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1 Stille coupling with an appropriate pyridyl stannane.
2 pecific silver-mediated fluorination of aryl stannanes.
3 than by transmetalation of the corresponding stannanes.
5 tting the stage for the acquisition of vinyl stannane 13 and its subsequent palladium-catalyzed Still
6 ladium-catalyzed coupling of the vinyl 6'(E)-stannanes 14 with (E) and (Z) ethyl 3-iodoacrylate gave
7 ediated Stille cross-coupling of the vinylic stannane 4 and the alkenyl bromide 5 to produce a highly
8 which was coupled in a Stille reaction with stannane 68 to give 2 after cleavage of the TIPS ether.
9 ng showed that the alkyls originate from the stannane and not from ambient impurities, and that trial
10 tille coupling of an acetylene-derived vinyl stannane and vinyl iodide of approximate equal complexit
11 yl groups) can be generated from (2-azaallyl)stannanes and (2-azaallyl)silanes through an intramolecu
12 a mild copper-mediated fluorination of aryl stannanes and aryl trifluoroborates with N-fluoro-2,4,6-
13 or carbon-carbon bond formation between aryl stannanes and olefins via Pd(II) catalysis in the presen
14 rated by tin-lithium exchange of (2-azaallyl)stannanes and underwent [pi4s+pi2s] and [pi6s+pi4s] cycl
15 to both enantiomeric forms of an epoxy vinyl stannane, and a series of coupling reactions, including
17 substrate (C(1)-C(27) fragment) with a vinyl stannane as the main coupling processes to assemble the
18 ircumvents isomerization by the synthesis of stannanes as intermediates and their use in a Stille cou
19 (ee 99%) were generated from the respective stannanes by tin-lithium exchange at temperatures rangin
20 acetylenes into functionalized phenanthrenyl stannanes can be initiated via two potentially equilibra
23 terodimer cation radicals formed between the stannane cation radicals and the neutral codonors, which
26 er, the first X-ray structure of a [Ru(sigma-stannane)] complex (12a) is presented, which indeed feat
27 epoxidation/enzymatic kinetic resolution of stannane-containing substrates that led selectively to b
29 des to the corresponding trifluoromethylated stannane ether intermediates at room temperature in high
31 the functionalized five-membered ring vinyl stannane from the monoterpene R-(-)-carvone featuring a
32 se high E/Z 1-bromo-1-fluoroalkenes and aryl stannanes gave (Z)-alpha-fluorostilbenes in high stereos
33 rst, methods for the preparation of anomeric stannanes have been developed and optimized to afford bo
34 ce on the bulk solution concentration of the stannane, hinting that more than one alkyl can be transf
35 allylation of aldehydes with fluorous allyl stannanes illustrates the usefulness of the new fluorous
37 fonyl)vinyl AA-esters undergo smooth sulfone-stannane interchange to stereoselectively give the corre
43 did not suffer from competitive reduction by stannane, offering an advantage over the use of diazo an
44 the double allylation of either (2-azaallyl)stannanes or (2-azaallyl)nitriles, both of which thereby
46 uch as allylic silanes, boronates, germanes, stannanes, pivalates, phosphonates, phthalimides, and to
47 ocol avoids usage of the arylboronic acid or stannane precursors for the synthesis of 5-(2-furyl, or
49 ) macrocyclic iodide with a C(29-46) oxazole stannane side chain to establish the complete phorboxazo
50 metal-catalyzed addition of metal hydrides (stannanes, silanes, and germanes) and bimetallic species
51 (Ge(4)H(10)), tetrasilane (Si(4)H(10)), and stannane (SnD(4)) hydride precursors, allowing the simul
53 s byproducts during the synthesis of the DHA stannanes, this approach allowed the regioselective inco
54 eta face directs deuterium transfer from the stannane to C2'(C3') on the alpha face of the furanose r
55 talyzed reactions with silanes, germanes and stannanes to form disiloxanes, and R(3)SiOER(3) E = Ge,
57 )methanethione, on treatment with silanes or stannane under heating or microwave irradiation undergoe
58 trate that configurationally stable anomeric stannanes undergo a stereospecific cross-coupling reacti
59 nnanes could be prepared from monosaccharide stannanes via O-glycosylation with Schmidt-type donors,
60 2-azaallyllithium species derived from these stannanes were shown to undergo efficient [3 + 2] cycloa
61 or the preparation of the cyclic (2-azaallyl)stannanes, which are precursors to the nonstabilized 2-a
62 9% ee) were generated from the corresponding stannanes, which themselves were prepared by Hoppe-Beak
64 tille cross-coupling reaction of propargylic stannanes with 5-iodo-1,3-oxazoles to produce 1,1-disubs
65 nesium reagents and (3-methylthio-2-azaallyl)stannanes with a Ni(0) catalyst provided cyclic nonstabi
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