ライフサイエンスコーパス: single bond

1 between the two local conformations around a single bond.

2 ntiaromatic fluorenyl cations connected by a single bond.

3 he alpha,beta-carbon=carbon double bond to a single bond.

4 active site that is s-trans about the =C-C=O single bond.

5 ron donor and acceptor directly linked via a single bond.

6 the entropy associated with rotation about a single bond.

7 imerize rapidly with the formation of a MnMn single bond.

8 ion and functionalization of a carbon-carbon single bond.

9 ses a highly strained and hindered aryl-aryl single bond.

10 le bond and 0.5 when they are connected by a single bond.

11 to construct the central aryl carbon-carbon single bond.

12 6-, or 7-membered rings are joined by a C-C single bond.

13 r to that for rotation about a carbon-carbon single bond.

14 by forming weak and long intermolecular C-C single bonds.

15 trogen-naphthalene and the nitrogen-carbonyl single bonds.

16 nvestigation of extremely long carbon-carbon single bonds.

17 he Ga-Ga bonds are significantly weaker than single bonds.

18 mplying that >80% of adhesive events involve single bonds.

19 n extended covalent solid with carbon-oxygen single bonds.

20 retinal) or C12-C13 (11,13-bridged retinal) single bonds.

21 the electrophilic reactivity of C-H and C-C single bonds.

22 instead of one of the oxygen atoms with only single bonds.

23 ng ligands supporting the five indium-indium single bonds.

24 nt four-membered "aromatic" rings linked by "single" bonds.

25 distances near 2.49 A, consistent with Ga-Ga single bonding.

26 torsional angle of 59 degrees and a long C-C single bond (1.60 A) connecting them.

27 )-C(2) bond cleavage/rotation around the N-C single bond/1,6-cyclization" sequence.

28 s significantly affected by "adhesive type" (Single Bond 2 vs experimental antibacterial adhesive p =

29 omplex in this series contains a metal-metal single bond (2.29 A).

30 )(-)](2) show the formation of a Au-Au sigma single bond (2.66 A) in the triplet excimer, compared to

31 per manufacturers' instructions, with either Single Bond (3M) or One-Step adhesive (Bisco).

32 The relative percent of Single Bond adhesive was < 50% throughout more than half

33 base model compound which contained only one single bond adjacent to two double bonds, we have found

34 Force-regulated single bonds akin to those of alphabetaTCRs but with mor

35 ar bispentalene cores with large double- and single-bond alternation in the pentalene units, characte

36 eaction-limited detachment rate k(off) for a single bond and also for multiple bonds.

37 nal atoms and an open-shell structure with a single bond and two lone electrons on each terminal atom

38 Surprisingly, a mixture of 10% single bonds and 90% dimeric bonds is sufficient to full

39 ls method, dissect pi effects from the sigma single bonds and lone pair influences.

40 gths of axial and equatorial P-O phosphorane single bonds and P-O single and double bonds in metaphos

41 structure and bonding, the activation of C-C single bonds and, thus, catalytic methods of C-C bond fo

42 ion (BC), two bonds are sacrificed to form a single bond, and the reaction progress is interrupted at

43 ca. 0.15 A shorter than a conventional Sn-Sn single bond, and the trans-bent structure indicate the p

44 g increasing binding energy from no bonds, a single bond, and two double bond steroids.

45 120 degrees intramolecular rotation around a single bond; another is a molecule capable of repetitive

46 steroidal skeleton system containing a C3-C9 single bond as well as conditions to selectively ketaliz

47 merization followed by rotation around a C-N single bond, as opposed to the more common rotation mech

48 have found that the stretch mode of this C-C single bond at 1232 cm-1 shifts up by 15 cm-1 and its in

49 uble bond with concomitant introduction of a single bond at C-11 piperidine resulted in compound 3 th

50 Single bond attachments between spacers and glycoluril m

51 is in part a result of the introduction of a single bond between the C2' and C6 carbon atoms of cis-r

52 to measure the force-dependent lifetimes of single bonds between a fibronectin fragment and an integ

53 Single bonds between carbon atoms are inherently challen

54 The kinetic parameters of single bonds between neural cell adhesion molecules were

55 which the C(60)O moieties are linked by two single bonds between sp(3)-hybridized carbon atoms adjac

56 trates, which exhibit two or three rotatable single bonds between the binding site and the reactive o

57 ater efficiency than for comparable cases of single bond breaking.

58 e experimentally indistinguishable from true single bonds, but which have considerable effects on the

59 The variability of carbon-carbon single bonds by steric and electronic effects is probed

60 h molecules, the activation of carbon-carbon single bonds (C-C bonds) in simple substrates is strateg

61 iants of HO-:C-OH contains two very short CO single bonds (ca. 1.32 A).

62 bis(boratabenzene) moiety with a boron-boron single bond can be viewed as a symmetric dimer of the pa

63 trace the origin of the effect to increased single bond character for the C(carbonyl)-N bond due to

64 Here, we adapt recently developed single-bond chemistry techniques to study individual dis

65 spects of key methodologies that exploit C-C single-bond cleavage of strained ring systems are highli

66 imum for Sn-Sn, is a relatively closed-shell single-bond configuration where LP and LP are nominally

67 consists of a 120 degrees rotation around a single bond connecting a three-bladed subunit to the bul

68 d that the conformation of the retinal C6-C7 single bond connecting the beta-ionone ring and the reti

69 h decreasing solvent viscosity, suggesting a single-bond decomposition mechanism.

70 rmational stability of the A1 domain and the single bond dissociation kinetics of the A1-GPIbalpha in

71 e fairly short, average 1.7 A, relative to a single bond distance of approximately 1.8 A and are coor

72 iently long-lived to rotate around the C2-C3 single bond during catalysis.

73 denote as TMA-OH2, containing a stable Al-O single bond emerged as the building block molecule.

74 kcal/mol binding energy, akin to typical M-M single-bond energies.

75 rom the 70 pN force quantum, we estimate the single bond energy to be approximately 4-5 kJ/mol, in re

76 CD44v-HA and CD44s-HA single bonds exhibit similar kinetic and micromechanical

77 n constants for L-selectin and P-selectin at single bond forces above 125 pN were considerably lower

78 At estimated single bond forces of 125 pN and below, all three select

79 addressin (PNAd) were compared at estimated single bond forces ranging from 37 to 250 pN.

80 ical binding probability on the detection of single-bond forces are examined systematically.

81 oranes, 9-BBN and Ph3 B, provide facile B-B' single bond formation.

82 e data at different loading rates, using the single-bond full microscopic model, indicates that the b

83 eric nitrogen (cg-PN) with nitrogen-nitrogen single bonds has been synthesized together with a relate

84 by selective reduction of the triple bond to single bond have been utilized as the decisive steps to

85 deed only two complexes with thorium-arsenic single bonds have been structurally authenticated, refle

86 d cationic carbenes are known to insert into single bonds; however, this is the first observation of

87 gy barrier for rotation around the aryl-aryl single bond in 3 is 31 kcal/mol.

88 .24 A, both of which indicate an iron-oxygen single bond in a ferryl-hydroxide, Fe(IV)OH, moiety.

89 demonstrate that the very small change of a single bond in CNC to a double bond in CeNC causes signi

90 tional isomerization about the carbon-carbon single bond in simple ethane derivatives in room-tempera

91 rom epsilonA by change of a double bond to a single bond in the 5-member exocyclic ring and are forme

92 double bond in 7-norbornenylidene (1) by the single bond in the endo-fused cyclopropane unit of carbe

93 rier for rotation around the carbon-nitrogen single bond in the tetrahedral intermediate derived from

94 ovo enzyme templates for the cleavage of C-C single bonds in long-chain hydrocarbons, we analyzed pro

95 nes to their corresponding formal double and single bonds in nonaromatic systems.

96 Carbon-fluorine bonds are the strongest single bonds in organic chemistry, making activation and

97 are outside the range (2.88-2.97 A) of Tl-Tl single bonds in R(2)TlTlR(2) compounds.

98 breach into the range of extremely stretched single bonds in terms of bond distances and binding ener

99 hat the number of cis double bonds and s-cis single bonds in the polyene chain determine the topology

100 ectrons to the di-gallium unit to generate a single bond (in addition to the weak interaction in the

101 the polarity of the solvent, either complete single bond (in DMSO) or double bond (in cyclohexane) ro

102 The correlation and comparison with aryne single bond insertion chemistry will be discussed.

103 biomembrane force probe capable of measuring single bond interactions, we showed ICAM-1 binding to LF

104 omplexes (s-, d- and f-block) in which a C-C single bond interacts with a metal centre are discussed:

105 bstituent and linked via three carbon-carbon single bonds into a three-dimensional random network of

106 ent nitrogen atoms that are connected with a single bond is highly structure dependent.

107 The catalytic cleavage of two C-C single bonds is achieved by treatment of the hydrocarbon

108 ization of unactivated carbon-hydrogen (C-H) single bonds is an efficient strategy for rapid generati

109 pane carboxaldehyde above the barrier to C-C single-bond isomerization, we applied line-shape analysi

110 bridge-acceptor torsional motions about the single bonds joining them.

111 model is comparable to the binding energy of single bond ketone steroids.

112 monstrating the impact of force history with single-bond kinetic experiments involving selectins and

113 ocyte interface measured in probe tests with single-bond kinetics and the kinetics of cytoskeletal di

114 at longer bond lengths than their respective single bond lengths or their separations in (calculated)

115 Our work at the single bond level directly demonstrates that thiol/disul

116 der high voltage bias at the single molecule/single bond level using the scanning tunneling microscop

117 d bond formation and characterization at the single-bond level probe chemistry at the spatial limit.

118 chamber system mirrored the force-dependent single-bond lifetimes.

119 inside-out and outside-in signaling exhibit single-bond-like statistics for dissociation under force

120 he result of the rotation around the pivotal single bond linking two planar frameworks.

121 e regressed Bell parameters (consistent with single bond Monte Carlo simulation) were zero-stress off

122 fragmentation patterns at the carbon-carbon single bonds neighboring the double bonds.

123 ced energy barrier to rotation about the C-C single bonds next to either a trans or cis carbon double

124 The rotational freedom of the carbon-carbon single bonds of 1,2-disubstituted ethanes affords the po

125 discriminating between the enantiotopic C-O single bonds of a gem-diacetate.

126 accommodated by a model in which many of the single bonds of suramin are unrestricted at room tempera

127 are not compatible with a model in which the single bonds of the linker are completely restricted whe

128 is observed and this suggests torsion around single bonds of the retinylidene chromophore.

129 sion is across the C(2)-C(3) cyclopentadiene single bond, only a single benzene is needed to bind an

130 ed either by bond reforming in the case of a single bond or by asynchronized rupture of multiple indi

131 display an alternating triple and very short single bond pattern, with the degree of bond alternation

132 TCR/pMHC couples in a cell-free system with single bond resolution.

133 ntact atomic force microscopy, we imaged the single-bond-resolved chemical structure of transient met

134 rbon--carbon double bonds and carbon--carbon single bonds, respectively.

135 g-zag lattice direction mediated either by a single bond rotation or through the loss of two carbon a

136 of conformational entropy due to freezing of single bond rotations and the favorable burial of the hy

137 Experiments yielded median single-bond rupture forces from 25 to 44 pN for IgG from

138 Average single-bond rupture forces of -0.95 +/- 0.04 nN were obs

139 e tip and substrate and allows estimation of single-bond rupture forces.

140 ineralized, dehydrated, and infiltrated with Single Bond (SB) adhesive under optimum conditions; the

141 with adjacent nitrogen atoms connected by a single bond should be abandoned.

142 ns linked to the outside of the complex by a single bond showed no inhibition whatsoever at any conce

143 A single bonding site for the iridium is identified on the

144 t undergoes reversible activation of the C-C single bond that interacts with the metal center, establ

145 thus transforming all C=C double bonds into single bonds, the stability of the LiF inside was reduce

146 s of atropisomerism around C(sp(2))-C(sp(3)) single bonds through theoretical calculations.

147 The heme is linked to this protein through a single bond to the 1-methyl group.

148 arbon-fluorine bonds are the strongest known single bonds to carbon and as a consequence can prove ve

149 l motions within the cavity, implicating the single-bond torsion as an important contributor to inter

150 eight of rotational barriers around formally single bonds, UV-vis spectra and electrochemical behavio

151 double bond transformation to a Ti(3+)-O(1-) single bond via the individual atomic displacements of t

152 approximately 0.6 kcal/mol, equivalent to a single bond vibration).

153 e lifetimes near 10(-13) sec, the time for a single bond vibration.

154 Monte Carlo simulation indicates that only a single bond was probably involved in every adhesion even

155 consisting of three or more rotors linked by single bonds, whereby the two terminal rotors are static

156 nto two or more fragments at central acyclic single bonds, while removing any core fragment structura

157 ying micromechanical properties adhered by a single bond with a constant kinetic off-rate.

158 ated to those of the corresponding CH3-XHn+1 single bonds with a slope of 2.5.

159 with benzenoid structures, which form ring-M single bonds with X = CN, CO2Me, CHO, C3HMeBF2O2, and NO

160 is the primary determinant of cleavage of a single bond within the 5 nt strand of the internal loop.

161 ladium-catalyzed activation of carbon-carbon single bonds within triarylmethanols has led to a greate

162 eling, an initial phase is proposed in which single-bonded "Y-ladder" polymers rapidly elongate befor