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1 group is covalently bound to sulfur (sulfane sulfur).
2 las were more photolabile than those without sulfur.
3 ) are required to use fuels with </=0.1 wt % sulfur.
4 hrough Cu-catalyzed in situ incorporation of sulfur.
5 as chemical signatures of copper, oxygen and sulfur.
6 th the altering concentration of calcium and sulfur.
7 onents, including metal oxides, calcium, and sulfur.
8 certed with cyclative attack by nucleophilic sulfur.
9 sulfite were the primary acceptor of sulfane sulfur.
11 on reactions is formulated for production of sulfur allotropes in the anoxic atmosphere of Archean Ea
12 l homocystinuria (HCU) is an inborn error of sulfur amino acid metabolism caused by deficient activit
13 -porphyrin nanorings with outwardly pointing sulfur anchors were prepared for exploring quantum inter
15 natase TiO2 was designed by doping TiO2 with sulfur and incorporating reduced graphene oxide (TiO2-S/
16 lerant r-GO/Li-metal anode, bendable lithium-sulfur and lithium-oxygen batteries with long cycling st
17 participate in the biogeochemical cycling of sulfur and nitrogen, filling previously unassigned niche
19 The results showed that both the doping of sulfur and the introduction of rGO worked as designed, a
20 etidines with a variety of nitrogen, oxygen, sulfur, and fluorine nucleophiles afforded chiral 3,4-di
25 s between residential proximity to elemental sulfur applications and respiratory symptoms and spirome
26 ere used to estimate the amount of elemental sulfur applied within 0.5, 1, and 3km of a child's resid
27 es (NHases), and yet the mechanisms by which sulfurs are oxidized by these enzymes are unknown, in pa
28 terized IssA, a protein that stores iron and sulfur as thioferrate, an inorganic anionic polymer prev
29 ex, and Fe-containing enzymes of the plastid sulfur assimilation pathway were major targets of Fe def
31 gements in RNAi seeds resulted in an altered sulfur-associated metabolism, such as lower amounts of C
32 noncovalent interactions between a thioether sulfur atom and various pi systems in designed top pan m
34 depends on initial chemical activation by a sulfur atom of a methylthioalkyl protecting group, follo
36 cessive thiolation reactions by donating the sulfur atom of their exclusive cysteine residues to the
37 dination of the Co(II) ion by a py-DTDA ring sulfur atom, orbitally favored spin-pairing, and the for
40 by replacing stepwise the oxygen atoms with sulfur atoms in the carboxylate groups of sodium terepht
43 functionalization is that either nitrogen or sulfur atoms present in heterocyclic substrates may bind
45 ulfide oxidation products with 2-6 catenated sulfur atoms with or without oxygen insertion, which acc
47 and critical information on the plethora of sulfur-based chiral ligands and organocatalysts used in
49 strates a viable approach to develop lithium-sulfur batteries with practical energy densities exceedi
50 it a promising cathode material for lithium-sulfur batteries, displaying a high capacity of 520 mAh
56 ther, our results highlight the key roles of sulfur biogeochemistry and ecology in influencing estuar
58 f organosulfur ligands, we describe the gold-sulfur bond formation and the nature of the resulting in
59 acile hydrolytic cleavage of both CS2 carbon-sulfur bonds at 25 degrees C to produce CO2 and trimeric
61 ction of RS(-) with CO2 produces a terminal, sulfur-bound monothiocarbonate, RSCO2(-), which acts as
62 alcohol compounds associated with distinct 'sulfur-cabbage', 'fruity', 'rosy', and 'boiled potato' a
63 chemical devices, transport ions between the sulfur/carbon composite cathode and the lithium anode in
66 o paired with high-capacity Li-free V2O5 and sulfur cathodes to achieve stable full-cell cycling.
67 formed due to a specific orientation of the sulfur-centered radical cation and a phenyl ring stabili
68 ine and glutathione, while those with longer sulfur chains, Cys-SSnH and GSSnH, were produced in the
69 ytes, in this work we create a unique Li-ion/sulfur chemistry of both high energy density and safety.
70 S]-cluster (4FeH) linked to a binuclear iron-sulfur cluster (2FeH) that has an open coordination site
71 iB1 structure suggests that loss of the iron-sulfur cluster (by nitrosylation) permits positively cha
72 of a [4Fe-4S] cluster by the cytosolic iron-sulfur cluster assembly (CIA) system, converting it into
73 ividual components of the mitochondrial iron-sulfur cluster assembly (ISC) and the CIA machineries.
75 al cytidilation reaction and the use of iron-sulfur cluster cofactors in reductive ring opening and h
77 toxicity is also strictly connected to iron-sulfur cluster proteins and to their assembly processes.
79 containing peptides and the assembly of iron-sulfur cluster-peptide complexes can take place within m
82 roles performed by multiple, auxiliary iron-sulfur clusters and the paucity of protein X-ray structu
87 is largely regulated by the binding of iron-sulfur clusters to the activator domain of the transcrip
94 cohnii was characterised by a high level of sulfur compounds (dimethyl sulfide, ethanethiol), and es
95 ((34)S/(32)S) analysis of ppm-level organic sulfur compounds (OSCs) in the presence of percent-level
97 In contrast, selective ligation to the other sulfur-containing amino acid, methionine, has been precl
99 re the highest dietary source for the unique sulfur-containing antioxidant ergothioneine, little is k
100 ding interactions with acceptor proteins for sulfur-containing biosynthetic pathways, elucidating mec
101 nds produced from amino acids, including the sulfur-containing compounds and acetaldehyde, as well as
103 FT-ICR-MS, and thus revealing the extent of sulfur-containing compounds which could show some correl
104 of an in-house compound library revealed two sulfur-containing compounds which possess structural res
105 nes, aldehydes, amines, alcohols, aromatics, sulfur-containing compounds, phenyls, phenols, and volat
107 that aromatic residues, especially Trp, and sulfur-containing residues at the i-2 position improved
108 Furthermore, polar (oxygen-, nitrogen-, and sulfur-containing) analytes found in low-concentrations
109 pectedly gives both the first five-membered, sulfur-containing, zwitterionic silylene ring (3) via in
110 ross all wetland sites and depths, the total sulfur content of DOM correlated with the relative abund
111 nd electronic structure as a function of the sulfur content: first-principles density functional theo
112 e bacteria, is a key component of the global sulfur cycle and effects atmospheric chemistry and poten
113 acteria interactions drive the surface ocean sulfur cycle and local climatic processes through the pr
114 nized in past years, their importance in the sulfur cycle, both oceanic and physiological, has only r
115 tial of genes involved in stress, virulence, sulfur cycle, metal resistance, degradation of plant cel
117 cords reflect temporal changes in the global sulfur cycle; this assumption may be well grounded for s
120 bon (delta(13)C), nitrogen (delta(15)N), and sulfur (delta(34)S) stable isotopes to examine the ecolo
121 model lacks an explanation for the origin of sulfur-depleted organic matter in the deep ocean and can
122 order to increase the efficacy of chrysin, a sulfur derivative (thio-chrysin), and ruthenium-complexe
123 archaeology reveal hermetic sealing, burning sulfur, desiccant dusts, and toxic botanicals as early c
124 fuel economy test (HWFET) cycles on ultralow sulfur diesel (ULSD) and a soy-based biodiesel blend to
125 ive 1,4-aminothiolation of 1,3-dienes with a sulfur diimide reagent, a copper catalyst, and alkyl Gri
126 ific measurements of nitrogen dioxide (NO2), sulfur dioxide (SO2) and volatile organic compounds (VOC
127 untries rely heavily on coal for energy, and sulfur dioxide (SO2) emitted from coal-fired power plant
128 xtract (VIN) as a sustainable alternative to sulfur dioxide (SO2), in this study, the chromatic featu
129 reast development, whereas among 2,136 boys, sulfur dioxide and nitrogen dioxide exposure in utero, d
133 em has been validated and optimized for free sulfur dioxide detection in the range of 1-60mgL(-1) and
134 risk was significantly increased by 18% for sulfur dioxide during the 3 months before conception and
137 tracting flash vacuum pyrolytic extrusion of sulfur dioxide from the respective 16-membered sulfone p
138 on in the range of 1-60mgL(-1) and for total sulfur dioxide in the range of 30-300mgL(-1) with a limi
139 s was kinetically preferred over the loss of sulfur dioxide leading to o-quinodimethane, which is the
141 to 10 mum in diameter (PM10), nitric oxide, sulfur dioxide, and nitrogen dioxide in different growth
143 ate in positive polarity and carbon dioxide, sulfur dioxide, hydrochloric acid, cyanogen chloride, an
150 basic surface/interfacial properties of the sulfur electrode has not been achieved, although the cat
152 centrated aqueous electrolyte, lithiation of sulfur experiences phase change from a high-order polysu
153 ACP (SDA) complex forms the core of the iron-sulfur (Fe-S) assembly complex and associates with assem
156 2-Y(*) cofactor in RNR and the cellular iron-sulfur (Fe-S) protein biogenesis pathways by examining b
157 the matrix where also the mitochondrial iron-sulfur (Fe/S) cluster assembly machinery resides to matu
160 H-cluster, CpI contains four accessory iron-sulfur [FeS] clusters in a branched series that transfer
161 c data revealed that transfer of the sulfane sulfur from an SQR-bound cysteine persulfide intermediat
163 Li-ion cathode materials, the aqueous Li-ion/sulfur full cell delivers record-high energy densities u
165 unique protocol provides remote nitrogen and sulfur functionalities with high levels of stereocontrol
174 thod for indirect determining phosphorus and sulfur in animal feed by ion chromatography was proposed
175 alteration of the content and speciation of sulfur in dissolved organic matter (DOM), which influenc
176 environments, which we attribute to oxidized sulfur in PPR DOM that would increase molecular weight w
178 ther reaction of 3 with 2 equiv of elemental sulfur in THF affords 4(*) via unexpected C-H bond activ
180 itution of the C2-uridine carbonyl oxygen by sulfur is catalyzed by tRNA thiouridine synthetases call
181 ulfuration of difluorocarbene with elemental sulfur is described for the first time, which overrides
183 llular levels, tracking the fate of a stable sulfur isotope ((34)S) from its incorporation by microal
185 e a simple, sensitive, and robust method for sulfur isotope ratio ((34)S/(32)S) analysis of ppm-level
186 The results show good precision and reveal sulfur isotope variability between individual OSCs that
187 redox-controlled (Fe-speciation) carbon- and sulfur-isotope record reveals sustained systematic strat
188 e striking mass-independent fractionation of sulfur isotopes that took place in the Archean atmospher
190 gate alternative controls on the sedimentary sulfur isotopic composition of marine pyrite by examinin
191 ce time of marine sulfate, any change in the sulfur isotopic record preserved in pyrite (delta(34)Spy
192 tural organic matter (NOM), as determined by sulfur K-edge X-ray absorption near-edge structure (XANE
196 hanges with overlying surface waters and the sulfur likely undergoes oxidative transformations in the
198 arbon cathode is presented here that enables sulfur loading and content as high as 46 mg cm(-2) and 7
202 nal role for the previously described carbon-sulfur lyase SUR1 in processing cysteine-isothiocyanate
204 DNA phosphorothioate (PT) modification is a sulfur modification on the backbone of DNA introduced by
205 cumulation and retain biologically available sulfur, most organisms possess the "universal" methionin
206 honate (DECP) and selective oxidation of the sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CE
208 roups are found in diverse environments with sulfur, nitrogen and methane cycling, indicating that th
211 ficant role in the redox cycling of iron and sulfur on Earth and is the primary cause of acid mine dr
213 putatively associated with chemoautotrophic sulfur oxidation and nitrification dominated the free-li
215 sed proteins involved in SCN(-) degradation, sulfur oxidation, carbon fixation, and nitrogen removal.
216 CO2 and N2 fixation, anaerobic respiration, sulfur oxidation, fermentation and potential for metabol
217 tudy focuses on revealing the interaction of sulfur oxides (SOx) and nitrogen oxides (NOx) and invest
220 the other uses bacteriochlorophyll-a and the sulfur-oxidizing sox cluster for energy acquisition.
221 -associated SO42--reducing taxa and abundant sulfur-oxidizing taxa in both size fractions across the
222 ted that a variety of couplings of nitrogen, sulfur, oxygen, and carbon nucleophiles with organic hal
223 the drug colchicine into tubulin and native sulfur phasing of the human G protein-coupled adenosine
224 rop species are prolific producers of indole-sulfur phytoalexins that are thought to have an importan
227 activation strategy by a reaction with cheap sulfur powder under stirring and heating to recover the
228 e dead sulfide species by reacting them with sulfur powder with stirring and heating (70 degrees C) t
232 st comprehensive characterization of an iron-sulfur protein complex that regulates Spo0A approximatel
233 n dealt with here include biogenesis of iron-sulfur proteins and chaperones that deliver iron cofacto
236 T proteins belong to a unique family of iron-sulfur proteins in which the 2Fe-2S cluster is coordinat
237 e conventional pyrethroid (beta-cyfluthrin), sulfur &pyrethrin mixture, and some organic commercial p
245 from capillarity-induced-self-crumpling and sulfur (S) vacancies intrinsic to chemical exfoliation e
246 rved low concentrations of volatile elements sulfur (S), selenium (Se), tellurium (Te), and antimony
249 ural changes suggest that FeMo-cofactor belt sulfurs S3A or S5A are potential protonation sites.
254 vels has unearthed a broad range of enzymes, sulfur shuttles, and chemical mechanisms for generating
258 h is further metabolized as a usable organic sulfur source, generating stoichiometric amounts of ethy
259 ations of dissolved organic carbon (DOC) and sulfur species ever recorded in terrestrial aquatic envi
261 ion of peptides and amino acids, response to sulfur starvation, potentially NADPH-producing pathways
263 termined by the structural similarity of the sulfur sublattices between the initial and final phases,
266 residues that form intra- and interprotamine sulfur-sulfur bonds during the final stages of sperm mat
267 urprisingly, reduction of the intermolecular sulfur-sulfur bonds of bull protamine results in tighter
272 on spectroscopy indicates the formation of a sulfur thereforepi-bonded radical cation due to the meth
273 thyl transfer to electrophilic carbon atoms, sulfur to Calpha atom thioether bonds, or carbon-carbon
275 st PDO activity and preferentially catalyzed sulfur transfer in the direction of thiosulfate to sulfi
276 lfate to sulfite and glutathione persulfide; sulfur transfer in the reverse direction was detectable
277 nism that establishes LarE as a paradigm for sulfur transfer through sacrificing its catalytic cystei
278 ncoding sulfur-utilizing proteins, including sulfur transferases, were enriched at sulfidic depths.
280 loroplasts and physically interacts with Low Sulfur Upregulated 2 (LSU2), which positively regulates
281 10-fold increase in the estimated amount of sulfur used within 1 km of child residence during the ye
283 ghout the OMZ, although transcripts encoding sulfur-utilizing proteins, including sulfur transferases
284 r its catalytic performance, but the role of sulfur vacancies and the mechanism determining the react
285 Our results highlight the beneficial role of sulfur vacancies in the electrocatalytic performance of
286 th isolated Co atoms that bond covalently to sulfur vacancies on the basal planes that, when compared
287 cribe the higher activity to the presence of sulfur vacancies that are created local to the observed
289 ge of cations) as powerful catalysts for the sulfur(VI) fluoride exchange (SuFEx) reaction between ar
290 yl fluorosulfates, an underexplored class of sulfur(VI) halides, that are generally unreactive unless
295 actions, cyclopropanation, cyclopropenation, sulfur ylide formation/2,3-sigmatropic rearrangement, as
297 different Michael-addition approaches of the sulfur ylide, the transition state (TS) energies for the
298 demonstrated the utilization of fluorinated sulfur ylides as versatile reagents for Corey-Chaykovsky
299 ulation reaction of vinyl benzoxazinones and sulfur ylides in good yields and good enantioselectiviti
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