ライフサイエンスコーパス: supercooled

1 ft for pure liquid water as it is cooled and supercooled.

2 s found to be stable from ambient (300 K) to supercooled (259 K) temperatures, although a lower-densi

3 ture, from ambient temperature to the deeply supercooled and amorphous states, and of water diffusive

4 on of the phase diagram, where water is both supercooled and at negative pressure.

5 s for packing fractions corresponding to the supercooled and glassy regimes, which are probed via con

6 We review the recent research on supercooled and glassy water, focusing on the possible o

7 ion fine structure features was observed for supercooled and normal liquid water droplets prepared fr

8 We find that the onset of the Boson peak in supercooled bulk water coincides with the crossover to a

9 he two competing scenarios for understanding supercooled bulk water.

10 Here we report viscosity of water supercooled close to the limit of homogeneous crystalliz

11 rument, it appears that the variation in the supercooled cloud fraction is negatively correlated with

12 ulations, show that the 20% variation in the supercooled cloud fraction is quantitatively important i

13 20 degrees C, the global average fraction of supercooled clouds in the total cloud population is foun

14 to the cold cloud layer effectively glaciate supercooled clouds.

15 within a confluent layer and the dynamics of supercooled colloidal and molecular fluids approaching a

16 est near the alpha-relaxation time scale for supercooled colloidal fluids, but were also present, alb

17 ration between adjacent nucleation sites for supercooled condensate is properly controlled with chemi

18 owth of ice bridges across the population of supercooled condensate.

19 inates at a critical point located at deeply supercooled conditions.

20 a lower-density liquid would be expected at supercooled conditions.

21 A transition in the rapidly supercooled disordered material, from an ergodic liquid-

22 At T < 40 degrees C the supercooled disordered state evolves into a metastable D

23 Remarkably, the DDQC forms only from the supercooled disordered state, whereas the sigma phase gr

24 so observed a rotary action in the suspended supercooled drop driven by repetitive transitions (a pol

25 ir ice-nucleating ability when immersed in a supercooled droplet.

26 the edge-to-edge separation between adjacent supercooled droplets decreases with growth time, deliber

27 ese observations are consistent with charged supercooled droplets or ice particles as intermediates i

28 nteraction of rapidly solidifying, typically supercooled, droplets with surfaces, and to harvest bene

29 shorter beta-relaxation time scales, in both supercooled fluid and glass colloidal phases.

30 acteristic cluster size grew markedly in the supercooled fluid as the glass transition was approached

31 mensional dynamics of particles in colloidal supercooled fluids and colloidal glasses.

32 The process by which supercooled fluids form stable, crystalline solids has b

33 lusters, which serve as tracers in colloidal supercooled fluids.

34 Nanotubes crystallize inside the supercooled, glass-coated liquid-carbon drops.

35 nature of the dynamics of fluids as they are supercooled, leading to the concept of a dynamic crossov

36 The nature of the transformation by which a supercooled liquid 'freezes' to a glass--the glass trans

37 les that determine many important aspects of supercooled liquid and glass phenomenology.

38 The dynamics of supercooled liquid and glassy systems are usually studie

39 ultaneously explains both the equilibrium of supercooled liquid and the thermal hysteresis observed i

40 The increasingly sluggish response of a supercooled liquid as it nears its glass transition (for

41 icles from an equilibrium configuration of a supercooled liquid at a temperature T.

42 sure-temperature region similar to where the supercooled liquid Bi is observed.

43 r is a notoriously poor glassformer, and the supercooled liquid crystallizes easily, making the measu

44 -phase clouds consisting of ice crystals and supercooled liquid droplets are constrained by global sa

45 ozen droplets harvest water from neighboring supercooled liquid droplets to grow ice bridges that pro

46 he need for realistic representations of the supercooled liquid fraction in mixed-phase clouds in GCM

47 The supercooled liquid has been probed experimentally to nea

48 Its supercooled liquid has divergent thermodynamic response

49 n, we have simulated an atomistic model of a supercooled liquid in three and four spatial dimensions.

50 A redox-active supercooled liquid is obtained by forming a "solvate ion

51 On heating, the glass transition into the supercooled liquid is shown by the 85Al and 84Al glasses

52 sed-form expression for the fragility of the supercooled liquid metal in terms of few crucial atomic-

53 k at low q values that is not present in the supercooled liquid or melt-quenched glasses.

54 ates requires thermalizing the system in the supercooled liquid phase, where the thermalization time

55 temperature increase, the alloy reenters the supercooled liquid phase, which forms the room-temperatu

56 alloys have a hidden amorphous phase in the supercooled liquid region.

57 al evidence of surface-induced nucleation in supercooled liquid silicon and germanium, and we illustr

58 that Zr-based metallic alloy, heated to the supercooled liquid state under hydrostatic pressure and

59 the properties expected for the equilibrium supercooled liquid state, and optimal stability is attai

60 Ice crystals in the atmosphere nucleate from supercooled liquid water and grow by vapor uptake.

61 nt in mixed-phase clouds, which contain both supercooled liquid water droplets and ice particles, aff

62 vel, mixed-phase clouds (i.e., consisting of supercooled liquid water drops and ice crystals).

63 he fraction of four-coordinated molecules in supercooled liquid water explains its anomalous thermody

64 ate that ice nucleated and grown from deeply supercooled liquid water is metastable stacking disorder

65 The self-diffusion of supercooled liquid water, D(T), is obtained from G(T) us

66 arrangements of the type responsible for the supercooled liquid's high viscosity account quantitative

67 nd that Ice 0 is structurally similar to the supercooled liquid, and that on growth it gradually conv

68 In the supercooled liquid, many quantities, for example heat ca

69 Akin to supercooled liquid, the pressure-induced metastable liqu

70 rements also indicate substantial regions of supercooled liquid.

71 A "supercooled" liquid develops when a fluid does not cryst

72 known to occur in confined liquids, exist in supercooled liquids and emerge in liquids driven from eq

73 We propose an Eulerian formulation of supercooled liquids and glasses that allows for a simple

74 cage stage characteristic of the dynamics in supercooled liquids and glasses, consistent with its int

75 in a propensity for these materials to form supercooled liquids and glasses, rather than undergoing

76 lar forces give rise to complex behaviour in supercooled liquids and glasses.

77 precise picture of dynamic heterogeneity in supercooled liquids and other complex systems.

78 teresting behavior that has been observed in supercooled liquids appears to be related to dynamic het

79 Supercooled liquids are characterized by their fragility

80 e at the nanoscale, one may expect to obtain supercooled liquids below the bulk homogeneous nucleatio

81 Classic supercooled liquids exhibit specific identifiers includi

82 tended to predict the dynamical behaviour of supercooled liquids in general.

83 Supercooled liquids near the glass transition exhibit th

84 al microscopic dynamics, akin to the ones in supercooled liquids or glasses.

85 Studies of these supercooled liquids reveal a considerable diversity in b

86 For decades, scientists have debated whether supercooled liquids stop flowing below a glass transitio

87 consensus on a theory of the transition from supercooled liquids to glasses, the experimental observa

88 uctural glasses including window glasses and supercooled liquids, and may be applicable across many s

89 a polyamorphous phase transition between two supercooled liquids, involving a change in the packing o

90 mployed single molecule approach to studying supercooled liquids, the measurement of rotational dynam

91 sure the configurational entropy Sigma(T) in supercooled liquids, using a direct determination of the

92 Glasses are often described as supercooled liquids, whose structures are topologically

93 e balance is what distinguishes glasses from supercooled liquids.

94 o considered for the dynamics of glasses and supercooled liquids.

95 tation in governing structural relaxation in supercooled liquids.

96 y collected data of probes in small molecule supercooled liquids.

97 dying dynamics of complex systems, including supercooled liquids.

98 materials, such as meta-stable undercooled (supercooled) liquids, have been widely recognized as a s

99 therefore exhibits the characteristics of a supercooled magnetic liquid.

100 hexadecane into its triclinic phase from the supercooled melt was directly observed with time-resolve

101 quid phase transition in this metallic alloy supercooled melt.

102 relevant length scales in crystallization of supercooled metallic glasses, thus offering accurate pro

103 he fast kinetics and structural behaviour of supercooled metallic liquids within the nanosecond to pi

104 pha), when the glassy state is approached in supercooled molecular liquids.

105 In contrast, the liquid-crystal phase in supercooled n-butanol is found to inhibit transformation

106 ctrochemical advantage while maintaining its supercooled nature and the liquid shows a high energy de

107 of surface or bulk preference at either the supercooled or ambient condition, a phenomenon not previ

108 tructure similar to that of dense fluids and supercooled phases at intermediate range up to 4.2 A, an

109 with cryoprotectants to facilitate long-term supercooled preservation.

110 r simulations with the mW water model in the supercooled regime around T(H) which reveal that a sharp

111 e hydrogen-bonding environment in the deeply supercooled regime surprisingly remain in bulk water eve

112 eveals a first-order phase transition in the supercooled regime with the critical point at ~207 K and

113 h extrapolation of the IAPWS equation in the supercooled regime.

114 Studies of liquid water in its supercooled region have helped us better understand the

115 ater anomalously increase on moving into the supercooled region, according to power laws that would d

116 of water in the experimentally inaccessible supercooled region.

117 demonstrate that evaporation from a freezing supercooled sessile droplet, which starts explosively du

118 els for supercooled water, liquid carbon and supercooled silica predict a LDL-HDL critical point, but

119 0 mM) at pH 8.5 at 22 +/- 2 degrees C and in supercooled solution at -6 +/- 2 degrees C.

120 The rate of the reaction decreased 6-fold in supercooled solution at -6 +/- 2 degrees C.

121 the two structural species postulated in the supercooled state are seen to exist in bulk water at amb

122 Cooling to a supercooled state is controlled, followed by 3 h of SNMP

123 liquids can be maintained for some time in a supercooled state, that is, at temperatures below their

124 emperature range that provides access to the supercooled state.

125 strong evidence of dynamic heterogeneity in supercooled systems.

126 sonance experiments of mouse and human aS at supercooled temperatures (263 K) are used to understand

127 -ray absorption spectroscopy from ambient to supercooled temperatures at relative humidity up to 95%.

128 formation of optically thin liquid clouds at supercooled temperatures--a process potentially necessar

129 table crystal phase exist at the same deeply supercooled thermodynamic condition, and that the transi

130 ations, here we show that glassy dynamics in supercooled two- and three-dimensional fluids are fundam

131 ced ring-flipping rate constant of Phe 45 in supercooled water allowed very precise determination of

132 hase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids o

133 erpolation between ambient pressure data for supercooled water and high pressure data for stable wate

134 g the liquid below the melting point such as supercooled water and silicon.

135 nces intramolecular spatial interactions via supercooled water and uses the resulting spatial correla

136 ications for NMR-based structural biology in supercooled water are addressed.

137 s of a typical storm cloud, in which ice and supercooled water coexist, no direct influence of the pl

138 study of halide anion solvation in a deeply supercooled water droplet (with diameter approximately 1

139 ice nucleation by particles immersed within supercooled water droplets.

140 riments indicate that the surface tension of supercooled water follows a smooth extrapolation of the

141 e putative liquid-liquid phase transition in supercooled water has been used to explain many anomalou

142 loud droplets can explain why low amounts of supercooled water have been observed in the atmosphere n

143 of the Boson peak reported in experiments on supercooled water in nanoconfined pores, and in hydratio

144 , and the "fragile-to-strong" transition for supercooled water is interpreted by adding a "critical p

145 Understanding deeply supercooled water is key to unraveling many of water's a

146 hat ice that crystallizes homogeneously from supercooled water is neither of these phases.

147 . suggested that the anomalous properties of supercooled water may be caused by a critical point that

148 report direct computational evidence that in supercooled water nano-droplets ice nucleation rates are

149 , no data are available for the viscosity of supercooled water under pressure, in which dramatic anom

150 ported volume-based freezing rates of ice in supercooled water vary by as many as 5 orders of magnitu

151 escribes all available experimental data for supercooled water with better quality and fewer adjustab

152 de range of temperatures (from 400 K down to supercooled water) and pressures (from ambient up to mul

153 ar prevented decisive measurements on deeply supercooled water, although this challenge has been over

154 geneous freezing rates of ice in droplets of supercooled water, both in air and emulsion oil samples,

155 /or chemical exchange processes occurring in supercooled water, can be expected to be well estimated

156 results demonstrate that dust, by glaciating supercooled water, can decrease albedo, thus compensatin

157 mics simulations of very specific models for supercooled water, liquid carbon and supercooled silica

158 hepcidin was determined at 325 and 253 K in supercooled water.

159 le at ambient T can be effectively slowed in supercooled water.

160 structure functions measured for ambient and supercooled water.

161 ucleation rate in a freestanding nanofilm of supercooled water.

162 ng analogies with the features of liquid and supercooled water.

163 is interpreted within the thermodynamics of supercooled water.

164 me, motional modes of a protein dissolved in supercooled water: the flipping kinetics of phenylalanyl