZFS parameter E, as expected from the low (virtu
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