ライフサイエンスコーパス: supramolecular

1 This contribution introduces main-chain supramolecular ABC and ABB'A block copolymers sustained

2 ing-shaped anion {Mo154}, which contains the supramolecular adduct based on the symmetric encapsulati

3 Supramolecular adsorbents are expected to fully expose t

4 same time, distinct similarities with chiral supramolecular and biological systems also emerged.

5 een considerably less observed in artificial supramolecular and colloidal homologues.

6 Initial studies revealed that with this supramolecular approach, high-resolution structures can

7 suggests the possibility of programming the supramolecular architecture of GNRs by tuning the functi

8 ntribute to an improved understanding of the supramolecular architecture of plant secondary cell wall

9 of individual molecules is transmitted to a supramolecular architecture, with a sense of directional

10 ate photoswitchable building blocks in their supramolecular architecture.

11 for the rational design of surface-confined supramolecular architectures involving specific biointer

12 assembly to generate highly intricate closed supramolecular architectures, ranging from self-assembli

13 Three generations of metalated trigonal supramolecular architectures, so-called metallo-triangle

14 ogrammably self-assemble into various chiral supramolecular architectures, thereby regulating the chi

15 are two proven methods for creating defined supramolecular architectures.

16 chemistry, but also for the design of novel supramolecular architectures.

17 inding suggests the possibility of designing supramolecular arrays in which organic molecules support

18 Two-dimensional (2D) supramolecular arrays provide a route to the spatial con

19 Peptide-based supramolecular assemblies are a promising class of nanom

20 ght microscopy allows the imaging of labeled supramolecular assemblies at a resolution surpassing the

21 Typically, switching the helicity of supramolecular assemblies involves external stimuli or k

22 Here, we report tailoring the supramolecular assemblies of protein complexes with a su

23 The dynamic generation of supramolecular assemblies of small molecules has made co

24 e a consequence of conformational changes in supramolecular assemblies thought to exist in humic subs

25 Particularly for supramolecular assemblies with large subunits (>150 resi

26 has provided a large number of unprecedented supramolecular assemblies with new geometric and electro

27 y evaluate kinetic phenomena associated with supramolecular assemblies, in real time, is key to a bet

28 materials, including multicomponent blends, supramolecular assemblies, novel hybrid materials, and l

29 lysis of structure, dynamics and function of supramolecular assemblies, using both solution- and soli

30 in the mitochondrial inner membrane various supramolecular assemblies.

31 olymerization techniques in combination with supramolecular assembly are used to engineer heterotelec

32 rality of a ligand decisively influences its supramolecular assembly behavior.

33 munication, we report on a noteworthy hybrid supramolecular assembly built from three functional comp

34 been to make use of frustrated growth of the supramolecular assembly by tuning the balance of attract

35 Biosurface-induced supramolecular assembly for diagnosis and therapy has re

36 In agreement with the supramolecular assembly hypothesis, molecular size distr

37 Predictable stereoselective formation of supramolecular assembly is generally believed to be an i

38 This paper describes the supramolecular assembly of a macrocyclic beta-sheet cont

39 Supramolecular assembly of two heterotelechelic PPVs is

40 Herein by employing supramolecular assembly, enhanced theranostic capability

41 ns, these interactions defer to an organized supramolecular assembly, leading to thermoreversible org

42 es the helical organization of the resulting supramolecular assembly.

43 hography has been created that is based on a supramolecular assembly.

44 ave the way toward the development of novel, supramolecular-based green catalysts.

45 lation of the polymer chains by changing the supramolecular behavior of the Upy units.

46 equired for interaction with natural tissue, supramolecular biomaterials are promising candidates for

47 The basic concept of many of these supramolecular biomaterials is based on their ability to

48 ECM, the first examples of these functional supramolecular biomaterials reaching the clinic have bee

49 Furthermore, we predict that supramolecular buffering can be significantly improved u

50 both solutions and thin films, and extensive supramolecular C-H...F interactions in their crystalline

51 A novel supramolecular cage built from the self-assembly of tris

52 ate that a synergistic interplay between the supramolecular capsule and the acid traces is required f

53 ribution, we introduced cucurbit[6]uril as a supramolecular capsule for reversible storage/delivery o

54 Supramolecular capsules can now be prepared with a wide

55 The implementation of supramolecular capsules offers insights into intricate m

56 The Li-S battery equipped with the supramolecular capsules retains a high Coulombic efficie

57 Supramolecular capsules were assembled by neutral haloge

58 ur clusters by stabilizing them within ionic supramolecular capsules.

59 vage assay is reported that utilizes in situ supramolecular capture of the fluorescent product.

60 Cells extensively employ supramolecular catalysis and dynamic assemblies for cont

61 tive on future directions of the research on supramolecular catalysis and dynamic assemblies for medi

62 In this review, supramolecular catalysis refers to the integration of th

63 he reline solvent plays the role of a latent supramolecular catalyst where the increase in reaction r

64 lly, both building blocks, i.e., the ditopic supramolecular cation {[Ta6Br12(H2O)6]@2CD}(2+) and the

65 ing from the periodic alternation of POM and supramolecular cation, featuring short hydrogen-bonding

66 The PNB is designed, through supramolecular chain collapse, to expose benzene and per

67 ce in crystal packing or in the formation of supramolecular chains.

68 s or carboxylic moieties form self-assembled supramolecular channels within lipid bilayers.

69 Here we report supramolecular charge-transfer cocrystals formed by elec

70 The supramolecular chemical complementarities between the ga

71 tectures, tunable electronic properties, and supramolecular chemistries, cycloparaphenylenes (CPPs) h

72 esign of drug delivery approaches leveraging supramolecular chemistry (i.e., "chemistry beyond the mo

73 ystems are interesting for their fundamental supramolecular chemistry and have also been shown to be

74 uences, but are also interesting targets for supramolecular chemistry and nanotechnology.

75 r to accelerate our understanding of aqueous supramolecular chemistry and water writ large.

76 oneered by Lehn, Cram, Peterson and Breslow, supramolecular chemistry concepts have evolved providing

77 His influence on macrocyclic and supramolecular chemistry has been pervasive.

78 gement of the component parts, and therefore supramolecular chemistry has developed a highly importan

79 ir aryl derivatives in materials science and supramolecular chemistry has risen.

80 In the past decades, supramolecular chemistry has taught us the rules to prec

81 The application of supramolecular chemistry on solid surfaces represents an

82 s such, the design opportunities afforded by supramolecular chemistry will play a vital role in the f

83 his phenomenon has been utilized recently in supramolecular chemistry with the discovery that MV(+*)

84 he giant inorganic torus to develop relevant supramolecular chemistry, probing the strong affinity of

85 ecognition toolkit pioneered by the field of supramolecular chemistry, thereby permitting the bottom-

86 ry (ITC), a method still underrepresented in supramolecular chemistry, which however offers some adva

87 ystems have been an inspiration to synthetic supramolecular chemistry.

88 bioactive compounds and for applications in supramolecular chemistry.

89 ng important advances in the rising field of supramolecular chemistry.

90 fueled important advances in macrocyclic and supramolecular chemistry.

91 ential application in material chemistry and supramolecular chemistry.

92 s as well as to unleash new opportunities in supramolecular chemistry.

93 otein conjugates using cucurbit[6]uril (CB6) supramolecular chemistry.

94 es, as well as new avenues in host-guest and supramolecular chemistry.

95 rties with vital implications for host-guest/supramolecular chemistry.

96 en engineering has considerable potential in supramolecular chemistry.

97 hers, what is widely considered the birth of supramolecular chemistry.

98 on remains one of the foremost challenges in supramolecular chemistry.

99 rties with vital implications for host-guest supramolecular chemistry.

100 More recently, however, supramolecular chemists - with their expertise in macroc

101 are discussed, namely, via the formation of supramolecular chiral ensembles made out of small chiral

102 In this approach, the supramolecular chirality of NPCs can be adaptively impar

103 Supramolecular columnar arrangement was also shown for t

104 ogen dications alternate with those of a 1:2 supramolecular complex of BU6 and PF6(-).

105 rucial factor for the stabilization of their supramolecular complex through C-H...pi and N(+)...pi(1,

106 intermolecular electron correlation in large supramolecular complexes at equilibrium distances is app

107 Our analysis suggests that pi-pi stacking in supramolecular complexes can be characterized by strong

108 The single-step assembly of supramolecular complexes containing both i-motifs and G-

109 mechanisms underlying the assembly of these supramolecular complexes could help inform new approache

110 The formation of supramolecular complexes is found in many natural system

111 The reported binding energies of ten supramolecular complexes obtained from the quantum-mecha

112 onnectivity in the network, participation in supramolecular complexes, and regulatory interactions) u

113 model grants a greater understanding of such supramolecular complexes, enabling the design of enginee

114 arises different aspects of cooperativity in supramolecular complexes.

115 SPCH represents a class of hybrid supramolecular composites, opening a window into fiber t

116 Assembly of a family of 12 supramolecular compounds containing [AnO2Cl4](2-) (An =

117 The combination of the supramolecular concepts of mechanical motion and guest b

118 ducting signal previously observed for this "supramolecular" conductor can be readily understood with

119 Supramolecular construction strategies have overwhelming

120 mimic the activity of natural enzymes using supramolecular constructs (artificial enzymes) is a vibr

121 ased computations suggest that each of these supramolecular constructs encompasses two twisted [organ

122 nation polymers (PCPs) are open, crystalline supramolecular coordination architectures with porous fa

123 Here, the supramolecular copolymerization between two slightly str

124 fect of these mechanistic differences in the supramolecular copolymerization process is investigated

125 compositions and stack lengths of the formed supramolecular copolymers existing at various feed ratio

126 Supramolecular copolymers, non-covalent analogues of syn

127 into the structure and composition of these supramolecular copolymers.

128 Supramolecular crystalline assembly constitutes a ration

129 Herein we present a supramolecular (delayed luminescent) Eu(III)-based pH-re

130 context of clinical translation, features of supramolecular design may prove additionally advantageou

131 In sum, supramolecular design offers ample opportunity to improv

132 We exploit a prototype (Cr7Ni)2 supramolecular dimer as a benchmark to demonstrate the p

133 embedded within two gamma-CD units to give a supramolecular ditopic cation, suitable to be used as a

134 le building blocks for engineering 2D and 3D supramolecular DNA assembly.

135 Biomimetic supramolecular dual networks: By mimicking the structure

136 le assembly, the mechanisms underlying their supramolecular dynamics and internal organization remain

137 We can capture differences in supramolecular dynamics consistent with the experimental

138 in foldaxanes to design complex sequences of supramolecular events within networks of equilibria thro

139 ula: see text]6-[Formula: see text]m thick) "supramolecular fibers" at room temperature.

140 The supramolecular formulation of porphyrins also facilitate

141 ls the formation of a three-dimensional (3D) supramolecular framework with ca. 2.8 nm diameter one-di

142 Crystalline supramolecular frameworks consisting of charged molecule

143 In our strategy, a highly robust supramolecular H-bonded 1D ensemble was used to order th

144 ovided for the first time the formation of a supramolecular H-bonded polymeric ribbon.

145 olymerization process is cooperative and the supramolecular helicity is biased toward the helical pre

146 osition of one 2D array on another to form a supramolecular heterostructure and realize the growth-no

147 4,5-tetrakis(4-carboxyphenyl)benzene to form supramolecular heterostructures.

148 Finally, a pure supramolecular hexagram [Fe12V3LB3](36+) was successfull

149 operty relationships induced by the specific supramolecular hierarchical organization of lignocellulo

150 of microporous materials: trapdoor zeolites, supramolecular host calixarenes and metal-organic framew

151 l in organic chemistry, its combination with supramolecular host systems has remained largely unexplo

152 The crystallography of supramolecular host-guest complexes is reviewed and disc

153 e N-terminus is triggered upon addition of a supramolecular host.

154 first example of iminium catalysis inside a supramolecular host.

155 confirm that the noncovalent combination of supramolecular hosts with iminium catalysis is opening u

156 nting minimal examples of out-of-equilibrium supramolecular hosts.

157 Herein, we report on a three-component supramolecular hybrid system built from specific recogni

158 Recent focus is on applying these supramolecular hybrids for enzyme operated biosensors th

159 -ordered hybrid material derived either as a supramolecular hydrogel or single crystals.

160 ides enabling the self-assembly to result in supramolecular hydrogels upon mixing, aromatic-aromatic

161 gation of RNase A with HA both increased the supramolecular interaction with carrier lipidoids, promo

162 complexes become available for capture, via supramolecular interaction, onto a nentravidin-modified

163 rtise in macrocyclic synthesis and measuring supramolecular interactions - have renewed their interes

164 The modularity of supramolecular interactions also facilitates opportuniti

165 n polymerizations often relies on the use of supramolecular interactions and the organization of func

166 estigations since work began exploring their supramolecular interactions with DNA.

167 igma-holes which are able to form attractive supramolecular interactions, known as chalcogen bonding

168 exes, the host binds the guests through weak supramolecular interactions, such as hydrogen and haloge

169 Our results demonstrate that common supramolecular interactions-for example, [methylpi] coor

170 unanimously deliver a remarkable finding: a supramolecular "Janus" ligand can bind simultaneously to

171 chimedean and Platonic bodies, renders these supramolecular keplerates as a class of cages whose comp

172 The supramolecular layers are formed by solution deposition

173 This equilibrator approach adds a supramolecular level of control over the dynamic system

174 e first structural and functional proof of a supramolecular ligand targeting a PPI interface and stab

175 eveloped a cell delivery strategy based on a supramolecular liquid crystal formed by peptide amphiphi

176 We envision a strategy toward supramolecular machines generating directional pulling f

177 Our findings pave the way toward supramolecular machines that would photogenerate pulling

178 ilitate significantly accelerated studies of supramolecular machines using methyl-based NMR spectrosc

179 The energy landscape of a supramolecular material can include different molecular

180 cally controlled, which gives the associated supramolecular material unique properties.

181 The properties of supramolecular materials are dictated by both kinetic an

182 l, the unique concepts at the basis of these supramolecular materials will be discussed.

183 Supramolecular materials, in which small organic molecul

184 rder derived from PIC assembly to create new supramolecular materials.

185 report that a polyaromatic capsule acts as a supramolecular matrix for the mass determination of the

186 The presented supramolecular methodology highlights the merits of comp

187 Supramolecular mixed metal complexes combining the trime

188 Synthetic supramolecular molecules and materials are creating new

189 A particular fascinating class of metallo-supramolecular molecules are hollow coordination cages t

190 in PIC assemblies to direct formation of new supramolecular morphologies is unprecedented.

191 specific interactions can drastically change supramolecular morphology and even cross from nano to mi

192 th dodecanoic acid transform the cylindrical supramolecular morphology into ribbon-like structures.

193 rial's functional dependence on sequence and supramolecular morphology is highlighted 2-fold.

194 Some of the most recognizable supramolecular motifs - macrocyclic host-guest complexes

195 Furthermore, given the majority of supramolecular motifs in water are directed by hydrophob

196 The use of supramolecular motifs may further give rise to materials

197 n, as a mechanism to control the length of a supramolecular nanofiber formed by self-assembly of pept

198 apped nonapeptide (Nap-FFKKFKLKL, 1) to form supramolecular nanofibers consisting of alpha-helix.

199 Supramolecular nanoparticle hybrids for biosensing of an

200 talline order transition in the landscape of supramolecular nanostructures formed by charged chromoph

201 bly (EISA) represents a dynamic continuum of supramolecular nanostructures that selectively inhibits

202 xpand the structural and functional space of supramolecular nanostructures.

203 is a shape distinct from naturally occurring supramolecular nanostructures.

204 complexes that result from the formation of supramolecular nanostructures.

205 orrelation between the crystal structure and supramolecular nanostructures.

206 n used to make viral capsids of DNA strands, supramolecular nanotapes and pH-responsive gels.

207 phyll (BChl) c, d, or e, which assemble into supramolecular, nanotubular structures in large light-ha

208 which link the discrete metallacycles into a supramolecular network, leaving the B21C7 groups free fo

209 The CB[8]-based supramolecular networks are synthetically accessible in

210 btain images of the BP surface and hexagonal supramolecular networks of trimesic acid and melamine cy

211 Here we show that supramolecular networks stabilised by hydrogen bonding c

212 kinds of shape-controllable and fluorescent supramolecular organic frameworks (cuboid or spheroid) a

213 ticle tracking demonstrate that mobility and supramolecular organization are critical for immunity.

214 arge-scale simulations of the lipid-mediated supramolecular organization of GPCRs.

215 cell membrane and the consequences on their supramolecular organization.

216 cinal water molecules within the volume of a supramolecular peptide nanofiber measuring 6.7 nm in dia

217 Columnar supramolecular phases with polarization along the column

218 itional variation changed the self-assembled supramolecular phases, but also specific sequences induc

219 Dynamic assemblies of supramolecular phosphoglycopeptides (sPGPs) transform a

220 Taking advantages of the supramolecular "pi-pi" stacking and hydrophobicity inter

221 ore than a month, and also provides a stable supramolecular platform for the sequential deposition of

222 lar communication by establishing an ordered supramolecular platform.

223 se limitations instigated the development of supramolecular platforms that improved porphyrin pharmac

224 nges arising from their incorporation within supramolecular platforms.

225 Facile construction of metallo-supramolecular poly(3-hexylthiophene) (P3HT)-block-poly(

226 The sequestration of luminophores within supramolecular polyhedral compartments of a crystalline

227 in access into the intrinsic dynamics of the supramolecular polymer (dynamic exchange of monomers) wh

228 Controlling the number of monomers in a supramolecular polymer has been a great challenge in pro

229 change in structural variants of a synthetic supramolecular polymer in different conditions.

230 These supramolecular polymer networks can be stretched more th

231 Here, we describe the construction of supramolecular polymer networks through an in situ copol

232 ol%), yields extremely stretchable and tough supramolecular polymer networks, exhibiting remarkable s

233 Inspired by biological systems, we report a supramolecular polymer-colloidal hydrogel (SPCH) compose

234 esent a fuel-dependent helical assembly of a supramolecular polymer.

235 Supramolecular polymerization has been traditionally foc

236 f competing pathways, and shown how to steer supramolecular polymerization in the desired direction (

237 Here, we describe the supramolecular polymerization of triarylamine molecules

238 Supramolecular polymerization or assembly of proteins or

239 -equilibrium states found in one-dimensional supramolecular polymerization.

240 t polymers, one-dimensionally (1D) elongated supramolecular polymers (SPs) can be encoded with high d

241 However, examples of supramolecular polymers at the liquid-liquid interface a

242 To rationally design supramolecular polymers capable of self-healing or recon

243 The study of supramolecular polymers in the bulk, in diluted solution

244 , we show the translation of one-dimensional supramolecular polymers into multi-component functional

245 ulting interfacial nematic layer of these 1D supramolecular polymers is further used as a template fo

246 l twisted ribbons, which behave as effective supramolecular polymers whose structure and elastic prop

247 nd kinetics of monomer exchange in synthetic supramolecular polymers.

248 erges as the minimal model for antibacterial supramolecular polymers.

249 les) can be linked into main-chain Upy-based supramolecular polymers.

250 Supramolecular porphyrin structures can overcome additio

251 titution of CBPQT(4+) , not only changes the supramolecular properties of the tetracation in the soli

252 Interestingly, the supramolecular reconfiguration to the stable crystalline

253 we demonstrate time-dependent regulation of supramolecular self-assembly by connected, kinetically c

254 Supramolecular self-assembly enables access to designer

255 Controlling supramolecular self-assembly in water-based solutions is

256 Supramolecular self-assembly is an important process tha

257 A rapid supramolecular self-assembly methodology at ambient cond

258 Thanks to the in situ supramolecular self-assembly of the pi-gelator occurring

259 review, the topics that we discuss here are supramolecular sensors, imaging for medical applications

260 ient method to generate a family of platinum supramolecular square complexes, including previously in

261 We examined the binding of the new supramolecular squares to guanine quadruplexes, includin

262 A "solution-state supramolecular structure control" strategy is proposed t

263 This work demonstrates that "solution-state supramolecular structure" control is critical for unders

264 originates from the defects present in their supramolecular structure.

265 chanism by which the EMPs self-assemble into supramolecular structures and demonstrate that this proc

266 bly of identical building blocks into closed supramolecular structures and that this scaling behavior

267 These remarkably stable complexes have supramolecular structures for enzymatic cellulose hydrol

268 However, unraveling the solution-state supramolecular structures is challenging, not to mention

269 Controlling the self-assembly of supramolecular structures is vital for living cells, and

270 llustrates a bioinspired approach to develop supramolecular structures modulated by endogenous small

271 The electronic and supramolecular structures of these SAMs were well charac

272 Lipids self-assemble into diverse supramolecular structures that exhibit thermotropic and/

273 flexible, relatively small molecules forming supramolecular structures through weak interactions.

274 ing the creation of diverse, self-assembling supramolecular structures with precision on the atomic s

275 advances in the design of polypeptide-based supramolecular structures, including complexes with nucl

276 The self-assembly of peptides into ordered supramolecular structures, such as fibrils and crystals,

277 en confirmed to cluster into plasma membrane supramolecular structures, termed orthogonal arrays of p

278 inherits the features of its solution-state supramolecular structures.

279 arged macromolecules affects their resulting supramolecular structures.

280 We report here on supramolecular sulfated glycopeptide nanostructures, whi

281 by a dynamic mechanical stimulus using a new supramolecular surface-pressure-controlled strategy.

282 of a molecular synthon -O-CO- in lieu of the supramolecular synthon Br...Br in the precursor.

283 FPP]2 H2 O and cognate structures may act as supramolecular synthons, which, given their chirality, m

284 A supramolecular system in which the concentration of a mo

285 n mechanism (as opposed to induced fit) in a supramolecular system.

286 d assembly pathways to realize a reproducing supramolecular system.

287 Kinetics and thermodynamics in supramolecular systems are intimately linked, yet both a

288 l over the helical organization of synthetic supramolecular systems is intensively pursued to manifes

289 tands can be coupled to a fluorescence-based supramolecular tandem assay that allows site-selective i

290 We envisage that supramolecular technologies based upon these concepts co

291 The polymeric nature of the supramolecular terpolymer is confirmed in both solution

292 hat then generate an ABC sequence-controlled supramolecular terpolymer.

293 eport the development of sequence-controlled supramolecular terpolymerization via a self-sorting beha

294 Here the authors show sequence-controlled supramolecular terpolymerization via self-sorting behavi

295 Ce(IV)-oxo complex, that was stabilized by a supramolecular, tetrameric oligomerization of the Ce hor

296 helix dissociation reassociation step in the supramolecular trajectory.

297 y purposeful motion of molecular switches in supramolecular tubules.

298 cholesteric liquid crystals, one-dimensional supramolecular twisted ribbons and two-dimensional collo

299 ATP synthase is organized into supramolecular units called synthasomes that increase th

300 ate polymers, which are interlocked into the supramolecular wall structure through intra- and inter-m