ライフサイエンスコーパス: thermolysis

1 intramolecular loss of dinitrogen upon mild thermolysis.

2 t afford carbon-fluorine bond formation upon thermolysis.

3 tride materials that are formed via triazine thermolysis.

4 basis of spectroscopic characterization and thermolysis.

5 amolecular aggregates and microwave-assisted thermolysis.

6 that 1-butene and n-butane are formed during thermolysis.

7 ely, for the aza-Wittig reaction followed by thermolysis.

8 tigated after processing, in comparison with thermolysis.

9 itions of matrix photolysis and flash vacuum thermolysis.

10 ]octan-8-ylidene (3) by either photolysis or thermolysis.

11 hanisms of the oxidations and the subsequent thermolysis.

12 to packing in the crystalline phase prior to thermolysis.

13 undergo high yielding Ar-CF(3) coupling upon thermolysis.

14 The quinolone intermediates were prepared by thermolysis (220-240 degrees C) of anilinomethylene deri

15 Thermolysis (60 degrees C, 16 h) of 1 in py gave ((t)Bu3

16 dation of 29 to the sulfoxide and subsequent thermolysis afforded the hexenulose 30.

17 Thermolysis and photolysis experiments suggest that the

18 iazolyl cation (1) has been attempted by the thermolysis and photolysis of 1-(1,2,4-triazol-4-yl)-2,4

19 Furthermore, the products obtained from thermolysis and the kinetics of the thermolysis are inve

20 t precursor pretreatments in the solventless thermolysis approach, respectively.

21 ned from thermolysis and the kinetics of the thermolysis are investigated.

22 Mechanistic studies of thermolysis at 122 degrees C reveal a dramatic reactivit

23 a6,eta5-bis(indenyl)zirconium THF compounds, thermolysis at 85 degrees C also resulted in C-O bond cl

24 based methods, many that involve solid-state thermolysis at or above 500 degrees C.

25 lso afford allenyl ketones upon flash vacuum thermolysis, but in addition, 3-ethynylcoumarins 6 are f

26 free amino acids were similar after HPH and thermolysis, but the former gave a more interesting vola

27 Following the thermolysis by NMR spectroscopy indicated that only a mi

28 Under microwave/thermolysis, carboxylic acids can couple with isonitrile

29 DPC, because it is not observed at all under thermolysis conditions, where only S1 and T0 are populat

30 omerization is reversible under flash vacuum thermolysis conditions.

31 in the production of silica nanoparticles by thermolysis, due to their structural similarities with s

32 Thermolysis experiments have also been conducted on a mo

33 nerally match those observed in flash vacuum thermolysis experiments.

34 in the "reverse sense" addition, which upon thermolysis forms the metal aryl complex (L)(2)Sc(C(6)F(

35 Flash vacuum thermolysis (FVT) of 1-methyl-5-phenyltetrazole (5b), 2-

36 Flash vacuum thermolysis (FVT) of 3-methylidenefuran-2(3H)-ones 3 cau

37 In contrast, flash vacuum thermolysis (FVT) of diazoamides 1a-d, in which reaction

38 Flash vacuum thermolysis (FVT) of phenyl azide 29 as well as precurso

39 2, the nitrene was generated by flash vacuum thermolysis (FVT) of phenylazide and subsequently isolat

40 enone (1) has been generated by flash vacuum thermolysis (FVT) with Ar-matrix isolation of methyl sal

41 nzannulated enyne-carbodiimides 25, which on thermolysis gave the isoquinolino[2',1':1,2]pyrimido[4,5

42 icularly stable trialkylhydroxylamine, whose thermolysis half-life is 2.1 h at 150 degrees C.

43 Upon thermolysis, HC(SiHMe(2))(3) is formed.

44 Kinetic investigations of (i)Pr2NPA thermolysis in 1,3-cyclohexadiene and/or benzene-d6 are

45 facile 1,5-hydrogen transposition upon mild thermolysis in benzene or toluene solution (80-110 degre

46 F(5))(3)]][B(C(6)F(5))(4)] (29) also undergo thermolysis in benzene to produce their respective pheny

47 )(mu-H)2W(NSi(t)Bu3)py2 (5-py2, 5%), whereas thermolysis in DME produced ((t)Bu3SiN)2WCl(OMe) (7, 30%

48 at the rate-determining step of nitrosoamide thermolysis is made, and a mechanistic framework is prop

49 Thermolysis is shown to affect C-N bond scission while r

50 t likely by a concerted mechanism, while the thermolysis is well explained by the formation of radica

51 observed forming ureate ligands, which upon thermolysis isomerize to bridging carbodiimides.

52 The thermolysis kinetics of this vicinal trisazoalkane were

53 trast, the c,c-C(70)O(3) isomer, which has a thermolysis lifetime of 650 min at 296 K, decays thermal

54 ectrochemical, hydrothermal, and solventless thermolysis methods in order to compare their common opt

55 These microcrystals have been obtained by thermolysis of (AuCl4)(-) stabilized with tetraoctylammo

56 Thermolysis of (eta(5)-Me(5)C(5))(2)LaCH(TMS)(2) in cycl

57 could be synthesized (70% isolated yield) by thermolysis of (i)Pr(2)NPA in 1,3-cyclohexadiene.

58 In the absence of a hydrogen acceptor, thermolysis of (PNP)IrH2 in t-butyl methyl ether under a

59 HCP generated by thermolysis of 1 has been observed by molecular beam mas

60 Thermolysis of 1 in the presence of H2C=CH(t)Bu and PhC

61 thylpyridinium tetrafluoroborate (2) and the thermolysis of 1- and 4-diazonium-1,2,4-triazoles, using

62 Inspection of the methane byproducts from thermolysis of 13, 14, 15, 25, and 29 in benzene-d(6) sh

63 Thermolysis of 15 under refluxing p-xylene furnished the

64 Extended thermolysis of 17 and 18 results in an aryl coupling pro

65 Thermolysis of 1a in C(6)D(6) at 45-55 degrees C leads t

66 Thermolysis of 1b at ~100 degrees C leads to the expulsi

67 Thermolysis of 2 gave mostly 1,2,4-triazole, together wi

68 In this work, thermolysis of 2 in an attempt to favor a monomeric kety

69 m of the formation of carbon nitrides during thermolysis of 2,4,6-triazidopyrimidine.

70 Thermolysis of 3 in C6D6 at 95 degrees C over 48 h gener

71 Interestingly, thermolysis of 37f bearing a 2-(methoxymethyl)phenyl sub

72 Thermolysis of 3a-g in the presence of zinc bromide indu

73 Compound 7 was independently produced via thermolysis of 4-py and DME (-MeOEt, -py), and THF and e

74 Thermolysis of 6-Me ultimately gives (PCP)Ir(CH3)(kappa(

75 Thermolysis of 7 at 50 degrees C formed carbocycles 6 in

76 In addition, thermolysis of [TCT](2)(2-) yields [TCBT]*-.

77 Thermolysis of a 2'-[(16)O]-O-benzoyl-[(17)O]-5'-O-(tert

78 hologies were synthesized by the solventless thermolysis of a copper alkylthiolate molecular precurso

79 formation of an acylketene generated by the thermolysis of a m-dioxolenone.

80 following bromide abstraction and subsequent thermolysis of a Pt(IV) complex bearing both Csp(3)- and

81 and composition are synthesized by efficient thermolysis of a single source precursor of mixed metal-

82 Here we show the thermolysis of a single-source precursor (1,3-(BBr2)2C6H

83 eters wide were synthesized by a solventless thermolysis of a single-source precursor in the presence

84 colloidal nanocrystals have been prepared by thermolysis of a stoichiometric Co(2+)Fe(2)(3+)-oleate c

85 20:4omega6) or peroxyl radicals generated by thermolysis of ABIP in the presence of oxygen.

86 lenes are obtained from the high temperature thermolysis of alkanes.

87 Diradical intermediates, formed by thermolysis of alkynylcyclobutenones, can display radica

88 onditions (solution versus solid-state), the thermolysis of azide precursors yielded bridging phosphi

89 Reinvestigation of the thermolysis of azido-meta-hemipinate (I) yielded, in add

90 mounts of 1-phenyl-1-buten-3-ynes from flash thermolysis of azulene has an activation energy of 360 k

91 Thermolysis of benzannulated enyne-isocyanates 13 and en

92 The thermolysis of bicyclo[3.2.0]hept-6-ene via a conrotator

93 The lowest-energy pathway for thermolysis of both structures proceeds through the (E,Z

94 sive CQDs can be prepared by straightforward thermolysis of citric acid in a simple one-pot, multigra

95 Thermolysis of compounds 2-4 in the solid-state results

96 It was shown that thermolysis of CPs follows first-order kinetics.

97 In contrast, thermolysis of dicobalthexacarbonyl-complexed enynes und

98 Thermolysis of each of the diazonium salts in the presen

99 The thermolysis of furan-2-carbonyl azide results in a Curti

100 Subsequent thermolysis of imidazoles 14 in diphenyl ether affords 2

101 Thermolysis of isonitriles with carboxylic acids provide

102 Chemically inert F2PhEtyCbl resisted thermolysis of its Co-C bond at 100 degrees C, was stabl

103 elimination of methane occurs upon solution thermolysis of kappa(3)-Tp(Me)2Pt(IV)(CH(3))(2)H (1, Tp(

104 Mild thermolysis of Lewis base stabilized phosphinoborane mon

105 yrolysis" (FFP) technique was applied to the thermolysis of Meldrum's acid derivatives, pyrrole-2,3-d

106 on polyethylene processing temperatures, the thermolysis of Meldrum's acid to ketene provides the des

107 nitrido complexes have been prepared via the thermolysis of metastable vanadium(III)-azido precursors

108 This is the result of the very fast thermolysis of MPAN at high temperatures that affects th

109 Furthermore, thermolysis of N-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)

110 d core was formed stereoselectivity from the thermolysis of N-[(2-methyl-2-cyclopentenyl)methyl]-N-(4

111 Extended thermolysis of neutral [Ph(2)BP(2)]Pt(Ph)(THF) (16) resu

112 absence of metals have been achieved by the thermolysis of nonconjugated 2-azetidinone-tethered bis(

113 old NP core (PS-AuCoNPs) were synthesized by thermolysis of octacarbonyldicobalt [Co(2)(CO)(8)] in th

114 esis of non-PGM ORR electrocatalysts through thermolysis of one-pot synthesized ZIF is demonstrated.

115 es include organic solution-phase synthesis, thermolysis of organometallic precursors, sol-gel proces

116 In contrast to the thermolysis of p-benzoquinone, which does not decompose

117 thermodynamic activation parameters for the thermolysis of P2A2 in a solution containing different a

118 in approximately 50% yield by the short-time thermolysis of Pd10(CO)12{P(p-Tolyl)3}6 in THF solution

119 re exposed to hydroxyl radicals generated by thermolysis of persulfate under basic pH conditions and

120 Thermolysis of phosphorus-based vinyl azides under solve

121 ed nine exposure units of smoke generated by thermolysis of pine woodchips (80 g).

122 The thermolysis of polyfused cyclobutanes with a cis,syn,cis

123 Thermolysis of RPA benzene-d(6) solutions leads to anthr

124 ents and thermal gravimetric analysis of the thermolysis of Ru(2)(D(3,5-Cl(2))PhF)(4)N(3), and by Arr

125 s absorb light, get heated, and induce focal thermolysis of sebaceous glands.

126 olecular beam mass spectrometry study on the thermolysis of solid P2A2 reveals the direct detection o

127 Thermolysis of spiro[2.4]hepta-1,4,6-triene (1a) at 50 d

128 The pyrazino derivative 1c was formed upon thermolysis of sulfoxide 14c obtained from 2c.

129 Mild flash vacuum thermolysis of tetrazolo[1,5-b]pyridazines 8T generates

130 Thermolysis of the arylpalladium cyanoalkyl complexes le

131 Thermolysis of the complex results in N-O bond homolysis

132 Thermolysis of the crude peroxoniobium compounds (72-96

133 Controlled thermolysis of the deposited alkoxide gives the metal a

134 Thermolysis of the enyne-carbodiimide 42 having a methox

135 edirect the reaction toward 32 by conducting thermolysis of the enyne-carbodiimide 7e in the presence

136 Thermolysis of the enyne-carbodiimides 7 having the cent

137 Thermolysis of the heterobimetallic phosphinidene comple

138 ehyde, which is easily generated as a gas by thermolysis of the inexpensive and abundant paraformalde

139 Thermolysis of the iron(IV) nitride complex [PhB(tBuIm)3

140 Thermolysis of the latter mixture afforded ((t)Bu3SiNH)(

141 While thermolysis of the macrobicyclic triene lactone 12 did n

142 Thermolysis of the methyl and hydride derivatives, ((tBu

143 Thermolysis of the methyl-borylamide (NacNac(NMe2))Sc(Me

144 Thermolysis of the Pd chelates results in beta-acetate e

145 Mass spectrometry and solid state thermolysis of the precursors generated common fragments

146 Thermolysis of the pyrazolo[3,4-e][1,2,4]dithiazines 7 g

147 ido[4',3':4,5]pyrrolo[2,3-b]quinolines 8 via thermolysis of the pyridannulated enyne-carbodiimides 14

148 Thermolysis of the Rh(III)-Me complex (DPEphos)RhMeI2 (1

149 Thermolysis of the ring-opened product ICF(2)CF(2)CFIOR(

150 Thermolysis of the silver complexes in the presence of C

151 Thermolysis of the terminal azido Ru(2)(D(3,5-Cl(2))PhF)

152 Thermolysis of the titanocene TEMPO complexes in the pre

153 d 8-MeOAdo(*) radicals are generated by Co-C thermolysis of their respective precursors, AdoCbl and 8

154 Flash vacuum thermolysis of these adducts leads to various isotopic i

155 Thermolysis of these complexes in the presence of PPh(3)

156 Thermolysis of these furans resulted in an intramolecula

157 Thermolysis of these furans resulted in an intramolecula

158 Thermolysis of this complex at 80 degrees C resulted in

159 Thermolysis of this complex promotes extrusion of azoben

160 Product studies upon thermolysis of this precursor give the same products as

161 Ammonia (NH(3)) is produced in situ from thermolysis of urea and hydrolysis of isocyanic acid (HN

162 Thermolysis of {[PhBP(CH(2))(Cy)(3)]Fe}(2)(mu-eta(1):eta

163 photolysis and two possible pathways for the thermolysis, one involving proton transfer from the OOH

164 ylamine derivatives in aromatic solvents via thermolysis or acid-catalyzed decomposition may not be c

165 The Boc group can be removed on thermolysis or left intact during subsequent transformat

166 (mu2 -CH2 )] (2) can be cleanly prepared via thermolysis or photolysis of [(Ar'O)2 Nb(CH3 )2 Cl] (1)

167 These ozonides lose O(2) through thermolysis or photolysis to form various isomers of C(7

168 es (N-ethoxycarbonyl)carbamoyl chloride upon thermolysis, or (N-ethoxycarbonyl)isocyanate upon treatm

169 Slow, protracted thermolysis produces a fractionation line of shallower s

170 The thermolysis product readily reverts to active catalysts

171 The thermolysis products obtained by refluxing a series of v

172 the 26-mer), but a significant abundance of thermolysis products were also observed.

173 s and strong vertical mixing the slower MPAN thermolysis rate aloft could increase the fraction of MP

174 THF inhibits the rate of the thermolysis reaction in all three cases.

175 l ether from 2,2-dimethoxypropane during the thermolysis reaction.

176 s carbon nitride networks formed by triazine thermolysis reactions.

177 ement of the thiophene ylide, in contrast to thermolysis results.

178 r [2 + 2] photocyclization is present in the thermolysis step, however, the result of a formally "sym

179 The microwave-assisted thermolysis strategy is simple, rapid, and robust, there

180 nd indicate the utility of gas-phase NMR for thermolysis studies of a variety of materials that relea

181 In their denuded state produced by gentle thermolysis, the cluster carbonylates yield nanoparticle

182 Upon thermolysis, these compounds give YbSe(x)().

183 itive C-N and C-C reductive elimination upon thermolysis to form N-methylsulfonamides and ethane, res

184 Because thermolysis to form seven stable products proceeds stepw

185 er, by using multiphoton infrared photolysis/thermolysis to initiate decarbonylation, it was shown th

186 S5 nanosheets that are formed by solventless thermolysis, utilizing Cu alkanethiolates as single-sour

187 rathiomolybdate ((NH4)2MoS4), and subsequent thermolysis was used to produce large area MoS2 layers.

188 that the polymer decomposes to monomer upon thermolysis, which indicates that the polymerization-dep

189 f diatomic oxygen to IPU and is subjected to thermolysis whose rate depends on temperature, pH, the p

190 The a,b-C(70)O(3) isomer dissociates through thermolysis with a decay time of 14 min at 296 K to form