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1 -based reaction mechanism possibly involving semiquinone radical.
2 tron out of the substrate to form a reactive semiquinone radical.
3 d a species with the optical properties of a semiquinone radical.
4 yrosyl radical in the formation of the ortho-semiquinone radical.
5 uced enzyme exhibits a stable anionic flavin-semiquinone radical.
6 75 or the introduced His, interacts with the semiquinone radical.
7 idue of HbO(2) to generate its corresponding semiquinone radical.
8 57 and the proton on N(5) of the neutral FMN semiquinone radical.
9 activity becomes one-electron-oxidized to a semiquinone radical.
10 de synthase (eNOS) reduces adriamycin to the semiquinone radical.
11 lavin in resting nNOS exits as an air-stable semiquinone radical.
12 ve proxies, which includes the generation of semiquinone radicals.
13 a big concern, because the catechol-derived semiquinone radical after the oxidation of catechol (CA)
15 ite first produces some neutral, blue flavin semiquinone radical and, finally, fully reduced FADH2.
16 environments, we were able to stabilize two semiquinone radicals and thus observed their weak emissi
18 e low-energy (3)MLCT(SQ) state (Ru(III) phen-semiquinone radical anion) as the predominant nonradiati
19 mmogram, which leads to the formation of the semiquinone radical anions (P)-(+)-1(*-) and (M)-(-)-1(*
24 eased amounts of reactive oxygen species and semiquinone radical, both of which can cause DNA damage,
25 characterized the nNOS heme iron and flavin semiquinone radical by electron paramagnetic resonance (
26 adical, Ph = 1,4-phenylene, SQ = S = (1)/(2) semiquinone radical, Cat = S = 0 catecholate, and py = p
27 We report the first direct detection of a semiquinone radical generated by the Q(o) site using con
29 are rapidly oxidized by dioxygen, while the semiquinone radicals generated in SRFA solution are resi
30 rent relaxation behavior and a stable flavin semiquinone radical identified by EPR as a neutral radic
31 by EPR spectroscopy, the properties of this semiquinone radical in appropriately poised samples of p
33 e critical role of quinoid intermediates and semiquinone radicals in CL generation from polychlorinat
34 odynamic and EPR spectroscopic properties of semiquinone radicals in these mutants were characterized
38 of cytochrome bo(3) from Escherichia coli, a semiquinone radical is stabilized in a high-affinity bin
40 (2)O(2)/NO(2)(-) generates the corresponding semiquinone radicals presumably via one-electron oxidati
41 ces Fe(III) in acidic conditions, generating semiquinone radicals (Q(*-)) that can oxidize Fe(II) bac
42 he characteristic hyperfine structure of the semiquinone radical signal observed in the wild-type oxi
43 uced forms exhibit neutral and anionic flavo-semiquinone radical signals, respectively, demonstrating
45 chain-propagating species, the deprotonated semiquinone radical (SQ(*) (-)) generated from both the
48 n as isolated contained an air-stable flavin semiquinone radical that was sensitive to FeCN6 oxidatio
49 1 complex in the presence of an intermediate semiquinone radical, thus making the Qo-site a strong ca
50 agents, the flavin can be cycled through the semiquinone radical to the fully reduced state with ligh
52 F and the R71H mutants, no EPR signal of the semiquinone radical was observed in the redox potential
53 inoid intermediates, but more interestingly, semiquinone radicals were produced during the degradatio
54 ron reduction of adriamycin forms adriamycin semiquinone radical, which rapidly reacts with oxygen to
55 ation methods gave rise to a transient DOPAL semiquinone radical, which was characterized by electron
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