ライフサイエンスコーパス: spectroscopically

1 ement could never be unambiguously evidenced spectroscopically.

2 y, but differed both chromatographically and spectroscopically.

3 charge-transfer complexes have been observed spectroscopically.

4 in argon matrices at 15 K and characterized spectroscopically.

5 ese complexes was probed computationally and spectroscopically.

6 ted in low-temperature matrices and observed spectroscopically.

7 4b), have been synthesized and characterized spectroscopically.

8 s predicted by DFT calculations and observed spectroscopically.

9 hich was also characterized structurally and spectroscopically.

10 ach dipyrrinone was synthesized and examined spectroscopically.

11 cles were investigated electrochemically and spectroscopically.

12 with the CO recombination kinetics measured spectroscopically.

13 of structural regions of the protein probed spectroscopically.

14 m Hall effect, has proved difficult to probe spectroscopically.

15 C5R5) and Cr2(CO)5(C5R5)2 have been detected spectroscopically.

16 lbenzene core have been prepared and studied spectroscopically.

17 ared by the hot injection method and studied spectroscopically.

18 three methods and characterized the product spectroscopically.

19 he Keap1 sensor for inducers is demonstrated spectroscopically.

20 egrees C to remove the addends, and analyzed spectroscopically.

21 uclear Cu enzymes can be trapped and studied spectroscopically.

22 d in good yield and studied structurally and spectroscopically.

23 flavin in the reduced enzyme can be observed spectroscopically.

24 -OS(CD(3))(2)(+), which can be characterized spectroscopically.

25 ethylene group were synthesized and examined spectroscopically.

26 nonheme macrocyclic ligand and characterized spectroscopically.

27 f photosystem I complexes were characterized spectroscopically.

28 node was elucidated both computationally and spectroscopically.

29 utation in sickle cell hemoglobin was probed spectroscopically.

30 ropanone could be observed and characterized spectroscopically.

31 scattering and infrared molecular absorption spectroscopically.

32 ) within the {W18O56} cage could be followed spectroscopically.

33 ed platinacyclobutane that has been observed spectroscopically.

34 r this inactive COR variant was demonstrated spectroscopically.

35 at cryogenic temperatures, and characterized spectroscopically.

36 temperature inert matrixes and characterized spectroscopically.

37 the pyrene polymer core that can be followed spectroscopically.

38 ed the production of Hg(0) that was observed spectroscopically.

39 ted-are largely unknown because they are not spectroscopically accessible from the ground state.

40 many-body molecular dynamics, which enables spectroscopically accurate simulations of water from the

41 tal ion, which are difficult to study due to spectroscopically active and complex backgrounds, short

42 abled the inclusion of analytes that are not spectroscopically active and were not among the original

43 Co(IV) to be isolated and studied against a spectroscopically active Co(III) background.

44 y(ethylene glycol) graft copolymers from six spectroscopically active styrene monomers: styrene, 2,5-

45 o-field splitting parameters that create two spectroscopically addressable transitions, with one bein

46 the interstitial fluid could be measured by spectroscopically addressing the sensor through an optic

47 f steps required for 1, and yet behaves in a spectroscopically analogous manner to 1 in oligonucleoti

48 This study aims to spectroscopically analyze brains from free-flying birds

49 certainties of 25 to 50 per cent if measured spectroscopically and 90 to 150 per cent if measured pho

50 intermediates have been fully characterized spectroscopically and analytically.

51 rhodium compounds with dsDNA were determined spectroscopically and are in the order Rh1 << Rh2 < Rh3.

52 roximately 70% to an epoxyalcohol identified spectroscopically and by chemical synthesis as 9R,10S-ep

53 ignal from myelin suspensions is shown, both spectroscopically and by imaging, to scale with concentr

54 r a second addition of H(2)O(2), as observed spectroscopically and by mass spectrometry.

55 d their conformational behavior was examined spectroscopically and by molecular modeling.

56 Both III and IV have been characterized spectroscopically and by single-crystal X-ray diffractio

57 These species, characterized spectroscopically and by X-ray crystallography, feature

58 Compound 10, characterized spectroscopically and by X-ray crystallography, was tran

59 ium complexes, which have been characterized spectroscopically and by X-ray crystallography.

60 (3))(5), has been prepared and characterized spectroscopically and by X-ray crystallography.

61 These compounds have been characterized spectroscopically and by X-ray crystallography.

62 few examples of Fe(V) species that could be spectroscopically and chemically characterized.

63 While Cu sites are spectroscopically and chemically distinct away from thes

64 arallels and contrasts are drawn between the spectroscopically and computationally supported mechanis

65 This lithium-rich zincate has also been spectroscopically and crystallographically characterized

66 to afford phosphonium salts, which have been spectroscopically and crystallographically characterized

67 d these processes can be followed optically, spectroscopically and crystallographically.

68 C3H6)(CO)3(PMe3)2(NO)]BF4 were characterized spectroscopically and crystallographically.

69 s been prepared and thoroughly characterized spectroscopically and electrochemically.

70 omologs in other organisms, we characterized spectroscopically and functionally the Fe(II), Fe(II)-NO

71 tidine-glutamate pair formation, as observed spectroscopically and in the crystal structure, determin

72 ss could be verified by gel electrophoresis, spectroscopically and in vitro confocal imaging studies.

73 om Rhodobacter capsulatus have been examined spectroscopically and kinetically.

74 idopsis thaliana has been characterized both spectroscopically and kinetically.

75 uried" metallic structures are characterized spectroscopically and modeled using rigorous coupled wav

76 This charge-transfer transition is observed spectroscopically and probed using resonance Raman spect

77 The latter two complexes were spectroscopically and structurally characterized for com

78 All compounds were spectroscopically and structurally characterized.

79 lly bound azide ligand has been prepared and spectroscopically and structurally characterized.

80 The shell growth is characterized both spectroscopically and structurally.

81 is formed, whose structure was investigated spectroscopically and theoretically.

82 Ar3(*+) --> 2TiO2/Ru(III)-NAr3) was observed spectroscopically and was modeled by Monte Carlo simulat

83 halosporin sulfone was examined kinetically, spectroscopically, and crystallographically.

84 r-induced, solvent-free nature, was followed spectroscopically, and found to occur concurrently with

85 s complex was characterized structurally and spectroscopically, and its electronic structure is discu

86 e pMMO metal centers have been characterized spectroscopically, and the first pMMO crystal structure

87 The oxygenation products were characterized spectroscopically, and the structure of the octahedral i

88 re have been structurally confirmed and also spectroscopically, and the Ti-Nnitride bonding has been

89 trodes were characterized electrochemically, spectroscopically, and with electron microscopy.

90 = 2,3) established crystallographically and spectroscopically, are quite similar, with Fe---Fe dista

91 lex, which is characterized structurally and spectroscopically as a mononuclear side-on (eta(2)) mang

92 N(n)(-*) radical anion was directly observed spectroscopically as an intermediate in the charge-separ

93 All compounds are characterized spectroscopically as well as by X-ray crystallography of

94 cs of covalent modification can be monitored spectroscopically at 354 nm in the presence of the QD an

95 ungstic acid complexes, which are determined spectroscopically at 765 nm.

96 CH(2))(H)][OTf] (4), which was characterized spectroscopically at low temperature.

97 oles in function, yet are difficult to study spectroscopically because of their sparse population.

98 The spectroscopically best defined cluster accounts for ca.

99 The cluster has been investigated spectroscopically both experimentally and theoretically

100 ses in water are slow and difficult to probe spectroscopically but are fundamental to the performance

101 ure of the [B12 Cl11 ](-) anion is confirmed spectroscopically by the observation of a blue shift of

102 natural organic matter (NOM) were addressed spectroscopically by the sorption of paramagnetic nitrox

103 these high-symmetry models, were explored by spectroscopically calibrated bonding calculations, and t

104 Spectroscopically calibrated density functional calculat

105 data for Hase I, which, in conjunction with spectroscopically calibrated density functional theory (

106 Spectroscopically calibrated quantum-chemical computatio

107 hole transport in the dye monolayer observed spectroscopically can be explained by incomplete coverag

108 agraphic telescope in space could detect and spectroscopically characterize nearby exoplanetary syste

109 Here, we spectroscopically characterize the DNA-mediated oxidatio

110 scan FTIR (s2-FTIR) spectroscopy was used to spectroscopically characterize the photoproduct, W, and

111 In an effort to spectroscopically characterize this species in P450BM3,

112 and phenyldihalomethide carbanions have been spectroscopically characterized and computationally inve

113 The cyclic dimers 12 and 22 were spectroscopically characterized and found to direct thei

114 The new compounds have been spectroscopically characterized and their redox potentia

115 The borirenes were isolated and spectroscopically characterized by multinuclear NMR, IR,

116 ylgermane cation radicals were generated and spectroscopically characterized by nanosecond transient

117 that of ligated diboranes and diborenes, was spectroscopically characterized during photolysis of di-

118 Spectroscopically characterized for the first time, 1 (+

119 NO(2))(TC-6,6)] complex was structurally and spectroscopically characterized from the reaction mixtur

120 riafulvene cyclopropenium salt, and has been spectroscopically characterized in [D8 ]THF solution at

121 Free borylenes (R-B:) have only been spectroscopically characterized in the gas phase or in m

122 ructurally characterized in the solid state, spectroscopically characterized in the gas phase, and mo

123 sors have been synthesized, structurally and spectroscopically characterized, and implemented in grow

124 These stable adducts were spectroscopically characterized, and in one case, the B-

125 )-propenyl)(H), was independently generated, spectroscopically characterized, and observed to convert

126 his proposed mechanism have been isolated or spectroscopically characterized, including two new iridi

127 )dien)(CH(3)CN)](2+) (7) was synthesized and spectroscopically characterized.

128 ol)CO(2))Ag] (3), which was structurally and spectroscopically characterized.

129 H4)2Sn AriPrs (4) that were structurally and spectroscopically characterized.

130 the monomeric (IPr**)CuH complex, which was spectroscopically characterized.

131 er complex has been crystallographically and spectroscopically characterized.

132 Clusters III-VIII have been structurally and spectroscopically characterized.

133 rio cholerae, and the H-NOX protein has been spectroscopically characterized.

134 R = Me, nPr, nBu] have been synthesized and spectroscopically characterized.

135 dedicated facility for directly imaging and spectroscopically characterizing extrasolar planets.

136 The identity of 2 was confirmed spectroscopically, chemically, crystallographically, and

137 The constructs were characterized spectroscopically, chromatographically, and electrophore

138 data set of light curves for 247,000 known, spectroscopically confirmed quasars with a temporal base

139 Here we report three spectroscopically confirmed type IIn supernovae, at reds

140 xisting structural templates and generated a spectroscopically constrained model of the hHv1 dimer ba

141 The excited singlet S1 state is spectroscopically dark, whereas photoexcitation to highe

142 -Fe(ii) and alpha-O-are challenging to probe spectroscopically: data from bulk techniques such as X-r

143 I)-X-Fe(4)S(4)] bridged assembly that is the spectroscopically deduced structure of the A-Cluster in

144 d provide structural evidence supporting the spectroscopically derived conclusions.

145 An NMR spectroscopically derived structure of a TEL fragment, d

146 [Re(DPPBT)(3)], no reaction with ethylene is spectroscopically detectable consistent with the determi

147 former type leads to a moderately stable and spectroscopically detectable platinum(IV) intermediate.

148 These spectroscopically detectable states represent a chemical

149 to the ionization of the internal groups was spectroscopically detectable, especially in the less sta

150 capped on both ends with NMM, supporting the spectroscopically determined 1:1 stoichiometry.

151 termination of acidity in ice cores based on spectroscopically determined color changes of two common

152 of the charge separation kinetics using the spectroscopically determined reorganization energies and

153 It was spectroscopically determined that heating the platinum s

154 We have spectroscopically determined the relative angle between

155 on kinetics of neutravidin to the surface by spectroscopically determining the fractional occupancy a

156 terest from other naturally occurring lipids spectroscopically, deuterium labels were introduced.

157 n (NBD-Coum) construct, which fragments into spectroscopically differentiable products upon nucleophi

158 temperature and chaotropic denaturation are spectroscopically differentiable.

159 ate that although N-myristoylation causes no spectroscopically discernible conformational change in p

160 mitted light signals that were collected and spectroscopically dispersed, in essence creating a senso

161 a monomer contains a FAD redox cofactor, two spectroscopically distinct [2Fe-2S] clusters, and a moly

162 oduct binding studies were used to show that spectroscopically distinct Chlide species could be obser

163 These reveal two spectroscopically distinct classes of such ferriheme cen

164 apsulation protocols to trap kinetically and spectroscopically distinct conformational populations of

165 Addition of TFA resulted in the formation of spectroscopically distinct dications.

166 amagnetic (S=0) 8-Fe cluster, containing two spectroscopically distinct Fe sites that appear in a 3:1

167 ting NADH:quinone oxidoreductase forms three spectroscopically distinct flavin radicals as follows: 1

168 red1 state, is generated by reducing another spectroscopically distinct form called ox1 with titanium

169 Three spectroscopically distinct forms of the enzyme are obser

170 Two spectroscopically distinct forms of this cluster have be

171 These excimers are spectroscopically distinct from singlet and triplet exci

172 CmlI-peroxo is spectroscopically distinct from the well characterized a

173 No spectroscopically distinct intermediates are observed in

174 that melting/refolding occurred without any spectroscopically distinct intermediates, yet the relaxa

175 iophenol, we present a novel approach toward spectroscopically distinct NIR dyes for which the degree

176 We present evidence that two spectroscopically distinct redox-active carotenoids are

177 3ReO3 on silica-alumina contain two types of spectroscopically distinct sites.

178 25 degrees C, but slowly converts to another spectroscopically distinct species with a lambda(max) at

179 indicates that at low salt there is a third spectroscopically distinct species, while at higher salt

180 = 0, 1, or 2) as well as two mechanisms with spectroscopically distinct starting structures (F(1) and

181 ICT excitation reveal the appearance of two spectroscopically distinct states having different dynam

182 heterogeneous protein environments that are spectroscopically distinct.

183 transition frequency shifts, we were able to spectroscopically distinguish sites with different occup

184 posite direction of this shift enabled us to spectroscopically distinguish the target from nonspecifi

185 aramagnetic resonance (EPR) spectroscopy, we spectroscopically distinguish two Cu(II) binding sites o

186 orphyrin (TSPP) diacid, the concentration of spectroscopically distinguishable aggregates increases w

187 rocarbon interior of the droplets, which are spectroscopically distinguishable and allow for chemical

188 +) and acts as a synergistic anion to give a spectroscopically distinguishable intermediate, Fe(3+)Fb

189 he reaction involves several kinetically and spectroscopically distinguishable intermediates.

190 This indicates that several spectroscopically distinguishable metal coordination env

191 -phase and interfacial acetonitrile are thus spectroscopically distinguishable.

192 Two conformational isomers of triplet 3 are spectroscopically distinguishable.

193 itions resulting in these Cu(II) sites being spectroscopically distinguishable.

194 he ligand bound versus unbound states can be spectroscopically distinguished.

195 bstrate, has been prepared and characterized spectroscopically, electrochemically, and with a solid s

196 The latter has been spectroscopically elucidated by NMR via C-H coupled and

197 the cluster species extracted from NifEN is spectroscopically equivalent and functionally interchang

198 PEG bears a large number of spectroscopically equivalent protons exhibiting a narrow

199 e rapid phase to form a heme-protein complex spectroscopically equivalent to that of the wild-type in

200 residues of Ca(II)- and Mn(II)-bound CP are spectroscopically equivalent.

201 area of host-guest organic chemistry, or to spectroscopically evaluate in-depth the intramolecular e

202 methano[10]annulene unit is synthesized and spectroscopically evaluated.

203 The (3)NI yields monitored spectroscopically exhibit resonances as a function of ma

204 i(IV) species was observed and characterized spectroscopically for a nickelacycle system.

205 equencies so that it could be differentiated spectroscopically from the phosphoglycerol component in

206 he oxidation of 4e, the product aziridine is spectroscopically identical to its parent, 1e, indicatin

207 etween 60 and 130 degrees C were shown to be spectroscopically identical to those obtained by slow so

208 This photoproduct is spectroscopically identifiable as a cob(II)alamin specie

209 s fundamentally interesting because it forms spectroscopically identifiable complexes with water at a

210 In this study, we spectroscopically identified methylglyoxal diol (MGD) an

211 Surface-bound morantel was spectroscopically identified using second harmonic gener

212 we use the 'Campanile' nano-optical probe to spectroscopically image exciton recombination within mon

213 characterize large populations of such tags spectroscopically in a high-throughput flow-based platfo

214 onding diazo compound precursors and studied spectroscopically in cryogenic matrices (N(2) or Ar) at

215 dene (MeC3Me, (3)3), which was characterized spectroscopically in cryogenic matrices.

216 species have been trapped and characterized spectroscopically in enzymatic and biomimetic reactions,

217 SLNs were identified spectroscopically in photoacoustic images.

218 tive bound states can be created and studied spectroscopically in present-day experiments with ultrac

219 It is possible to watch the reaction spectroscopically in real time, determine when it reache

220 ve) intermediate that is fleetingly detected spectroscopically in solution versus that rigorously def

221 n spectra in the near-infrared was monitored spectroscopically in the presence of analyte.

222 rations in the surface region are identified spectroscopically in varying bulk pH solutions, and are

223 ic variations should therefore be detectable spectroscopically in X-ray observations of solar analogs

224 e deuteration of the matrix lipid to make it spectroscopically inactive.

225 n radical (Compound I) intermediate which is spectroscopically indistinguishable from those that perf

226 ative where the T1 Cu has been replaced by a spectroscopically innocent Hg2+ ion has led to a detaile

227 d at nanomolar levels to allow for SMs to be spectroscopically interrogated.

228 ecific Oct1-DNA complex, sparsely-populated, spectroscopically "invisible" states reveal their footpr

229 roteins can offer fundamental information on spectroscopically "invisible" steps.

230 plementary parallel ion pair-pi repulsion is spectroscopically irrelevant, in part because of charge

231 lly all maturation stages in dentin could be spectroscopically isolated and analyzed.

232 been shown to be suitable for preparation of spectroscopically labeled lysophosphatidylcholines.

233 d by the development of instrumentation that spectroscopically maps nanotube contents inside undistur

234 S,39R)-azaspiracid-3 chromatographically and spectroscopically matched naturally occurring azaspiraci

235 As expected, spectroscopically measurable unwinding penetrates approx

236 spectral approach to spatially delineate and spectroscopically measure single nanotube fluorescence i

237 Conventional MR imaging findings, spectroscopically measured absolute NAA and choline conc

238 The 28-mer Cu-HTH peptide P7 spectroscopically mimics the PrP octarepeat (P7 = TERRRQ

239 GATA proteins as potential targets for lead, spectroscopically monitored metal-binding titrations wer

240 roach described here shows the potential for spectroscopically monitoring changes in macromolecular o

241 ctrochemical FT-IR setup was demonstrated by spectroscopically monitoring microstructured polymer dep

242 ng effluent Fe(II) (aq) concentration and by spectroscopically monitoring the hematite dissolution fr

243 led us to the use of the less-sensitive but spectroscopically more robust 2.9 mum laser.

244 for the 8-propionate in the formation of the spectroscopically native P(r) dark states of these bilip

245 The bis-thiocyanato Ru(II) complex has been spectroscopically (NMR and UV-vis), electrochemically, a

246 undetectable for the H2IMes system, but was spectroscopically observable for the IMes system.

247 exciplexes as the dominant, kinetically and spectroscopically observable intermediate.

248 that exhibit reactivity with O2 and lead to spectroscopically observable metal-oxygen species, and/o

249 Continued operation leads to spectroscopically observable Ni oxidation and another st

250 The spectroscopically observable tris(thiolate) complex [Ru(

251 ections are reported for the closely spaced, spectroscopically observed (tilde)B(2A1), (tilde)C(2B1),

252 , nonmetallic nitrenes have so far only been spectroscopically observed at low temperatures, despite

253 (2))](+) lead to accurate predictions of the spectroscopically observed IVCT transition energies.

254 pectedly similar to that found in cryogenic, spectroscopically observed phosphinidene species.

255 -XYL)(O2)](2+) complex, only a P species was spectroscopically observed.

256 Spectroscopically observing the translational and rotati

257 ash-quench experiments and could be observed spectroscopically on the nanoseconds to microseconds tim

258 plex under these conditions is verified with spectroscopically orthogonal nitroxide and Gd(III)-based

259 tuent on one pyridyl ligand arm, affording a spectroscopically pure end-on bound disulfido-dicopper(I

260 cavity at the cluster surface, and they are spectroscopically quite similar to internalized cavity i

261 t doubly pi(2)pi*(2) excited state, which is spectroscopically rather dark.

262 The acetal (H1C1) groups suffice to spectroscopically resolve approximately 20 different sta

263 Spectroscopically resolved carbohydrates include more th

264 itions into d orbitals of t(2g) symmetry are spectroscopically resolved for all four complexes, the e

265 producing the real-time reaction courses of spectroscopically resolved kinetically competent interme

266 IR spectroscopy to reveal equilibria between spectroscopically resolved substates of the lipidated si

267 ly oxidized form of the blue dimer [4,5] was spectroscopically resolved within the time frame of the

268 factor in the active site of VHPOs contains "spectroscopically silent" V(V), which does not change ox

269 acts with H(2)O(2) to form a complex that is spectroscopically similar to a synthetic model that stru

270 It is spectroscopically similar to red copper nitrosocyanin, b

271 x supernovae are stellar explosions that are spectroscopically similar to some type Ia supernovae at

272 is the finding that the autofluorescence was spectroscopically similar to the bisretinoids that const

273 arsenate species could not be differentiated spectroscopically, since their U-As distances were equal

274 These compounds are spectroscopically, structurally, and stereodynamically v

275 structure of doubly ionized benzene has been spectroscopically studied for the first time.

276 None of the complexes observed spectroscopically subsequent to [(FI)Ti(CH2CMe3)2](+) is

277 Of several dozen galaxies observed spectroscopically that are candidates for having a redsh

278 Raman multivariate curve resolution to probe spectroscopically the hydrophobic hydration shell and, u

279 If the complex ML(n) could be observed spectroscopically, the absorbance of the product A(p) fo

280 individual vibrational bands can be resolved spectroscopically, their assignment becomes problematic

281 atomic molecule, N(2) is difficult to detect spectroscopically through infrared or millimeter-wavelen

282 electron-hole pairs (excitons) are accessed spectroscopically through their allowed single-quantum t

283 eme 19 in the article) which was also proven spectroscopically to be non-identical to the naturally o

284 Subsequently, it was measured spectroscopically to be z = 6.29 +/- 0.01, in agreement

285 tures, for example nanorods, have been shown spectroscopically to display increased multiple exciton

286 ng the oxygen redox couple, which we observe spectroscopically to persist for 500 charge/discharge cy

287 ific and site selective C-H hydroxylation is spectroscopically trapped, and its catalytic reactivity

288 In spectroscopically underdetermined structure elucidation

289 ociated with either competing aggregation or spectroscopically unfavorable size and exchange rates ha

290 ve a small population of molecules that were spectroscopically unique from the large population of mo

291 This intermediate was observed spectroscopically upon addition of a pyridine base to pr

292 addition, these compounds have been examined spectroscopically (UV-vis-NIR, IR) in all accessible red

293 ry of peptide constructs, we show that three spectroscopically (UV/visible and electron paramagnetic

294 Spectroscopically validated computations corroborate the

295 Spectroscopically validated density functional theory ca

296 Spectroscopically validated DFT calculations are used he

297 Spectroscopically validated electronic structure calcula

298 bistriazole/phen macrocycles, characterized spectroscopically, were obtained in 65-70% yield.

299 strong affinity to HSA that was investigated spectroscopically with compound 3h.

300 produced within the film, which is analyzed spectroscopically, yielding a detection limit of 0.830 p