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2 oxide and vinyl ethyl sulfoxide using nearly stoichiometric 3 % aqueous H2 O2 with a turnover frequen
3 etect in biological samples owing to its low stoichiometric abundance and the lack of effective enric
4 cat of 11 +/- 0.4 s(-1) We also quantify the stoichiometric accumulation of formic acid as the produc
7 l troublesome sulfonamide hydrolysis, a near-stoichiometric amount of acid was found to be sufficient
10 zed with tantalum and prepared with a nearly stoichiometric amount of boron (4.5) as W0.668Ta0.332B4.
11 ellurides can be accessed upon mixing with a stoichiometric amount of dissolved selenium or tellurium
12 enone derivatives mediated by a catalytic or stoichiometric amount of new chiral non-C2-symmetric iod
16 tyrosinase-like fashion and (ii) addition of stoichiometric amounts (1 or 2 equiv) of Lewis acids (LA
20 eutral and anionic phases upon reaction with stoichiometric amounts of halide or pseudohalide salts.
22 ut recourse to transition-metal catalysis or stoichiometric amounts of organometallic building blocks
24 -stannyl benzoates need to be prepared using stoichiometric amounts of the (+)- or (-)-enantiomer of
26 nits of complexes that are produced in super-stoichiometric amounts relative to their exponentially d
27 chlorine occurs in air-saturated solution in stoichiometric amounts with 2 mol of AgNPs oxidized for
28 istributed on dendritic scaffolds in tunable stoichiometric amounts, and in a second approach, Cy5 dy
34 ex and show that this species is involved in stoichiometric and catalytic C-C bond formation reaction
35 relevant to substrate oxygenation; and both stoichiometric and catalytic formation of C-O, C-C, and
37 lications of dihydrogen bonding in different stoichiometric and catalytic reactions, such as hydrogen
40 coupled sufficiently strongly to catalyze a stoichiometric and efficient energy transduction reactio
46 ion, we used protein semisynthesis to insert stoichiometric and site-specific phospho-Ser/Thr(s) in t
48 ss spectrometry, we showed that 3G11 forms a stoichiometric and stable complex without inducing a sig
49 dict and steer performance, we delved into a stoichiometric and thermodynamic model that sheds light
51 ions in the gas phase, the process is either stoichiometric (and therefore requires a water extractio
52 ted products coupled with isotopic labeling, stoichiometric, and kinetic studies established 1,2-alke
54 n is prevented, an I-like complex forms with stoichiometric association of U2 snRNPs and the U2 snRNA
56 er of quality checking procedures to examine stoichiometric balance and to identify blocked reactions
58 rs and product yields than systems employing stoichiometric benzoquinone (BQ) as the terminal oxidant
60 f may have evolved to inhibit A3F and A3G by stoichiometric binding and subsequently acquired the abi
61 can obscure specific binding, and since non-stoichiometric binding necessitates the explicit choice
67 generation of allylmetal species often form stoichiometric by-products, the recent use of alkynes as
69 g group or intermolecular), and the context (stoichiometric C-H activation or within a variety of cat
70 ing this protocol a practical alternative to stoichiometric carbanions in enantioselective carbonyl r
72 molytic products (surface OHs) on a close-to-stoichiometric ceria surface or heterolytic products (Ce
74 of known crystal phases and possesses a non-stoichiometric, charged core composed of a series of fus
75 nd living cells, as a consequence of the off-stoichiometric chemical nature of its surface at the nan
77 Indeed, even use of an efficient and general stoichiometric chiral reagent has yet to be reported.
78 gy to generate constructs for the temporary, stoichiometric co-expression of six different combinatio
80 n is biologically imperfect, and several key stoichiometric coefficients are experimentally inferred
81 ross the CHO cell proteome, and have derived stoichiometric coefficients for NS consumption towards C
82 emes is exact for reaction schemes where the stoichiometric coefficients of the constituent steps are
84 rs of BINOL that are produced with different stoichiometric combinations of BINOL with B(OPh)3 in the
85 timer-PAGE technique was validated, relative stoichiometric comparisons could be conducted simultaneo
86 sulfate over other oxoanions, forming a 1:2 stoichiometric complex that is stabilized via strong H-b
87 e demonstrate that PA-PB1 forms a stable and stoichiometric complex with host nuclear import factor R
89 Erh1 and the RNA-binding protein Mmi1 form a stoichiometric complex, called the Erh1-Mmi1 complex (EM
91 dings indicate that Rcf1 does not serve as a stoichiometric component, i.e. as a subunit of complex I
92 emimetal candidate in an inversion-breaking, stoichiometric compound strontium silicide, SrSi2, with
93 eduction at our composition (compared to the stoichiometric compound) to the suppression of pair-brea
97 c studies conducted under both catalytic and stoichiometric conditions were employed to investigate t
98 one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the
99 cing term in marine denitrifying systems, as stoichiometric constraints indicate anammox-based NO3(-)
102 ighted plant nitrogen, leading to the strong stoichiometric convergence of ground-layer plant communi
104 proper control of the plume kinetic energy, stoichiometric crystalline films can be synthesized with
109 n this network, the small-RNA RyhB undergoes stoichiometric degradation with the transcripts of targe
112 ined to the (111) growth plane and it is non-stoichiometric due to a missing Fe octahedral plane.
114 address these shortcomings, we assessed the stoichiometric efficiency and products of transition met
116 A continuous flow protocol for the direct stoichiometric electrophilic amination of aromatic hydro
120 n the electron donor formate was supplied in stoichiometric excess to TCE, both tceA-containing and v
121 ely studied ClC transporter that enables the stoichiometric exchange of 2 Cl(-) ions for 1 proton (H(
127 , this motif coordinates the synchronous and stoichiometric expression of the protein components of t
128 astaxanthin and fatty acid biosynthesis in a stoichiometric fashion was observed in H. pluvialis, the
131 300 K revealed that on a silicon-rich and a stoichiometric film, Pt13 exhibits a similar activity to
133 vidence of theoretically predicted, enhanced stoichiometric fluctuations in transcript numbers, nor o
136 nding, we describe herein our studies of the stoichiometric generation of S-acylthiosalicylamides und
137 intrinsic small bandgap semiconductors, off-stoichiometric GFO NCs, produced under either Fe-rich or
143 about possible models that can overcome the stoichiometric imbalance, including quaternary organizat
144 is summarized, and a synthetic cycle for the stoichiometric incorporation of atmospheric N2 into acet
145 the most reliable way to obtain kinetic and stoichiometric information on the activity of radical-tr
147 these inhibitors is a substrate as well as a stoichiometric inhibitor of the cell-cycle activator.
148 ality of the training data for virtually any stoichiometric inorganic crystalline material, reciproca
149 icient and practical directing groups, their stoichiometric installation and removal limit efficiency
151 its rRNA binding site, and therefore ensures stoichiometric integration of these r-proteins into the
152 PR) is a powerful technique for studying 1:1 stoichiometric interactions but has limited application
153 this work we explore the compositions of non-stoichiometric intermediate phases formed by diffusion r
156 echanistic investigations of C-H activation; stoichiometric intra- and intermolecular C-H activation;
160 ng of tRNA with the unique advantage of both stoichiometric labeling and broader application to all c
161 e application of SPR beyond the realm of 1:1 stoichiometric ligand-receptor binding into a new and im
162 Li)n, (B)n, (LiB)n, (LiH)n, and Li2BnHn; off-stoichiometric LinBnHm (m </= 4n) clusters were consider
164 FLU, SA, silicates or HA as compared to the stoichiometric magnetite (i.e., Fe(II)/Fe(III) = 0.50).
165 RNA containing a poly A tail with PABPs in a stoichiometric manner and stabilized the ribonucleoprote
166 s than metabolites and therefore have a wide stoichiometric matrix that corresponds to infinitely man
167 lassical functional groups for directing the stoichiometric metalation and functionalization of C-H b
169 dles of these two peptides, as well as their stoichiometric mixture, and the analog MG-H2 in DMPC or
170 or low-temperature ammonia oxidation at near-stoichiometric mixtures using a bottom-up approach.
173 compile and evaluate a comprehensive curated stoichiometric model of this two-cell system, with the o
177 educed by an order of magnitude and tuned by stoichiometric modulation of the iron concentration.
178 Here, we synthesized a new phase of sub-stoichiometric molybdenum sulfide (s-MoSx) on sulfur-enr
179 properties, their combining behavior to form stoichiometric nanocompounds/assemblies as well as to ex
180 rmediate growth stages and conversion of non-stoichiometric nanoparticles into stoichiometric 2D MoSe
181 show that three-way catalyst (TWC) equipped stoichiometric natural gas vehicles emit 96% lower NOx e
184 anion recognition sites to form a unique 1:1 stoichiometric nitrate anion-rotaxane sandwich complex.
186 ion schemes composed of series of steps with stoichiometric numbers equal to unity by calculating the
187 t the cubane core remains intact during this stoichiometric OER, implying that terminal oxo ligands a
189 reactions, in which triflate may be either a stoichiometric or catalytic nucleophile, leading to the
191 rganometallic reagents in conjunction with a stoichiometric or substoichiometric amount of chiral con
193 nt an alternative to the longstanding use of stoichiometric organometallic reagents in carbonyl addit
195 nucleophilic fluoride source with a peracid stoichiometric oxidant, and provides access to lactones
196 conditions and requires only persulfate as a stoichiometric oxidant, making the procedure suitable fo
199 ne and the olefin and are atom-economical as stoichiometric oxidants or reductants are not required.
201 entrations, with the mechanism shifting from stoichiometric oxidation of AgNPs by OCl(-) in the prese
203 interactions, which position the enzymes for stoichiometric phosphorylation of substrates co-localize
204 soil microbial communities, suggesting that stoichiometric plasticity arises because of a decoupling
205 be stoichiometrically homeostatic but their stoichiometric plasticity has rarely been examined, part
210 s core-shell nanoparticles composed of quasi-stoichiometric PuO2 cores and hydrolyzed Pu(IV) moieties
211 ed catalysts promote effective turnover with stoichiometric quantities of arene substrate and B2Pin2.
212 (POCOP)Ir system depends on the presence of stoichiometric quantities of sacrificial olefin, which i
213 f trafficking might ensure delivery of large stoichiometric quantities of SNARE proteins required for
216 ng additional methylammonium halide over the stoichiometric ratio for tuning the coordination degree
220 ccurs on the four glycosyl residues in a non-stoichiometric ratio, and each octasaccharide subunit is
223 eractor, and B cell maturation antigen, at a stoichiometric ratio; blocked the activity of mouse BAFF
224 ile ring, are discrete structural units with stoichiometric ratios and distinct distributions of cons
226 ructural diamagnetic host TiOPc in different stoichiometric ratios, namely VOPc:TiOPc 1:10 (2) and 1:
228 posure to chlorpyrifos affected the key body stoichiometric ratios: chlorpyrifos consistently increas
229 cation occurs readily in a one-pot, two-step stoichiometric reaction at room temperature to form uran
232 n be used to predict the rate of the overall stoichiometric reaction, making it possible to estimate
237 tes in the absence of free silanolate (i.e., stoichiometric reactions of arylpalladium(II) arylsilano
238 zes the synthesis, characterization, and key stoichiometric reactions of isolable or observable coina
239 echanistic pathways have been elucidated for stoichiometric reactions of these complexes: (1) transme
240 dies and the isolation of intermediates from stoichiometric reactions support a mechanism initiated b
241 n accord with the effect on these individual stoichiometric reactions, NaBAr(F)4 was also found to co
242 escribed first, followed by a description of stoichiometric reactions, with the competition between t
244 t of the synthesis, electronic structure and stoichiometric reactivity of dinuclear Pd(I) complexes w
246 ns in catalysis as well as novel fundamental stoichiometric reactivity, including the activation of i
247 ations of these novel P-based Lewis acids in stoichiometric reactivity, Lewis acid catalysis and frus
251 on system relies on triethylphosphite as the stoichiometric reductant and organocatalytic benzoisothi
253 (phenyl)silane is an exceptionally efficient stoichiometric reductant, and it is now possible to sign
255 sults provide quantitative insights into the stoichiometric relationship between miRNAs and target ab
257 varied between 1.4% and 90%, we observed the stoichiometric removal of one O2 per N,N-dimethylamine g
258 gatively regulates Dsh, to ensure its proper stoichiometric requirement and localization during PCP e
259 es: (1) metabolite uptake sufficient for the stoichiometric requirement to sustain observed growth, (
260 and nitrogen cycles are coupled through both stoichiometric requirements for microbial biomass and di
262 on diffraction and muon spin relaxation on a stoichiometric sample under pressure, we evidence a magn
264 increasing temperature may not only induce a stoichiometric shift but also loose the coupling between
267 d diastereo-selectivity, avoiding the use of stoichiometric silver(I) oxidants under ambient conditio
268 sm between positive and negative charged off-stoichiometric sites (i.e., N-vacancies versus silanols
271 the use of TMSCl and 2,6-dibromophenol as a stoichiometric source of HCl to facilitate catalyst turn
272 e (Li2CO3) on the surface of both Ni-rich Li-stoichiometric (specifically LiNi0.6Mn0.2Co0.2O2) and Li
273 trate how time-course EM can further dissect stoichiometric states of complexes that are not readily
274 orporates the various independently verified stoichiometric steps is presented, and a comparison to r
278 units seems transient, as it appears to be a stoichiometric subunit neither of complex III nor of com
279 ermease (LacY) of Escherichia coli catalyzes stoichiometric symport of a galactoside with an H(+), us
281 udies, assisted by catalyst poison tests and stoichiometric tests performed using an electrospray ion
282 cell approximately 12 times larger than the stoichiometric tetragonal parent phase of CeNbO4 as a re
284 The microdevices were fabricated using off-stoichiometric thiol-ene-epoxy (OSTEMER) polymer resulti
292 the reactivity patterns of other methods of stoichiometric transition-metal-based dearomatization (i
295 4,2-dioxazole moiety allowed for designing a stoichiometric version of the catalytic C-N coupling rea
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