ライフサイエンスコーパス: solvent

1 ambient temperature, open flask, and undried solvents).

2 radical cage pairs to the properties of the solvent.

3 ine chloride urea as a natural deep eutectic solvent.

4 tes characterized by the total absence of co-solvent.

5 bstantial charge transfer between solute and solvent.

6 osulfonyl)imide [C4mim][Tf2N]) as extraction solvent.

7 and 8MPa pressure, using 63.5% ethanol as co-solvent.

8 trate and, importantly, the use of (2)H2O as solvent.

9 ve the recovery efficiency of the extraction solvent.

10 methylammonium chloride (CTMA) in an organic solvent.

11 d expose their C-terminal extension into the solvent.

12 onversion efficiency, processed by low toxic solvents.

13 lity and low surface tension of most organic solvents.

14 environmental conditions found in different solvents.

15 second lifetime observed for dCyd in all the solvents.

16 nufacturing using green, economic, non-toxic solvents.

17 I) at 32 degrees C in Et2O or in hydrocarbon solvents.

18 orm label-free monitoring of various organic solvents.

19 thermal stability and solubility in organic solvents.

20 columns are best packed using agglomerating solvents.

21 ds than in pure water or many common organic solvents.

22 AE+PLE>PLE, using hydroethanolic mixtures as solvents.

23 f adopting a middle electrode and orthogonal solvents.

24 polar, aromatic, polar, and hydrogen bonding solvents.

25 formed using water and ethanol as extraction solvents.

26 , similar to that found for globular protein solvents.

27 cooperative binding that is present in both solvents.

28 or one substrate, and this is facilitated by solvent 2,2,2-trifluoroethanol (TFE) acting as a proton

29 700muL of acetonitrile for Pb as dispersive solvents, 60muL of CCl4 as extraction solvent for both a

30 photoreactivity of His is determined by both solvent accessibility and structural flexibility.

31 predicted secondary structure, the predicted solvent accessibility and the contact prediction scores

32 The solvent accessibility of R696 is likely mediated by the

33 anine nucleotides resulted in changes in the solvent accessibility of regions of each protein that le

34 ity, their largest effect is in altering the solvent accessibility of the active site by expanding th

35 ere we determined the membrane partition and solvent accessibility of the TMD in bicelles that mimic

36 s of these His residues were correlated with solvent accessibility-related parameters both by crystal

37 r the Zn(2+) binding site and reached into a solvent accessible area.

38 The secondary structure and solvent accessible regions of oncomiR-1 reveal that most

39 The solvent accessible surface area of the K1-K10 structure

40 r the headgroups, making the headgroups more solvent-accessible and increasing surface hydrophilicity

41 s, hydrogen bonding energies, and amino acid solvent-accessible areas.

42 h by crystal structure-based calculations of solvent-accessible surface area and by hydrogen-deuteriu

43 bility and structure-based identification of solvent-accessible surface area, the latter does not dis

44 l forms that experience a large reduction in solvent-accessible volume.

45 time, we report epitaxial growth in aqueous solvent, achieving precise control over 1D nanostructure

46 This research investigated solvent addition order and composition on lycopene extra

47 n be based on various stimuli, such as heat, solvent adsorption/desorption, or electrochemical action

48 oducts in aprotic solvent, whereas in protic solvent almost full conversions were reached.

49 ields under ambient conditions in dioxane as solvent and aqueous tert-butyl hydroperoxide (TBHP) as t

50 eutectic gallium-based alloys as a reaction solvent and co-alloyed desired metals into the melt.

51 The processing solvent and polymer-solvent interactions are important t

52 otein folding, including the balance between solvent and polypeptide chain entropies.

53 es was enhanced by using a less coordinating solvent and short reaction times.

54 The structure is resilient to solvent and temperature changes, and accommodates divers

55 vity of the diamination is controlled by the solvent and the electronics of the cyclopentadienyl (Cp(

56 ich facilitates the rapid evaporation of the solvent and the subsequent deposition of the PbS QD ink

57 scence properties were determined in organic solvents and aqueous surfactants.

58 nd measure OH-pi interactions between protic solvents and aromatic surfaces.

59 ortex agitation (>/=3200 rpm) in LC/MS-grade solvents and by exposing them to the DART source jet str

60 Gamma-oryzanol was extracted with organic solvents and its extracts were characterized by GC-FID a

61 lpha helical to beta strand depending on the solvents and molecules added to the buffer.

62 lection of the proper electrolyte, including solvents and salts, for LSBs strongly depends on its phy

63 nol, acetone, dichloromethane and chloroform solvents and their binary, ternary and quaternary mixtur

64 caffold of a gel that could be filled with a solvent, and thereby form a mechanically stable gel-like

65 ity, excellent resistance to various organic solvents, and its ability to withstand relatively high t

66 lms are soluble in most of the polar organic solvents, and thus until now, they were not considered s

67 low cell yields and require large volumes of solvent "antifreezes".

68 scher glycosidations in low-polarity organic solvents are described.

69 for the production of echium oil using green solvents are proposed.

70 n reaction enabled just by using DMSO as the solvent as well as an oxidant.

71 ptor, due to desolvation penalties in protic solvents, as shown for a tetraquinuclidine XB acceptor h

72 Solvent assisted linker exchange (SALE) and de novo synt

73 ed and its suitability for both thermal- and solvent-assisted desorption, these new SPME probes will

74 oto-demetalation; nucleophilic addition; and solvent-assisted methanol elimination.

75 his work, we report a hydrofluoroether (HFE) solvent-based electrolyte for electrochemical processing

76 entifying mixed (MF, urine) compounds versus solvent-based extraction and chemical analyses.

77 the surface of gp120, and utilized continuum solvent-based loop prediction protocols to improve sampl

78 proton exchange between intermediate(s) and solvent (Bronsted-Lowry base) is known to drive the reac

79 embrane proteins distributed among different solvents, buffers and solutions used due to their physic

80 ls designed at the nanoscale is not simply a solvent, but rather an integral part of their structure

81 ntly used as a substitution agent in a polar solvent by simply adding the polar solvent, thereby tran

82 of postcombustion CO2 capture by water-lean solvents, by separating fact from fiction for both skept

83 led us to the rotation of NH4(+) within its solvent cage and then to the symmetry of hydrogen bonds.

84 ng of medicines as films, without the use of solvents, can accelerate drug screening and enable conti

85 tem, previously described for use in organic solvents, can hydrogenate CO2 to formate in water with b

86 ramatic enhancement of solubility in organic solvents (CH2Cl2, CHCl3) is observed for n >/= 8, and in

87 polar cations were avoided in the less polar solvent (chloroform).

88 eractions than aprotic solvents with similar solvent cohesion parameters.

89 uate the impact of the sample reconstitution solvent composition on metabolome coverage in untargeted

90 modifications were completely controlled by solvent composition, laser wavelength, and peak irradian

91 ecular phenol-amide H-bonds as a function of solvent composition.

92 ulating the starting peptide and fluorinated solvent concentrations during synthesis.

93 In relation to the low solvent consumption, the proposed methodology could be c

94 evealed by higher yield with lesser time and solvent consumption, which can contribute in green extra

95 ILs have been studied as solvents, cosolvents, cosurfactants, electrolytes, and a

96 Advantageously, the oxidant (IBX) and solvent could be recycled up to five times with only a s

97 E devices enabled fast emulsion breaking and solvent deasphalting of petroleum, yielding high recover

98 re perfused using a combined detergent/polar solvent decellularization protocol.

99 sized temperature as the primary variable in solvent degradation.

100 The aluminum-based deep-eutectic solvent demonstrated a significantly enhanced concentrat

101 l investigation accounting for the anomalous solvent dependence of NMR shifts for a series of lanthan

102 ontact shift behavior, as well as a striking solvent dependence.

103 The different solvent dependencies reveal that the dynamics of the all

104 Importantly, unprecedented solvent-dependent and anion-binding-induced circumrotato

105 the basis of DFT calculations, the catalysts/solvent-dependent switchable diastereoselectivities are

106 the chemical and physical properties of the solvent-derived ligand of the enzyme, which will help to

107 the active-site triggers the release of the solvent-derived ligand, priming the metal center for red

108 Deep eutectic solvent (DES) formed by mixing of choline chloride and p

109 The utilization of deep eutectic solvents (DESs) in electrochemical studies has grown in

110 An unprecedented solvent-directed "switch" both in helical pattern and ha

111 Protic solvents displayed systematically weaker solvophobic int

112 odel compound fluorescein, where the organic solvent DMSO is exchanged against an aqueous buffer.

113 mically orthogonal electrolytes based on HFE solvents do not dissolve organic perovskite films and th

114 yst where the increase in reaction rate from solvent-driven pre-organization of the reactants is most

115 for reductive dechlorination of chlorinated solvents due to high reaction rates and the opportunity

116 ization of the membrane-forming block by hot solvent, effectively increasing the volume fraction of t

117 ergetics of cooperativity are complicated by solvent effects and the dynamics of intermolecular inter

118 tion even in the presence of strong cohesive solvent effects.

119 using non-toxic and eco-friendly extraction solvents: either deionized water or aqueous solutions of

120 F) activation involving solvent exchange and solvent evacuation are reported.

121 As solvent evaporation from gels is a concern for various a

122 les (NMP) were prepared by a single emulsion solvent evaporation method with 72.8% encapsulation of V

123 sing a water-in-oil-in-water double emulsion solvent evaporation method with polyethyleneimine (PEI)

124 rn for various applications, we also studied solvent evaporation of wetting and non-wetting liquids d

125 organic framework (MOF) activation involving solvent exchange and solvent evacuation are reported.

126 minal hydrophobic core showed extremely slow solvent exchange, suggesting the trimer formed by this r

127 ndom shuttling and stationary states through solvent exchange, the polyrotaxane monolith not only exh

128 The X-ray data show how Tyr34 maintains solvent exclusion and the core H-bond network in the act

129 emplating base, the B[a]P moiety is in a non-solvent exposed conformation stacked within the DNA heli

130 s: while sequons were positively selected in solvent exposed regions, they were almost completely eli

131 bserved for Fd, where the [Fe4S4] cluster is solvent exposed.

132 xide (DMSO), the adduct is able to move to a solvent-exposed conformation, which enables error-prone

133 d hydrophobic BP pyrenyl residue is entirely solvent-exposed in the major groove of the DNA.

134 cular self-cleavage at Asp-193 evoked higher solvent exposure in the regions of the substrate-binding

135 lar dynamics simulations display alternating solvent exposure of Y671 in the closed and open states.

136 eased inter-beta-sheet distance and a higher solvent exposure than WT-alphaS fibrils, which is also i

137 total visible light absorption (>400 nm) by solvent extractable BrC.

138 nteractions on formation of compounds in the solvent-extractable C70-C100 region are determined by in

139 ech Republic, were achieved, using optimized solvent extraction and liquid chromatography coupled wit

140 rozen storage was recommended when using the solvent extraction methodology.

141 Accelerated solvent extraction was performed using water and ethanol

142 fect of three extraction procedure including solvent extraction, cold pressing and microwave pretreat

143 operties, such as distribution equilibria in solvent extraction.

144 Tests on the composition of the extraction solvent, extraction time and the number of repetitions o

145 The effects of pH, extraction solvent, extraction time, stirring rate, and extraction

146 In this study, solvent extracts (x) of delayed and fluid petcoke (xDP a

147 Solvent extracts of human and mouse food were also able

148 roma extract dilution analysis (AEDA) of the solvent extracts revealed the presence of 76 odorants of

149 n the sampling end of the probe, and carrier solvent flow rate were optimized for maximum signal.

150 The most suitable solvent for antioxidant extraction was 80% acetone.

151 ersive solvents, 60muL of CCl4 as extraction solvent for both analytes and 500muL of 1.5% DDTC soluti

152 een used to study the competition of a polar solvent for formation of intramolecular H-bonds.

153 n, when dried samples are reconstituted in a solvent for injection on column.

154 cteristics (benzoisothiazolone structure and solvent) for the generation of thioesters.

155 A metal and solvent free strategy to functionalize aryl methyl ether

156 vern protein stabilities and structures in a solvent-free environment are still poorly understood.

157 A solvent-free induced self-assembly technology for the sy

158 As a consequence, solvent-free milling can lead to different product compo

159 generated by electrospray ionization) to the solvent-free peptide ion.

160 ols was investigated in solvent-mediated and solvent-free reactions.

161 This interesting metal-solvent-free tactic allows a wide range of useful functi

162 The solvent-free technology developed in this work can also

163 An efficient, solvent-free, and eco-friendly domino reaction of 5/6-me

164 er samples that is both rapid and relatively solvent-free.

165 cts and external parameters (temperature and solvent) generating negligible contributions.

166 spective provides an extensive set of slurry solvents, hardware designs, and a flowchart, a logical a

167 Highly polar protic solvents (hexafluoroisopropanol) favor the formation of

168 An interesting substrate-solvent hydrogen-bonding interaction was observed.

169 urther predicts that residues are exposed to solvent in a coordinated fashion, but without necessaril

170 hloride and phenol was used as an extraction solvent in microextraction study to extract the curcumin

171 als in NMP and the optical absorbance of the solvent in the dispersion.

172 e titration was repeated in pure methanol, a solvent in which the sensor does not aggregate, no fluor

173 osphatase and transferase domains creating a solvent inaccessible cavity.

174 ibiotic vancomycin in four different aqueous solvents (including a medically-used formulation) have b

175 The design is based on the solvent-induced shifting of the patch shape between conc

176 erdye distances, without taking into account solvent-induced spectral and photophysical changes of th

177 The processing solvent and polymer-solvent interactions are important to achieve morphologi

178 tion energy analysis indicate less favorable solvent interactions of 2-5-linkages comparing to the na

179 and ultrafast perturbations from biomolecule-solvent interactions.

180 ation of the polar group next to the protein-solvent interface are difficult to compensate by interac

181 o even low-affinity binding events at the QD/solvent interface.

182 The uptake of solvent into the skin may change the molecular organizat

183 eaction with nitric oxide radical in all the solvents investigated.

184 droxyl radical via both HAT and SPLET in the solvents investigated.

185 Herein, an aluminum-based deep-eutectic-solvent is investigated as an anolyte for redox-flow bat

186 r understanding of it as both a liquid and a solvent is still incomplete.

187 sound in ILs vs those in classical molecular solvents is presented to compare these two classes of co

188 l anion, formed from a strong base and DMSO (solvent), is responsible for inducing the initiation by

189 ter, rather than traditional aprotic organic solvents, is used to dissolve the precursors.

190 and thiol pKa, and the absence of deuterium solvent kinetic isotope effects suggested stepwise mecha

191 Desolvation of the MOF in two different solvents leads to two polymorphic activated forms with v

192 druggable pockets of p53 are identified via solvent mapping to aid future drug discovery studies.

193 ples and data will reduce the need for using solvent masking software (e.g. SQUEEZE) to obtain accept

194 d or cooled in certain polar or paramagnetic solvents may behave as if they carry an electric/magneti

195 The optimum solvent/meal ratio, number of extractions, temperature a

196 atic and aromatic thiols was investigated in solvent-mediated and solvent-free reactions.

197 tial arrangement of the structural units and solvent-mediated effects.

198 found to form J-aggregates in methanol-water solvent mixture and brightly emissive in the solid state

199 s compared to a commonly used reconstitution solvent mixture of 50/50 MeOH/H2O, our results indicate

200 ed on silica gel 60 F254 HPTLC plates with a solvent mixture of ethyl formate, formic acid, water, to

201 ation, temperature, and the variation of the solvent mixture.

202 tadiene)2 reacts with K3Sb7 in en/tol/Bu4PBr solvent mixtures to give black precipitates of Sb@Ni12@S

203 of choline chloride/urea/water deep eutectic solvent mixtures was characterized across a wide hydrati

204 ed anion binding was also studied in aqueous solvent mixtures, which revealed considerable difference

205 lves the relaxation of intramolecular and/or solvent modes.

206 ls and opens the way to large-scale explicit-solvent molecular dynamics simulations of complex system

207 t molecules is further unraveled by explicit solvent molecular dynamics simulations.

208 and bistetradecyl derivatives, containing no solvent molecule, provided the first examples of direct

209 en the iron bound aspartate and the bridging solvent molecule, the DFT calculations of structures con

210 s could not collect any evidence for a bound solvent molecule.

211 the helical assembly, molecular pockets, and solvent molecules is further unraveled by explicit solve

212 n of sodium carbonate, mesitylenic acid, and solvent molecules on sodium ion all are critical in iden

213 g an in situ microextraction device in which solvent moves through the probe, drawing in the analytes

214 n reacts vigorously with the standard slurry solvent N-methyl-2-pyrrolidinone (NMP), indicating it is

215 ncrease the CO concentration by changing the solvent or alloying the surface.

216 products were isolated by decantation of the solvent or by recrystallization.

217 ominantly molecular ions without evidence of solvent or dopant effects as observed in atmospheric pre

218 since they rely on extractions with organic solvents or on in vitro digestion without a subsequent f

219 process determined that careful catalyst and solvent pairing is critical for optimal yield and select

220 ere we show that the accurate measurement of solvent paramagnetic relaxation enhancement (sPRE) in th

221 ctured thin COF films demonstrate remarkable solvent-permeance and solute-rejection performance.

222 ighting the diverse roles that proteinaceous solvents play in dictating the properties of dissolved s

223 The solvent plays a key role in stabilizing the leaving glut

224 These studies demonstrate that the solvent plays a pivotal role in determining the reaction

225 The reline solvent plays the role of a latent supramolecular cataly

226 ission, which red shifts upon increasing the solvent polarity and stems from an excited complex (i.e.

227 Additionally, solvent polarity influences the deactivation pathway, gr

228 In addition, neither solvent polarity nor radical rotation affects the correl

229 ength across the visible spectrum by varying solvent polarity.

230 m 2-carboxylate, was remarkably sensitive to solvent polarity.

231 ng of evaporant, surfactant, and plasticizer solvents, polylactic-co-glycolic acid (30% by solids vol

232 NH3 -MeNH2 , is presented in which the mixed solvent produces a novel type of electron solvation and

233 The electronic cigarette solvents propylene glycol and glycerol are known to prod

234 xtreme external stressors, including organic solvents, proteases, and ethylene oxide gas sterilizatio

235 scence experiments, addressing the effect of solvent proticity on the relaxation dynamics of dCyd and

236 d and selectivity; proper choice of nonpolar solvent provided improved yield through suppression of a

237 general method to extract the dimensions and solvent quality (self-interactions) of IDPs from a singl

238 C-Cl bond cleavage was reduced in an organic solvent (reaction with arene radical anions in glyme).

239 Extraction solvent recovery was found to be a crucial uncertainty t

240 ift from 2DES spectra revealing an ultrafast solvent relaxation.

241 ng a post-deposition annealing treatment for solvent removal.

242 water libration bands at ca. 730 cm(-1) upon solvent replacement by adsorbed MOP.

243 The solvent retention capacity profile was also affected by

244 that was stable at varying pH and in various solvents, salts, and chemicals.

245 m dots were prepared in a variety of organic solvents stabilized with a quaternary ammonium halide sa

246 This solvent strength related incompatibility can lead to sev

247 In nonaqueous solvents such as organic nitriles, the prototype TAML ac

248 While solvents such as THF promote these complex redistributio

249 se complex redistribution pathways, nonpolar solvents such as toluene enable increased stabilization

250 t moderate-to-good solubility in chlorinated solvents, such as 1,2-dichlorobenzene and chloroform.

251 loyed in competition experiments using polar solvents, such as DMF, no "mixed" products possessing st

252 c description of the dynamics of the protein-solvent system has yet to be achieved.

253 viscosity is valid over a range of different solvent system types, including nonpolar, aromatic, pola

254 n of strong longer-range order in this mixed solvent system.

255 ationship of FcP to microviscosity holds for solvent systems containing mixtures of these solvent typ

256 tein ionic liquids represent multifunctional solvent systems that are well suited to overcoming low m

257 ity factor, the use of electrolytes based on solvent systems that exclusively use components that are

258 t-butoxyaniline our optimized reaction (i.e. solvent, temperature and catalyst study) affords excelle

259 The solvent, temperature, and nucleophile are in addition va

260 ess I is seen at temperatures below the bulk solvent Tg, has low activation energy, and is likely due

261 es to be assayed per unit time, it uses less solvent than other techniques and therefore reduces cost

262 c and significantly more soluble in nonpolar solvents than their oxosquaramide counterparts, and they

263 ry systems consisting of an amphiphile and a solvent, the ability to tune the 3D cubic phase nanostru

264 the QuEChERS method, such as the extraction solvent, the buffer salt, or the purification procedure,

265 n a polar solvent by simply adding the polar solvent, thereby transforming the polymer-iodide to poly

266 ses of antioxidants, but the ability of this solvent to extract free fatty acids also decreases.

267 luding the use of methanol at a 3:1 ratio of solvent to milk for protein precipitation and dichlorome

268 living radical polymerization in a nonpolar solvent to produce a polymer-iodide and was subsequently

269 on precious metals and operate in nonaqueous solvents to suppress competing H2 generation.

270 on of reaction mixture to acetonitrile (anti-solvent) to form a slurry and further separating the sol

271 sulting nanocomposite membranes prepared via solvent transfer-induced phase separation and photopolym

272 anilines-based COF (SA-COF), which undergoes solvent-triggered tautomeric switching.

273 mbly (e.g., NC concentration and solubility, solvent type, evaporation rate, seed mediation and therm

274 solvent systems containing mixtures of these solvent types.

275 other emission sector contributions such as solvent use remains tenuous.

276 F membranes is incompatible with the organic solvents used for the COF IP process.

277 nti-diastereoselectivity irrespective of the solvents used.

278 on technique based on the continuous flow of solvent using an in situ microextraction device in which

279 ppm-limits of detection were achieved with a solvent volume as low as 160muL.

280 mn) to allow unparalleled minimum sample and solvents volumes usage.

281 ne dissolved in a water-immiscible, volatile solvent was deposited in a humid environment on a variet

282 dispersed in caprylic acid as an extraction solvent was placed into a polypropylene porous hollow fi

283 ive principles, limiting extraction time and solvent waste.

284 ase in covalency is observed upon removal of solvent water from EndoIII and MutY, opposite to the sig

285 ntrast to the case of hydrogen bonding among solvent water molecules, we find that energy mismatch be

286 By varying the reaction solvent (water or ethanol), NPs with different sizes and

287 ted state relaxation of dCyd/5mdCyd in three solvents-water, acetonitrile, and tetrahydrofuran-by com

288 Using epitaxial growth in an alcoholic solvent, we show exquisite control over the dimensions a

289 cation and the type of sorbent or extraction solvent were assayed.

290 f 1,3-benzoxazines with thiols in absence of solvents where acidity predominates nucleophilicity.

291 amounts of reactants and products in aprotic solvent, whereas in protic solvent almost full conversio

292 na proteins can be thought of as "programmed solvents", which bind pigments at specific mutual orient

293 urface that can super-repel even fluorinated solvents, which highly wet all materials.

294 Distinct controls of NC assembly in solvent with variable concentrations confirm the NC conc

295 abilization of charged solutes works well in solvents with high dielectric constants, such as water (

296 weaker solvophobic interactions than aprotic solvents with similar solvent cohesion parameters.

297 using environmentally benign, nonchlorinated solvents, with the CPDS and IDSe copolymers exhibiting h

298 olubility in a variety of polar and nonpolar solvents without changing the anion structure and proper

299 control directly in a biologically relevant solvent, without affecting cell viability, opens the doo

300 l salts that spontaneously dissolve in polar solvents yielding ionic solutions.