ライフサイエンスコーパス: scandium

1 gated the effect of fluoride complexation on scandium accumulation by two unicellular algae, Chlamydo

2 The scandium alkyl Cp*(2)ScCH(2)CMe(3) (2) was synthesized b

3 s to be second order overall: first order in scandium and first order in substrate (pyridine).

4 )-N(2)), which has a coplanar arrangement of scandium and nitrogen atoms within a square planar array

5 ctory 'lithophile' elements such as calcium, scandium and the rare-earth elements are known to be pre

6 Substoichiometric quantities of scandium and ytterbium triflate increase the yield of Ug

7 Scandium and ytterbium triflates respond very differentl

8 les of an aromatic N-heterocycle mediated by scandium and yttrium benzyl complexes supported by a fer

9 The scandium antimony telluride (Sc0.2Sb2Te3) compound that

10 The first phosphinidene complexes of scandium are reported in this contribution.

11 ng of the electronic structures of these new scandium arene complexes.

12 synthesis and characterization of the first scandium arene inverted-sandwich complexes supported by

13 r primary phosphide produces the mononuclear scandium ate complex [(PNP)Sc(mu(2)-P[DMP])(mu(2)-Br)Li]

14 unit consists of a distorted tetrahedron of scandium atoms with oxygen atoms bridging two of its fac

15 nique motif [OCPPCO](4-) , stabilized by two scandium centers.

16 The methylidene scandium complex (PNP)Sc(mu3-CH2)(mu2-CH3)2[Al(CH3)2]2 (

17 wo simple competitive binding assays using a scandium complex derived from 1,8-bis(3-(3',5'-dimethylp

18 -symmetric ligand forms a highly fluorescent scandium complex that can be used for enantioselective s

19 The scandium dihydrosilyl complexes Cp*(2)ScSiH(2)R (R = Mes

20 gADP (MgADPVi-S1) with aluminum fluoride and scandium fluoride trapped MgADP (MgADPA1F4-S1 and MgADPS

21 as the sum of the lanthanides, yttrium, and scandium) for ashes derived from Appalachian sources was

22 The erbium, chromium:yttrium-scandium-gallium-garnet (Er,Cr:YSGG) laser has been wide

23 , most recently the erbium, chromium:yttrium-scandium-gallium-garnet (Er,Cr:YSGG) laser.

24 ylcyclopentadienyl) metallocene chemistry of scandium has revealed that the method involving reductio

25 lnaphthalene N,N'-dioxide ligands, 1, from a scandium(III) complex can be used for quantitative detec

26 phite rods doped with copper(II) nitrate and scandium(III) oxide in an electric arc under a low press

27 indoles catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes (Sc(III)-pybox) was acc

28 First, the scandium(III)-catalyzed addition of diverse nucleophiles

29 ed molecular ladders with up to 12 rungs via scandium(III)-catalyzed imine metathesis by employing th

30 Asymmetric scandium(III)-catalyzed rearrangement of 3-allyloxyflavo

31 ective [3+2] annulation is catalyzed using a scandium(III)/indapybox complex with tetrakis-[3,5-bis(t

32 esence of pyridine to generate the transient scandium imido (PNP)Sc horizontal lineN[DIPP](NC(5)H(5))

33 that this species possesses a fairly linear scandium imido motif (169.7 degrees ) with a very short

34 at no back-transfer of hydride from boron to scandium occurs.

35 fer addition compound, 6, in the presence of scandium or ytterbium triflate in 1,2-dichloroethane or

36 rip = 2,4,6-(i)Pr(3)C(6)H(2)), the dinuclear scandium phosphinidene complex [(PNP)Sc(mu(2)-P[Trip])](

37 In the present study, short-term scandium (Sc) internalization fluxes (Jint) were measure

38 -1) at 298 K), specifically in the magnesium scandium selenide spinel.

39 Scandium surface-bound concentrations (Sc(ads)) and upta

40 reversibility of dinitrogen binding in this scandium system.

41 ion through geometrically matched and robust scandium telluride (ScTe) chemical bonds that stabilize

42 nse to methanol uptake at high pressure on a scandium terephthalate MOF (Sc2BDC3, BDC = 1,4-benzenedi

43 e [Cp*(2)Sc](+) in which the CO is bonded to scandium through the oxygen atom, not the carbon atom.

44 ances of odd and even element pairs, such as scandium/titanium and cobalt/nickel.

45 used with lanthanides can also be applied to scandium to make a dinitrogen complex of the first membe

46 ne (typically, 2.5 equiv) in the presence of scandium triflate (10 mol %) in ether to form in high yi

47 indolylmethyl Meldrum's acids with catalytic scandium triflate and a variety of nucleophiles results

48 hol in the presence of a catalytic amount of scandium triflate Sc(OTf)3.

49 assium permangnate, furan acetalization with scandium triflate, and mesylation and fluorination react

50 Scandium triflate-catalyzed [4 + 2] aza-annulation was e

51 nthesis of key intermediate triol 5, and the scandium triflate-catalyzed acetalization, in particular

52 The scandium triflate-catalyzed cycloaddition reaction of po

53 sylnitrene species, 3-Sc, in the presence of scandium triflate.

54 Scandium trifluoride maintains a cubic ReO(3) type struc

55 ydrazine (BTBSH) and a catalytic quantity of scandium trifluoromethanesulfonate (typically, 0.01 mol

56 ge dimerization of (-)-mehranine mediated by scandium trifluoromethanesulfonate completed the first t

57 Scandium uptake could be modeled reasonably well using a

58 Sc(4)O(2)@C(80) with a mixed redox state of scandium was found to be an exciting molecule for endohe

59 Scandium was selected for its chemical similarities with