ライフサイエンスコーパス: supercritical

1 cess that may dissipate, maintain, or become supercritical.

2 itatively different regimes: subcritical and supercritical.

3 s 10(40) ergs per second can be explained by supercritical accretion onto massive stellar-mass black

4 spectral curvature are indeed signatures of supercritical accretion.

5 Supercritical and liquid mixtures of ethanol/H2O/CO2 are

6 me measurements of the DNA synthesis using a supercritical angle fluorescence biosensor.

7 n fluorescence, evanescent field excitation, supercritical angle fluorescence detection, and CCD dete

8 we use a combination of TIRF excitation and supercritical angle fluorescence emission detection to d

9 read function, in a technique called virtual supercritical angle fluorescence.

10 combining objective-type EW excitation with supercritical-angle fluorescence (SAF) detection efficie

11 Here we show that supercritical antisolvent (SAS) precipitation using carb

12 primary crust reacted with a dense steam or supercritical atmosphere of water and carbon dioxide tha

13 e or critical oscillatory conditions using a supercritical bifurcation model.

14 zed and their self-assembly into micelles in supercritical carbon dioxide (CO2) has been demonstrated

15 olysis of dicumyl ketone in conventional and supercritical carbon dioxide (SC--CO(2)) solvents has be

16 hancement of poly(vinyl ester) solubility in supercritical carbon dioxide (sc-CO(2)) can be achieved

17 ning high vitamin E and carotenoid yields by supercritical carbon dioxide (SC-CO(2)) extraction from

18 ep by particle formation based on the use of supercritical carbon dioxide (SC-CO(2)) has been develop

19 Supercritical carbon dioxide (SC-CO2) extraction of sunf

20 In this study, supercritical carbon dioxide (SC-CO2) extraction was opt

21 a novel green method based on atomization of supercritical carbon dioxide (SC-CO2)-expanded lipid.

22 ylmaleimide and 9-hydroxymethylanthracene in supercritical carbon dioxide (scCO(2)) was determined by

23 This Tutorial Review focuses on supercritical carbon dioxide (scCO(2)), and discusses so

24 ction phases investigated, ethanol, CXE, and supercritical carbon dioxide (scCO2) containing ethanol

25 ic framework (MOF) materials with liquid and supercritical carbon dioxide (ScD) leads to substantial,

26 hing residues were biorefined by consecutive supercritical carbon dioxide (SFE-CO2) pressurised liqui

27 and S. verticillata were fractionated using supercritical carbon dioxide and pressurized liquid (eth

28 d from trout heads, spines and viscera using supercritical carbon dioxide and Randall extraction with

29 Supercritical carbon dioxide and synthetical brine were

30 lic copolymers of controlled architecture in supercritical carbon dioxide and their use as stabilizer

31 ylidene fluoride, and vinylidene chloride in supercritical carbon dioxide are compared over a range o

32 This suggests that supercritical carbon dioxide as a solvent may be used to

33 t to perform the epoxidation of alkenes 1 in supercritical carbon dioxide at 250 bar and 40 degrees C

34 Supercritical carbon dioxide can be employed as an envir

35 Supercritical carbon dioxide extraction of bioactive com

36 Liquid and supercritical carbon dioxide have attracted much interes

37 actors) of organic solutes between water and supercritical carbon dioxide have been correlated with e

38 reactants (e.g., nonpolar free radicals) in supercritical carbon dioxide near the critical point.

39 We used supercritical carbon dioxide process to encapsulate ATRA

40 organometallic compounds with hydrogen in a supercritical carbon dioxide solution.

41 Liquid and supercritical carbon dioxide swell potassium carboxylate

42 The effect of supercritical carbon dioxide technology (SCCD, 14, 16, a

43 high diffusion rates and solvation power of supercritical carbon dioxide to rapidly expand and super

44 metal cations between aqueous solutions and supercritical carbon dioxide where limited experimental

45 Supercritical carbon dioxide with ethanol as co-solvent

46 y extraction from E. angustifolia roots with supercritical carbon dioxide, 60 percent ethanol, or 20

47 copolymers in a dispersion polymerization in supercritical carbon dioxide, an efficient process which

48 investigation into the interactions between supercritical carbon dioxide, brines, and the mineral ph

49 Replacement of water with supercritical carbon dioxide, for example, results in co

50 essure, irradiation, ultrasound, filtration, supercritical carbon dioxide, plasma technology, and ele

51 pumpkin and tomato oleoresins, extracted by supercritical carbon dioxide, to obtain freeze-dried pow

52 olymerization of N-substituted aziridines in supercritical carbon dioxide.

53 rated block copolymer templates dilated with supercritical carbon dioxide.

54 or on-line measurement of uranyl chelates in supercritical carbon dioxide.

55 c solutions with tributyl phosphate modified supercritical carbon dioxide.

56 evidence that they were crystallized from a supercritical carbon-oxygen-hydrogen fluid.

57 A further study with supercritical CH4 at 3-25 kbar demonstrates hyperfilling

58 critical point is particularly important for supercritical chemical extraction.

59 Supercritical CHF3 and methanol-modified CHF3 were compa

60 tion of the mineral brucite, Mg(OH)(2), with supercritical CO(2) (88 bar) in aqueous conditions at 80

61 The injected supercritical CO(2) (sc-CO(2)) is a nonpolar solvent tha

62 mics to understand the capillary trapping of supercritical CO(2) (scCO(2)) under relevant reservoir c

63 compounds in deep saline aquifers may change supercritical CO(2) (scCO(2))-induced geochemical proces

64 Very little information on wettability in supercritical CO(2) (scCO(2))-mineral-brine systems is a

65 terite (Mg(2)SiO(4)) exposed to variably wet supercritical CO(2) (scCO(2)).

66 cessing the ultrahigh areas, is the use of a supercritical CO(2) activation technique.

67 The supercritical CO(2) and brine are clearly distinguished

68 in saline aquifers requires the detection of supercritical CO(2) and CO(2)-saturated brine as distinc

69 the hydroformylation reaction of propene in supercritical CO(2) and different reactant concentration

70 en" chemistry and technologies in liquid and supercritical CO(2) as alternative solvent systems.

71 ined with either the neat organic solvent or supercritical CO(2) as the reaction medium.

72 ively extracted with trimethylamine-modified supercritical CO(2) at 35 degrees C and 300 atm.

73 We reacted rock samples with brine and supercritical CO(2) at 51 degrees C and 19.5 MPa to acce

74 graphene and carbon nanotubes (CNTs) using a supercritical CO(2) fluid (SCCO(2)), which has gas-like

75 Supercritical CO(2) ganglia can be engineered by promoti

76 ability to monitor the chemical evolution of supercritical CO(2) in relevant conditions for geologica

77 analogues were studied as neat liquid and as supercritical CO(2) solutions at pressures up to 3.1 kba

78 f the interface between aqueous solution and supercritical CO(2) support this suggestion in that some

79 trate an all-optical approach to detect both supercritical CO(2), and saturated brine under sequestra

80 kinds of solvent, liquid CS(2) and liquid or supercritical CO(2), have been studied with 266-nm UV la

81 ients of organic compounds between water and supercritical CO2 (sc-CO2) are necessary to assess the r

82 Don with that of conventional supercritical CO2 (SC-CO2) extraction and heat-reflux ex

83 by leaching out the excess substrate through supercritical CO2 (Sc-CO2) extraction.

84 bes the results of laboratory scale lycopene supercritical CO2 (SC-CO2) extractions carried out with

85 ting from interactions between water-bearing supercritical CO2 (scCO2) and silicates in reservoir roc

86 s of forsterite (Mg2SiO4) during exposure to supercritical CO2 (scCO2) that had been equilibrated wit

87 tudy compared the use of ultrasound-assisted supercritical CO2 (USC-CO2) extraction to obtain apigeni

88 nced in the presence of organic solvents and supercritical CO2 + methanol.

89 By supercritical CO2 activation, a record-high Brunauer-Emm

90 ynamics simulations to study the behavior of supercritical CO2 and aqueous fluids on both the hydroph

91 ariably hydrated Ca-rich montmorillonites to supercritical CO2 and CO2-SO2 mixtures under geologic st

92 ds from Brassica oleracea var capitata using supercritical CO2 and evaluated the antioxidant potentia

93 nd methanol-modified CHF3 were compared with supercritical CO2 and methanol-modified CO2 for the extr

94 ists on the partitioning of organics between supercritical CO2 and water.

95 dified and tributyl phosphate (IBP) modified supercritical CO2 are presented.

96 lopment of new processes utilizing liquid or supercritical CO2 as a solvent will benefit from the rat

97 Mg(OH)2 reaction in solutions saturated with supercritical CO2 at high pressures (90 and 110 atm) and

98 les were immersed in water equilibrated with supercritical CO2 containing 1 wt % sulfur dioxide (SO2)

99 at the botanical drug candidate PBI-05204, a supercritical CO2 extract of Nerium oleander, provides n

100 ained from Lycium europaeum fruits following supercritical CO2 extraction (at 30MPa and 40 degrees C)

101 easing polarities obtained from a sequential supercritical CO2 extraction of Stillingia lineata leave

102 The use of supercritical CO2 extraction to obtain bioactive compoun

103 s in aqueous solution and in the presence of supercritical CO2 fluid (scCO2).

104 In the presence of a bulk aqueous phase, supercritical CO2 forms a nonwetting droplet above the h

105 Here, we found that residual trapping of supercritical CO2 in a limestone altered to a mixed-wet

106 ed trapping using pore scale observations of supercritical CO2 in mixed-wet carbonates.

107 ramethyl-p-phenylenediamine were obtained in supercritical CO2 in the presence of the microemulsion.

108 novel method for voltammetric measurement in supercritical CO2 is described.

109 metric behavior experimentally observed when supercritical CO2 is dissolved in 1-butyl-3-methylimidaz

110 When supercritical CO2 is dissolved in an ionic liquid, its p

111 Supercritical CO2 is injected into subsurface environmen

112 proach to the measurement of solubilities in supercritical CO2 is reported, utilizing laser-induced f

113 thesis involving ionic or radical species in supercritical CO2 may be possible utilizing the microemu

114 In this method a water-in-supercritical CO2 microemulsion is utilized to raise the

115 ochemical results obtained from the water-in-supercritical CO2 microemulsion system are different fro

116 es, specifically the point at which water in supercritical CO2 mixtures condenses to a liquid state.

117 icients were determined for benzene in water/supercritical CO2 over the range 35-65 degrees C and app

118 Supercritical CO2 processing of the POP dramatically inc

119 ophisticated oil extraction method utilising supercritical CO2 resulted in a significant decrease in

120 Plant extracts produced by supercritical CO2 technology from rosemary (R), oregano

121 pment of a selective extraction method using supercritical CO2 that allows the GC/MS quantitation of

122 ation can prompt a heterogeneous reaction in supercritical CO2 to switch from a mechanism most common

123 Supercritical CO2 was used to isolate the gas-included s

124 e CO2 relative permeabilities for liquid and supercritical CO2 were found to be clustered around 0.4

125 In the presence of bulk supercritical CO2, nonwetting aqueous droplets interact

126 oleoresin (BO) obtained using ultrasound and supercritical CO2, respectively, or a powdery lyophilize

127 stem are different from that obtained from a supercritical CO2-ethanol mixture system.

128 ilms with hexafluoroacetylacetone (hfacH) in supercritical CO2.

129 hod for determining the nucleus size and the supercritical concentration from experimental measuremen

130 The supercritical concentration is measured to be between 15

131 n the nucleus, a quantity we have named the "supercritical concentration".

132 When the concentration exceeds the supercritical concentration, the monomer, not the nucleu

133 lag phase, even at concentrations below the supercritical concentration.

134 per kilogram of water) has been measured at supercritical conditions of water with a yttria-stabiliz

135 e microscopic structure of water at sub- and supercritical conditions studied using X-ray Raman spect

136 cal properties of aqueous environments under supercritical conditions, for example, in the Earth inte

137 Under supercritical conditions, the measured bond distances of

138 liquid-like and gas-like regimes even under supercritical conditions.

139 dral at ambient conditions to tetrahedral at supercritical conditions.

140 well as exoplanets: as planets cool off, the supercritical core undergoes the transition to the rigid

141 tion seem to take place through a continuous supercritical crossing from a diluted to a dense fluid,

142 al of the surface thiolates, followed by CO2 supercritical drying to produce metallic Ag aerogels.

143 These gels are transformed to aerogels after supercritical drying with carbon dioxide.

144 aerogel by solvent exchanging and subsequent supercritical drying with CO(2).

145 conditions, >250 degrees C), followed by CO2 supercritical drying, is described.

146 After supercritical drying, the MoS(x) amorphous aerogel shows

147 The viscosity of a supercritical electrolyte solution is measured for the f

148 The most effective was the supercritical extract obtained by fractional extraction

149 The best conditions for the supercritical extraction, based on the content of polyph

150 lytes one of the more difficult aspects of a supercritical extraction.

151 and Klebsiella pneumoniae, comparing to the supercritical extracts but at the same affected the norm

152 nion radical scavenging activity assays, the supercritical extracts expressed stronger antioxidant ac

153 of an internal control became trapped in the supercritical flow.

154 ted by lipids in single-phase membranes with supercritical fluctuations.

155 hree end-member processes: CO(2) stored as a supercritical fluid (structural or stratigraphic trappin

156 Supercritical fluid carbon dioxide was investigated for

157 tential new method of sterilization by using supercritical fluid carbon dioxide.

158 Packed-column supercritical fluid chromatography (pSFC) coupled to an

159 s compounds in mouse plasma by packed-column supercritical fluid chromatography (pSFC) was achieved o

160 and high diffusivity of the mobile phase in supercritical fluid chromatography (SFC) allows higher f

161 error of 0.8) to historical results from the supercritical fluid chromatography (SFC) analysis.

162 matography (UHPLC), core shell HPLC, achiral supercritical fluid chromatography (SFC) and chiral SFC)

163 Tandem column supercritical fluid chromatography (SFC) has demonstrate

164 protected Fmoc-DSA subunit was separated by supercritical fluid chromatography (SFC) into the single

165 aphthyl isomers were resolved by preparative supercritical fluid chromatography (SFC) on chiral suppo

166 Supercritical fluid chromatography (SFC) provides a numb

167 Chiral supercritical fluid chromatography (SFC) screening of th

168 RPLC-HILIC) coupling and an analytical scale supercritical fluid chromatography (SFC) system, and val

169 In the domain of ultrafast supercritical fluid chromatography (SFC), unexpected res

170 tion and selectivity variation over time for supercritical fluid chromatography (SFC).

171 rming stationary-phase optimized selectivity supercritical fluid chromatography (SOS-SFC) are demonst

172 ological samples using ultrahigh-performance supercritical fluid chromatography (UHPSFC) with electro

173 es were measured using ultrahigh-performance supercritical fluid chromatography coupled to tandem mas

174 A supercritical fluid chromatography method was developed

175 the current study, a new and straightforward supercritical fluid chromatography purification procedur

176 or a water stationary phase in packed column supercritical fluid chromatography using a CO2 mobile ph

177 d chromatographic phenomenon in the field of supercritical fluid chromatography with helium headspace

178 Packed column supercritical fluid chromatography with tandem mass spec

179 lving compressible fluids, as is the case in supercritical fluid chromatography, had thus far not bee

180 In this report, the use of supercritical fluid chromatography-mass spectrometry for

181 incorporated the high efficiency of sub- and supercritical fluid chromatography.

182 low for accurate measurements under variable supercritical fluid conditions.

183 igh surface area, nanostructured aerogels by supercritical fluid drying.

184 In this study, a supercritical fluid extract (SFE) of H. pluvialis was ob

185 o as well as the extraction techniques (i.e. supercritical fluid extraction (SFE) and conventional so

186 These compounds were extracted using supercritical fluid extraction (SFE) and purified by a s

187 The supercritical fluid extraction (SFE) behavior of cocaine

188 e, including C18 adsorbent, is placed in the supercritical fluid extraction (SFE) chamber.

189 action of these polar compounds from soil is supercritical fluid extraction (SFE) coupled with in sit

190 rd, the developed method was compared with a supercritical fluid extraction (SFE) method and a conven

191 Supercritical fluid extraction (SFE) using CO2 modified

192 Supercritical fluid extraction (SFE) was directly couple

193 reek oregano extracts obtained by fractional supercritical fluid extraction (SFE) with carbon dioxide

194 ique) and an innovative technique, i.e., the supercritical fluid extraction (SFE), were applied to gr

195 Supercritical fluid extraction analyses are often compro

196 simultaneous distillation extraction (SDE), supercritical fluid extraction and beverage method.

197 A supercritical fluid extraction procedure and a chromatog

198 Supercritical fluid extraction was directly coupled with

199 It involves on-line coupling of supercritical fluid extraction with liquid chromatograph

200 ch in pure fluids and gases (N2 and CO2) and supercritical fluid mixtures (acetaldehyde vapor in N2).

201 An example of supercritical fluid phase behavior monitored with NMR is

202 de) (PLGA) microparticles of celecoxib using supercritical fluid pressure-quench technology and demon

203 strate the utility of this cell for studying supercritical fluid solution systems relevant to analyti

204 wn to a length of several micrometers with a supercritical fluid solution-phase approach.

205 nalogues generated in frozen gas matrices or supercritical fluid solutions.

206 ed cage effect near the critical pressure in supercritical fluid solvents.

207 he theoretical solubility of apigenin in the supercritical fluid system was obtained from the USC-CO2

208 celecoxib-PLGA microparticles prepared using supercritical fluid technology exhibited sustained drug

209 Although dehydration reactions would yield supercritical fluid water in most slabs, we report here

210 cts of mango seed fat (MSF), extracted using supercritical fluid, and palm stearin (PS) to formulate

211 The popularity of packed-column supercritical fluid, subcritical fluid, and enhanced flu

212 er passivated silicon (Si) nanocrystals in a supercritical fluid.

213 to APLI, a new hyphenation setup of APLI and supercritical-fluid chromatography (SFC) was constructed

214 persed on graphene nanosheets (GNSs) using a supercritical-fluid-assisted deposition technique to inc

215 The nanowires, made by the supercritical-fluid-liquid-solid process, are crystallin

216 s is known about the structural behaviour of supercritical fluids and no structural crossovers have b

217 e the general understanding of reactivity in supercritical fluids and provide a rationale for selecti

218 d reactions in organic solvents, and even in supercritical fluids and the gas phase, have found numer

219 50 degrees C, 90-180 bar) employing near- or supercritical fluids as reaction media can mimic the res

220 mineral stabilities in contact with injected supercritical fluids containing water are relatively unk

221 MR spectroscopy to high-pressure liquids and supercritical fluids has been limited due to the complex

222 f analogous state transitions in mixtures of supercritical fluids has not been determined, and it is

223 Since their discovery in 1822, supercritical fluids have been of enduring interest and

224 surement of the density-viscosity product of supercritical fluids is inherently simpler than traditio

225 Supercritical fluids play a significant role in elucidat

226 An understanding of homogeneous catalysis in supercritical fluids requires a knowledge of the phase b

227 a high-attenuation 3-4 km deep reservoir of supercritical fluids under Pozzuoli and migrated towards

228 l media such as water, fluorinated solvents, supercritical fluids, or ionic liquids is also discussed

229 o tune the reaction behavior of solids using supercritical fluids.

230 This is reminiscent of the behavior of supercritical fluids.

231 viscoelastically and form viscous tethers at supercritical force.

232 le-brain model based on the normal form of a supercritical Hopf bifurcation and studied the dynamical

233 responses to TNFalpha are characterised by a supercritical Hopf bifurcation point: above a critical i

234 gh-stiffness load, a bundle functions near a supercritical Hopf bifurcation, in which case it respond

235 with the optimized parameters exhibited two supercritical Hopf points and, for the choice of paramet

236 eradicated with police suppression, whereas supercritical hotspots are displaced following a charact

237 and Li2Rb4[(TiO)Si4O12], by using a flux and supercritical hydrothermal method.

238 Our results enable predicting the state of supercritical iron in several conditions of interest.

239 map the Frenkel line on the phase diagram of supercritical iron using molecular dynamics simulations.

240 modynamic phase of a fluid (liquid, vapor or supercritical) is fundamental to all chemical processes,

241 l line and the metal-insulator transition in supercritical liquid metals.

242 The supercritical liquid-gas transition is marked by maxima

243 veal a complex, rippled, quasi-perpendicular supercritical magnetohydrodynamic shock of moderate stre

244 ard the purification of gamma-Mg(BH4)2 using supercritical nitrogen drying techniques, (1) showing th

245 rease during the CO(2) phase transition from supercritical or liquid phase to gas phase.

246 Crime hotspots may form as either supercritical or subcritical bifurcations, the latter th

247 ation of a longitudinal phononic mode in the supercritical phase is observed for the first time.

248 l reconsideration of the mere essence of the supercritical phase.

249 l increase plant water use by roughly 30% in supercritical pulverized coal-fired power plants.

250 The supercritical regime takes place if p is small but not e

251 hen temperature and pressure increase to the supercritical regime.

252 ut increased in the slightly subcritical and supercritical region between 350 and 390 degrees C.

253 the thermodynamic properties of water in the supercritical region by analysing both available experim

254 ension of that first-order transition in the supercritical region.

255 Liquid, vapor, and supercritical regions are clearly differentiated, and th

256 al crossovers for the first time in a deeply supercritical sample through diffraction measurements in

257 of Fe(CO)5 (5) has been studied in heptane, supercritical (sc) Ar, scXe, and scCH4 using time-resolv

258 The interactions of supercritical (sc) CO(2) with Na saturated montmorilloni

259 e expected to influence the fate of injected supercritical (sc) CO2 following geological carbon seque

260 but few measurements have been reported for supercritical (sc) CO2-water.

261 A trapping curve for supercritical (sc)CO(2) in Indiana showing the relations

262 We conducted multiphase [supercritical (sc)CO(2)-brine] coreflood experiments tha

263 is taxon against the bactericidal effects of supercritical (sc)CO2.

264 We derive a power law and analyse supercritical scaling exponents in the system above the

265 The method of rapid expansion of a supercritical solution into a liquid solvent (RESOLV) wa

266 articles were produced by rapid expansion of supercritical solutions (RESS), and deposited directly o

267 ontrast to vapor-phase synthetic routes, the supercritical solvent provides high precursor concentrat

268 ide nanoparticle building blocks followed by supercritical solvent removal.

269 ere we study thermodynamic properties of the supercritical state and discover that specific heat show

270 n view of currently perceived homogeneity of supercritical state in terms of physical properties.

271 modynamic and dynamic features show that the supercritical state in water is far more complex than wh

272 from a natural CO2 reservoir was injected in supercritical state into the reservoir.

273 The structure of supercritical state is currently perceived to be uniform

274 Theoretical understanding of the supercritical state is lacking and is seen to limit furt

275 ations and a precise characterization of the supercritical state is of uttermost importance for this

276 an interesting feature, transition into the supercritical state is shown to become directly observab

277 Recent advance in understanding the supercritical state posits the existence of a new line a

278 e behavior analogous to a pure fluid and the supercritical state space is characterized by a single l

279 on behavior emphasizes the complexity of the supercritical state to be expected in high-order mixture

280 s C and 65 bar, where acetonitrile is in its supercritical state, the transformation of benzoic acid

281 he symmetric case, the eigenfunctions of the supercritical states are expressed as spheroidal wave fu

282 The utility of packed-column supercritical, subcritical, and enhanced fluidity liquid

283 his work, the low viscosity advantage of the supercritical/subcritical CO2 is coupled with the high e

284 d research applications of near-critical and supercritical technology there is a pressing need for a

285 adsorption and desorption kinetics above the supercritical temperature of H2 that reflects the dynami

286 carbon nanotubes (MWNTs) were synthesized in supercritical toluene at 600 degrees C and approximately

287 n(II)(H2O)6]+2 to [Mn(II)(H2O)2(Br(-1))2] in supercritical water (scH2O).

288 )H(5)NO(2)) were measured in subcritical and supercritical water (SCW) at temperatures between ambien

289 rformed to clarify why solutions of MnBr2 in supercritical water are known to effectively catalyze th

290 sing a continuous hydrothermal process using supercritical water as a reagent.

291 es the potential of etching with sub- and/or supercritical water for reproducible preparation of fuse

292 The prospects of near- and supercritical water for treatment of the inner surfaces

293 Supercritical water is fundamental in many fields of app

294 Fits to the supercritical water spectra demonstrate consistency with

295 sterically stabilized nanocrystal growth in supercritical water that describes competing pathways of

296 The method makes use of a supercritical water-treated fused silica capillary, the

297 (-1) ions that exist as contact ion pairs in supercritical water.

298 st-lying electronic state of subcritical and supercritical water.

299 sight into the extent of hydrogen bonding in supercritical water.

300 ded for reactions in liquid n-heptane and in supercritical Xe (scXe) and Ar (scAr).