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1 aporation effects are controlled kinetically/thermodynamically.
2 gas subjected to spin current can be treated thermodynamically.
3 ead to cleavage of this bond, very favorable thermodynamically.
4 ork types have been synthesized and >330,000 thermodynamically accessible zeolite structures have bee
5 hth key metabolite is molecular oxygen (O2), thermodynamically activated for reduction by one electro
6 In many plants, source pressure results from thermodynamically active loading in which energy is used
7 This enzyme used solar energy to power the thermodynamically and chemically demanding reaction of w
9 lution of colloidal metal nanocrystals under thermodynamically and kinetically controlled conditions.
11 f agonist-bound LBDs that may potentially be thermodynamically and kinetically important during stati
13 ted for N2 binding and reduction through the thermodynamically and kinetically reversible reductive-e
15 ate that an extensional flow readily unfolds thermodynamically and kinetically stable proteins, expos
16 This article shows that MoS2 nanosheets are thermodynamically and kinetically unstable to O2-oxidati
17 ate-based model, RateFrac in Aspen Plus, was thermodynamically and kinetically validated by experimen
18 ty in magmas has until now been viewed (both thermodynamically and kinetically) in terms of the press
20 e self-assembly of graphene sheets is driven thermodynamically, as graphite is found to act as a 2D s
21 ntal methods that "count" the number of ions thermodynamically associated with the ion atmosphere all
22 kinetically during the oxidation process or thermodynamically at basic conditions via disulfide bond
23 -scanning process allows for kinetically and thermodynamically balanced engineering of DNA-binding pr
24 at the structure alternatives are controlled thermodynamically by the nucleation, while kinetically b
27 ivatives into coenzyme B12 by catalyzing the thermodynamically challenging reduction of Co(II) rrinoi
30 insight into Trx-target recognition, we have thermodynamically characterized the noncovalent interact
31 sis in the forward and reverse reactions are thermodynamically consistent, complying with the expecte
32 vious mathematical models, we present a new, thermodynamically consistent, statistical-mechanical mod
33 Experimental data were analyzed to yield a thermodynamically constrained four-redox-state model of
34 pic space, the reversibility of reactions is thermodynamically constrained in modern metabolic networ
35 predicted gene essentiality as accurately as thermodynamically constrained networks, but predicted su
37 ights some of the challenges inherent to the thermodynamically controlled assembly of rigid, compact,
46 of Trx-like proteins is the key factor that thermodynamically controls reactivity toward nitrosylate
47 ns of known structure into their constituent thermodynamically cooperative components using protein-g
49 0.55 V in overpotential with respect to the thermodynamically demanding reduction-first pathway, whi
52 ing explains the experimental observation of thermodynamically destabilizing mutations that accelerat
54 upporting the hypothesis that life arose via thermodynamically directed events at hydrothermal vents.
55 can be promoted by reaction conditions that thermodynamically disfavor the [2,3] rearrangement step
56 igned to stabilize otherwise kinetically and thermodynamically disfavored 6-membered alkyl palladacyc
57 thesis reactions may be designed to generate thermodynamically disfavored alkenyl chlorides and fluor
58 hree enol-ketone pairs, equilibration of the thermodynamically disfavored tautomer was attempted with
60 an that for water (pK(a)(H3O(+)) = 0), which thermodynamically disfavors a concerted proton transfer
61 ly separate GSH and GAQ gating, which report thermodynamically distinct initial and final steps, resp
62 ism is more complex and instead involves two thermodynamically distinct solid solutions in which the
63 s the free energy released in the process to thermodynamically drive proton pumping across its membra
64 ed to an energy transduction step that could thermodynamically drive proton pumping in complex I.
66 (PLS) and to the binuclear center (BNC) are thermodynamically driven by electron transfer from heme
69 triggered by a hydrometalation event and is thermodynamically driven by the refunctionalization of a
70 chanism for axial configuration is primarily thermodynamically driven by the vapor-liquid-solid growt
71 in the absence of ribosomal DNA, whereas the thermodynamically driven components assemble but lose te
72 ce modification, as opposed to promoting the thermodynamically driven dissolution common for molecule
74 the alloyed interface of core/shell QDs is a thermodynamically driven process to minimize the lattice
75 s indicated by RP-HPLC and verified later by thermodynamically driven release of sCT, from the conjug
76 oparticle surface patterning, which utilizes thermodynamically driven segregation of polymer ligands
78 nd show that a small number of particles are thermodynamically driven to rearrange in regions of low
81 ides new design rules for the development of thermodynamically efficient catalysts for an important c
82 show that for intersurface separations that thermodynamically favor dewetting, the barrier to dewett
84 functional theory (DFT) simulations found a thermodynamically favorable and non-OH(*) mediated pathw
85 sociation despite the overall reaction being thermodynamically favorable at ambient temperatures and
86 bcg4 dimer suggested that desmosterol showed thermodynamically favorable binding at the putative ster
87 sampled on the ground state, with the former thermodynamically favorable by approximately 3 kcal/mol.
88 ase pathway, consisting of a small number of thermodynamically favorable chemical transformations tha
90 tified a chemical reaction mechanism that is thermodynamically favorable in which thiol-bound mercury
91 pattern conducive to the proton relay is not thermodynamically favorable on the ground state but beco
92 calculations suggest that the N2 binding is thermodynamically favorable only with the highly reduced
93 A key step in the proposed mechanisms is a thermodynamically favorable PCET reaction composed of in
94 librium of CoxB reduction by TlpA revealed a thermodynamically favorable reaction, with a less negati
97 with an excess of unlabeled DNA to initiate thermodynamically favorable unfolding-refolding reaction
98 nding of these AMLP micelles to membranes is thermodynamically favorable, but in contrast to the mono
99 w that PET in several amino-modified dyes is thermodynamically favorable, even though it was not expe
105 cts, and is a nucleated process that remains thermodynamically favored at lower temperatures, but is
106 that the formation of solid carbon [C(s)] is thermodynamically favored at temperatures above approxim
107 us conversion of the desired products to the thermodynamically favored bisindolyl(aryl)methanes, a pr
108 ctive because of overoxidation of propene to thermodynamically favored CO2 Here, we report that hexag
109 ods permit the hydrogenation of alkenes to a thermodynamically favored configuration when steric effe
110 The system harnesses an assistant strand and thermodynamically favored designation of unpaired nucleo
111 vored spin-pairing, and the formation of the thermodynamically favored diamagnetic five-coordinate S-
112 lated intermediate (up state) leading to the thermodynamically favored down binding mode in the chann
113 terestingly, we find that these features are thermodynamically favored even in the absence of a heter
114 icates prevented their reorganization to the thermodynamically favored Fe(II)4L4 tetrahedral cages, t
115 binding of dATP to the enzyme-DNA complex is thermodynamically favored for TTD-containing DNA over un
116 site is oxidized via the T1 Cu, a different thermodynamically favored half oxidized T3 form, i.e., t
117 Reaction at high temperature quickly forms thermodynamically favored nanocubes, but low temperature
119 lations also illustrate that dATP binding is thermodynamically favored over dGTP binding at both thym
120 is heteroleptic architecture was shown to be thermodynamically favored over the corresponding homolep
122 or trisubstituted alkyl complex as the more thermodynamically favored state, depending on either the
123 e-dimensional simulator designed to find the thermodynamically favored states for given chromosome ge
124 ne-dimensional fibrous nanostructures as the thermodynamically favored states in solvents of low pola
125 Finally, these findings confirm that, in its thermodynamically favored Td form, the utilization of WT
127 m this ferric intermediate, hydroxylation is thermodynamically favored, but chlorination is intrinsic
129 emperatures, while the hcp structure is more thermodynamically favourable at lower temperatures.
131 ing whereby the structure formed is the most thermodynamically favourable, thermodynamics have an inc
132 scape, the peptide-amphiphile system forms a thermodynamically favoured product characterized by long
134 ins provide a kinetic barrier to prevent the thermodynamically feasible reduction of Mia40 substrates
135 al engineering rules" as there is a range of thermodynamically feasible structures with no distinctio
136 Computational studies indicate that it is thermodynamically feasible to synthesize FAU with SAR=2-
138 to give boronate esters are the most favored thermodynamically, followed by diazaborole formation.
139 domains that couple non-adjacent G5 domains thermodynamically, forming interfaces that are more stab
141 hat the preceding formation of a 1:2 complex thermodynamically hampers the voltammetric observation o
143 teins of these pathogens is refolding into a thermodynamically highly stable fusion core structure co
144 s, enabling them to adopt what are otherwise thermodynamically inaccessible functional conformations.
145 Ostwald's rule of stages and proceed toward thermodynamically increasingly stable, more dense phases
146 lidin-5-ones is favored both kinetically and thermodynamically independently of the solvent, in agree
149 The protein drug, rhGM-CSF, was partitioned thermodynamically into a dextran dispersed phase of the
150 e O2s exciton, which is the most favored one thermodynamically, is unreactive because of a high prope
151 Theoretical calculation suggests that the thermodynamically less favorable core-shell Ag@Au nanost
152 ergy differences make cryptomelane formation thermodynamically less favorable than birnessite formati
153 and consequently enables the observation of thermodynamically less favored and therefore low populat
154 strates that the relative populations of the thermodynamically less favored gaseous carboxylate tauto
156 tioselective method for the synthesis of the thermodynamically less stable indanedione-fused 2,6-tran
158 nomeric ApoE3 and ApoE4, which renders ApoE4 thermodynamically less stable, less structured, and topo
164 tructures, some of which are predicted to be thermodynamically more favorable as well as slightly den
165 an efficient strategy to replace OER with a thermodynamically more favorable reaction, the oxidation
167 chloramine, and tribromamine are found to be thermodynamically more favorable than was previously bel
168 favored gaseous carboxylate tautomer or the thermodynamically more favored gaseous phenoxide tautome
170 lternative conformations are kinetically and thermodynamically more readily accessible for the Gly41S
171 " species, that subsequently converts to the thermodynamically more stable "bis-mu-oxo" isomer (Keq =
172 eletons, which were further transformed into thermodynamically more stable 1H- and 6H-tautomers, resp
174 -allylruthenium complex that isomerizes to a thermodynamically more stable monosubstituted pi-allylru
175 ne month, the PCO-isomer rearranges into the thermodynamically more stable POC-isomer of the cage-lik
177 RAF pathways are faster, but HAT yields thermodynamically more stable radical products, indicati
179 pounds with polycyclic structures, which are thermodynamically more stable than the corresponding pi-
180 ron oxyhydroxide (ferrihydrite structure) is thermodynamically more stable than the equivalent undope
181 ow that the perovskite (SH(-) )(H3 S(+) ) is thermodynamically more stable than the Im3 m structure o
182 ans nonchelated enol conformers of MA become thermodynamically more stable than the internally hydrog
184 rom the nonbulky end of the rod to reach the thermodynamically most stable state before unfolding-med
185 Although proteins generally fold to their thermodynamically most stable state, some metastable pro
186 trong aliphatic C-H bond is activated, while thermodynamically much weaker aliphatic C-H groups, that
188 ptides bind MHC class II molecules through a thermodynamically nonadditive process consequent to the
189 hange of interlayer K(+) for Cs(+) is nearly thermodynamically nonselective, recent experiments show
191 olysulfide phase in the sulfide electrode is thermodynamically phase-separated from the superconcentr
192 s display a Poisson's ratio of -1-the lowest thermodynamically possible value for an isotropic materi
193 ally studied species, whereas pathway "b" is thermodynamically preferable for the small-sized model s
194 e of L, with smaller phosphines favoring the thermodynamically preferred (from DFT calculations) tran
199 inate acyl dicarbonyl complexes appear to be thermodynamically preferred over the four-coordinate acy
201 the problem becomes purely geometrical: the thermodynamically preferred state should maximize the nu
202 For the other 3, misfolded structures are thermodynamically preferred, suggesting opportunities fo
205 ion potential of the distal [4Fe-4S] cluster thermodynamically restricts the Fdox/Fdred ratio at whic
208 , which we designate as smectic-fA phase, is thermodynamically stabilized by both entropic and energe
211 , in the carbon family, graphite is the most thermodynamically stable allotrope, conversion of other
212 lattice, where complete conversion into the thermodynamically stable alpha-domain is shown in dyspro
213 ite-sized aggregates are further shown to be thermodynamically stable and tunable with a single dimen
216 these observations and predicts that LAMP is thermodynamically stable below a critical chiAC, above w
219 are relatively unknown compared to the more thermodynamically stable calcium carbonate polymorph, ca
220 lohexanone ring was then epimerized into its thermodynamically stable cis counterpart, with little lo
221 superhelicity is necessary, which leads to a thermodynamically stable complex between hnRNP K and the
222 h pair of orientational BN isomers, the more thermodynamically stable compound has the lower HOMO ene
223 ond anvil cell, we report the discovery of a thermodynamically stable compound of helium and sodium,
225 an extremely complex phase diagram, with new thermodynamically stable compounds K3Cl, K2Cl, K3Cl2, K4
229 the nucleation density dramatically under a thermodynamically stable environment, yielding uniform a
230 gly, precursors that directly crystallize to thermodynamically stable FeSb2 products also contain loc
231 f-pathway aggregate state with regard to the thermodynamically stable fibrous supramolecular polymers
233 structures are available, they refer to the thermodynamically stable forms but little or no informat
236 extraordinary compounds Al4O7 and AlO2 to be thermodynamically stable in the pressure ranges 330-443
237 rs over several tens of seconds during which thermodynamically stable inner-sphere Rb(+) slowly trans
238 nds and find no computational evidence for a thermodynamically stable intermediate for any of these c
239 actors, the immature particles evolve into a thermodynamically stable intermediate that exhibits low
241 aggregation, PrP dimers were funneled into a thermodynamically stable misfolded state along a single
242 ing support for not only metastable but also thermodynamically stable multimeric clusters in aqueous
244 -phase' in chiral magnets is an example of a thermodynamically stable phase with topologically nontri
245 m = n compounds were found to convert to the thermodynamically stable phase, the (1,1) compound.
248 cal nucleation mechanism via the assembly of thermodynamically stable prenucleation clusters, as well
249 self-assemble into colloidal monolayers with thermodynamically stable rafts exhibiting chiral structu
250 oS2 nanosheets, inhibiting conversion to the thermodynamically stable semiconducting state (2H) when
252 the two pathways diverge to produce distinct thermodynamically stable species (parallel and antiparal
257 es 0 and 1 (coding requirements), and form a thermodynamically stable stem-loop secondary structure (
258 cible but predominantly aqueous phases-offer thermodynamically stable steps in density that can be tu
259 a low capacity for base pairing, it forms a thermodynamically stable structure with a rather complex
260 information will be useful in the design of thermodynamically stable structures containing chemicall
261 th balanced enthalpy and entropy in creating thermodynamically stable supramolecular lattices with pr
262 ork here is to chemically probe the range of thermodynamically stable tetraboride compounds with resp
263 fectly matches experimental data, it is more thermodynamically stable than previously proposed recons
264 ike RuN3 and RuN4 are proposed firstly to be thermodynamically stable, and the dynamical and mechanic
266 an cationic trypsin, but not trypsinogen, is thermodynamically stable, such that cleavage by CTRC lea
267 ture conditions, we show that TDP-43(NTD) is thermodynamically stable, well-folded and undergoes reve
272 th of the benzylphenyl ether relative to the thermodynamically stronger carbon-sulfur bond is ascribe
273 hermal titration calorimetry to characterize thermodynamically the interactions between bNAb2F5 (in b
276 reaction conditions and kinetically (KRs) or thermodynamically (TRs) controlled regioisomers were obt
277 asymmetry caused the terminal alpha-helix to thermodynamically uncouple from the rest of the protein
280 rosine lowers the Cu potential to enable the thermodynamically unfavorable 1e(-) reduction of O2, and
281 MAP as a catalyst yield at -78 degrees C the thermodynamically unfavorable axial O-acylation product;
282 and potassium ion gradients to catalyze the thermodynamically unfavorable movement of synaptic serot
283 ) in the presence of ferrihydrite is largely thermodynamically unfavorable within the range of condit
284 s-trans butadienes is either kinetically or thermodynamically unfavorable, and the 1Z,4E,8E- and 1Z,
286 (nJ = 1) by a Ca(2+)-selective ionophore is thermodynamically unfavorable, thereby requiring a Li(+)
291 g the initial Co2 (CO)6 (alkyne) complex are thermodynamically unstable and do not build up in apprec
294 of heats of formation, MAPbI3 is shown to be thermodynamically unstable with respect to decomposition
295 ult to synthesize in pure form because it is thermodynamically unstable with respect to disproportion
297 ength of electronic coupling along the wire: thermodynamically uphill steps occur only between electr
299 d against 2 reveal that [Cu2O](2+) is likely thermodynamically viable in copper-dependent methane mon
300 les cause localisation of plectonemes within thermodynamically weaker AT-rich sequences, and can grea
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