ライフサイエンスコーパス: sulfoxide

1 ted protein 1 inhibitor or vehicle (dimethyl sulfoxide).

2 he S-oxidation products (aryl diphenylmethyl sulfoxides).

3 xFP) were prepared and dissolved in dimethyl sulfoxide.

4 be mistaken for the side chain loss from Met sulfoxide.

5 to causing oxidation of Met residues to Met-sulfoxide.

6 behavior to drugs pre-dissolved in dimethyl sulfoxide.

7 e posttranslationally oxidized to methionine sulfoxide.

8 i.e., glycerol, ethylene glycol and dimethyl sulfoxide.

9 y targeted, forming predominantly methionine sulfoxide.

10 the solvents deuterochloroform and dimethyl sulfoxide.

11 delivering isoquinolinones and methyl phenyl sulfoxide.

12 HD was oxidized to the nontoxic HD-sulfoxide.

13 in a mixture of thexyl alcohol and dimethyl sulfoxide.

14 henium catalyst containing a tethered chiral sulfoxide.

15 radical cation that in turn led to diphenyl sulfoxide.

16 ventually oxidized by 2 to the corresponding sulfoxide.

17 ere compared with dissolved PhIP in dimethyl sulfoxide.

18 HR-MS) to be irgarol sulfoxide and terbutryn sulfoxide.

19 rcome when cells were cultured with dimethyl sulfoxide.

20 S peptide mapping for the measurement of Met sulfoxide.

21 ivated by methionine oxidation to methionine sulfoxide.

22 uperoxide that could be quenched by dimethyl sulfoxide.

23 ations in a molar ratio of 1.5:1 in dimethyl sulfoxide.

24 rsible process, generally shifted toward the sulfoxide.

25 rhodium-catalyzed transfer of carbamates to sulfoxides.

26 strategies for the synthesis of enantiopure sulfoxides.

27 lidenes to ketenes is realized with tethered sulfoxides.

28 -amino iodides afford (S(S),R(C))-beta-amino sulfoxides.

29 proach to chiral beta-substituted beta-amino sulfoxides.

30 Dimethyl sulfoxide 2 M was used as cryoprotector for slow freezin

31 characterizations support the assignment of sulfoxide 4 as the native EgtE substrate and the involve

32 e radical cations of a series of aryl benzyl sulfoxides (4-X-C6H4CH2SOC6H4Y(+*)) have been generated

33 The oxidation of a series of aryl tert-butyl sulfoxides (4-X-C6H4SOC(CH3)3: 1, X = OCH3; 2, X = CH3;

34 Fresh culture contained only traces of sulfoxides 5 and 7, but these increased during storage o

35 The absolute configuration of stereogenic sulfoxide acceptors at the edge of the pi-acidic surface

36 anism leading to aryl 1-methyl-1-phenylethyl sulfoxides accompanied by products derived from Calpha-S

37 e glycans for labeling in anhydrous dimethyl sulfoxide-acetic acid medium.

38 erexpression, genotype D virus, and dimethyl sulfoxide added to culture medium.

39 on of S-allylcysteine (SAC), S-allylcysteine sulfoxide (alliin), S-methylcysteine (SMC), and S-ethylc

40 ly promotes a triple relay process involving sulfoxide alpha-arylation, CS bond cleavage, and CS bond

41 ions (M - HO-B(N(CH3)2)2) for N-oxides, but sulfoxides also formed diagnostic C ions (M - O horizont

42 of the response of Na-O2 cell chemistry with sulfoxide, amide, ether, and nitrile electrolyte solvent

43 ido sulfonate (10:2-FTSAS) and fluorotelomer sulfoxide amido sulfonate (10:2-FTSAS-sulfoxide) were al

44 er but also from such weak acids as dimethyl sulfoxide and acetonitrile.

45 pyran (DCM) laser dye in deuterated dimethyl sulfoxide and its excited state relaxation pathways.

46 two kinds of substrates, S-methyl-L-cysteine sulfoxide and L-cysteine, and had both cysteine sulfoxid

47 sulfur and nitrogen atoms in many drugs into sulfoxide and N-oxide functionalities is a common biotra

48 e protein modifications involving methionine sulfoxide and nitrotyrosine.

49 Dimethyl sulfoxide and polyurethane were assigned as surrogates t

50 brio fischeri exhibited that the TPs irgarol sulfoxide and terbutryn sulfoxide feature a similar bact

51 Irgarol sulfoxide and terbutryn sulfoxide were detected in the e

52 tion mass spectrometry (HR-MS) to be irgarol sulfoxide and terbutryn sulfoxide.

53 lly manipulating the oxidation states of the sulfoxide and the amide functional groups, halogenating

54 The method is developed for the sulfoxide and trichloroacetimidate glycosylation protoco

55 selectively to nontoxic 2-chloroethyl ethyl sulfoxide and vinyl ethyl sulfoxide using nearly stoichi

56 Cyanopyridone derivatives containing sulfoxides and sulfones showed cellular activity against

57 bution, and only photo-oxygenation products (sulfoxides and sulfones) were found.

58 E(i)5 elimination has been studied for sulfoxides and sulfones, but this represents the first s

59 Being mono-aza analogues of sulfoxides and sulfones, sulfimides and sulfoximines, re

60 alkyl methyl sulfoxides (including dimethyl sulfoxide) and aryl chlorides proved to be suitable unde

61 e effect of two solvents (water and dimethyl sulfoxide) and two MALDI matrices (2,5-dihydroxybenzoic

62 = mass% of chalcogel), dissolved in dimethyl sulfoxide, and added dropwise to deionized water to form

63 cystins containing methionine and methionine sulfoxide, and reveals the oxidation state of the methio

64 ctionality was replaced with oxygen, sulfur, sulfoxide, and sulfone, were prepared by a short sequenc

65 opy reveals the presence of H2O2, methionine sulfoxide, and tryptophan metabolites; i.e., N-formylkyn

66 energy of hydrogen in acetonitrile, dimethyl sulfoxide, and water to be 57.4, 55.5, and 30.0 kcal/mol

67 Moreover, aryl methyl sulfoxides, dibenzyl sulfoxides, and dimethylsulfoxide could be utilized to g

68 droxides and their keto tautomers, sulfates, sulfoxides, and N-oxides.

69 ,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding

70 Metal coordination of sulfoxide-appended fluorophores suppresses excited-state

71 ests that microcystins containing methionine sulfoxide are primarily postextraction oxidation artifac

72 Experimental data of ethanol and dimethyl sulfoxide are shown as proof-of-concept.

73 Furthermore, sulfoxides are able to capture nucleophiles and electrop

74 Sulfoxides are capable of forming stable complexes with

75 Sulfoxides are classical functional groups for directing

76 The weakly acidic alpha-protons of sulfoxides are reversibly deprotonated by LiOtBu, and a

77 Sulfoxides are shown to be viable reporting groups for f

78 s a renaissance period in the application of sulfoxides arising from their versatility in directing C

79 C-S lyase reaction using either thioether or sulfoxide as a substrate in the presence or absence of r

80 Therefore, it was impossible to generate Met sulfoxide as an artifact during sample preparation.

81 ocol using iodine as a catalyst and dimethyl sulfoxide as an oxidant under green chemistry conditions

82 iodine as a catalyst (30 mol %) and dimethyl sulfoxide as an oxidant under metal-free reaction condit

83 ion of imidazo[1,2-a]pyridines with dimethyl sulfoxide as the carbon synthon (CH2) using H2O2 as a mi

84 ation of proteins, which converts Met to Met sulfoxide as the common product.

85 o determine if replacing water with dimethyl sulfoxide as the solvent for fluconazole and flucytosine

86 ediate onto the alpha-alkoxy and alpha-amino sulfoxides as they form, and (ii) the alpha-alkoxy-subst

87 , the use of sulfoxides, particularly chiral sulfoxides, as ligands in transition metal catalysis is

88 A wide range of aryl benzyl sulfoxides, as well as alkyl benzyl sulfoxides with vari

89 an oxidized aS in which all methionines are sulfoxides (aS4ox); a fully lysine-alkylated aS (acetyl-

90 mation-friendly reactions to run in dimethyl sulfoxide at room temperature.

91 proach, leveraging the high IR absorbance of sulfoxides at 10.6 mum, for selective dissociation and d

92 Importantly, using a disuccinimidyl sulfoxide-based cross-linking MS platform, we mapped the

93 A sulfoxide-based imidazopyridazine analog 45, arising fro

94 nstrates the robustness and applicability of sulfoxide-based MS-cleavability in conjunction with vari

95 is challenging to determine the level of Met sulfoxide, because it can be generated during sample pre

96 rations may compete with crucial ligand (bis-sulfoxide) binding and inhibit catalysis.

97 Computational studies suggest that the sulfoxide binds to rhodium via O-coordination throughout

98 We also provide brief descriptions of metal-sulfoxide bonding and strategies for the synthesis of en

99 A Pd(II)/bis-sulfoxide/Bronsted acid catalyzed allylic C-H oxidation

100 reaction is reported under palladium(II)/bis-sulfoxide/Bronsted base catalysis.

101 s, we oxidized these quantitatively to their sulfoxides by the addition of 0.25% (w/w) hydrogen perox

102 accomplished via a combination of Pd(II)/bis-sulfoxide C-H activation and Lewis acid co-catalysis.

103 The reaction proceeds via oxidative Pd(II)/sulfoxide catalysis that retards palladium-hydride isome

104 Palladium(II)/bis-sulfoxide catalysis with a silver triflate cocatalyst le

105 een accomplished employing palladium(II)/bis(sulfoxide) catalysis.

106 in, 1 atm O2 or air) with reduced Pd(II)/bis-sulfoxide catalyst loadings while providing higher turno

107 atively nontoxic product 2-chloroethyl ethyl sulfoxide (CEESO) without formation of the highly toxic

108 b with the MEK inhibitor trametinib dimethyl sulfoxide (CombiDT therapy) increases response rate and

109 We have prepared two photochromic ruthenium sulfoxide complexes that feature two isomerization react

110 demonstrate quantitative mapping of dimethyl sulfoxide concentration in aqueous solutions and in fat

111 On the contrary, sulfoxides containing chirality at the sulfur atom have

112 aration of small peptides tethered to chiral sulfoxide-containing macrocyclic rings.

113 ision induced dissociation as amine-reactive sulfoxide-containing MS-cleavable cross-linked peptides,

114 ss-linked peptides further demonstrates that sulfoxide-containing MS-cleavable cross-linkers offer ro

115 viously developed a series of amine-reactive sulfoxide-containing MS-cleavable cross-linkers.

116 evelopment of a new acidic residue-targeting sulfoxide-containing MS-cleavable homobifunctional cross

117 ne propionate (1 mg/kg) or vehicle (dimethyl sulfoxide, control), 1 h before infection with rhinoviru

118 bly transfected with HBV DNA, while dimethyl sulfoxide could increase NTCP protein level despite tran

119 e homobifunctional cross-linker, dihydrazide sulfoxide (DHSO).

120 Moreover, aryl methyl sulfoxides, dibenzyl sulfoxides, and dimethylsulfoxide c

121 nd 5000-8000 for water and 2000 for dimethyl sulfoxide; differences between samples were revealed in

122 o 'cooked kidney bean' aroma, while dimethyl sulfoxide, dimethyl sulfone and ethyl methyl sulfone wer

123 s and alkynes, mediated by a multifunctional sulfoxide directing group, exploits nonprefunctionalized

124 romoethane (extraction solvent) and dimethyl sulfoxide (disperser solvent) was injected rapidly into

125 d0- and d10-labeled dimethyl disuccinimidyl sulfoxide (DMDSSO).

126 h strategically involves the use of dimethyl sulfoxide (DMSO) acting as an organic solvent for simult

127 d that CSOD can tolerate up to 3.9% dimethyl sulfoxide (DMSO) and up to 10% serum, which shows its co

128 ffer saline solution containing 10% dimethyl sulfoxide (DMSO) at 21 degrees C.

129 surfactant protein C, we found that dimethyl sulfoxide (DMSO) can improve the stability of the noncov

130 Dimethyl sulfoxide (DMSO) disrupts the hydrogen-bond networks in

131 Dimethyl sulfoxide (DMSO) has been broadly used in biology as a c

132 epG2/NTCP cells was attributable to dimethyl sulfoxide (DMSO) in culture medium, NTCP overexpression,

133 a medium comprised of Ficoll 70 and dimethyl sulfoxide (DMSO) in presence or absence of fetal bovine

134 Dimethyl sulfoxide (DMSO) is a common solvent and biological addi

135 Dimethyl sulfoxide (DMSO) is a promising solvent for this battery

136 Dimethyl sulfoxide (DMSO) is an important aprotic solvent that ca

137 Dimethyl sulfoxide (DMSO) is widely used as a cosolvent to solubi

138 n 153 (C153) in a series of toluene/dimethyl sulfoxide (DMSO) mixtures and find that the experimental

139 with dehydrating cosolutes [40% w/v dimethyl sulfoxide (DMSO) or acetonitrile (ACN)].

140 Dimethyl sulfoxide (DMSO) or sulfide ligands have positive and ne

141 ol (MeOH), 2-propanol (2-PrOH), and dimethyl sulfoxide (DMSO) reveal an internal substrate binding si

142 erovskite films are obtained from a dimethyl sulfoxide (DMSO) solution via a transitional SnI2.3DMSO

143 s anions (Ka = 1.6 x 10(4) M(-1) in dimethyl sulfoxide (DMSO)).

144 s Medium (KM) supplemented with 10% dimethyl sulfoxide (DMSO), 15% human serum albumin (HSA) and 0.1%

145 0 degrees C, the assay tolerates 5% dimethyl sulfoxide (DMSO), and it has a Z-score of 0.71, indicati

146 he media contains a small amount of dimethyl sulfoxide (DMSO), the adduct is able to move to a solven

147 ly polyhydroxylated alcohols and/or dimethyl sulfoxide (DMSO), which can damage cell membranes.

148 (cRbm20(DeltaRRM)-raloxifene), with dimethyl sulfoxide (DMSO)-injected mice (cRbm20(DeltaRRM)-DMSO) a

149 mediates as the dominant pathway in dimethyl sulfoxide (DMSO).

150 agent in a common organic solvent, dimethyl sulfoxide (DMSO).

151 with 5% ammonium persulfate (AP) or dimethyl sulfoxide (DMSO).

152 ce of a hydroxyl radical scavenger (dimethyl sulfoxide, DMSO), and different pH values.

153 and adopts a folded conformation in dimethyl sulfoxide due to Coulombic forces.

154 ene (TTF) in 1.0 m LiClO4 dissolved dimethyl sulfoxide electrolyte are reported.

155 dy of oxygen reduction on gold in a dimethyl sulfoxide electrolyte containing phenol as a proton sour

156 that the TPs irgarol sulfoxide and terbutryn sulfoxide feature a similar bacterial toxicity than the

157 A novel approach to produce diaryl sulfoxides from aryl benzyl sulfoxides is reported.

158 SO2), 6:2 fluorotelomerthiohydroxyl ammonium sulfoxide (FTSHA-SO), 6:2 fluorotelomer sulfonamide alky

159 d to allow the identification of N-oxide and sulfoxide functionalities in protonated polyfunctional d

160 mation on the environment of the N-oxide and sulfoxide functionalities.

161 Only ions with N-oxide or sulfoxide functionality formed diagnostic adducts that h

162 dation of aliphatic and aromatic sulfides to sulfoxides, giving quantitative conversions, high prepar

163 e prenyl group and cleavable properties of a sulfoxide group in the gas phase to produce a signature

164 o form stable isolable alpha-diazo-beta-keto sulfoxides has been achieved for the first time.

165 dynamic kinetic resolution (DKR) of allylic sulfoxides has been demonstrated by combining the Mislow

166 In recent times, sulfoxides have been given a new lease on life owing to

167 ds with different functional groups, such as sulfoxides, hydroxylamines, N-oxides, anilines, phenol,

168 ains of ADAMTS13 were oxidized to methionine sulfoxide in an HOCl concentration-dependent manner.

169 To determine the level of Met sulfoxide in proteins accurately, an isotope labeling an

170 mg/kg body weight) or vehicle (20% dimethyl sulfoxide in saline) was administered intravenously at r

171 differentiate and calculate the level of Met sulfoxide in the sample originally.

172 he synthesis of alpha-alkoxy and alpha-amino sulfoxides in >/=99:1 dr and >/=99:1 er via asymmetric d

173 anions is introduced that affords aryl alkyl sulfoxides in high yields.

174 presented to elucidate the effect of chiral sulfoxides in inducing backbone alpha-helicity.

175 tributed to an allergic reaction to dimethyl sulfoxide) in the 29 patients enrolled, who received 42

176 ging coupling partners, such as alkyl methyl sulfoxides (including dimethyl sulfoxide) and aryl chlor

177 l/CD14+ monocyte co-cultures, thymosin beta4-sulfoxide inhibits interferon-gamma, and increases monoc

178 was utilized to synthesize bioactive benzyl sulfoxide intermediates.

179 with diacetoxyiodobenzene directly converts sulfoxides into sulfoximines.

180 lfoxide could be utilized to generate diaryl sulfoxides involving multiple catalytic cycles by a sing

181 Oxidation of methionine to methionine sulfoxide is a common form of damage observed during agi

182 n accurate determination of the level of Met sulfoxide is critical.

183 protocol to access substituted amino dienyl sulfoxides is also reported.

184 o produce diaryl sulfoxides from aryl benzyl sulfoxides is reported.

185 um-catalyzed benzylative CS bond cleavage of sulfoxides is unprecedented.

186 ses excited-state pyramidal inversion of the sulfoxide, leading to enhanced fluorescence emission.

187 Here we reveal that thymosin beta4-sulfoxide lies downstream of hydrogen peroxide in the wo

188 Simple removal of the bis-sulfoxide ligand from this reaction results in a complet

189 a metal or through the action of an external sulfoxide ligand.

190 ail the history of the development of chiral sulfoxide ligands for asymmetric catalysis.

191 cation of acyclic C2-symmetric chelating bis-sulfoxide ligands in the Rh(I)-catalyzed enantioselectiv

192 ur in the reaction of 1 with mCPBA, yielding sulfoxide-ligated [Fe(II)(N3Py(amide)S(O)R)](BF4)2 (4).

193 ique aroma of Lentinula edodes, and cysteine sulfoxide lyase (C-S lyase) is the key enzyme in this tr

194 foxide and L-cysteine, and had both cysteine sulfoxide lyase and cysteine desulfurase activity.

195 teine desulfurase and not a type of cysteine sulfoxide lyase.

196 Mg) as well as the feasibility of asymmetric sulfoxide-magnesium exchanges (from the perspective of A

197 tem: oxidation of the methylthio groups into sulfoxides make them electron-deficient and allows their

198 roducts and Cys-SO2H, Cys-SO3H, and Met(329) sulfoxide may be potential biomarkers to assess exposure

199 benomyl, via its bioactivated thiocarbamate sulfoxide metabolite, inhibits aldehyde dehydrogenase (A

200 ecies (ROS) oxidize methionine to methionine sulfoxide (MetSO) and thereby inactivate proteins.

201 ecies (ROS) oxidize methionine to methionine sulfoxide (MetSO) and thereby inactivate proteins.

202 ROS oxidize methionine to methionine sulfoxide (MetSO), rendering several proteins nonfunctio

203 -Sulfox-1, which is equipped with a reactive sulfoxide moiety.

204 leimide with remarkable stereocontrol by the sulfoxide moiety.

205 s illustrated in the synthesis of methionine sulfoxide (MSO).

206 e the catalytic reduction of either dimethyl sulfoxide or trimethylamine N-oxide.

207 tively and quantitatively oxidized to either sulfoxides or sulfones by treatment with dilute hydrogen

208 pment and utilization of a novel chiral aryl sulfoxide-oxazoline (ArSOX) ligand.

209 However, the use of sulfoxides, particularly chiral sulfoxides, as ligands i

210 T cell-specific ligand, or vehicle (dimethyl sulfoxide/PBS).

211 ssive activity than their reduced methionine sulfoxide peptide forms 4 and 6, respectively.

212 he phosphoric acid is to furnish a Pd(II)bis-sulfoxide phosphate catalyst that promotes allylic C-H c

213 o[(1,3-dibenzyl)imidazol-2-ylidene](dimethyl sulfoxide) platinum(II) 3a induced G2/M phase arrest.

214 cell lines by methylation-sensitive dimethyl sulfoxide-polymerase chain reaction and bisulfite genome

215 methylmethionine was obtained, with dimethyl sulfoxide producing significantly less DMS with a maximu

216 lmost barrierless sulfoxidation leads to the sulfoxide product complexes.

217 the oxidation of thioether substrates gives sulfoxide product, consistent with single OAT.

218 and small molecules yielding stable alkenyl sulfoxide products at rates more than 100x greater than

219 ulfenate anion intermediates, and alkyl aryl sulfoxide products, the use of a mild method to generate

220 Taxol and dimethyl sulfoxide promote rapid polymerization of microtubules t

221 theoretical modeling support a novel mode of sulfoxide racemization which occurs via a rhodium pi-all

222 Formation of sulfoxide radical cations was unequivocally established

223 A first-order decay of the sulfoxide radical cations, attributable to C-S bond clea

224 he same process occurring in aryl tert-butyl sulfoxide radical cations.

225 mon HTS buffer additives, including dimethyl sulfoxide, reducing agents, detergents, and bovine serum

226 ed with those of previously studied dimethyl sulfoxide reductase (DMSOr) models.

227 The methionine sulfoxide reductase (MSR) enzyme converts MetSO back to

228 Methionine sulfoxide reductase (MSR) enzyme converts MetSO back to

229 phaS are excellent substrates for methionine sulfoxide reductase (Msr), thereby providing an efficien

230 Methionine sulfoxide reductase A (MsrA) is an enzyme involved in re

231 led the redox relay mechanisms of methionine sulfoxide reductase A of the pathogen Corynebacterium di

232 uctase, glutathione reductase and methionine sulfoxide reductase A proteins were significantly up-reg

233 of only glutathione reductase and methionine sulfoxide reductase A proteins were significantly up-reg

234 ling by targeting the antioxidant methionine sulfoxide reductase A to modulate liposarcoma cell survi

235 cted transgenic overexpression of methionine sulfoxide reductase A, an enzyme that reduces oxidized C

236 oxide dismutase (SOD2), catalase, methionine sulfoxide reductase A, and the 20S proteasome subunits P

237 ues of diverse targets, including methionine sulfoxide reductase A, myosin light chain kinase, and Ru

238 MsrPQ is a newly identified methionine sulfoxide reductase system found in bacteria, which appe

239 reversible through the action of methionine sulfoxide reductases (MSRs), which play key roles in lif

240 thionine residues is catalyzed by methionine sulfoxide reductases (Msrs).

241 a model, we show that of the two methionine sulfoxide reductases (MXR1, MXR2), deletion of mitochond

242 e intracellular and extracellular methionine sulfoxide reductases (SpMsrAB1 and SpMsrAB2, respectivel

243 activation of HypT depends on the methionine sulfoxide reductases A/B.

244 Methionine sulfoxide reductases are conserved enzymes that reduce o

245 Peptide methionine sulfoxide reductases are conserved enzymes that reduce o

246 f stereospecific enzymes known as methionine sulfoxide reductases.

247 Alternatively, MsrA catalyzes methionine sulfoxide reduction linked to the mycothiol/mycoredoxin-

248 Alkyl aryl sulfoxides resulted in up to quantitative yield and with

249 s (OSCs): S-allylcysteine, S-allylcysteinine sulfoxide, S-methylcysteine, and S-ethylcysteine are abu

250 ted by photochemical oxidation of the parent sulfoxides sensitized by 3-cyano-N-methylquinolinium per

251 of the bridging sulfur from sulfide (S), to sulfoxide (SO), to sulfone (SO2).

252 izing the sulfur bridge from sulfide (S), to sulfoxide (SO), to sulfone (SO2).

253 l acceptors have been determined in dimethyl sulfoxide solution at 20 degrees C.

254 ution by glutamine, mimicking the methionine sulfoxide state, increased the viability of E. coli cell

255 , FRET experiments in formamide and dimethyl sulfoxide suggest that interactions between hydrophobic

256 Due to the base sensitivity of the starting sulfoxides, sulfenate anion intermediates, and alkyl ary

257 Proof of concept is offered by the sulfoxide/sulfenate-catalyzed (1-10 mol%) coupling of be

258 The sulfoxide, sulfilimine, and sulfur ylid prepared from th

259 ssess a stereogenic sulfur atom and includes sulfoxides, sulfinamides, N-sulfinyl ureas, sulfoximines

260 riazolium anion recognition units containing sulfoxide, sulfone, and sulfoximine groups at C4 unveils

261 The sulfoxide synthase EgtB represents a unique family of no

262 ecular mechanics study into the mechanism of sulfoxide synthase enzymes as compared to cysteine dioxy

263 ive-site setup of the enzyme that drives the sulfoxide synthase reaction.

264 products thiodiglycol (TDG) and thiodiglycol sulfoxide (TDGO) in water and sediment samples using gas

265 eir main transformation products (disulfoton sulfoxide, terbufos sulfone and disulfoton sulfone).

266 Among the acyclic ethane-bridged bis-sulfoxides tested, the ligand Ferbisox (11), bearing fer

267 nd onions (N-acetyl-S-(1Z)-propenyl-cysteine-sulfoxide) that can be used to enhance dietary assessmen

268 methyl thioether with preference for the (S)-sulfoxide, the evolved mutant I67Q/P440F/A442N/L443I is

269 n proceeding via coordination of an internal sulfoxide to a metal or through the action of an externa

270 eric structure with an S coordination of the sulfoxide to rhodium.

271 e [2,3]-sigmatropic rearrangement of allylic sulfoxides to allylic sulfenates is a reversible process

272 Diazo transfer to beta-keto sulfoxides to form stable isolable alpha-diazo-beta-keto

273 employed with alkyl 2-(trimethylsilyl)ethyl sulfoxides to liberate the requisite alkyl sulfenate ani

274 rganic solvents such as glycerol or dimethyl sulfoxide, to promote vitrification and prevent ice form

275 These amido dienyl sulfoxides undergo highly selective Diels-Alder cycloadd

276 es of MTEGE can be selectively oxidized into sulfoxide units, leading to full disassembly of the mice

277 -chloroethyl ethyl sulfoxide and vinyl ethyl sulfoxide using nearly stoichiometric 3 % aqueous H2 O2

278 ent malignant neoplasms; trametinib dimethyl sulfoxide was approved by the US Food and Drug Administr

279 cy of sulfenate anions, and the deprotonated sulfoxide was determined to be the resting state of the

280 ies, particularly when solvation by dimethyl sulfoxide was taken into account by applying the SMD con

281 iodide and solid sodium hydroxide in methyl sulfoxide was used for the first time for analysis of bl

282 Interestingly, when dimethyl sulfoxide was used instead of Triton((R)) X-100 in the e

283 n and the base promoted elimination of alkyl sulfoxides was overridden.

284 as a model protein, much lower levels of Met sulfoxide were detected for the two susceptible Met resi

285 Irgarol sulfoxide and terbutryn sulfoxide were detected in the effluents (average concen

286 s(34)-sulfonic acid (Cys-SO3H), and Met(329) sulfoxide were greatly increased.

287 oxidative stress such as urinary methionine sulfoxide were observed in Hhip (+/-) but not in Hhip (+

288 l, ethanol, caffeine, nicotine, and dimethyl sulfoxide were tested as model chemical stressors.

289 A variety of aryl methyl sulfoxides were coupled with aryl bromides.

290 clic and benzofused ketone derived beta-keto sulfoxides were successfully explored as substrates for

291 elomer sulfoxide amido sulfonate (10:2-FTSAS-sulfoxide) were also occasionally reported after the AFF

292 electrophiles yielded (R(S),S(C))-beta-amino sulfoxides, whereas (R)-amino iodides afford (S(S),R(C))

293 ve utilized the chemical denaturant dimethyl sulfoxide which, in conjunction with a short thermal den

294 of benomyl to S-methyl N-butylthiocarbamate sulfoxide, which inhibits ALDH at nanomolar levels.

295 e bromination using HBr paired with dimethyl sulfoxide, which serves as the oxidant as well as cosolv

296 e reactions of tBuOH with (*)OH and dimethyl sulfoxide with (*)OH.

297 ecular weight difference of 2 Da between Met sulfoxide with the (16)O atom and Met sulfoxide with the

298 en Met sulfoxide with the (16)O atom and Met sulfoxide with the (18)O atom was used to differentiate

299 The reaction of chiral (hetero)aryl benzyl sulfoxides with Grignard reagents affords enantiomerical

300 l benzyl sulfoxides, as well as alkyl benzyl sulfoxides with various (hetero)aryl bromides were emplo